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CALCIUM STEARATE

SYNONYMS: Stéarate de calcium; kalsiyum distearat; kalsiyum oktadekanoat; kalsiyum stearate; aluminum monostearate; aluminum tristearate; ammonium stearate; Octadecanoic acid, calcium salt; Calcium bis(stearate)

Calcium stearate is a carboxylate of calcium, classified as a calcium soap. It is a component of some lubricants, surfactants, as well as many foodstuffs. It is a white waxy powder.

 

SYNONYMS:
Stéarate de calcium; Stearate de calcium; kalsiyum stearat; calcium stearate; kalsiyumstearat; calciumstearate; kalsiyum sterat; calcium stearat; calcium ctearat; Kalsiyum Stearat; Calcium Stearate; Kalsiyumstearat; Calciumstearate; Kalsiyum Sterat; Calcium Stearat; Calcium Ctearat; KALSİYUM STEARAT; CALCIUM STEARATE; KALSİYUMSTEARATE; KALSİYUM STERAT; CALCIUM STEARAT; CALCIUM CTEARAT; KALSIYUM STEARAT; kalsiyum distearat; calciumstearate; kalsiyum oktadekanoat; kalsiyum stearate; kalsiyumstearate; aluminum monostearate; aluminum tristearate; ammonium stearate; calcium stearate; magnesium stearate; octadecanoic acid; sodium stearate; stearic acid; zinc stearate; CALCIUM STEARATE; 1592-23-0; Calcium octadecanoate; Calcium distearate; Octadecanoic acid, calcium salt; Calcium bis(stearate); Calcium distearate, pure; Stearic acid, calcium salt; Stéarate de calcium;  CalciumStearatePowder; Stearic acid calcium; CALCIUMSTEARATE; calcium dioctadecanoate; Hydrogenated tallow fatty acids calcium salts; Hydrogenated tallow fatty acids, calcium salt; Octadecanoic acid, calcium salt (2:1); Fatty acids, tallow, hydrogenated, calcium salt; Fatty acids, tallow,hydrogenated, calcium salts; Tallow fatty acids, hydrogenated, calcium salt, Fatty acids, tallow, hydrogenated, calcium salts; CALCIUM STEARATE; Calcium octadecanoate; Flexichem; alcium distearate; Octadecanoic acid, calcium salt; Aquacal; Calstar; Flexichem CS; Stavinor 30; Stearates; Calcium bis(stearate); Nopcote C 104; Witco G 339S; Stearic acid, calcium salt; Calcium distearate, pure; calcium dioctadecanoate; Calcium stearate [JAN]; CalciumStearatePowder; Stearic acid calcium; CALCIUMSTEARATE; Calcium Stearate NF/FCC; Hydrogenated tallow fatty acids calcium salts; Calcium stearate (JP17/NF); Calcium Stearate (technical grade); CALCIUM ; Fatty acids, tallow,hydrogenated, calcium salts; Pralmorelin Glyceryl monostearate Stearic acid CALCIUM Calcium nitrite Calcium stearate Barium stearate DL-α-Tocopherol CALCIUM PALMITATE CALCIUM; BUTYRATE CALCIUM; LAURATE CALCIUM CAPRYLATE; MONOHYDRATE ; calcium diiodostearate; POTASSIUM IODIDE WITH CA STEARATE; Calcium formate; Calcium hydroxide; Calcium acetate; Calcium carbonate; STEARIC ACID CALCIUM; SALTOCTADECANOIC ACID; CALCIUM SALTCALCIUM OCTADECANOATECALCIUM STEARATE; aquacal calciumdistearate calstar dibasiccalciumstearate flexichem flexichemcs g339s nopcotec104 stavinor30 stearatedecalcium witcog339/s witcog339s calcium distearate, pureCalcium Stearate (Light)CalciumstearateminCalciumstearatetechCalciuM Stearate, 95.0%(T)Calcium stearate 6.6-7.4% Ca basisCalcium stearate Vetec(TM) reagent gradeACRYL/BIS (37,5:1)Calcium stearate, 6.4 to 7.4% (Ca)calaiumstrarateCALCIUM STEARATSTEARIC ACID CALCIUM SALT 9.0-10.5%Calcium Stearate NFCalciumSulphate(Dihydrate)Gr(PrecipitatedPowd)CalciumStearatePureCALCIUM STEARATE (CEASIT)CALCIUM STEARATE, PHARMACalcium stearinateCalciumstearate, min.85% CALCIUMSTEARATE,FCCCalciumdistearatCalcium stearate dispersion liquidBis(octadecanoic acid)calcium saltBis(stearic acid)calcium saltBisstearic acid calcium saltDistearic acid calciumCalcium stearate, extra pure, Ph Eur, BP, NF, FCC, E 470Calcium Stearate (2 g) (AS)CalciuM Stearate (AS)CalciuM stearate NF/FCCCalcii stearasDeasit PCHyQualKemistab EC-F1592-23-0CaC17H35COO2CH3CH216COO2CaC18H36O212CaCH3CH216C00CaCaC36H70O4CaCH3CH216CO22C36H70O4Ca; Stéarate de calcium; CALCİUM STEARATE; CALCIUM STEARATE; Stearate de calcium; Stéarate de calcium

Calcium stearate

Calcium stearate
Stearic Acid Calcium Salt Structural Formula V.2.svg
Names
IUPAC name
Calcium octadecanoate
Other names
E470
Identifiers
CAS Number    
1592-23-0 ☑
3D model (JSmol)    
Interactive image
ChEMBL    
ChEMBL2106092 ☒
ChemSpider    
14587 ☑
ECHA InfoCard    100.014.976 Edit this at Wikidata
PubChem CID    
15324
UNII    
776XM7047L ☑
CompTox Dashboard (EPA)    
DTXSID7027419 Edit this at Wikidata
InChI[show]
SMILES[show]
Properties
Chemical formula    C36H70CaO4
Molar mass    607.030 g·mol−1
Appearance    white to yellowish-white powder
Density    1.08 g/cm3
Melting point    155 °C (311 °F; 428 K)
Solubility in water    0.004 g/100 mL (15 °C)
Solubility    soluble in hot pyridine
slightly soluble in oil
insoluble in alcohol, ether
Hazards
NFPA 704 (fire diamond)    
NFPA 704 four-colored diamond
120
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Calcium stearate is a carboxylate of calcium, classified as a calcium soap. It is a component of some lubricants, surfactants, as well as many foodstuffs. It is a white waxy powder.[1]

Production and occurrence
Calcium stearate is produced by heating stearic acid and calcium oxide:

2 C17H35COOH + CaO → (C17H35COO)2Ca + H2O
It is also the main component of soap scum, a white solid that forms when soap is mixed with hard water. Unlike soaps containing sodium and potassium, calcium stearate is insoluble in water and does not lather well.[2] Commercially it is sold as a 50% dispersion in water or as a spray dried powder. As a food additive it is known by the generic E number E470.

Applications
Calcium stearate is a waxy material with low solubility in water, unlike traditional sodium and potassium soaps. It is also easy and cheap to produce, and exhibits low toxicity. These attributes are the basis of many of its applications. Related applications exist for the magnesium stearate.[1]

Calcium stearate is used as a flow agent and surface conditioner in some candies such as Smarties, jawbreakers and Sprees.
It is a waterproofing agent for fabrics.
A lubricant in pencils and crayons.
The concrete industry uses calcium stearate for efflorescence control of cementitious products used in the production of concrete masonry units i.e. paver and block, as well as waterproofing.[3]
In paper production, calcium stearate is used as a lubricant to provide good gloss, preventing dusting and fold cracking in paper and paperboard making.[4]
In plastics, it can act as an acid scavenger or neutralizer at concentrations up to 1000ppm, a lubricant and a release agent. It may be used in plastic colorant concentrates to improve pigment wetting. In rigid PVC, it can accelerate fusion, improve flow, and reduce die swell.
Applications in the personal care and pharmaceutical industry include tablet mold release, anti-tack agent, and gelling agent.
Calcium stearate is a component in some types of defoamers.
Anticaking agent.[5]

Computed Properties    HelpNew Window
Property Name    Property Value    Reference
Molecular Weight of Calcium stearate:    607 g/mol    Computed by PubChem 2.1 (PubChem release 2019.06.18)
Hydrogen Bond Donor Count of Calcium stearate:    0    Computed by Cactvs 3.4.6.11 (PubChem release 2019.06.18)
Hydrogen Bond Acceptor Count of Calcium stearate:    4    Computed by Cactvs 3.4.6.11 (PubChem release 2019.06.18)
Rotatable Bond Count of Calcium stearate:    30    Computed by Cactvs 3.4.6.11 (PubChem release 2019.06.18)
Exact Mass of Calcium stearate:    606.490002 g/mol    Computed by PubChem 2.1 (PubChem release 2019.06.18)
Monoisotopic Mass of Calcium stearate:    606.490002 g/mol    Computed by PubChem 2.1 (PubChem release 2019.06.18)
Topological Polar Surface Area of Calcium stearate:    80.3 Ų    Computed by Cactvs 3.4.6.11 (PubChem release 2019.06.18)
Heavy Atom Count of Calcium stearate:    41    Computed by PubChem
Formal Charge of Calcium stearate:    0    Computed by PubChem
Complexity of Calcium stearate:    196    Computed by Cactvs 3.4.6.11 (PubChem release 2019.06.18)
Isotope Atom Count of Calcium stearate:    0    Computed by PubChem
Defined Atom Stereocenter Count     of Calcium stearate:0    Computed by PubChem
Undefined Atom Stereocenter Count of Calcium stearate:    0    Computed by PubChem
Defined Bond Stereocenter Count of Calcium stearate:    0    Computed by PubChem
Undefined Bond Stereocenter Count of Calcium stearate:    0    Computed by PubChem
Covalently-Bonded Unit Count of Calcium stearate:    3    Computed by PubChem
Compound Is Canonicalized of Calcium stearate:    Yes    Computed by PubChem (release 2019.01.04)

Physical Description    HelpNew Window
DryPowder; DryPowder, Liquid; DryPowder, PelletsLargeCrystals; DryPowder, PelletsLargeCrystals, OtherSolid; Liquid; OtherSolid; OtherSolid, Liquid; PelletsLargeCrystals; PelletsLargeCrystals, Liquid; WetSolid

EPA Chemicals under the TSCA

CA – 30  is a neutral Calcium Soap and most powerful mould release agent for polyolefin. It has  hydrophobic effect. It used as an internal lubricant. It is very compatible for polyolefin and plastic application

PROPERTIES
Chemical characteristics    :  Calcium soap

Appearance                       :   Fine, white powder

Melting point                    :   155 ºC± 5

Calcium content                :   7.2 % ± 0,5

Ash content (CaO)            :   10.3 % ± 0,5

Iodine Value                     :  below 0.5 %

Moisture                            :  1 Max.

pH                                     :  7.3 ± 0.2

Screen Test (200 Mesh)    :  99 % passing

Free fatty acid                   :   below 0.5 %

Bulk Density                     :  0.280 g/cm³

Storage Stability               :   2 years under cool and dry storage conditions in orginally packing


Introduction

Calcium stearate is an anticaking agent used in a wide variety of foods including salt, spices, confections, snack products and dry mixes. The VRG noticed while doing a Spring 2015 update on stearic acid and its derivatives that several websites and books list calcium stearate as being primarily derived from cows or pigs. When we discovered from food ingredient manufacturers and suppliers that most calcium stearate used today in food products is from vegetable oils, we decided to check food labels and contact food companies to confirm if the calcium stearate present today in foods was indeed mostly or even solely vegetable-derived.

To accomplish this, we made extensive use of the Internet for locating edible products containing calcium stearate. Google® images of nutrition and supplement labels listed thousands of mostly pharmaceutical products. We went through the pages excluding supplements and any foods containing meat and/or dairy.

An immediate observation we made while searching for calcium stearate-containing foods was that very few products today contain calcium stearate unlike twenty years ago when it was more common. There are many substitute ingredients available today to take its place in foods such as silicon dioxide. (Calcium stearate, magnesium stearate as well as stearic acid are more commonly included today in dietary supplements and pharmaceuticals serving as binders or lubricants. Recent VRG research on the latter two ingredients also shows that for food and drug uses today, magnesium stearate and stearic acid are vegetable-derived in all cases we could find.)

Here is a list of food products containing calcium stearate.

Calcium stearate Properties
Melting point of Calcium stearate:147-149°C
Density of Calcium stearate: 1.08g/cm3
storage temp. of Calcium stearate: Store at +5°C to +30°C.
solubility of Calcium stearate: Soluble in hot pyridine, slightly soluble in oil, but insoluble in alcohol and ether.
form of Calcium stearate: Powder
color of Calcium stearate: white
Odor of Calcium stearate:Fatty acid odor
PH of Calcium stearate:7-9 (2.2 mg/l, H2O, 20°C)
Water Solubility of Calcium stearate: insoluble H2O, ether, chloroform; slightly soluble hot mineral oils

About Calcium Stearate
Calcium Stearate is one of numerous organo-metallic compounds sold by American Elements under the trade name for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Calcium Stearate is generally immediately available in most volumes, including bulk quantities. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional technical and safety (MSDS) data

Description of calcium stearate:
Calcium stearate

stearic acid

calcium soap

calcium distearate

Description of Calcium Stearate:

Calcium stearate is made by the international advanced dry manufacturing technique (high speed direct dispersion neutralization titration), applying to the manufacture of various kinds of pe, pp, pnc, abs resin. Calcium stearate achieves the requirement of high purity additive pe spinning, eliminates negative impact on the residual catalyst to color and resin stability, improves index and fluidity of yellow resin. Melt index, heat stability, filtration set the tone in the domestic market. Calcium stearate can be used as lubricant in polyolefin, lubricating grease thickening agent, water checking agent of textile, paint dullness agent etc and it is fit to introduce equipment and can substitute similar imported additives.


characters:

Calcium stearate is white, fine powder, insoluble in water. When mixed with hot strong mineral acids, they break down into stearic acid and the corresponding calcium salts.

Uses of Calcium Stearate:

They are widely used as lubricants, slip agents, thermal stabilizers, mold release agents and plastic accelerators, engineering machinery, rubber, paints and inks industry etc.

It is the stabilizer and lubricant for pvc, which enjoy more thermal stabilization effect and good long-term stability. It can be used as non-toxic food packaging, medical equipment and other flexible plastic containers. Aslo as halogen absorber in polyethylene and polypropylene, eliminates the harmful effect of residual catalyst in the resin on the color and stability of the resin. This product is also widely used as a lubricant of polylefin fibers and molded products, as a sealant of waterproof rain materials, and it is available as a lubricant and mold release agent for phendic, amino and other thermosetting plastics and polyester reinforced with plastic. And it is also used as thicknening grease agent, textile sealant and painted plain agent.

storage of calcium stearate:

Calcium stearate should be placed in a cool, dry and well ventilated shade, moisture resistant, anti-high erasure, not keep distance with acid or alkali.

applications:

A . Widely used as heat stabilizer for pvc. The rate of gelation can be increased with the base of lead salt and lead soap.

2. Calcium stearate Used as pp and pe halogen absorber eliminates negative impact on the residual catalyst to color and resin stability, improves the index and fluidity of yellow resin.

3. Polyolefin fiber and moldedwork lubricant.

4. Mold release agent, plasticizer, lubricant grease thickening agent, textile water checking agent, paint dullness etc agent for rubber processing.

5. Calcium stearate can also be used for food additives, roughage and cosmetic additives etc.
CAS No .: 1592-23-0 Calcium stearate Calcium distearate Stearic acid Calcium soap.

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