PRODUCTS

EXOLIT AP 422

EXOLIT AP 422 = E452

CAS Number: 68333-79-9
EC Number： 269-789-9
Chemical formula: [NH4PO3]n(OH)2

Exolit AP 422 is fine-particle ammonium polyphosphate.
Exolit AP 422 is a colorless, non-hygroscopic, non-flammable, fine particle ammonium polyphosphate (phase II).
Exolit AP 422 acts as a flame retardant used as an acid donor due to its low water solubility.
Exolit AP 422 exhibits very low acid number.
Imparts lower viscosity in aqueous suspensions and in PU polyol suspension.

Recommended dosage level is 15-20% to achieve DIN EN 13501-1 classification with chipboard products.
Exolit AP 422 is colorless, non-hygroscopic, and non-flammable.
Exolit AP 422 is largely insoluble in water and completely insoluble in organic solvents.
When incorporated into the base formulation at the rate of 10-20%, Exolit AP 422 imparts a good flame-retardant effect to adhesives and sealants.

Exolit AP 422 has a shelf life of 12 months.
Exolit AP 422 is a fine-particle ammonium polyphosphate (phase II) produced by a special method.
Exolit AP 422 is largely insoluble in water and completely insoluble in organic solvents.
Exolit AP 422 is colorless, non-hygroscopic and non-flammable.

The Exolit AP products are phosphorus-based flame retardants for polyurethanes that allow meeting stringent emission and migration requirements, because they are inorganic solids with low vapor pressure and solubility.
Furthermore stringent fire safety standards such as the FMVSS 302 (SE), EN 13501-1 (E) or DIN 4102 (B2) can be passed.
They are based on high molecular weight ammonium polyphosphate (phase II).
Because of lower solubility in water, catalyst interaction is reduced.

Exolit AP 422 is a fine-particle ammonium polyphosphate produced by a special method.
Exolit AP 422 is large lyinsoluble in water and completely insoluble in organic solvents.
Exolit AP 422 is colourless, non-hygroscopic and non-flammable.
Exolit AP 422 differs from most other commercial products in the following ways: - greatly reduced solubility in water - lower viscosity in aqueous suspensions - lower viscosity in PU polyol suspensions - very low acid number.

Exolit AP Sophisticated chemistry in a simple formula Ammonium polyphosphate - a polymeric flame retardant material - is the basis for the Exolit AP product family, which, as a result of modification and synergist mixtures, covers a very broad application spectrum.
Exolit AP 422 is an inorganic salt of polyphosphoric acid and ammonia containing both chains and possibly branching.
Exolit AP 422's chemical formula is [NH4 PO3]n(OH)2 showing that each monomer consists of an orthophosphate radical of a phosphorus atom with three oxygens and one negative charge neutralized by an ammonium cation leaving two bonds free to polymerize.

In the branched cases some monomers are missing the ammonium anion and instead link to three other monomers.
The properties of Exolit AP 422 depend on the number of monomers in each molecule and to a degree on how often it branches.
Shorter chains (n<100) are more water sensitive and less thermally stable than longer chains (n>1000), but short polymer chains (e.g. pyro-, tripoly-, and tetrapoly-) are more soluble and show increasing solubility with increasing chain length.

Exolit AP 422 can be prepared by reacting concentrated phosphoric acid with ammonia.
However, iron and aluminum impurities, soluble in concentrated phosphoric acid, form gelatinous precipitates or "sludges" in ammonium polyphosphate at pH between 5 and 7.
Other metal impurities such as copper, chromium, magnesium, and zinc form granular precipitates.
However, depending on the degree of polymerization, ammonium polyphosphate can act as a chelating agent to keep certain metal ions dissolved in solution.

Flame Retardant Exolit AP 422 Fine-grained white APP (phase II) powder with low water solubility Exolit AP 422 is a fine-grained ammonium polyphosphate (phase II) produced by a special method.
Exolit AP 422 is largely insoluble in water and completely insoluble in organic solvents.
Exolit AP 422 is Colorless, non-hygroscopic, non-flammable.
The mechanism of action of flame retardants is complex and not yet very clear.

It is generally believed that the halogen compound undergoes a decomposition reaction when exposed to fire and heat, and the decomposed halogen ion reacts with the polymer compound to generate hydrogen halide.
The latter reacts with a large number of active hydroxyl radicals (HO·) that proliferate during the combustion of the polymer compound, reducing its concentration and slowing down the combustion speed until the flame is extinguished.
Among the halogens, the flame retardant effect of bromine is greater than that of chlorine.

The function of phosphorus-containing flame retardants is that they form metaphosphoric acid when they burn, and metaphosphoric acid polymerizes into a very stable multimeric state, which becomes a protective layer of plastic and isolates oxygen.
Flame retardants exert their flame retardant effect through several mechanisms, such as endothermic effect, covering effect, inhibition of chain reaction, suffocation effect of non-combustible gas, etc.

Most flame retardants work together to achieve the purpose of flame retardant through several mechanisms.
Non-halogenated flame retardants with good environmental and health profile.
Substantially reduced water solubility, low viscosity in aqueous suspensions, very low acid value.
(Bio-) Degrades by breaking down into naturally occurring phosphates and ammonia safety.

Exolit AP 422 is a low viscosity, biodegradable fine particle ammonium polyphosphate.
Exolit AP 422 contains aliphatic amines as hardeners.
Exolit AP 422 is halogen-free and non-hygroscopic.
Exolit AP 422 exhibits reduced solubility in water, extremely low acid value and high thermal stability.
The shelf life of Exolit AP 422 is 12 months.

USES and APPLICATIONS of EXOLIT AP 422:
-Applications:
Coatings; Waterbase Coatings, Electrical markets, Foams, Halogen-free flame retardant
-Exolit AP 422 's mainly application is intumescent coating, polymer and textile
-Exolit AP 422 designed for intumescent coatings on wood or plastics.

-Exolit AP 422 is used Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, DIN, BS, ASTM and others.
-Exolit AP 422's application on wood or plastics enables these materials to qualify for Building Material Class B (DIN EN 13501-1).
-Polyurethane foams with Exolit AP 422 can be recycled.

-Exolit AP 422 acts as a flame retardant.
Fine-grained white APP powder with low water solubility
-Exolit AP 422 non-halogenated flame retardants are safer and more sustainable alternatives to volatile and scrutinized flame retardants such as halogenated and non-halogenated phosphate esters (e. g. TCPP1).

-Exolit AP 422 can be used on their own in synergistic combinations.
-Thanks to microencapsulation, Exolit AP 462 is even less susceptible to reaction with amine catalysts, and easily dispersible in typical polyester polyols.

-Lower fogging and VOC values can be achieved which meet stringent emission standards for PUR flexible foams in the automotive industry.
PUR producers are facing demanding regulations regarding the emission of volatile organic compounds (VOC)2.
With respect to this need, Exolit AP 422 is an excellent choice.
Being non-hazardous, inorganic substances, Exolit AP 422 pose no additional risk to health and environment, and do not contribute to harmful VOC emissions.

-Exolit AP 422 was the pioneer in non-halogenated flame retardants that could withstand the demanding requirements of different high end segments for plastics.
-Rigid PUR and PIR for insulation containing Exolit AP can pass DIN 4102 (B2) or EN 13501-1 (E).
-Flexible PUR for automotive slabstock can pass FMVSS 302 (SE).

-Exolit AP 422 shows a favorable environmental and health profile compared to TCPP with negligible plasticizing effect, reduced influence on mechanical properties and higher system-stability compared to other APP grades.
-Intumescent coatings:
On account of its low water solubility, Exolit AP 422 is particularly suitable as an “acid donor” for intumescent coatings.
Other essential components of intumescent systems include a binder, a carbon donor (eg pentaerythritol) and a blowing agent (egmelamine).

-On exposure to flame, intumescent coatings form a carbonaceous foam which effectively shields the underlying material from temperature increases.
-Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, DIN, BS, ASTM and others.
-The application of Exolit AP 422 based intumescent coatings on wood or plastics enables these materials to qualify for Building Material Class B (DIN EN 13501-1).
-Exolit AP 422 imparts a good flame-retardant effect to adhesives and sealants when Exolit AP 422 is incorporated into the base formulation at the rate of 10 - 20 %.

Because of the low acid number of Exolit AP 422, Exolit AP 422 is also possible to incorporate this flame retardant in an Exolit AP 422/isocyanate suspension.
To prevent the solids from settling, the Exolit AP 422 suspensions should be stirred or circulated by pump.
The stirrers commonly found in service tanks are adequate for this purpose.

-Other applications:
Exolit AP 422 has an excellent flame-retardant effect in cellulose-containing materials such as paper and wood products.
With chipboard products, the DIN EN 13501-1 classification can be achieved by adding 15 - 20 % Exolit AP 422.
-Because of its high heat stability, Exolit AP 422 is an essential component in intumescent formulations for thermoplastics, particularly polypropylene, for which the classification UL 94-V0 is specified for applications in the electrical sector.

-Casting resins based on epoxy resins or unsaturated polyester resins achieve the classification UL 94-V0 with Exolit AP 422
-Permitted for use as an inert ingredient in non-food pesticide products
-Exolit AP 422 is used as a fertilizer
-Exolit AP 422 is usedin the chemical, paints-lacquers-varnishes, paper-pulp-board, and polymers industries
-Exolit AP 422 is used as a construction-material additive and flame retardant

-Exolit AP 422 is used as a sequestrant and emulsifier for foods;
-Exolit AP 422 and Exolit AP 462 are high-quality additives for intumescent coatings.
Even at layer thicknesses of less than 1 mm they achieve fire resistance times of over 30 minutes.
-Apart from the protection of steel structures in buildings, application areas include cable and wood.
In addition, the fire properties of textiles and papers can be improved with intumescent coatings based on Exolit AP.

-In the case of thermosets like epoxy resins and unsaturated polyester resins, Exolit AP 422 paves the way for the production of lightweight components with low solids content.
In polyurethane rigid foams that are used e.g. for insulation purposes by the building industry, low smoke density in a fire and avoiding flame retardant migration are important criteria.
PUR Foams with Exolit AP 422 can also be recycled.

-Exolit AP 422 is combined with synergists, ammonium polyphosphate becomes highly effective in polyolefins (polypropylene and polyethylene).
-Exolit AP 422 is also used as a flame retardant in many applications such as paints and coatings, and in a variety of polymers: the most important ones are polyolefins, and particularly polypropylene, where Exolit AP 422 is part of intumescent systems.
-Compounding with Exolit AP 422-based flame retardants in polypropylene is described in.

-Further applications are thermosets, where Exolit AP 422 is used in unsaturated polyesters and gel coats (Exolit AP 422 blends with synergists), epoxies and polyurethane castings (intumescent systems).
-Exolit AP 422 is also applied to flame retard polyurethane foams.

-Exolit AP 422 as used as flame retardants in polymers have long chains and a specific crystallinity (Form II).
They start to decompose at 240 °C to form ammonia and phosphoric acid.
The phosphoric acid acts as an acid catalyst in the dehydration of carbon-based poly-alcohols, such as cellulose in wood.
The phosphoric acid reacts with alcohol groups to form heat-unstable phosphate esters.
The esters decompose to release carbon dioxide and regenerate the phosphoric acid catalyst.
In the gas phase, the release of non-flammable carbon dioxide helps to dilute the oxygen of the air and flammable decomposition products of the material that is burning.
In the condensed phase, the resultant carbonaceous char helps to shield the underlying polymer from attack by oxygen and radiant heat.

-Exolit AP 422 is used as an intumescent is achieved when combined with starch-based materials such as pentaerythritol and melamine as expanding agents.
The mechanisms of intumescence and the mode of action of Exolit AP 422 are described in a series of publications.
-Exolit AP 422 is used Tissue improver; emulsifier; stabilizer; chelating agent; yeast food; curing aid; water binding agent. Used for cheese, etc.
-Particularly suitable as "acid donors".
Due to Exolit AP 422's low water solubility, Exolit AP 422 can be used in intumescent coatings.

-Steel structures coated with intumescent coatings can meet the fire resistance class requirements specified by EN, DIN, BS, ASTM, etc.
-Their application on wood or plastic makes these materials comply with the requirements of Build Material Class B (DIN EN 13501-1)
-When the adhesive and sealant are incorporated into the base formulation at a ratio of 10-20%, it imparts good flame retardant effect <p>Non-halogenated flame retardant suitable for polyurethane foam.
PUR Foams with Exolit AP 422 can be recycled.

-Excellent flame retardancy in cellulose-containing materials such as paper and wood products. With particleboard products, DIN EN 13501-1 classification can be achieved by adding 15 - 20% Exolit AP 422
-An important component in intumescent formulations of thermoplastics, especially polypropylene, UL 94-V0 classification for electrical applications.

-In the case of thermosets, epoxy resins and unsaturated polyester solid resins, it paves the way for the production of lightweight components with low solids content
-Exolit AP 422 is used as a flame retardant in recyclable polyurethane foam and electrical applications (UL 94 V-0).
-Exolit AP 422 is used Compatible with PU polyols, PP, epoxy and unsaturated polyester resins.
-Exolit AP 422 is Suitable for laminate processing.

-Exolit A422 is White fine powder, low water solubility, suitable for thin and ultra-thin steel structure and cable fire retardant coatings, epoxy resin-based and unsaturated resin-based glass fiber reinforced plastic composite materials, electrical and electronic adhesives for high-speed rail, carriage and other transportation vehicles Adhesive, molding compound, potting compound, EVA, PE, PP, PU and many other uses.

-Exolit AP 422 and Exolit AP 462 meet the fire regulations covering epoxy resin laminates for rolling stock.
By using Exolit RP 650 the high levels of ATH* filler in electrocasting resin systems necessary for reaching UL 94: V-0 classification can be substantially reduced.
-Exolit AP 422 has a favorable environmental and health profile, and is both halogen-free and bio-degradable.

-Exolit AP 422 is used as a flame retardant and as a fertilizer.
The chain length (n) of Exolit AP 422 is variable and can be linear or branched.
Exolit AP 422 has a role as a flame retardant, a fertilizer and a food emulsifier.
Exolit AP 422 contains a polyphosphate.

-The flame retardant Exolit AP 422, an ammonium polyphosphate, can be used to confer flame-retardant properties to polyolefin compounds.
-At the same time Exolit AP 422 is an efficient flame retardant that maintains the physical properties of WPC compounds and is easy to process.
-Exolit AP 422 leads to increased char formation, functioning as a protective layer, assisted by intumescence or swelling/foaming of the thermoplastic material on exposure to flame.
This effect can lead fire to be self-extinguishing.

-For construction applications, the performance of wood-filled polypropylene (70% wood / 30% PP) in the German Fire Test DIN 4102 B2 shows positive indication for effective fire protection using Exolit AP 422 treated compounds
-Intumescent coatings:
On account of its low water solubility, Exolit AP 422 is particularly suitable as an ”acid donor” for intumescent coatings.
-Other essential components of intumescent systems include a binder, a carbon donor (e.g. pentaerythritol) and a blowing agent (e.g. melamine).

-Exolit AP 422 imparts a good flame-retardant effect to adhesives and sealants when Exolit AP 422 is incorporated into the base formulation at the rate of 10 - 20 %.
-Exolit AP 422 has an excellent flame-retardant effect in cellulose-containing materials such as paper and wood products.
With chipboard products, the DIN EN 13501-1 classification can be achieved by adding 15 - 20 % Exolit AP 422.

-Because of its high heat stability, Exolit AP 422 is an essential component in intumescent formulations for thermoplastics, particularly polypropylene, for which the classification UL 94-V0 is specified for applications in the electrical sector.
-Casting resins and composites based on epoxy resins or unsaturated polyester resins achieve the classification UL 94-V0 with Exolit AP 422. Combinations of AP 422 with ATH show synergistic effects in UL94 and LOI tests.
-To prevent the solids from settling, the Exolit AP 422 suspensions should be stirred or circulated by pump.

-The stirrers commonly found in service tanks are adequate for this
purpose.
-Exolit AP 422 can be used in intumescent coatings, adhesive and sealants.
Polyurethane foam, PU rigid, PU rigid integral skin foam, PU flexible.
-It can be used in cellulose-containing material (paper, wood).
Meanwhile, this grade can also be used in casting resin based on epoxy resin, unsaturated PE resin, thermoplastics Plastic etc.

-Polyurethane foams:
Exolit AP 422 is a suitable non-halogenated flame retardant for polyurethane foams.
If handling of Exolit AP 422 as a solid is not possible we recommend the dosage of the flame retardant by preparing an Exolit AP 422/polyol-suspension.
Because of the low acid number of Exolit AP 422, it is also possible to incorporate this flame retardant in an Exolit AP 422/isocyanate suspension.

BENEFITS of EXOLIT AP 422:
-Non-halogenated flame retardant with favorable environmental and health profile.
-Greatly reduced water solubility, low viscosity in aqueous suspension, very low acid number.
-Particularly suitable as an ”acid donor” for intumescent coatings thanks to its low water solubility.
Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, DIN, BS, ASTM and others.
-Their application on wood or plastics enables these materials to qualify for Building Material Class B (DIN EN 13501-1).

-Excellent flame-retardant effect in cellulose-containing materials such as paper and wood products.
With chipboard products, the DIN EN 13501-1 classification can be achieved by adding 15-20 % Exolit AP 422.
-Excellent flame-retardant effect in polyolefin based wood plastic composites (WPC) with high wood contents (> 50%) at a dosage of 10-15% Exolit AP 422.
-Imparts a good flame-retardant effect to adhesives and sealants when Exolit AP 422 is incorporated into the base formulation at the rate of 10-20%.

-Efficient non-halogenated alternative for conventional flame retardants (e.g. TCPP) in various PUR applications, with minimum impact on reaction profiles and material properties.
-An essential component in intumescent formulations for thermoplastics, particularly polypropylene, for which the classification UL 94-V0 is specified for applications in the electrical sector.
However, for PP V-o injection molding applications Exolit AP 766 as ready-made intumescent formulation is recommended.

-In the case of thermosets like epoxy resins and unsaturated polyester resins, it paves the way for the production of lightweight components with low solids content.
-Can be used in transport applications to obtain good fire, smoke and toxicity results.
-(Bio-)degradable by breaking down to naturally occurring phosphate and ammonia.

ADVANTAGES of EXOLIT AP 422:
*greatly reduced solubility in water
*colorless, non-hygroscopic and non-flammable
*very low acid number
*high heat stability

METHODS of MANUFACTURING of EXOLIT AP 422:
Fluidized bed method→The bed layer is cooked with resistance wire to 220～250℃.
1050 parts of urea and 100 (parts of 85% phosphoric acid) are melted in a tank with steam jacket and stirring, and then added to the upper part of the bed at a rate of 120 parts per hour.
The gas (mainly containing ammonia and carbon dioxide) is passed through The cyclone separator and the bag filter return to the lower part of the corridor, and the recovered powder returns to the bed.

Exolit AP 422 obtained is basically water-insoluble type II crystalline polyammonium nitrate.
Exolit AP 422 is discharged from the bed and cooled to room temperature.
Shao crushed To the required particle size, the finished ammonium polyphosphate is obtained.
n HPO4+(n-1)(NH2)2CO→(NH4)n+2PnO3n+1+(n-4)NH3+(n-1)CO2

PHYSICAL and CHEMICAL PROPERTIES of EXOLIT AP 422:
Chemical Composition: Ammonium polyphosphate
Chemical formula: [NH4PO3]n(OH)2
Molar mass: 97.01 g/mol
Appearance: white powder
Density: 1,9 g/cm3; bulk density = 0,7 g/cm3
Molecular Weight： 149.087
Exact Mass： 149.056549
Characteristics PSA： 89.2
XLogP3： 0.04310
Appearance： white power

Storage Conditions： −20°C
Molecular Weight: 343.11
Hydrogen Bond Donor Count: 5
Hydrogen Bond Acceptor Count: 10
Rotatable Bond Count: 2
Exact Mass: 343.04230284
Monoisotopic Mass: 343.04230284
Topological Polar Surface Area: 190 Å²
Heavy Atom Count: 18

Formal Charge: 0
Complexity: 241
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 6
Compound Is Canonicalized: Yes

Form: solid
Color: white
Odor: odourless
pH: approx. 6.5 (25 °C, 10 g/l)
Solubility in water: <= 5 g/l (25 °C)
Density: 1.9 g/cm3 (25 °C)
Decomposition point : > 527 °F
Vapor pressure: < 0.75 Torr (20 °C)
Bulk density: approx. 700 kg/m3 (20 °C)
Partitioning coef. octanol/water: Not determined
Viscosity / (dynamic): <= 100 mPa.s (25 °C) 100 g/l in water

Phosphorus (% w/w) 31 min.
Nitrogen (%w/w) 14 min.
PH value(10% suspension): 5.5 - 7.5
Water(% w/w) 0.25 max.
Thermal decomposition (℃): 275 min.
Density (@25℃ ) (kg/L): 1.90
Apparent density (kg/L): 0.70
Viscosity (25℃ in 10% suspension) (mPa.s): 50 max.
Solubility in water(g/100ml): 0.5 max.
Averageparticlesize(D50,um): 15 max.

FIRST AID MEASURES of EXOLIT AP 422:
-After inhalation:
Get victim to fresh air.
Get prompt medical attention.

-After contact with skin:
Wash thoroughly with soap and water for 15 minutes.

-After contact with eyes:
Flush immediately under running water for fifteen minutes.

-After ingestion:
If victim is conscious, give large amounts of water or milk.
Consult a physician.

-Advice to doctor / Treatment:
None known.

ACCIDENTAL RELEASE MEASURES of EXOLIT AP 422:
-Steps to be taken in case of spill or leak:
Wear proper protective equipment.
Sweep up spill and place in proper waste container for disposal.

FIRE FIGHTING MEASURES of EXOLIT AP 422:
*Flashpoint: Not applicable
*Lower explosion limit: Not applicable
*Upper explosion limit: Not applicable
*Self ignition: Not applicable
*Ignition temperature: Not applicable
*Extinguishing media: water

EXPOSURE CONTROLS/PERSONAL PROTECTION of EXOLIT AP 422:
*Hand protection:
Butyl Rubber, PVC Or Neoprene.
*Eye protection:
Safety glasses or chemical splash goggles.
*Other protective equipment:
Clothing suitable to prevent skin contact.

HANDLING and STORAGE of EXOLIT AP 422:
-Advice on safe handling:
Wear proper protective equipment.
Wash thoroughly after handling.
Store in a dry place.
Keep containers tightly closed when not in use.

-Further info on storage conditions:
Store in original container.
Keep tightly sealed.
Store in a cool, dry, well-ventilated area.

STABILITY and REACTIVITY of EXOLIT AP 422:
Thermal decomposition: > 275 °C
Chemical stability: Stable.
Hazardous Polymerization: Will not occur.
Conditions to avoid: None known.

SYNONYMS:
Exolit AP 422
FR CROS 484
CS FR APP 231
AP 422
AP 462
APP (fireproofing agent)
Albaplas AP 95
Amgard CL
Amgard MC
Amgard TR
Ammonium ortho and polyphosphate solution
Ammonium orthophosphate, superphosphate
Ammonium polyphosphates
Antiblaze MC
Antiblaze MCM
Budit 3076
Budit 3076DC
Budit 3077
Budit 365
DFP-I
EXO 462
Exolit 263
Exolit 422
Exolit 442
Exolit 454
Exolit 455
Exolit 462
Exolit 470
Exolit AP 422
Exolit AP 423
Exolit AP 462
FR-Cros 480
FR-Cros 484
Fire-Trol LCG-R
Flameguard PT 8
Hostaflam 423
Hostaflam AP 420
Hostaflam AP 422
Hostaflam AP 462
Hostaflam AP 464
Hostaflam TP-AP 751
Hostaflam TP-AP 752
Novawhite
Phos-Chek P 30
Phos-Chek P 40
Phos-Chek P 60
Poly-N 10-34-0
Poly-N 11-37-0
Polymetaphosphoric acid, ammonium salt
Polyphosphoric acid, ammonium salt
Sumisafe
Taien A
Taien H
Polyphosphoric acids, ammonium salts Ammoniumpolyphosphat
Phos-chek P/30
Phos-chek P/40
Polyphosphoric acids,ammonium salts
Ammonium polyphosphates
Poly-N 11-37-0
Poly-N 10-34-0
Exolit 454
Exolit 462
Exolit 455
Phos-Chek P 30
Phos-Chek P 60
Exolit 263
Albaplas AP 95
DFP-I
Exolit 422
Ammonium polyphosphate
Amgard TR
Exolit 470
Sumisafe
Taien A
Amgard MC
Amgard CL
Flameguard PT 8
Phos-Chek P 40
Hostaflam AP 422
Hostaflam AP 420
Hostaflam AP 462
Fire-Trol LCG-R
AP 422
AP 462
Exolit 442
Hostaflam 423
Budit 365
Hostaflam AP 464
Terraju S
Novawhite
Terraju C 70
APP 422
Terraju 60
EXO 462
Exolith 462
FR-Cros 484
Exolit AP 462
FR-Cros 480
Exolit AP 422
Exolit AP 423
Hostaflam TP-AP 751
Hostaflam TP-AP 752
Antiblaze MC
Antiblaze MCM
Budit 3076DC
Taien H
APP (fireproofing agent)
APP
Budit 3076
Budit 307
Magma Firestop BP 422
Nicca Fi-None HF 1
Exolit AP 751
FR Cross 484
Pekoflam TC 203PDR
Fran GP 7
Exolit AP 420
FR-Cros S 10
Budit 3118
Budit 3118F
Budit 3127
Novawhite DA 6
Terraju S 20
Fire Cut FCP 730
Pekoflam TC 203
Nicca Fi-None HF 34
Pekoflam TC 204
Pekoflam TC 151
Novawhite PA 2
FR-Cros 484F15
APP 204
FCP 730
FR-Cros 480P
Exolit AP 740
PNP 1
Phos-Chek 80
Pekoflam TC 204P
Flameproof 1945
Taien P
R 056-7
APP 50
Budit 3167
Exolit AP 760
Glotard FFR 2
BL 50452
Neostecker HF 680C
GD 101
FCP 720
P 30
S 20
Exolit AP 742TP
Exolit AP 766
CF-APP 201
GD-APP 101
AP 760
Fire Cut 760
Nord-Min JLS
No-Burn Plus
PNP 1C
Terraju S 10
JLS-APP
JLA-PNP 1
Antiblaze LR 2
FR-Cros 134
FCP 770
69494-34-4
158859-30-4
179095-17-1
307314-12-1
811862-84-
866775-46-4
1174498-63-5
1204183-58-3
1310326-46-5
2243063-70-7
2306251-62-5
Ammonium triphosphate
Novawhite
Sumisafe
Antiblaze MC
Antiblaze MCM
Amgard CL
Amgard MC
Amgard TR
Taien A
Taien H
Flameguard PT 8
Hostaflam 423
Fire-Trol LCG-R
Albaplas AP 95
Hostaflam AP 420
Hostaflam AP 422
Hostaflam AP 462
Hostaflam AP 464
Exolit 263
Exolit 422
Exolit 442
Exolit 454
Exolit 455
Exolit 462
Exolit 470
Phos-Chek P 30
Phos-Chek P 40
Phos-Chek P 60
Budit 365
Exolit AP 422
Exolit AP 423
Exolit AP 462
Budit 3076DC
DFP-I
Budit 3076
Budit 3077
Hostaflam TP-AP 751
Hostaflam TP-AP 752
FR-Cros 480
FR-Cros 484
Poly-N 10-34-0
Poly-N 11-37-0
polyphosphoric acid ammonium salt
APP 422
CHEBI:147408
AP 422
AP 462
FT-0650713
pentaazanium
[oxido(phosphonatooxy)phosphoryl] phosphate