PRODUCTS

TERT-BUTYL HYDROPEROXIDE

tert-Butyl Hydroperoxide (tBuOOH) is the organic compound
tert-Butyl Hydroperoxide's molecular formula is (CH3)3COOH.
tert-Butyl Hydroperoxide is more soluble in organic solvents.

CAS NUMBER: 75-91-2

EC NUMBER: 200-915-7

MOLECULAR FORMULA: (CH3)3COOH

MOLECULAR WEIGHT: 90.12

IUPAC NAME: 2-hydroperoxy-2-methylpropane

tert-Butyl Hydroperoxide is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
tert-Butyl Hydroperoxide is normally supplied as a 69–70% aqueous solution.

Compared to hydrogen peroxide and organic peracids, tert-Butyl Hydroperoxide is less reactive
Overall, tert-Butyl Hydroperoxide is renowned for the convenient handling properties of its solutions.

tert-Butyl Hydroperoxide's solutions in organic solvents are highly stable.
tert-Butyl Hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.

tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.
tert-Butyl Hydroperoxide has a role as an antibacterial agent

tert-Butyl Hydroperoxide is used as an oxidising agent.
tert-Butyl Hydroperoxide is a natural product found in Apium graveolens with data available.

tert-Butyl Hydroperoxide is watery colorless liquid.
tert-Butyl Hydroperoxide floats on and dissolves slowly in water.
tert-Butyl Hydroperoxide is odorless compound

Applications:
Industrially, tert-Butyl Hydroperoxide is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:

(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3

The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, tert-Butyl Hydroperoxide is used to produce some fine chemicals by the Sharpless epoxidation

tert-Butyl Hydroperoxide is used as the oxidant for nearly all titanium-catalyzed asymmetric epoxidations.
tert-Butyl Hydroperoxide is used as an initiator for radical polymerization

tert-Butyl Hydroperoxide is used in various oxidation process such as sharpless epoxidation
tert-Butyl Hydroperoxide is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.

Furthermore, tert-Butyl Hydroperoxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary
tert-Butyl Hydroperoxide is used in the oxidation of dibenzothiophenes.

tert-Butyl Hydroperoxide plays an important role for the introduction of peroxy groups in organic synthesis.
tert-Butyl Hydroperoxide is an organic peroxide widely used in a variety of oxidation processes, for example Sharpless epoxidation.

tert-Butyl Hydroperoxide is normally supplied as a 69–70% aqueous solution
tert-Butyl Hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.

tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.
tert-Butyl Hydroperoxide (tBuOOH) is the organic compound with the formula (CH3)3COOH.

tert-Butyl Hydroperoxide's solutions in organic solvents are highly stable.
tert-Butyl Hydroperoxide is a flammable liquid and a highly reactive oxidizing agent.

tert-Butyl Hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.

tert-Butyl Hydroperoxide (TBHP) is a water-white liquid commonly commercially available as a 70% solution in water
tert-Butyl Hydroperoxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.

tert-Butyl Hydroperoxide vapor can burn in the absence of air
tert-Butyl Hydroperoxide may be flammable at either elevated temperature or at reduced pressure.

tert-Butyl Hydroperoxide may be combustible at temperatures below the normal flash point.
Closed containers may generate internal pressure through the degradation of tert-Butyl Hydroperoxide to oxygen .

tert-Butyl Hydroperoxide is a highly reactive product.
tert-Butyl Hydroperoxide is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.

tert-Butyl Hydroperoxide is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.

tert-Butyl Hydroperoxide is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
tert-Butyl Hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.

tert-Butyl Hydroperoxide is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, tert-Butyl Hydroperoxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
tert-Butyl Hydroperoxide plays an important role for the introduction of peroxy groups in organic synthesis.

PHYSICAL PROPERTIES:

-Molecular Weight: 90.12

-XLogP3-AA: 0.6

-Exact Mass: 90.068079557

-Monoisotopic Mass: 90.068079557

-Topological Polar Surface Area: 29.5 Å²

-Physical Description: Watery odorless colorless liquid

-Color: White-white

-Form: Liquid

-Boiling Point: 192 °F

-Melting Point: 18 °F

-Flash Point: 80 °F

-Solubility: Soluble in water

-Density: 0.88 g/cu cm

-Vapor Density: 2.07

-Vapor Pressure: 5.46 mmHg

-LogP: -1.3

-Autoignition Temperature: 238 °C

-Refractive Index: 1.4015

tert-Butyl Hydroperoxide is normally supplied as a 69–70% aqueous solution.
tert-Butyl Hydroperoxide's solutions in organic solvents are highly stable.

tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.
tert-Butyl Hydroperoxide has a role as an antibacterial agent

tert-Butyl Hydroperoxide is used as an oxidising agent.
tert-Butyl Hydroperoxide is watery colorless liquid.

CHEMICAL PROPERTIES:

-Hydrogen Bond Donor Count: 1

-Hydrogen Bond Acceptor Count: 2

-Rotatable Bond Count: 1

-Heavy Atom Count: 6

-Formal Charge: 0

-Complexity: 35.3

-Isotope Atom Count: 0

-Defined Atom Stereocenter Count: 0

-Undefined Atom Stereocenter Count: 0

-Defined Bond Stereocenter Count: 0

-Undefined Bond Stereocenter Count: 0

-Covalently-Bonded Unit Count: 1

-Compound Is Canonicalized: Yes

-Chemical Classes: Other Classes -> Peroxides, Organic

tert-Butyl Hydroperoxide is odorless compound
tert-Butyl Hydroperoxide is used as the oxidant for nearly all titanium-catalyzed asymmetric epoxidations.

tert-Butyl Hydroperoxide is used as an initiator for radical polymerization
tert-Butyl Hydroperoxide is used in various oxidation process such as sharpless epoxidation

tert-Butyl Hydroperoxide is used in the oxidation of dibenzothiophenes.
tert-Butyl Hydroperoxide is an organic peroxide widely used in a variety of oxidation processes, for example Sharpless epoxidation.

tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.
tert-Butyl Hydroperoxide is a flammable liquid and a highly reactive oxidizing agent.

tert-Butyl Hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
tert-Butyl Hydroperoxide is widely used in a variety of oxidation processes.

tert-Butyl Hydroperoxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
tert-Butyl Hydroperoxide is a highly reactive product.

tert-Butyl Hydroperoxide is an intermediate
tert-Butyl Hydroperoxide is primarily used as an initiator

SYNONYMS:

TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
tert-Butyl hydrogen peroxide
Terc. butylhydroperoxid
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
t-BuOOH
Tertiary-butyl hydroperoxide
tert-Butyl-hydroperoxide
Dimethylethyl hydroperoxide
T-Hydro
Perbutyl H 69T
Luperox TBH 70X
Trigonox A-W 70
Trigonox A-75
tBOOH
terc.Butylhydroperoxid
terc.Butylhydroperoxid
terc. Butylhydroperoxid
tert Butylhydroperoxide
EINECS 200-915-7
Hydroperoxyde de butyle tertiaire
Kayabutyl H
tBuOOH
tert-BuOOH
Hydroperoxide, 1,1-dimethylethyl-
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
tert-butylhydrogen peroxide
EC 200-915-7
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
tert-Butyl hydroperoxide (8CI)
tert-Butyl hydroperoxide
2-Methyl-prop-2-yl-hydroperoxide
Aztec t-butyl Hydroperoxide-70, Aq
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl hydroperoxide
1,1-Dimethylethyl hydroperoxide
2-Hydroperoxy-2-methylpropane
Dimethylethyl hydroperoxide
Hydroperoxyde de butyle tertiaire Français
t-butyl hydroperoxide
t-Butylhydroperoxide
TBHP
tert-butyl hydroperoxide
tert-Butylhydroperoxide
Tertiary-butyl hydroperoxide