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TRIAZINETRIETHANOL

CAS NUMBER: 4719-04-4 
 
MOLECULAR FORMULA: C10H25N3O3

MOLECULAR WEIGHT: 235.32

 

GENERAL INFORMATION:

Triazinetriethanol is a formaldehyde condensate product. 
Triazinetriethanols are produced by reacting formaldehyde with one or more substituted alkylamines. 

The result is a cyclic, saturated, symmetrical triazine.
Triazinetriethanol is presented to the CSWG for review because of its high production volume, 789,118-1,200,195 pounds a year, and its potential for exposure to large numbers of workers, approximately 225,000. 

Triazinetriethanol was selected as a member of a Biocides Class Study but was rejected for nomination in 1979 because of lack of suspicion of toxicity. 
Triazinetriethanol has not been adequately tested, that there is the possibility of the release of formaldehyde from Triazinetriethanol-like biocides, and that inhalation of oil mists, themselves, may be toxic.

 

PROPERTIES:

-Molecular Weight: 235.32    
-Hydrogen Bond Donor Count: 3    
-Hydrogen Bond Acceptor Count: 3
-Rotatable Bond Count: 6    
-Exact Mass: 235.18959167    
-Monoisotopic Mass: 235.18959167    
-Topological Polar Surface Area: 70.4 Ų    
-Heavy Atom Count: 16    
-Formal Charge: 0    
-Complexity: 130    
-Isotope Atom Count: 0    
-Defined Atom Stereocenter Count: 0    
-Undefined Atom Stereocenter Count: 0    
-Defined Bond Stereocenter Count: 0    
-Undefined Bond Stereocenter Count: 0    
-Covalently-Bonded Unit Count: 2    
-Compound Is Canonicalized: Yes

 

Structural Class: 

-Triazine 

 

DESCRIPTION:


The annual production volume of Triazinetriethanol has been estimated to range from 789,118 to 1,200,195 pounds.
Clear amber-colored liquid.

 

USES:

Triazinetriethanol is widely used as an antimicrobial agent in metal working fluids. 
Triazinetriethanol is marketed for addition to water-miscible fluids of the oil-in-water emulsion (soluble oil) and synthetic types. 

Water-miscible fluids provide cooling and lubrication for metalworking processes such as cutting and grinding. 
Bacterial growth in these fluids can cause odor and metal corrosion problems as well as emulsion breakdown. 

Triazinetriethanol biocides are also recommended for use in aqueous-based paint, coating, and latex emulsion products and in oilfield water systems, drilling muds, and in workover and completion fluids. 
Triazinetriethanol has been evaluated for use in water-compensated fuel tanks.

Triazinetriethanol is effective against both Gram-positive and Gram-negative bacteria. 
Triazinetriethanol is also effective against fungi or it may be combined.

Triazinetriethanol is an in-can biocide basen on Hexahydrotriazine (HHT).
Triazinetriethanol is an aqueous based low toxicity biocide developed for the complete in-can protection of water based products. 

Triazinetriethanol is effective against a wide range of microorganisms including gram positive and gram negative bacteria, yeast and fungi. 
Triazinetriethanol can be used over a wide pH and temperature range.

 

CHEMICAL PROPERTIES:

-Boiling Point: 106°C 
-Freezing Point: -24°C 
-Flash Point: >100°C, CC
-Vapor Pressure: 19 mm Hg @ 20°

 

SOLUBILITY:

Soluble in water, ethylene glycol, acetone, and the lower alcohols; insoluble in most hydrocarbons.

 

HUMAN EXPOSURE:

There is potential for widespread human exposure to Triazinetriethanol in occupational settings related to its use as an industrial biocide. 
The formaldehyde condensate products, which include Triazinetriethanol, represent 60 percent of the total sales of metalworking biocides. 

Triazinetriethanol is estimated that over 10 million US workers are exposed to machining or metalworking fluids. 
This figure includes employees of many industries who are involved in drilling, grinding, cutting, textile production, mist lubrication, and printing.

The metalworking fluids are directed at the working surface in a spray or stream and are generally collected and reused. 
Workers may be exposed through skin contact as well as by inhaling and swallowing the oil mist that is produced when metalworking fluids are used.

 

STORAGE:

Keep in a well-closed, avoid light, dry and cool place.
The shelf life of Triazinetriethanol is two years in original, unopened containers.
-18°C

 

DEFINITION:

Triazinetriethanol is an organic chemical compound with the formula (HCN)3. 
Triazinetriethanol is a six-membered heterocyclic aromatic ring, one of several isomeric triazines. 

Triazinetriethanol isomer—and its derivatives are useful in a variety of applications.
Triazinetriethanol is an organic compound used as a solvent and stabilizer in many industrial processes. 
Triazinetriethanol has been widely used in the manufacture of polymers, pharmaceuticals, cosmetics, paints, adhesives, textiles, detergents, and lubricants.

 

COSMETIC USES:

-antimicrobial agents

 

PREPARATION:

Triazinetriethanols are prepared by trimerization of certain nitriles such as cyanogen chloride or cyanimide. 
Triazinetriethanol is synthesised from benzonitrile and dicyandiamide.

Triazinetriethanol synthesis the reactants are an alkyl or aryl amidine and phosgene.
Insertion of an N-H moiety into a hydrazide by a copper carbenoid, followed by treatment with ammonium chloride also gives the triazine core.

 

PRODUCT DESCRIPTION:

Triazinetriethanol range of products, can be used as a Hydrogen Sulfide (H2S) Scavenger in Oil & Gas industries. 
Other applications include biocide, algaecide and preservative in a range of oilfields, pulp and paper as well as other industrial applications. 

Triazinetriethanol is brine soluble and it remains brine and water soluble even after reacting with H2S. 
Triazinetriethanol can be supplied in any concentrations as per client needs.

Triazinetriethanol triazine is a reliable storage tank side antimicrobial chemical. 
People usually put Triazinetriethanol directly into the sump of a badly fouled, high smell system. 

Triazinetriethanol works well against both gram-positive and also gram-negative microorganisms. 
The effectiveness of Triazinetriethanol triazine is not influenced by either the water hardness or various other chemicals. 

This micro biocide can also boost the efficiency of the liquid. 
Triazinetriethanol triazine is mainly used as hydrogen sulfide scavenger and anti-mildew agent.

As hydrogen sulfide scavenger, Triazinetriethanol triazine is mainly to remove the H2S generated from the exploitation of crude oil and natural gas. 
Thus guaranteeing the health in the production field. 

Triazinetriethanol triazine has the following advantages in low H2S situation.
Triazinetriethanol is the main ingredient of MEA triazine and sym-triazine. 
Triazinetriethanol is widely used in metal processing (cutting and grinding fluid), papermaking (paper coating), painting and coating, electroplating and leather (lustering agent).

 

FEATURES:

-Non-Zinc based
-Unlike conventional products, the byproduct is still brine and water soluble, giving a solids free solution
-Triazinetriethanol is compatible with other anionic, cationic, and nonionic products at the proper pH range of 9-12
-Economical
-The preferred additive for use in flare gas, LPG, residual and crude oils
-Less likely to cause any fouling, corrosion problems in crude oil distillation unit or refinery equipment

 

APPLICATION:

As a reagent in organic synthesis, Triazinetriethanol is used as the equivalent of hydrogen cyanide (HCN). 
Triazinetriethanol is sometimes easier to handle in the laboratory. 

One application is in the Gattermann reaction, used to attach the formyl group to aromatic substrates.
Triazinetriethanol is a compound useful in organic synthesis.

 

USAGE AREAS:

-in pigments, dyes and printing inks
-in adhesives and binding agents
-in anti-setoff and anti-adhesive agents
-in paints, lacquers and varnishes
-as a cleaning/washing agent
-as a corrosion inhibitor
-in cutting fluids
-in hydraulic fluids
-in reprographic agents
-as a fuel additive
-as a process regulator
-preservative
-heat treatment agent

 

TECHNICAL INFORMATION:

-Physical State: Liquid
-Storage: Store at -20° C

 

SYNONYM:

Hexahydro-1,3-5-triazine-1,3,5-triethanol
hexahydro-1,3,5-Names: tris(2-hydroxyethyl)triazine
1,3,5-tris(2-hydroxyethyl)hexahydro-1,3,5-triazine
1,3,5-tris-(2-hydroxyethyl)hexahydro-s-triazine
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