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ACENAPHTHYLENE


EC / List no.: 205-917-1
CAS no.: 208-96-8
Mol. formula: C12H8

Acenaphthylene, a polycyclic aromatic hydrocarbon is an ortho- and peri-fused tricyclic hydrocarbon. 
The molecule resembles naphthalene with positions 1 and 8 connected by a -CH=CH- unit. 
Acenaphthylene is a yellow solid.
Unlike many polycyclic aromatic hydrocarbons, it has no fluorescence.


Occurrence
Acenaphthylene occurs as about 2% of coal tar. Acenaphthylene is produced industrially by gas phase dehydrogenation of acenaphthene.

Reactions
Hydrogenation gives the more saturated compound acenaphthene. 
Chemical reduction affords the radical anion sodium or potassium acenaphthalenide, which is used as a strong reductant (E = -2.26 V vs FC).

Acenaphthylene functions as a ligand for some organometallic compounds.

Uses:
Polymerisation of acenaphthylene with acetylene in the presence of a Lewis acid catalyst gives electrically conductive polymers. 
Acenaphthylene possesses excellent properties as an antioxidant in cross-linked polyethylene and ethylene-propylene rubber. 
Thermal trimerization of acenaphthylene leads to decacyclene, which can be further processed to sulfur dyes.

Acenaphthylene is a colorless crystalline solid. Insoluble in water. Used in dye synthesis, insecticides, fungicides, and in the manufacture of plastics.

Acenaphthylene is a ortho- and peri-fused tricyclic hydrocarbon that occurs in coal tar. 
Acenaphthylene is an ortho- and peri-fused polycyclic arene, a member of acenaphthylenes and an ortho- and peri-fused tricyclic hydrocarbon.

Acenaphthylene is a natural product found in Artemisia capillaris, Tuber canaliculatum, and Tuber borchii with data available.

Description
Acenaphthylene is a PAH with three aromatic rings. 
Acenaphthylene is an intermediate chemical for the manufacture of dyes, soaps, pigments, pharmaceuticals, insecticides, fungicides, herbicides, plant growth hormones, naphthalic acids, naphthalic anhydride (pigments), and acenaphthylene (resins) and is used to manufacture plastics. 
The largest emissions of PAHs result from incomplete combustion of organic materials during industrial processes and other human activities. 
These include:
(1) processing of coal, crude oil, and natural gas, including coking, coal conversion, and petroleum refining; 
(2) production of carbon blacks, creosote, coal tar, and bitumen; 
(3) aluminium, iron, and steel production in plants and foundries; 
(4) heating in power plants and residences and cooking; 
(5) combustion of refuse; 
(6) motor vehicle traffic; and 
(7) environmental tobacco smoke.

Chemical Properties    
Acenaphthylene is a polycyclic aromatic hydrocarbon (PAH) with three aromatic rings. 
Acenaphthylene is used to manufacture plastics. 
Intermediate for dyes, soaps, pigments, pharmaceuticals, insec- ticide, fungicide, herbicide, and plant growth hormones. 
Intermediate for naphthalic acids, naphthalic anhydride (intermediate for pigments), and acenaphthylene (intermediate for res- ins). 
The largest emissions of PAH result from incomplete combustion of organic materials during industrial processes and other human activities. 

These include 
(a) processing of coal, crude oil, and natural gas, including coal; 
(b) coking, coal conversion, petroleum refi ning, and production of carbon blacks, creosote, coal-tar, and bitumen; 
(c) aluminium, iron, and steel production in plants and foundries; 
(d) heating in power plants and residences and cooking; 
(e) combustion of refuse; 
(f) motor vehicle traffi c; and 
(g) environmental tobacco smoke.

Chemical Properties    
Acenaphthylene is a flaky yellow crystalline powder or solid.

Physical properties    
Colorless to white prisms or crystalline plates from alcohol with an odor similar to coal tar or aromatic hydrocarbons.

Uses:
Polycyclic aromatic hydrocarbons as carcinogenic

Acenaphthylene has been used to investigate the photodimerization of acenaphthylene in micellar and hydrogel media.

Acenaphthylene may be used as an analytical reference standard for the determination of the analyte in water using ?gas chromatography-flame ionization detection (GC-FID).

Definition    
ChEBI: A ortho- and peri-fused tricyclic hydrocarbon that occurs in coal tar.

General Description    
Colorless crystalline solid. 
Insoluble in water. 
Used in dye synthesis, insecticides, fungicides, and in the manufacture of plastics.

Application
Acenaphthylene has been used to investigate the photodimerization of acenaphthylene in micellar and hydrogel media.


Acenaphthylene is a colorless crystalline solid. 
Insoluble in water. 
Used in dye synthesis, insecticides, fungicides, and in the manufacture of plastics. 
Acenaphthylene is a ortho- and peri-fused tricyclic hydrocarbon that occurs in coal tar.

Uses:
Acenaphthylene is used to make products for electronic engineering and plastics and to make dyes.

Acenaphthylene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short.  
PAHs are often found together in groups of two or more. 
They can exist in over 100 different combinations but the most common are treated as a group of 15.  
PAHs are found naturally in the environment but they can also be man-made.  
PAHs are solid and range in appearance from colorless to white or pale yellow-green.  
PAHs are created when products like coal, oil, gas, and garbage are burned but the burning process is not complete.  
Very little information is available on the individual chemicals within the PAH group. 
Most of the information available is for the PAH group as a whole. 
Information specific to acenaphthylene is included in this fact sheet when available. 

What is acenaphthylene used for? 
Most of the PAHs are used to conduct research. 
Like most PAHs, acenaphthylene is used to make dyes, plastics and pesticides

cenaphthylene is a polycyclic aromatic hydrocarbon that at first doesn't appear to follow all of the rules of aromaticity. We will learn why it is aromatic and how it is used.
Uses of Acenaphthylene
Acenaphthylene is used in making dyes and pigments that may have been used to dye your clothes. Since it isn't soluble in water it is useful in making dyes because it won't wash out when you wash your clothes.

Acenaphthylene is also used in making soaps, pesticides, and plastics. 
Acenaphthylene can be toxic, which is why it is a useful pesticide. 
And since it isn't soluble in water, it can act as the oil-binding molecule in soaps, which need to have one hydrophobic and one hydrophilic end.

Chemical NameAcenaphthene (1,2-Dihydro Acenaphthylene)
Synonyms
Acenaphthene; 1,2-Dihydroacenaphthylene; 1,8-Ethylenenaphthalene; NSC 7657; Naphthyleneethylene; peri-Ethylenenaphthalene;
CAS Number: 83-32-9
Molecular Formula: C₁₂H₁₀
Appearance: White to Off-White Solid
Melting Point: 93-95ºC
Molecular Weight:  154.21
Storage: Refrigerator
Solubility: Chloroform (Sparingly), Methanol (Slightly, Heated)
CategoryStandards; Environmental Standards, Mutagens and Metabolites;
Applications: Polycyclic aromatic hydrocarbons as carcinogenic agents.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package

Acenaphthylene is a polycyclic aromatic hydrocarbon consisting of naphthalene with an olefine bridge connecting positions 1 and 8. 
Acenaphthylene is a constituent of coal tar. 
Reduction of the olefin gives the related compound acenaphthene.

Acenaphthylene is one of over 100 different polycyclic aromatic hydrocarbons (PAHs). 
PAHs are chemicals that are formed during the incomplete burning organic substances, such as fossil fuels. 
They are usually found as a mixture containing two or more of these compounds.

Compound Type:    
- Aromatic Hydrocarbon
- Food Toxin
- Natural Compound
- Organic Compound
- Pollutant
- Polycyclic Aromatic Hydrocarbon

belongs to the class of organic compounds known as acenaphthylenes. 
These are aromatic polycyclic compounds containing an acenaphthylene moiety. 
Acenaphthylene is a carbotricyclic compound, consisting of a naphthalene with positions C1 and C8 connected by an ethylene bridge.


Acenaphthylene, a polycyclic aromatic hydrocarbon is an ortho- and peri-fused tricyclic hydrocarbon. 
The molecule resembles naphthalene with positions 1 and 8 connected by a -CH=CH- unit.
Acenaphthylene is a yellow solid. Unlike many polycyclic aromatic hydrocarbons, it has no fluorescence. 

Acenaphthylene, a polycyclic aromatic hydrocarbon is an ortho- and peri-fused tricyclic hydrocarbon. 
The molecule resembles naphthalene with positions 1 and 8 connected by a -CH=CH- unit. 
Acenaphthylene is a yellow solid.
Unlike many polycyclic aromatic hydrocarbons, it has no fluorescence.


Chemical formula: C12H8
Molar mass: 152.196 g·mol−1
Appearance: Yellow crystals
Density: 0.8987 g cm−3
Melting point: 91.8 °C (197.2 °F; 364.9 K)
Boiling point: 280 °C (536 °F; 553 K)
Solubility in water: Insoluble
Solubility in ethanol: very soluble
Solubility in diethyl ether: very soluble
Solubility in benzene: very soluble
Solubility in chloroform: soluble

Acenaphthylene is a polycyclic aromatic hydrocarbon consisting of naphthalene with an ethylene bridge connecting positions 1 and 8. Acenaphthylene is a constituent of coal tar. 
Reduction of the ethylene group gives the related compound acenaphthene.Unlike most polycyclic aromatic hydrocarbons, it has no fluorescence.

Chemical Properties
Appearance: Yellow crystalline powder
Boiling Point: 280 °C
CAS Number: 208-96-8
ChEBI: 33081
Chemical Composition: Calcium oxide;Potassium sulfate ;Polishing oil;Acenaphthene;Potassium chromate
Density: 0.8987 g cm-3
IUPAC Name: Acenaphthylene
Melting Point: 91.8 °C
Molar Mass: 152.19 g/mol
Molecular Formula: C12H8
RTECS Number: AB1254000
Related Compounds: Acenaphthene
Solubility: Insoluble

IUPAC NAMES:
Acenaphthylene
acenaphthylene

SYNONYMS:
ACENAPHTHYLENE
208-96-8
Acenaphthalene
Cyclopenta[de]naphthalene
Cyclopenta(de)naphthalene
acenaphthylen
CAS-208-96-8
189811-56-1
HSDB 2661
EINECS 205-917-1
NSC 59821
Acenaphthylene, radical ion(1-)
Acenaphthylene, 75%
Acenaphthylene, 99%
Acenaphthylene-[13C6]
Acenaphthylene, analytical standard
Acenaphthylene 10 microg/mL in Acetonitrile
Acenaphthylene 10 microg/mL in Cyclohexane
Acenaphthylene 100 microg/mL in Acetonitrile
Acenaphthylene, certified reference material, TraceCERT(R)
Acenaphthylene solution, 200 mug/mL in methanol, analytical standard
cyclopenta(de)naphthalene
Cyclopenta[de]naphthalene
acenaphthylene anion radical
1,2-dihydroacenaphthylene-1,2-diide
ACENAPHTHALENE
ACENAPHTHYLENE
acenaphthylene,industrial
Acenaphthylene Standard
acenaphthylene solution
Acenaphthylene, 80%,tech
ACENAPHTHYLENE, 99+%
ACENAPHTHYLENE, 100MG, NEAT
ACENAPHTHYLENE, 1X1ML, MEOH, 5000UG/ML
ACENAPHTHYLENE 80+%
ACENAPHTHYLENE 95%
Acenaphthylene, tech., 80%
Acenaphthylene 100mg [208-96-8]
Acenaphthylene @1000 μg/mL in MeOH
Acenaphthylene@0.2 mg/mL in MeOH
AcenaphthyleneSolution,500mg/L,1ml
Acenaphthylene >
Acenaphthylene @5.0 mg/mL in MeOH
Acenaphthylene@50 μg/mL in Toluene
AcenaphthyleneSolution,1000mg/L,1ml
Acenaphthylene@0.5 mg/mL in Acetonitrile
AcenaphthyleneSolution,100mg/L,1ml
Acenaphthylene @100 μg/mL in MeOH
AcenaphthyleneSolution,50mg/L,1ml
Acenaphthylene Standard 200 μg/mL In Isooctane
AcenaphthyleneSolution,100mg/L,10ml
AcenaphthyleneSolution,2000mg/L,1ml
ACENAPHTHYLENE ISO 9001:2015 REACH


 

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