Adipic Acid Dihydrazide (ADH) is used as a difunctional crosslinking agent in paints and coatings for certain water-based acrylic emulsions.
Adipic Acid Dihydrazide (ADH) is used as a hardener for epoxy resins and a chain extender for polyurethanes.
Adipic Acid Dihydrazide (ADH) is used Crosslinking Agent for Polymers, Elastomers and Rubber Industry, Adhesives and Sealants, Coatings and Paints, Textile Industry, and Corrosion Inhibitors.
CAS Number: 1071-93-8
EC Number: 213-999-5
MDL number: MFCD00007614
Chemical formula: C6H14N4O2
SYNONYMS:
ADH, ADIPIC ACID DIHYDRAZIDE, 403, dihydrazide, Adipohydrazide, HEXANEDIHYDRAZIDE, ADIPYL HYDRAZIDE, WSP ADH, Adip dihydr, WLN: ZMV4VMZ, Adipic Dihydrazide, Adipohydrazide, Adipyl Hydrazide, Adipic Dihydrazide, Hexanedioic acid, dihydrazide, dihydrazide, ADIPYL HYDRAZIDE, Hexanediohydrazide, adipoyl hydrazide, adipic hydrazide, ADH, Adipodihydrazide, Adipic acid dihydrazide, hexanedioic acid dihydrazide, HEXANEDIHYDRAZIDE, Adipohydrazide, Hexanedihydrazide, Adipohydrazide, Hexanedioic acid, 1,6-dihydrazide, Hexanedihydrazide, Adipic dihydrazide, Adipohydrazide, Adipyl hydrazide, Adipic dihydrazide, 1071-93-8, Adipohydrazide, Adipic acid dihydrazide, Hexanedihydrazide, Hexanedioic acid, dihydrazide, Adipic acid, dihydrazide, Adipoyldihydrazine, adipoyl dihydrazide, MFCD00007614, VK98I9YW5M, DTXSID0044361, Hexanedioic acid, 1,6-dihydrazide, NSC-3378, NSC-29542, WLN: ZMV4VMZ, Adipyl hydrazide, Adipodihydrazide, Adip dihydr, adipic hydrazide, Adipoyl hydrazide, adipic dihydrazone, Hexanedihydrazide #, NSC 3378, EINECS 213-999-5, NSC 29542, Adipic acid dihyrazide, Hexanedioic dihydrazide, AJICURE ADH, QUALIMER ADH, AI3-22640, ULTRALINK HYDRAZIDE, UNII-VK98I9YW5M, EC 213-999-5, Hexanedioic acid dihydrazide, SCHEMBL49856, CHEMBL3185968, DTXCID8024361, SCHEMBL11037942, NSC3378, 1,4-Butanedicarboxylic dihydrazide, ALBB-011767, BK 1000Z, BT 1000Z, NSC29542, STR02658, Tox21_301067, BBL022965, STK709135, AKOS000267183, NCGC00248276-01, NCGC00257525-01, CAS-1071-93-8, DB-022418, A0170, Adipic acid dihydrazide, >=98% (titration), CS-0010116, NS00003709, EN300-03706, D72486, T 2210, Adipic acid dihydrazide, purum, >=97.0% (NT), J-660023, Q-200600, Q4682936, Z56812730, F1943-0024, InChI=1/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12)
Adipic Acid Dihydrazide (ADH) is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.
Adipic acid dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) can also be used as a hardener for certain epoxy resins.
Adipic Acid Dihydrazide (ADH) is a symmetrical molecule with a C4 backbone, and the reactive group is C=ONHNH2.
Dihydrazides are made by the reaction of an organic acid with hydrazine.
Other dihydrazides with different backbones are also common, including isophthalic dihydrazide (IDH) and sebacic dihydrazide (SDH).
Adipic Acid Dihydrazide (ADH) is a distinctive crosslinking agent and curative that provides controlled reactivity and performance improvements in epoxy resins, polyurethane dispersions (PUDs), solvent-based polyurethanes (PURs), and emulsion acrylic resins.
Adipic Acid Dihydrazide (ADH) finds major applications as a latent curing agent for B-stageable epoxy resins and as an ambient temperature crosslinking agent for high-performance acrylic emulsion architectural coatings.
Materials crosslinked or cured with Adipic Acid Dihydrazide (ADH) demonstrate excellent colour stability, weathering resistance, adhesion, durability, hardness, and toughness.
Adipic Acid Dihydrazide (ADH) is an effective crosslinking agent, curative and hardener.
Adipic Acid Dihydrazide (ADH) is the most common dihydrazide crosslinking agent within a series of dihydrazides such as sebacic dihydrazide (SDH) and isophthalic dihydrazide (IDH).
Adipic Acid Dihydrazide (ADH)’s has a melting point of 180 °C and a molecular weight of 174; both are lower than the alternative dihydrazides SDH and IDH.
Adipic Acid Dihydrazide (ADH) is an effective crosslinking agent, curative and hardener.
Adipic Acid Dihydrazide (ADH) is the most common dihydrazide crosslinking agent within a series of dihydrazides such as sebacic dihydrazide (SDH) and isophthalic dihydrazide (IDH).
Adipic Acid Dihydrazide (ADH)'s has a melting point of 180 °C and a molecular weight of 174; both are lower than the alternative dihydrazides SDH and IDH.
Adipic Acid Dihydrazide (ADH) is non flammable.
Adipic Acid Dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) is also a hardener for certain epoxy resins.
Adipic Acid Dihydrazide (ADH) is a symmetrical molecule with a C4 backbone and the reactive group is C=ONHNH2.
Dihydrazides are made by the reaction of an organic acid with hydrazine.
Adipic Acid Dihydrazide, also known as ADH or Adipohydrazide, can be used as a hardener for epoxy resins and for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) is a symmetrical molecule with a C4 backbone and two reactive hydrazide groups.
The dihydrazide group allows Adipic Acid Dihydrazide (ADH) to react as crosslinking agent in epoxy, acrylic, and polyurethane compounds.
The applications of Adipic Acid Dihydrazide (ADH) are facilitated by the nucleophilicity of the amine function group, the good overall properties and weather ability of systems.
The moderate solubility of Adipic Acid Dihydrazide (ADH) in organic solvent and water facilitates the use of ADH in aqueous and solvent based systems.
Adipic Acid Dihydrazide (ADH) is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages.
Adipic Acid Dihydrazide (ADH) is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation.
Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines.
Adipic Acid Dihydrazide (ADH) is the most suitable hydrazide cross-linking agent, and ADH has been widely used in water-based paint emulsions in combination with diacetone acrylamide.
Adipic Acid Dihydrazide (ADH) is weakly alkaline, and there is a possibility of agglomeration when solid ADH is added directly to the emulsion, so usually ADH should be dissolved in hot water before use.
Adipic Acid Dihydrazide (ADH) is a white to slightly yellow crystalline powder.
Adipic Acid Dihydrazide (ADH) is a symmetrical molecule with a C4 backbone, and the reactive group is C=ONHNH2.
Dihydrazides are made by the reaction of an organic acid with hydrazine.
Other dihydrazides with different backbones are also common, including isophthalic dihydrazide (IDH) and sebacic dihydrazide (SDH).
USES and APPLICATIONS of ADIPIC ACID DIHYDRAZIDE (ADH):
Adipic Acid Dihydrazide (ADH) is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.
Adipic Acid Dihydrazide (ADH) is used in the following products: coating products, adhesives and sealants, fillers, putties, plasters, modelling clay, finger paints, polymers, non-metal-surface treatment products, textile treatment products and dyes and washing & cleaning products.
Other release to the environment of Adipic Acid Dihydrazide (ADH) is likely to occur from: outdoor use, indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids).
Other release to the environment of Adipic Acid Dihydrazide (ADH) is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
Adipic Acid Dihydrazide (ADH) can be found in complex articles, with no release intended: vehicles covered by End of Life Vehicles (ELV) directive (e.g. personal vehicles or delivery vans).
Adipic Acid Dihydrazide (ADH) is used in the following products: adhesives and sealants, coating products, paper chemicals and dyes, textile treatment products and dyes and washing & cleaning products. Adipic Acid Dihydrazide (ADH) is used for the manufacture of: textile, leather or fur and wood and wood products.
Other release to the environment of Adipic Acid Dihydrazide (ADH) is likely to occur from: outdoor use, indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids).
Adipic Acid Dihydrazide (ADH) is used in the following products: adhesives and sealants, coating products, fillers, putties, plasters, modelling clay, polymers, textile treatment products and dyes and finger paints.
Release to the environment of Adipic Acid Dihydrazide (ADH) can occur from industrial use: formulation of mixtures and formulation in materials.
Adipic Acid Dihydrazide (ADH) is used in the following products: paper chemicals and dyes, coating products, textile treatment products and dyes, adhesives and sealants, finger paints, laboratory chemicals, washing & cleaning products and water treatment chemicals.
Adipic Acid Dihydrazide (ADH) is used for the manufacture of: chemicals, pulp, paper and paper products and plastic products.
Release to the environment of Adipic Acid Dihydrazide (ADH) can occur from industrial use: for thermoplastic manufacture, as an intermediate step in further manufacturing of another substance (use of intermediates), in the production of articles and as processing aid.
Release to the environment of Adipic Acid Dihydrazide (ADH) can occur from industrial use: manufacturing of the substance.
Adipic Acid Dihydrazide (ADH) is used as a difunctional crosslinking agent in paints and coatings for certain water-based acrylic emulsions.
Adipic Acid Dihydrazide (ADH) is used as a hardener for epoxy resins and a chain extender for polyurethanes.
A small use is as a formaldehyde scavenger preventing the liberation of formaldehyde.
Adipic Acid Dihydrazide (ADH) is used Crosslinking Agent for Polymers, Elastomers and Rubber Industry, Adhesives and Sealants, Coatings and Paints, Textile Industry, and Corrosion Inhibitors.
Biomedical Applications of Adipic Acid Dihydrazide (ADH): Photography, Water Treatment, Fuel Additives, and Polymer Modification.
Adipic Acid Dihydrazide (ADH) is used as a difunctional crosslinking agent in paints and coatings for certain water-based acrylic emulsions. Adipic Acid Dihydrazide (ADH) is used as a hardener for epoxy resins and a chain extender for polyurethanes.
Adipic Acid Dihydrazide (ADH) is used crosslinking agent for self crosslinking emulsion resins using DAAM.
Adipic Acid Dihydrazide (ADH) is used as a difunctional crosslinking agent in paints and coatings for certain water-based acrylic emulsions.
Adipic Acid Dihydrazide (ADH) is used as a hardener for epoxy resins and a chain extender for polyurethanes.
The applications of Adipic Acid Dihydrazide (ADH) are facilitated by the nucleophilicity of the amine function (good reaction characteristics), the good overall properties and weatherability of cured systems.
The moderate solubility of Adipic Acid Dihydrazide (ADH) in water (50 g./liter) and common organic solvents facilitates the use of ADH in aqueous and solvent based systems.
Adipic Acid Dihydrazide (ADH) compounds are widely used in paint and adhesive thermoset applications.
This includes latent hardeners for epoxy resins, cross linking agents in acrylic emulsions with ketone groups, and chain extender for polyurethanes.
Adipic Acid Dihydrazide (ADH) is used for formaldehyde scavenger preventing the liberation of formaldehyde.
Adipic Acid Dihydrazide (ADH) is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages.
Adipic Acid Dihydrazide (ADH) is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation.
Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines.
Adipic Acid Dihydrazide (ADH) is a difunctional crosslinking agent used to cure functionalized copolymers, such as those containing aldehyde, ketone, and epoxy moieties.
At room temperature, the amino functionality of ADH rapidly crosslinks copolymers containing diacetone acrylamide (DAAM).
Adipic Acid Dihydrazide (ADH) is also used as a curing agent for bisphenol glycidyl epoxy resins, and for urethane pre-polymers.
Adipic Acid Dihydrazide (ADH) has been used to scavenge formaldehyde.
Adipic Acid Dihydrazide (ADH) is moderately soluble in water.
Adipic Acid Dihydrazide (ADH) is an effective curative in aqueous emulsions and dispersions.
Adipic Acid Dihydrazide (ADH) is widely used as Cross-linker in waterborne acrylic emulsions architectural coatings.
Adipic Acid Dihydrazide (ADH) is used Water based Coatings.
Adipic Acid Dihydrazide (ADH) enhances performance of epoxy resins.
Adipic Acid Dihydrazide (ADH) is used extender chains of polyurethane.
Adipic Acid Dihydrazide (ADH) is used finished textiles.
Adipic Acid Dihydrazide (ADH) is used wood processing to minimize formaldehyde exposure.
Key applications of Adipic Acid Dihydrazide (ADH): Adhesives & Sealants, Corrosion Inhibitors, Industrial Chemicals, Organic Intermediates, and Textile Auxiliaries.
Adipic Acid Dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) can also be used as a hardener for certain epoxy resins.
Adipic Acid Dihydrazide (ADH) is used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation.
Adipic Acid Dihydrazide (ADH) is mainly used as curing agent for epoxy powder coating and coating auxiliary, metal deactivating agent and other polymer auxiliary and water treatment agent.
Adipic Acid Dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) can also be used as a hardener for certain epoxy resins.
Adipic Acid Dihydrazide (ADH) is used as a formaldehyde scavenger and reacts with formaldehyde, thereby preventing the volatilizing of formaldehyde in the air.
Adipic Acid Dihydrazide (ADH) is also employed as a paint additive and coating additive.
Adipic Acid Dihydrazide (ADH) is also used as an intermediate.
Adipic Acid Dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) can also be used as a hardener for certain epoxy resins.
Further, Adipic Acid Dihydrazide (ADH) is used for cross-linking water-based emulsions and as a hardener for certain epoxy resins, which finds application in powder coating.
Adipic Acid Dihydrazide (ADH) is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages.
Adipic Acid Dihydrazide (ADH) is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation.
Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines.
Adipic Acid Dihydrazide (ADH) is used crosslinking agent for self crosslinking emulsion resins using DAAM.
End Uses of Adipic Acid Dihydrazide (ADH): Waterborne Coating
Adipic Acid Dihydrazide (ADH) is used Chemical Synthesis, Epoxy Resins, Plastic, Resin & Rubber, Crosslinkers, Emulsifiers, Fibers, Polymers.
Adipic Acid Dihydrazide (ADH) is used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation.
Adipic Acid Dihydrazide (ADH) is a chemical used for cross-linking water-based emulsions.
Adipic Acid Dihydrazide (ADH) can also be used as a hardener for certain epoxy resins.
EPOXY RESINS USES OF ADIPIC ACID DIHYDRAZIDE (ADH):
A notable fact with regard to Adipic Acid Dihydrazide (ADH) in epoxy formulations is that each of the primary amine end groups has a functionality of two, so the ADH molecule has an equivalency of four per epoxy moiety.
Accordingly, the active hydrogen equivalent weight of Adipic Acid Dihydrazide (ADH) is 43.5.
When formulated with epoxy resins, the Adipic Acid Dihydrazide (ADH) index can range between 0.85-1.15 of stoichiometric proportions, without a significant effect on mechanical properties.
The cure temperature for epoxy resins (glycidyl types) formulated with Adipic Acid Dihydrazide (ADH) is influenced by the melt-out temperature of the ADH, which allows an extended pot life at low temperatures.
Storage stability can be up to six-months at room temperature, with cure times of about one-hour at 130 °C.
Cure rates can be accelerated using tin or titanate catalysts, or imidazoles.
One-component Adipic Acid Dihydrazide (ADH) epoxy systems can be partially cured or “B-staged”, and later fully cured.
B-staging provides handling, processing, and fabrication advantages.
One component epoxy resins are used in coatings such as powder coatings, adhesives including hot melt adhesives, molding compounds and in fiber reinforced composites.
Glass and carbon fiber prepreg obtained by a hot melt impregnation method are used in the fabrication of sporting goods, wind turbine blades and aircraft/aerospace components.
With Adipic Acid Dihydrazide (ADH) cure, epoxy resins exhibit excellent toughness, flexibility, and adhesive properties.
Tg’s of 140-160 °C are achievable using a standard liquid bisphenol A epoxy resin (DGEBA) with Adipic Acid Dihydrazide (ADH) as the hardener.
Rigid and flexible epoxy adhesives have been formulated as one component systems that can be stored at room temperature using Adipic Acid Dihydrazide (ADH) as a latent curing agent.
Rigid epoxy adhesives are based on bisphenol A and novolac epoxides.
These rigid adhesives exhibit excellent cohesive and adhesive properties to a wide variety of surfaces.
Flexible epoxy adhesives produce more pliable bonds which better accommodate bond line stresses or differential substrate expansion rates.
Flexible epoxy resins include aliphatic di- and tri-epoxy resins such as hexanediol diglycidyl ether and poly(oxypropylene) diglycidyl ethers.
Semi-rigid epoxy-based adhesives utilize mixtures of both classes of epoxy resins or rigid formulations using flexibilizers.
POLYURETHANE DISPERSIONS (PUDs) USES OF ADIPIC ACID DIHYDRAZIDE (ADH):
Adipic Acid Dihydrazide (ADH) is an effective room temperature curative for aqueous PUDs and solution polyurethanes.
In this capacity, Adipic Acid Dihydrazide (ADH) provides polyurea coatings with higher hardness, toughness and adhesion properties, excellent mechanical properties, abrasion and chemical resistance.
Adipic Acid Dihydrazide (ADH) cured polyurethane coatings exhibit good color stability and weathering properties, which is not observed with standard amine curatives.
ADH is added to the water phase in a PUD.
Crosslinking occurs during the drying and film coalescence process which is ideal for maximizing the film properties including gloss, scrub, stain and wear resistance and durability.
Other crosslinking methods where crosslinking occurs prior to film coalescence exhibit reduced performance properties including poor flow and leveling.
The full reactivity characteristics of ADH are ideal for PUR systems.
Alternative curatives which show incomplete crosslinking due to slow reactivity and the lack of curative mobility in a dry film will also compromise performance.
ACRYLIC RESINS USES OF ADIPIC ACID DIHYDRAZIDE (ADH):
A large swath of our portfolio of customers at Gantrade produces acrylic resins to create high-performance products across a variety of industries worldwide.
The leading crosslinking technology for acrylic emulsion polymers is ambient temperature crosslinking chemistry based on diacetone acrylamide (DAAM) or acetoacetoxyethyl methacrylate (AAEM) and Adipic Acid Dihydrazide (ADH) monomers.
This technology, known as “keto-hydrazide crosslinking,” involves the direct reaction of the pendant ketone moiety on the DAAM-acrylic or AAEM acrylic polymer segment and the hydrazide moiety of the Adipic Acid Dihydrazide (ADH), with the evaporation of water in the film-forming process.
This self-crosslinking technology has been adopted in high-durability paints and coatings for architecture, wood, and concrete surfaces, and more.
The DAAM/Adipic Acid Dihydrazide (ADH) pair is also used in crosslinkable sizing agents, thickeners, adhesives, and sealants.
RELATED COMPOUNDS OF ADIPIC ACID DIHYDRAZIDE (ADH):
*hexanedioic acid
*hexanedihydrazide
*hexanedioyl dichloride
*hexanedinitrile
*hexanediamide
FUNCTION OF ADIPIC ACID DIHYDRAZIDE (ADH):
*Crosslinking Agent
USAGE OF ADIPIC ACID DIHYDRAZIDE (ADH):
Adipic Acid Dihydrazide (ADH) is a high-melting powder compound prepared from the reaction of organic acids with hydrazine.
Adipic Acid Dihydrazide (ADH) can be used as a latent curing agent for epoxy resins (EP).
The coating film of powder coating prepared with EP/SPH as adhesive system has very good flexibility, water resistance, weather resistance, corrosion resistance, insulation and decorative ability.
At home and abroad, Adipic Acid Dihydrazide (ADH) is an indispensable latent curing agent, especially in the manufacture of excellent high-temperature fast solid heavy duty powders and in the fields of petroleum pipelines, aerospace, aviation oil, etc.
Adipic Acid Dihydrazide (ADH) has very ideal effect in increasing strength of epoxy powder and FRP products. Especially combined with (DAAM), it can be made into high-performance water-soluble paint.
PROPERTIES OF ADIPIC ACID DIHYDRAZIDE (ADH):
Adipic Acid Dihydrazide (ADH) serves as a difunctional crosslinking agent in paints and coatings applied to specific water-based acrylic emulsions.
Additionally, Adipic Acid Dihydrazide (ADH) acts as a hardener for epoxy resins and a chain extender for polyurethanes.
Moreover, Adipic Acid Dihydrazide (ADH) finds a minor application as a formaldehyde scavenger, preventing the release of formaldehyde.
PHYSICAL and CHEMICAL PROPERTIES of ADIPIC ACID DIHYDRAZIDE (ADH):
Molecular Formula : C6H14O2N4
Molecular Weight : 174.20
Storage : -20 °C (Blue/Dry Ice)
Chemical formula: C6H14N4O2
Molar mass: 174.20 g/mol
Melting point: 176 to 185 °C (349 to 365 °F; 449 to 458 K)
Molecular Weight: 174.20 g/mol
XLogP3-AA: -2.1
Hydrogen Bond Donor Count: 4
Hydrogen Bond Acceptor Count: 4
Rotatable Bond Count: 5
Exact Mass: 174.11167570 Da
Monoisotopic Mass: 174.11167570 Da
Topological Polar Surface Area: 110 Ų
Heavy Atom Count: 12
Formal Charge: 0
Complexity: 142
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
CBNumber:CB4129556
Molecular Formula:C6H14N4O2
Molecular Weight:174.2
MDL Number:MFCD00007614
MOL File:1071-93-8.mol
Appearance (Colour): White to pale yellow
Appearance (Form): Powder
Solubility (Turbidity) 10% aq. solution: Clear
Solubility (Colour) 10% aq. solution: Colourless to pale yellow
Assay (NT): min. 95.0%
Melting Point: 178 - 182°C
Loss on drying: max. 0.5%
Molecular Formula: C6H14N4O2
Molecular Weight: 174.20 g/mol
CAS Description: Hexanedioic Acid, Dihydrazide
CAS No.: [1071-93-8]
EC-No.: 213-999-5
Appearance: White to off-white powder
Assay (%): min. 97
Loss on drying (%): max. 0.5
Odor: Odorless
pH (1% aq. Solution): 6.5 - 8.5
Melting point (oC): 178 - 185
Boiling point (oC): 426
Density (g/cm3): 1.29 (at 20 oC)
Solubility in water (g/L): 91
Appearance (Colour): White to pale yellow
Appearance (Form): Powder
Solubility (Turbidity) 10% aq. solution: Clear
Solubility (Colour) 10% aq. solution: Colourless to pale yellow
Assay (NT): min. 95.0%
Melting Point: 178 - 182°C
Loss on drying
Melting point: 180-182 °C (lit.)
Boiling point: 305.18°C (rough estimate)
Density: 1.2297 (rough estimate)
Vapor pressure: 0Pa at 25℃
Refractive index: 1.6700 (estimate)
Flash point: 150 °C
Storage temp.: -20°C
Solubility: H2O: 100 mg/mL
Form: Crystalline Powder
pKa: 12.93±0.35 (Predicted)
Color: White to slightly yellow
Water Solubility: Soluble
BRN: 973863
InChIKey: IBVAQQYNSHJXBV-UHFFFAOYSA-N
LogP: -2.7 at 20℃
CAS DataBase Reference: 1071-93-8 (CAS DataBase Reference)
EWG's Food Scores: 1-3
FDA UNII: VK98I9YW5M
NIST Chemistry Reference: Adipic dihydrazide (1071-93-8)
EPA Substance Registry System: Hexanedioic acid, dihydrazide (1071-93-8)
Formula: C6H14N4O2
InChI: InChI=1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12)
InChI key: IBVAQQYNSHJXBV-UHFFFAOYSA-N
SMILES: O=C(NN)CCCCC(=O)NN
Appearance: Pure white crystals
Melting point: 180-182ºC
Viscosity (25ºC): 300-1200 mPa·s
APHA color: ≤100
Water: ≤0.5%
Appearance: Dry Powder
Boiling point: 426 °C
Density: 1.28 g/cm3
Melting point: 180-182 °C
Molecular Weight: 174.20
Purity: ≥98%
Refractive index: 1.513
FIRST AID MEASURES of ADIPIC ACID DIHYDRAZIDE (ADH):
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available
ACCIDENTAL RELEASE MEASURES of ADIPIC ACID DIHYDRAZIDE (ADH):
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.
FIRE FIGHTING MEASURES of ADIPIC ACID DIHYDRAZIDE (ADH):
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.
EXPOSURE CONTROLS/PERSONAL PROTECTION of ADIPIC ACID DIHYDRAZIDE (ADH):
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.
HANDLING and STORAGE of ADIPIC ACID DIHYDRAZIDE (ADH):
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.
STABILITY and REACTIVITY of ADIPIC ACID DIHYDRAZIDE (ADH):
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available