AGNIQUE DFM 111 S

Agnique DFM 111 S is a silicone-based defoamer developed for controlling foam in aqueous agricultural and chemical-technical formulations.
Agnique DFM 111 S is supplied as a white liquid emulsion based principally on modified organopolysiloxanes together with proprietary carrier and stabilizing components.
Agnique DFM 111 S provides rapid foam knockdown and continued foam-control performance during formulation manufacturing, milling, pumping, filling, dilution, and application.

CAS Number: Proprietary mixture; no single CAS Number applies to the complete commercial product
EC Number: Proprietary mixture; no single EC Number applies to the complete commercial product
Molecular Formula: Not applicable to a proprietary aqueous organopolysiloxane formulation
Molecular Weight: Not applicable to a multicomponent silicone defoamer emulsion

SYNONYMS:

Agnique DFM 111 S, Agnique® DFM 111 S, AGNIQUE DFM 111 S, Agnique DFM-111 S, Agnique DFM111S, DFM 111 S, DFM-111 S, DFM111S, BASF Agnique DFM 111 S, BASF Agnique® DFM 111 S, Agnique DFM 111 S Defoamer, Agnique DFM 111 S Antifoam, Agnique DFM 111 S Antifoaming Agent, Agnique DFM 111 S Foam-Control Agent, Agnique DFM 111 S Silicone Defoamer, Agnique DFM 111 S Silicone Antifoam, Agnique DFM 111 S Silicone Emulsion, Agnique DFM 111 S Antifoam Emulsion, Agnique DFM 111 S Aqueous Silicone Emulsion, Agnique DFM 111 S Organopolysiloxane Defoamer, Agnique DFM 111 S Modified Organopolysiloxane Defoamer, Agnique DFM 111 S Polydimethylsiloxane Defoamer, Agnique DFM 111 S PDMS Defoamer, Agnique DFM 111 S Agrochemical Defoamer, Agnique DFM 111 S Agricultural Antifoam, Agnique DFM 111 S Pesticide Formulation Defoamer, Agnique DFM 111 S Suspension-Concentrate Defoamer, Agnique DFM 111 S Suspo-Emulsion Defoamer, Agnique DFM 111 S Seed-Treatment Defoamer, Agnique DFM 111 S Milling Defoamer, Agnique DFM 111 S Process Defoamer, Agnique DFM 111 S In-Can Defoamer, Agnique DFM 111 S Water-Based Defoamer, Agnique DFM 111 S Liquid Formulation Defoamer, Agnique DFM 111 S Chemical-Technical Raw Material, Agnique DFM 111 S Foam Suppressant, Agnique DFM 111 S Foam Breaker, Agnique DFM 111 S Air-Release Aid, Agnique DFM 111 S Bubble-Control Additive, Modified Silicone Antifoam Emulsion, Modified Organopolysiloxane Antifoam, Aqueous Polydimethylsiloxane Emulsion, Agricultural Silicone Defoamer, Agrochemical Silicone Antifoam, Silicone Emulsion Foam-Control Agent, PDMS-Silica Defoamer Emulsion, Hydrocarbon-Modified Silicone Defoamer, Silicone-Based Formulation Auxiliary, BASF Product Number 30535624

APPLICATIONS

Agnique DFM 111 S serves as a defoaming agent in aqueous suspension concentrates containing finely divided crop-protection active ingredients.
Agnique DFM 111 S breaks foam generated when powders, dispersants, wetting agents, rheology modifiers, and water are combined under mechanical agitation.
Agnique DFM 111 S supports more efficient suspension-concentrate manufacturing by limiting excessive air incorporation during premixing and homogenization.
Agnique DFM 111 S enables processing vessels to retain useful working capacity instead of losing volume to persistent foam.

Agnique DFM 111 S functions as a foam-control additive during bead milling of agricultural suspension concentrates.
Agnique DFM 111 S suppresses bubbles generated by high-speed circulation, particle impact, surfactant activity, and repeated pumping through the mill.
Agnique DFM 111 S promotes more consistent milling by reducing air pockets that can interfere with liquid circulation and heat transfer.
Agnique DFM 111 S contributes to reliable particle-size reduction when combined with an appropriate dispersant and validated milling procedure.

Agnique DFM 111 S finds application in fungicide suspension concentrates containing active ingredients such as azoxystrobin and other water-insoluble solids.
Agnique DFM 111 S controls foam while the active ingredient is dispersed and milled to the required particle-size distribution.
Agnique DFM 111 S helps improve process visibility and volume measurement by preventing stable foam layers from accumulating above the liquid.
Agnique DFM 111 S supports manufacturing consistency without replacing the dispersants and stabilizers required for long-term suspensibility.

Agnique DFM 111 S serves as an antifoam component in herbicide suspension concentrates containing hydrophobic particulate active ingredients.
Agnique DFM 111 S limits foam generated by wetting agents and dispersants during incorporation of herbicide powders into water.
Agnique DFM 111 S facilitates accurate batch-volume adjustment after milling because less air remains trapped in the formulation.
Agnique DFM 111 S contributes to smooth filling and packaging when the final concentrate has been properly deaerated.

Agnique DFM 111 S functions as a process aid in insecticide and acaricide suspension concentrates.
Agnique DFM 111 S reduces mechanically generated foam during high-shear mixing and recirculation.
Agnique DFM 111 S supports uniform transfer through pumps, hoses, filters, and filling equipment.
Agnique DFM 111 S enables formulators to control foam without introducing a strongly water-soluble conventional surfactant.

Agnique DFM 111 S finds application in suspo-emulsions containing both suspended pesticide particles and emulsified organic droplets.
Agnique DFM 111 S controls foam arising from the combined activity of emulsifiers, dispersants, wetting agents, and mechanical agitation.
Agnique DFM 111 S supports reliable preparation of the aqueous suspension phase before addition of the emulsified liquid phase.
Agnique DFM 111 S contributes to efficient vessel utilization and filling performance in complex multiphase formulations.

Agnique DFM 111 S serves as a defoamer in capsule-suspension formulations containing polymeric microcapsules.
Agnique DFM 111 S suppresses foam created during capsule dispersion, stabilization, dilution, and transfer.
Agnique DFM 111 S helps prevent foam from interfering with visual assessment of capsule-suspension homogeneity.
Agnique DFM 111 S supports controlled packaging where excessive trapped air could impair fill-weight consistency.

Agnique DFM 111 S functions as a foam-control agent in water-based seed-treatment formulations.
Agnique DFM 111 S reduces foam during incorporation of active ingredients, polymers, colorants, plasticizers, and formulation auxiliaries.
Agnique DFM 111 S facilitates smooth pumping and metering of seed-treatment slurries through coating equipment.
Agnique DFM 111 S contributes to consistent seed coverage by reducing air entrainment within the applied liquid film.

Agnique DFM 111 S finds application in seed-coating formulations based on polyvinyl alcohol, graft polymers, pigments, and pesticide active ingredients.
Agnique DFM 111 S suppresses bubbles generated during polymer hydration and high-speed blending.
Agnique DFM 111 S helps reduce surface defects associated with foam transfer onto treated seeds.
Agnique DFM 111 S supports more uniform dried coatings when the complete formulation and application process are properly optimized.

Agnique DFM 111 S serves as a process defoamer during preparation of aqueous biological pesticide formulations.
Agnique DFM 111 S controls foam in formulations containing RNA-based biological active ingredients and supporting formulation auxiliaries.
Agnique DFM 111 S facilitates mixing and transfer without requiring excessive mechanical deaeration.
Agnique DFM 111 S enables foam management while the biological stability of the complete formulation is assessed separately.

Agnique DFM 111 S functions as an antifoam in double-stranded RNA and single-stranded RNA agricultural formulations.
Agnique DFM 111 S reduces persistent foam during preparation of aqueous biopesticide concentrates.
Agnique DFM 111 S supports accurate dosing of biological formulation components by limiting foam-related volume errors.
Agnique DFM 111 S contributes processing control while compatibility with nucleic acids, preservatives, buffers, and delivery polymers remains formulation dependent.

Agnique DFM 111 S finds application in aqueous fertilizer-compatible pesticide concentrates.
Agnique DFM 111 S limits foam during blending of suspension concentrates with liquid fertilizers and nutrient solutions.
Agnique DFM 111 S supports easier evaluation of phase compatibility by reducing foam that can obscure separation, sedimentation, or flocculation.
Agnique DFM 111 S enables efficient tank preparation when the pesticide, fertilizer, water, and adjuvant system has been confirmed as compatible.

Agnique DFM 111 S serves as a foam-control agent during incorporation of water-soluble fertilizers into crop-protection formulations.
Agnique DFM 111 S suppresses bubbles generated by recirculation, salt addition, and surfactant-rich pesticide concentrates.
Agnique DFM 111 S contributes to stable pumping by reducing the risk of air entering centrifugal or positive-displacement equipment.
Agnique DFM 111 S supports formulation processing without functioning as a fertilizer stabilizer or compatibility agent by itself.

Agnique DFM 111 S functions as a manufacturing defoamer during preparation of aqueous pesticide concentrates containing polymeric dispersants.
Agnique DFM 111 S controls foam created as dispersant solutions are charged, hydrated, and subjected to high shear.
Agnique DFM 111 S supports more efficient particle wetting by reducing the foam blanket at the liquid surface.
Agnique DFM 111 S allows the dispersant to perform its primary stabilization function without excessive process foam.

Agnique DFM 111 S finds application in formulations containing nonionic block-copolymer dispersants and co-dispersants.
Agnique DFM 111 S reduces foam generated by ethylene oxide–propylene oxide polymers during agitation and dilution.
Agnique DFM 111 S facilitates milling and circulation where polymeric surfactants would otherwise stabilize unwanted bubbles.
Agnique DFM 111 S contributes to controlled processing while the polymeric dispersant maintains particle stabilization.

Agnique DFM 111 S serves as a defoaming additive in aqueous formulations containing alkoxylated phosphate-ester surfactants.
Agnique DFM 111 S suppresses foam generated by phosphate-ester wetting and dispersing agents during homogenization.
Agnique DFM 111 S supports visual evaluation of formulation stability by reducing persistent surface foam.
Agnique DFM 111 S enables more reliable measurement of bleeding, flocculation, sedimentation, and phase separation.

Agnique DFM 111 S functions as an in-process defoamer in pesticide-formulation reactors.
Agnique DFM 111 S limits foam caused by rapid raw-material charging, high-speed agitation, and recirculation.
Agnique DFM 111 S helps prevent foam from reaching vessel vents, filters, and vacuum systems.
Agnique DFM 111 S contributes to cleaner and safer processing by reducing uncontrolled foam overflow.

Agnique DFM 111 S finds application during formulation scale-up from laboratory batches to pilot and commercial production.
Agnique DFM 111 S helps compensate for the increased foam generation associated with larger mixers, pumps, and circulation loops.
Agnique DFM 111 S supports more predictable vessel occupancy and transfer time.
Agnique DFM 111 S allows developers to distinguish genuine formulation instability from apparent volume increase caused by entrained air.

Agnique DFM 111 S serves as a foam-control component during high-speed rotor–stator homogenization.
Agnique DFM 111 S destabilizes foam films that form as air is drawn into surfactant-containing liquid formulations.
Agnique DFM 111 S supports more effective liquid turnover by reducing low-density foam zones near the mixer head.
Agnique DFM 111 S promotes efficient homogenization when its addition point and concentration are optimized experimentally.

Agnique DFM 111 S functions as an air-release aid in low- to medium-viscosity aqueous chemical formulations.
Agnique DFM 111 S encourages entrained bubbles to coalesce and escape from the liquid.
Agnique DFM 111 S helps reduce apparent viscosity and density variation caused by dispersed air.
Agnique DFM 111 S contributes to reproducible quality-control sampling after the formulation has been adequately homogenized.

Agnique DFM 111 S finds application in filling operations for bottles, drums, intermediate bulk containers, and other chemical packages.
Agnique DFM 111 S controls foam produced as formulations pass through transfer pumps, valves, and filling nozzles.
Agnique DFM 111 S supports accurate net-volume and net-weight filling by reducing unstable foam heads.
Agnique DFM 111 S helps minimize product loss caused by overflow during high-speed packaging.

Agnique DFM 111 S serves as an antifoam during dilution of concentrated pesticide products with water.
Agnique DFM 111 S reduces foam generated when surfactant-rich concentrates enter turbulent spray-tank water.
Agnique DFM 111 S supports faster tank filling by preventing excessive foam accumulation.
Agnique DFM 111 S contributes to usable spray-tank capacity while normal agitation is maintained.

Agnique DFM 111 S functions as a foam-control auxiliary in recirculating agricultural spray systems.
Agnique DFM 111 S suppresses bubbles formed as the liquid repeatedly passes through pumps, bypass lines, and agitation jets.
Agnique DFM 111 S reduces the likelihood of foam interfering with level measurement and tank inspection.
Agnique DFM 111 S supports consistent spray delivery when its use is compatible with the registered formulation and application instructions.

Agnique DFM 111 S finds application in aqueous cleaning and rinsing operations associated with agrochemical manufacturing equipment.
Agnique DFM 111 S can control process foam in compatible cleaning solutions containing residual surfactants and formulation ingredients.
Agnique DFM 111 S supports faster vessel drainage by reducing persistent foam during circulation and rinsing.
Agnique DFM 111 S requires wastewater and disposal evaluation because silicone-containing residues may affect downstream treatment operations.

Agnique DFM 111 S serves as a defoamer in selected water-based industrial formulations outside crop protection.
Agnique DFM 111 S limits foam in compatible pigment dispersions, polymer suspensions, cleaning preparations, and technical aqueous mixtures.
Agnique DFM 111 S supports efficient mixing and filling where surfactants or particulate solids stabilize unwanted bubbles.
Agnique DFM 111 S requires application-specific testing because silicone defoamers can affect coating appearance, adhesion, printability, or surface finishing.

Agnique DFM 111 S functions as a laboratory reference defoamer during comparison of foam-control technologies.
Agnique DFM 111 S allows formulators to compare silicone-based performance with mineral-oil, polyether, fatty-acid, or block-copolymer defoamers.
Agnique DFM 111 S supports measurement of initial foam knockdown, long-term foam inhibition, compatibility, and storage stability.
Agnique DFM 111 S provides meaningful comparative results only when mixing energy, temperature, concentration, and test geometry are controlled.

Agnique DFM 111 S finds application at low formulation concentrations because silicone materials can provide strong interfacial activity.
Agnique DFM 111 S has been used at approximately 0.01–0.30% in published formulation examples.
Agnique DFM 111 S should not be assigned a universal dosage because the optimum level depends on surfactants, solids, viscosity, processing energy, and application requirements.
Agnique DFM 111 S requires incremental laboratory screening to identify the minimum effective level without creating incompatibility or surface defects.

DESCRIPTION

Agnique DFM 111 S is a BASF commercial foam-control product identified by product number 30535624.
Agnique DFM 111 S is supplied as a chemical-technical raw material rather than as a pesticidal active ingredient.
Agnique DFM 111 S is primarily associated with defoaming applications in aqueous agrochemical formulations.
Agnique DFM 111 S current product documentation is distributed through BASF’s controlled document-download system.

Agnique DFM 111 S is a proprietary multicomponent preparation rather than one pure molecular substance.
Agnique DFM 111 S is described in BASF agricultural literature as an aqueous product based on hydrocarbons and modified organopolysiloxanes.
Agnique DFM 111 S is described in patent literature as an antifoam emulsion containing polydimethylsiloxane and propylene glycol.
Agnique DFM 111 S has also been described in commercial shipping records as an aqueous preparation containing polydimethylsiloxane, silica, and petroleum-distillate components.

Agnique DFM 111 S should therefore be characterized broadly as a proprietary aqueous silicone defoamer.
Agnique DFM 111 S exact quantitative composition remains controlled by BASF and the applicable product specification.
Agnique DFM 111 S may contain emulsifying, stabilizing, carrier, preservative, and hydrophobic solid components in addition to the principal silicone phase.
Agnique DFM 111 S should not be represented by one CAS Number, EC Number, structural formula, or molecular weight.

Agnique DFM 111 S derives its foam-control action principally from organopolysiloxane materials with very low surface-energy characteristics.
Agnique DFM 111 S silicone droplets enter foam films and disrupt the arrangement of foam-stabilizing surfactants.
Agnique DFM 111 S promotes thinning and rupture of lamellae separating adjacent gas bubbles.
Agnique DFM 111 S consequently provides both rapid foam collapse and reduced persistence of newly generated foam.

Agnique DFM 111 S may contain hydrophobic silica or related dispersed solids that increase the efficiency of the silicone phase.
Agnique DFM 111 S hydrophobic particles can assist rupture of stabilized foam films when carried to the air–liquid interface.
Agnique DFM 111 S carrier components help distribute the active foam-control phase through an aqueous formulation.
Agnique DFM 111 S complete mechanism depends on the proprietary relationship among silicone fluid, hydrophobic solids, carrier phase, and emulsifiers.

Agnique DFM 111 S is supplied as a white liquid.
Agnique DFM 111 S has a representative viscosity range of approximately 1,500–2,500 mPa·s at 25°C.
Agnique DFM 111 S has a representative density of approximately 0.97 kg/L at 25°C.
Agnique DFM 111 S has a reported flash point above 100°C in BASF agricultural-product literature.

Agnique DFM 111 S viscosity is sufficiently high to help maintain the dispersed silicone phase within the commercial emulsion.
Agnique DFM 111 S viscosity can change with temperature, storage history, and the degree of product homogenization.
Agnique DFM 111 S cold material may become more difficult to pump, measure, or disperse.
Agnique DFM 111 S should be conditioned only within the temperature range permitted by the current BASF documentation.

Agnique DFM 111 S has a density slightly below that of water according to the representative BASF value.
Agnique DFM 111 S may therefore exhibit creaming or concentration gradients if the emulsion is stored without movement for prolonged periods.
Agnique DFM 111 S physical separation does not automatically demonstrate chemical decomposition, but the product should not be used without confirming that it can be restored to a uniform state.
Agnique DFM 111 S should be gently homogenized before representative sampling when permitted by the supplier.

Agnique DFM 111 S is an emulsion and should not be assumed to be molecularly soluble in water.
Agnique DFM 111 S is designed to distribute its active silicone phase throughout aqueous formulations at low use levels.
Agnique DFM 111 S effectiveness depends on controlled dispersion rather than complete molecular dissolution.
Agnique DFM 111 S may lose performance if the emulsion is broken by incompatible solvents, extreme pH, electrolytes, freezing, or excessive shear.

Agnique DFM 111 S is intended to destabilize foam without acting as the primary emulsifier or dispersant of the finished formulation.
Agnique DFM 111 S does not replace the wetting agents required to incorporate hydrophobic pesticide particles.
Agnique DFM 111 S does not replace the polymeric or ionic dispersants required to prevent particle aggregation.
Agnique DFM 111 S must therefore be balanced with the complete surfactant package rather than selected in isolation.

Agnique DFM 111 S may perform differently depending on whether it is added before, during, or after high-shear processing.
Agnique DFM 111 S early addition can suppress foam generated during raw-material incorporation and milling.
Agnique DFM 111 S late addition can restore foam control lost through prolonged processing or dilution.
Agnique DFM 111 S optimum addition sequence should be established through application-specific trials.

Agnique DFM 111 S excessive addition may create incompatibility, surface defects, separation, reduced wetting, or interference with coating performance.
Agnique DFM 111 S insufficient addition may provide temporary foam collapse without adequate long-term control.
Agnique DFM 111 S should therefore be evaluated over a concentration series rather than at one arbitrary level.
Agnique DFM 111 S finished formulations should be tested for foam, deaeration, storage stability, dilution behavior, suspensibility, and application performance.

Agnique DFM 111 S performance can be influenced by the hydrophilic–lipophilic balance of the formulation.
Agnique DFM 111 S can also be affected by solids loading, particle size, viscosity, electrolyte concentration, temperature, and mixing energy.
Agnique DFM 111 S may require different concentrations in a high-solids suspension concentrate and a low-viscosity aqueous solution.
Agnique DFM 111 S laboratory tests should reproduce the actual process equipment and dilution procedure as closely as practicable.

Agnique DFM 111 S can provide immediate foam knockdown when introduced into an established foam layer.
Agnique DFM 111 S can also provide preventive antifoam performance when uniformly incorporated before foam generation.
Agnique DFM 111 S long-term efficiency depends on whether the active droplets remain available and appropriately dispersed.
Agnique DFM 111 S performance may decline if the active phase becomes excessively emulsified by strong surfactants.

Agnique DFM 111 S historical BASF safety information classified the product as not requiring classification under the cited UN GHS criteria.
Agnique DFM 111 S historical labeling information nevertheless stated that an allergic reaction may occur because the product contained 5-chloro-2-methyl-2H-isothiazol-3-one.
Agnique DFM 111 S preservative content may be present at a low concentration intended to protect the water-based product from microbial spoilage.
Agnique DFM 111 S current hazard classification must be taken from the latest regional Safety Data Sheet because composition and regulatory thresholds may change.

Agnique DFM 111 S is expected to have comparatively low volatility under normal room-temperature conditions.
Agnique DFM 111 S can nevertheless produce airborne mist during spraying, high-speed mixing, pressure transfer, or mechanical atomization.
Agnique DFM 111 S heated material may release carrier vapors or decomposition products.
Agnique DFM 111 S processing should therefore include ventilation appropriate to the actual exposure conditions.

Agnique DFM 111 S is combustible as an organic formulation despite its aqueous-emulsion character and flash point above 100°C.
Agnique DFM 111 S should be protected from open flames, sparks, hot surfaces, and uncontrolled heating.
Agnique DFM 111 S severe thermal decomposition may generate carbon oxides, silicon-containing residues, smoke, and irritating organic fumes.
Agnique DFM 111 S firefighting procedures should follow the current regional Safety Data Sheet.

Agnique DFM 111 S stability depends on preservation of the commercial emulsion structure.
Agnique DFM 111 S should be protected from prolonged freezing, excessive heat, contamination, and repeated exposure to air.
Agnique DFM 111 S should not be mixed directly with concentrated acids, bases, oxidizing agents, or unfamiliar solvents without compatibility testing.
Agnique DFM 111 S partially used containers should be resealed promptly to limit microbial and particulate contamination.

Agnique DFM 111 S quality control may include appearance, homogeneity, viscosity, density, pH, solids content, foam knockdown, and persistent foam-control performance.
Agnique DFM 111 S exact acceptance limits remain part of the current BASF commercial specification.
Agnique DFM 111 S incoming batches should be compared with the applicable certificate of analysis before controlled production.
Agnique DFM 111 S historical brochure values should not replace current batch-release documentation.

PROPERTIES

Product Name: Agnique DFM 111 S
Registered Trade Name: Agnique® DFM 111 S
Brand Owner: BASF
BASF Product Number: 30535624
Product Type: Silicone-based defoamer and antifoaming agent
Commercial Form: Aqueous emulsion or aqueous dispersion
Chemical Family: Modified organopolysiloxanes
Representative Silicone Component: Polydimethylsiloxane or related modified organopolysiloxane
Additional Reported Components: Hydrocarbon carrier, silica, petroleum-distillate fractions, propylene glycol, emulsifiers, stabilizers, and preservative components
CAS Number: No single CAS Number applies to the complete proprietary mixture
EC Number: No single EC Number applies to the complete proprietary mixture
Molecular Formula: Not applicable to the complete proprietary mixture
Molecular Weight: Not applicable to the complete proprietary mixture
Primary Function: Foam knockdown and foam prevention
Additional Functions: Air release, processing support, vessel-capacity improvement, filling support, and dilution-foam control
Primary Industry: Agrochemical formulations
Additional Industry Classification: Chemical-technical raw material
Primary Formulation Type: Aqueous liquid formulations
Principal Agricultural Applications: Suspension concentrates, suspo-emulsions, seed treatments, capsule suspensions, biological formulations, and fertilizer-compatible pesticide systems
Physical Form: Liquid
Appearance: White liquid
Representative Viscosity at 25°C: 1,500–2,500 mPa·s
Representative Density at 25°C: Approximately 0.97 kg/L
Representative Flash Point: Greater than 100°C
Water Behavior: Aqueous emulsion; molecular solubility is not applicable to the complete product
Ionic Character: Proprietary emulsion system
Volatility: Comparatively low under normal ambient conditions
Recommended Use Level: Formulation-specific
Published Example Levels: Approximately 0.01–0.30% in selected patent examples
Universal Dosage: Not established
Foam-Control Mechanism: Disruption and rupture of surfactant-stabilized foam films
GHS Classification in Cited Historical SDS: No classification required according to the stated UN GHS criteria
Historical Special Labeling Statement: May produce an allergic reaction
Historical Sensitizing Preservative Statement: Contains 5-chloro-2-methyl-2H-isothiazol-3-one
Current Hazard Classification: Refer to the latest regional BASF Safety Data Sheet
Transport Classification: Refer to the latest regional BASF Safety Data Sheet
pH: Refer to the current BASF Technical Data Sheet or certificate of analysis
Solids Content: Proprietary; refer to the current BASF documentation
Freezing Point: Not published in the cited BASF product overview
Boiling Range: Not represented by one fixed value
Vapor Pressure: Mixture-specific; refer to the current Safety Data Sheet
Chemical Stability: Stable under recommended storage and handling conditions
Emulsion Stability: Protect from freezing, overheating, contamination, incompatible chemicals, and excessive shear
Hazardous Polymerization: Not expected under normal storage conditions
Incompatible Materials: Strong oxidizing agents and other materials identified in the current regional Safety Data Sheet
Hazardous Decomposition Products: Carbon oxides, silicon-containing residues, smoke, and irritating organic fumes may form during severe heating or combustion
Recommended Storage: Original tightly closed packaging in a cool, dry, and well-ventilated area
Current Data Requirement: Confirm all specifications against the latest BASF Technical Data Sheet, Safety Data Sheet, and certificate of analysis.

FIRST AID

Inhalation:
Move the affected person to fresh air.
Keep the person at rest in a position comfortable for breathing.
Avoid further exposure to Agnique DFM 111 S mist, aerosol, vapor, or thermal-decomposition fumes.
Obtain medical attention if coughing, throat irritation, headache, dizziness, nausea, or breathing discomfort develops or persists.

Skin Contact:
Remove contaminated clothing and footwear.
Wash the affected skin thoroughly with soap and plenty of water.
Continue rinsing if redness, irritation, itching, or discomfort is present.
Obtain medical advice if symptoms persist or signs of an allergic skin reaction develop.
Wash contaminated clothing thoroughly before reuse.

Eye Contact:
Rinse the eyes immediately with plenty of clean, gently flowing water.
Hold the eyelids open to ensure complete irrigation.
Remove contact lenses when present and easy to do, then continue rinsing.
Continue rinsing for at least 15 minutes.
Obtain medical attention if pain, redness, tearing, blurred vision, or irritation persists.

Ingestion:
Rinse the mouth thoroughly with water.
Do not induce vomiting unless directed by qualified medical personnel.
Never give anything by mouth to an unconscious or convulsing person.
Obtain medical advice if a significant quantity has been swallowed or symptoms develop.
Provide the product label and current Agnique DFM 111 S Safety Data Sheet to medical personnel.

Note to Physicians:
No product-specific antidote should be assumed.
Provide supportive care and treat according to the patient’s symptoms and clinical condition.
Assess the eyes, skin, respiratory tract, and gastrointestinal system following significant exposure.
Consider possible sensitization associated with preservative components identified in the current product documentation.
Use the latest regional BASF Safety Data Sheet as the primary medical reference.

HANDLING AND STORAGE

Handling:
Handle Agnique DFM 111 S in accordance with good industrial hygiene and chemical-safety practices.
Review the current Technical Data Sheet and Safety Data Sheet before opening or processing the product.
Avoid unnecessary contact with the skin, eyes, and clothing.
Do not breathe mist, aerosol, vapor, or fumes generated during spraying, heating, or high-speed mixing.
Use closed or low-splash transfer systems wherever reasonably practicable.
Use clean and chemically compatible equipment for pumping, weighing, sampling, and transfer.
Gently homogenize the product before representative sampling when permitted by BASF.
Avoid excessive high-shear treatment that could damage the commercial emulsion.
Wash the hands, face, and exposed skin thoroughly after handling.
Do not eat, drink, or smoke in areas where Agnique DFM 111 S is processed.
Keep containers tightly closed when the product is not being sampled or transferred.

Ventilation:
Provide adequate general ventilation in storage and processing areas.
Use local exhaust ventilation near mixers, drum openings, filling points, spray equipment, and sampling stations.
Control airborne mist and aerosol at the source rather than allowing it to spread through the workplace.
Provide additional ventilation when Agnique DFM 111 S is heated, atomized, sprayed, or handled in confined spaces.
Use suitable respiratory protection when engineering controls cannot adequately limit exposure.
Select respiratory equipment through a documented workplace exposure assessment.
Ensure that ventilation and exhaust systems comply with occupational and environmental requirements.

Storage:
Store Agnique DFM 111 S in its original, tightly closed, and correctly labeled packaging.
Keep the product in a cool, dry, and adequately ventilated location.
Protect Agnique DFM 111 S from direct sunlight, excessive heat, uncontrolled freezing, contamination, and physical damage.
Keep Agnique DFM 111 S separated from strong oxidizing agents and incompatible chemicals.
Prevent water, dirt, active ingredients, acids, bases, solvents, and process residues from entering opened containers.
Carefully reseal partially used containers immediately after sampling or transfer.
Maintain the storage-temperature range specified in the current BASF documentation.
Inspect stored material for irreversible separation, microbial growth, odor change, or contamination before use.
Gently homogenize material that has developed a reversible concentration gradient when permitted by the supplier.
Use first-in, first-out stock rotation within the stated shelf life.

Spill and Leak Procedures:
Restrict access to the affected area and remove unnecessary personnel.
Provide effective ventilation before beginning spill recovery.
Wear suitable gloves, protective clothing, eye protection, and respiratory protection as required.
Stop the source of the leak only when this can be done safely.
Prevent Agnique DFM 111 S from entering drains, sewers, soil, groundwater, or surface water.
Recover pumpable liquid into suitable and correctly labeled containers whenever practicable.
Contain remaining material with sand, earth, vermiculite, or another compatible inert absorbent.
Avoid absorbents whose strong acidity, alkalinity, or reactivity could destabilize the product.
Collect recovered product and contaminated absorbent in tightly closed and correctly labeled waste containers.
Clean the affected surface thoroughly because residual silicone emulsion can create a severe slipping hazard.
Prevent concentrated wash water from entering uncontrolled drainage systems.
Dispose of recovered material and cleaning residues through an authorized waste-management contractor.

Handling Precautions:
Wear chemical-resistant gloves selected from documented compatibility and permeation data.
Use safety glasses with side protection or tightly fitting chemical goggles.
Wear a face shield in addition to goggles where splashing is reasonably foreseeable.
Use protective clothing and footwear capable of limiting repeated skin contact.
Provide accessible eyewash and emergency-shower equipment near major handling areas.
Inspect pumps, hoses, valves, seals, gaskets, tanks, and transfer connections before use.
Use equipment compatible with aqueous silicone emulsions and the complete finished formulation.
Avoid uncontrolled high-speed mixing that may generate excessive airborne mist or irreversibly destabilize the emulsion.
Do not use open flames or uncontrolled direct heating to change the product viscosity.
Keep heated product, packaging, and contaminated absorbents away from ignition sources.
Determine the minimum effective dosage through laboratory and pilot-scale trials.
Review the current Agnique DFM 111 S Technical Data Sheet, Safety Data Sheet, certificate of analysis, and applicable regulatory requirements before formulation, production, transportation, storage, cleanup, or disposal.