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ALLYL METHACRYLATE

Allyl Methacrylate is an important cross-linking agent that can provide effective bifunctional cross-linking in the second stage, with good chemical resistance, impact strength, adhesion, hardness and low shrinkage.
Allyl Methacrylate can be used in dental materials, industrial paints, silicone intermediates, light stabilizers, optical polymers, elastomers and some vinyl and acrylate polymer systems.

CAS Number: 96-05-9
EC Number: 202-473-0
IUPAC Name: prop-2-enyl 2-methylprop-2-enoate
Chemical Formula: C7H10O2

Other names: ALLYL METHACRYLATE, 96-05-9, Ageflex AMA, Methacrylic acid, allyl ester, 2-Propenoic acid, 2-methyl-, 2-propenyl ester, Allylester kyseliny methakrylove, prop-2-enyl 2-methylprop-2-enoate, NSC 18597, HSDB 5297, EINECS 202-473-0, Methacrylic Acid Allyl Ester, UNII-G2IG50653Z, BRN 1747406, DTXSID2021816, AI3-37827, G2IG50653Z, NSC-18597, prop-2-en-1-yl 2-methylprop-2-enoate, DTXCID401816, 3-METHACRYLOYLOXYPROPYLENE, allylmethacrylate, EC 202-473-0, ALLYL ALCOHOL, METHACRYLATE, 2-Propenoic acid, 2-methyl-, 2-propen-1-yl ester, Allyl Methacrylate (stabilized with MEHQ), 2-METHYL-2-PROPENOIC ACID 2-PROPENYL ESTER, Allyl 2-methylacrylate, CAS-96-05-9, Allylester kyseliny methakrylove [Czech], Allyl ester of Methacrylic acid, allyl-methacrylate, 2-Methyl-2-propenyl 2-propenoate, MFCD00008592, SCHEMBL22017, 2-Propenyl 2-methylpropenoate, WLN: 1UY1&VO2U1, CHEMBL1889548, AMY4149, NSC18597, Tox21_201759, Tox21_302944, AKOS005207053, NCGC00166051-01, NCGC00166051-02, NCGC00256503-01, NCGC00259308-01, Allyl Methacrylate, (stabilized with MEHQ), M0075, NS00008098, Methacrylic Acid Allyl Ester (stabilized with MEHQ), Q2718014

Allyl Methacrylate is an acrylic monomer with two types of vinyl groups which include methacrylic and allylic based double bonds.
Allyl Methacrylate is mainly utilized as a cross-linking agent to increase the hardness of the base material.

Allyl Methacrylate also facilitates an improvement in the heat resistant property of the resin.
Allyl Methacrylate is an ester of Methacrylic acid and is used as a raw material component in the synthesis of polymers.

Allyl Methacrylate is a monomer of dual allylic and methacrylic functionalities consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group.
Allyl Methacrylate forms homopolymers and copolymers.

Allyl Methacrylate which can be prepared with (meth)acrylic acid and its salts, amides, and esters, etc.
Allyl Methacrylate is water-insoluble, with low volatility.

Allyl Methacrylate is used in oil additives as flow improver, in-floor waxes, textile and metal coatings, paint, varnishes, pressure-sensitive adhesives, low temperature caulks, and sealants.
Allyl Methacrylate is a low viscosity liquid monomer with dual allylic and methacrylic functionalities.

Allyl Methacrylate offers excellent second stage crosslinking, chemical and heat resistance, hardness, and low shrinkage.
Allyl Methacrylate forms homopolymers and copolymers.

Allyl Methacrylate is also a very useful feedstock for chemical syntheses, because it readily undergoes addition reactions with a wide variety of organic and inorganic compounds.
Allyl Methacrylate is of the gel type, insoluble in solvents.

Allyl Methacrylate is a low viscosity liquid monomer with dual allylic and methacrylic functionalities, offering chemical and heat resistance, adhesion, hardness, excellent second stage cross-linking and low shrinkage.
Allyl Methacrylate serves, inter alia, as an intermediate for preparing silyl-containing methacrylates.

Accordingly, various methods of obtaining Allyl Methacrylate are known.
These include especially processes in which allyl alcohol is reacted with methacrylates, for example methyl methacrylate or ethyl methacrylate.

To improve the yield and the selectivity of the reaction, different catalysts can be used.
As a result, Allyl Methacrylate is possible in an unforeseeable manner to provide a process for preparing allyl methacrylate in which the product is obtained with a very high purity.

Surprisingly, Allyl Methacrylate obtained contains only very small amounts of allyl alcohol and/or water.
According to the invention, allyl methacrylate is prepared.

Allyl Methacrylate (propenyl 2-methylpropenoate) has been known for some time and has the CAS number 96-05-9.
Allyl Methacrylate is a clear, colorless liquid with a melting point of -75 °C, boiling point of 141 °C, and measured vapor pressure of 7.7 hPa (5.77 mmHg) at 25 °C.

The measured octanol-water partition coefficient (log Kow ) is 2.15 at 25°C, and water solubility is 2200 mg/L.
Allyl Methacrylate was insoluble in common organic solvents.

Color / Form: Colorless liquid
Boiling Point: 150 °C
Flash Point: 33.9 °C
Density: 0.9335 g/cu cm at 20 °C

Molecular Weight: 126.15 g/mol
XLogP3-AA: 1.7
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 4

Exact Mass: 126.068079557 g/mol
Monoisotopic Mass: 126.068079557 g/mol
Topological Polar Surface Area: 26.3Å²
Heavy Atom Count: 9

Complexity: 136
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Allyl Methacrylate also facilitates an improvement in the heat resistant property of the resin.
For the homopolymerization of Allyl Methacrylate the maximum conversion depends on the reaction conditions and on the monomer/initiator ratio.

For the copolymerization, Allyl Methacrylate conversions of up to 90% were obtained while no cross-linking occurred.
Kinetic studies of the homopolymerization revealed a controlled polymerization up to a certain conversion whereas at higher conversions, multimodal molecular weight distributions caused by branching reactions and cross-linking were observed.

Allyl Methacrylate is an unsymmetrical divinyl compound with two types of vinyl groups (methacryolyl and allyl).
Allyl Methacrylate is also frequently used as a cross-linker.

Allyl Methacrylate is a copolymer of allyl methacrylate cross-linked with glycol dimethacrylate.
Allyl Methacrylate is a part of an advanced targeted delivery system.

Allyl Methacrylate is really helpful for emulsion stabilizing in humid or higher temperature locations.
Allyl Methacrylate also has viscosity controlling capacity and makes the cosmetic more appeal by opacifying the product.

Allyl Methacrylate is an important crosslinking agent, can supply double functional radicaleffective crosslinking in the second phase, and has well drug-fast, impact intension, adhesive force, rigidity and low shrinkability.
Allyl Methacrylate is used as dentistry material, industrial paint, organosilicon intermediate, light stability agent, optical macromolecule, elastomer, part of ethylene species and acrylic ester species polymer system.

Allyl Methacrylate can be analyzed by this reverse phase (RP) HPLC method with simple conditions.
Allyl Methacrylate is a monomer liquid that has low viscosity with dual allylic and methacrylic functionalities.

Allyl Methacrylate offers various chemical properties including heat resistance, hardness, adhesion, low shrinkage, and second stage cross-linking.
Allyl Methacrylate has a distinct odor and is a colorless transparent liquid.

Allyl Methacrylate has low solubility with water and has high stability and reactivity under sunlight and heat.
Allyl Methacrylate is categorized as explosives and is a hazardous and flammable liquid.

Allyl Methacrylate is harmful to humans as well as the environment.
Allyl Methacrylates extended contact with the skin can cause drying and dilapidation that can result in cracks.

Allyl Methacrylate is an EES (R43) specified sensitizing agent that has weak and acute toxicity.
Allyl Methacrylate has numerous applications including paints, coating compounds, as adhesive modifier, coatings, dental composites, cleaning & washing products, manufacturing of chemicals, or laboratory chemicals, manufacturing of drugs; modified by veterinary, animal, or pet if indicated by source.

Allyl Methacrylate is also used as raw materials in a wide range of products and industries including chemical manufacturing, cosmetics, production of metals, etc. Some other applications include food packaging, paper plates, cutlery, small appliances such as roastes, etc.
Allyl Methacrylate is used as silane coupling agents, which play a vital role in the manufacturing of various composites from inorganic fillers and organic polymers such as minerals, glass, and metals.

Allyl Methacrylate can be obtained by alcoholysis of methyl methacrylate with allyl alcohol in the presence of sodium methylate and hydroquinone , a polymerization inhibitor, or by esterification of the acid with allyl alcohol.
Allyl Methacrylate is a colorless liquid that is sparingly soluble in water.

Allyl Methacrylate is used for the production of homo- and copolymers.
The compound is also a very useful starting material for chemical synthesis because addition reactions take place with a large number of organic and inorganic compounds.

Allyl Methacrylate is used as a co-monomer for hard plastics, crosslinking agents or as a basic product for the production of silanes.
Allyl Methacrylate is an aminomethylpropanol salt of a copolymerof allyl methacrylate and one or more monomers consisting of acrylic acid, methacrylic acid or one of theirsimple esters.

Allyl Methacrylate is an cross-linking agent with methacrylate esters in contact lenses and with alkyl acrylates in pressure-sensitive adhesives; in curable acrylic coatings; for preparing mucilages and thickening agents for aqueous systems.
Allyl Methacrylate is also used in oil additives as flow improver, in-floor waxes, textile and metal coatings, paint, varnishes, pressure-sensitive adhesives, low temperature caulks, and sealants.

Allyl Methacrylate is water-insoluble, with low volatility clear liquid.
Allyl Methacrylate can be synthesized by the reaction of acrylamide and allyl alcohol under the action of concentrated acid and H2O2.

Allyl Methacrylate can also be obtained by transesterification of allyl acetate and methyl methacrylate.
Allyl Methacrylate is a very useful starting material for chemical synthesis since it easily undergoes addition reactions with a wide spectrum of organic and inorganic compounds.

Allyl Methacrylate is used mainly in closed system processing as a co-monomer (rigid plastics) and cross linker (silanes).
Allyl Methacrylate is mainly utilized as a cross-linking agent to increase the hardness of the base material.

Uses:
Architectural Coatings
Automotive Coatings
Construction Coatings
Industrial Coatings
Dental Composites
Optical Polymers
Photoresists
UV Inkjet Inks

Features:
Crosslinking
Adhesion
Chemical resistance
Hardness
Heat resistance
Low shrinkage