AMA ( ALLYL METHACRYLATE )

CAS NUMBER: 96-05-9

EC NUMBER: 202-473-0

MOLECULAR FORMULA: C7H10O2

MOLECULAR WEIGHT: 126.15300

AMA ( Allyl methacrylate ) is an important cross-linking agent that can provide effective bifunctional cross-linking in the second stage, with good chemical resistance, impact strength, adhesion, hardness and low shrinkage.
AMA ( Allyl methacrylate ) can be used in dental materials, industrial paints, silicone intermediates, light stabilizers, optical polymers, elastomers and some vinyl and acrylate polymer systems.

AMA ( Allyl methacrylate ) is an acrylic monomer with two types of vinyl groups which include methacrylic and allylic based double bonds. 
AMA ( Allyl methacrylate ) is mainly utilized as a cross-linking agent to increase the hardness of the base material. 

AMA ( Allyl methacrylate ) also facilitates an improvement in the heat resistant property of the resin.
AMA ( Allyl methacrylate ) is an ester of Methacrylic acid and is used as a raw material component in the synthesis of polymers. 

AMA ( Allyl methacrylate ) is a monomer of dual allylic and methacrylic functionalities consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group. 
AMA ( Allyl methacrylate ) forms homopolymers and copolymers. 

AMA ( Allyl methacrylate ) which can be prepared with (meth)acrylic acid and its salts, amides, and esters, etc.
AMA ( Allyl methacrylate ) is water-insoluble, with low volatility. 

AMA ( Allyl methacrylate ) is used in oil additives as flow improver, in-floor waxes, textile and metal coatings, paint, varnishes, pressure-sensitive adhesives, low temperature caulks, and sealants.
AMA ( Allyl methacrylate ) is a low viscosity liquid monomer with dual allylic and methacrylic functionalities. 

AMA ( Allyl methacrylate ) offers excellent second stage crosslinking, chemical and heat resistance, hardness, and low shrinkage. 
AMA ( Allyl methacrylate ) forms homopolymers and copolymers. 

AMA ( Allyl methacrylate ) is also a very useful feedstock for chemical syntheses, because it readily undergoes addition reactions with a wide variety of organic and inorganic compounds.
AMA ( Allyl methacrylate ) is of the gel type, insoluble in solvents.

AMA ( Allyl methacrylate ) is a low viscosity liquid monomer with dual allylic and methacrylic functionalities, offering chemical and heat resistance, adhesion, hardness, excellent second stage cross-linking and low shrinkage.
AMA ( Allyl methacrylate ) serves, inter alia, as an intermediate for preparing silyl-containing methacrylates. 

Accordingly, various methods of obtaining AMA ( Allyl methacrylate ) are known. 
These include especially processes in which allyl alcohol is reacted with methacrylates, for example methyl methacrylate or ethyl methacrylate. 

To improve the yield and the selectivity of the reaction, different catalysts can be used.
As a result, AMA ( Allyl methacrylate ) is possible in an unforeseeable manner to provide a process for preparing allyl methacrylate in which the product is obtained with a very high purity. 

Surprisingly, AMA ( Allyl methacrylate ) obtained contains only very small amounts of allyl alcohol and/or water.
According to the invention, allyl methacrylate is prepared. 

AMA ( Allyl methacrylate ) (propenyl 2-methylpropenoate) has been known for some time and has the CAS number 96-05-9.
AMA ( Allyl methacrylate ) is a clear, colorless liquid with a melting point of -75 °C, boiling point of 141 °C, and measured vapor pressure of 7.7 hPa (5.77 mmHg) at 25 °C. 

The measured octanol-water partition coefficient (log Kow ) is 2.15 at 25°C, and water solubility is 2200 mg/L.
AMA ( Allyl methacrylate ) was insoluble in common organic solvents.

AMA ( Allyl methacrylate ) is an acrylic monomer with two types of vinyl groups which include methacrylic and allylic based double bonds. 
AMA ( Allyl methacrylate ) is mainly utilized as a cross-linking agent to increase the hardness of the base material. 

AMA ( Allyl methacrylate ) also facilitates an improvement in the heat resistant property of the resin.
For the homopolymerization of AMA ( Allyl methacrylate ) the maximum conversion depends on the reaction conditions and on the monomer/initiator ratio. 

For the copolymerization, AMA ( Allyl methacrylate ) conversions of up to 90% were obtained while no cross-linking occurred. 
Kinetic studies of the homopolymerization revealed a controlled polymerization up to a certain conversion whereas at higher conversions, multimodal molecular weight distributions caused by branching reactions and cross-linking were observed.

AMA ( Allyl methacrylate ) is an unsymmetrical divinyl compound with two types of vinyl groups (methacryolyl and allyl). 
AMA ( Allyl methacrylate ) is also frequently used as a cross-linker.

AMA ( Allyl methacrylate ) is a copolymer of allyl methacrylate cross-linked with glycol dimethacrylate. 
AMA ( Allyl methacrylate ) is a part of an advanced targeted delivery system.

AMA ( Allyl methacrylate ) is really helpful for emulsion stabilizing in humid or higher temperature locations. 
AMA ( Allyl methacrylate ) also has viscosity controlling capacity and makes the cosmetic more appeal by opacifying the product.

AMA ( Allyl methacrylate ) is an important crosslinking agent, can supply double functional radicaleffective crosslinking in the second phase, and has well drug-fast, impact intension, adhesive force, rigidity and low shrinkability. 
AMA ( Allyl methacrylate ) is used as dentistry material, industrial paint, organosilicon intermediate, light stability agent, optical macromolecule, elastomer, part of ethylene species and acrylic ester species polymer system.

AMA ( Allyl methacrylate ) can be analyzed by this reverse phase (RP) HPLC method with simple conditions.
AMA ( Allyl methacrylate ) is a monomer liquid that has low viscosity with dual allylic and methacrylic functionalities. 

AMA ( Allyl methacrylate ) offers various chemical properties including heat resistance, hardness, adhesion, low shrinkage, and second stage cross-linking. 
AMA ( Allyl methacrylate ) has a distinct odor and is a colorless transparent liquid. 

AMA ( Allyl methacrylate ) has low solubility with water and has high stability and reactivity under sunlight and heat. 
AMA ( Allyl methacrylate ) is categorized as explosives and is a hazardous and flammable liquid. 

AMA ( Allyl methacrylate ) is harmful to humans as well as the environment. 
AMA ( Allyl methacrylate )s extended contact with the skin can cause drying and dilapidation that can result in cracks. 

AMA ( Allyl methacrylate ) is an EES (R43) specified sensitizing agent that has weak and acute toxicity. 
Allyl Methacrylate has numerous applications including paints, coating compounds, as adhesive modifier, coatings, dental composites, cleaning & washing products, manufacturing of chemicals, or laboratory chemicals, manufacturing of drugs; modified by veterinary, animal, or pet if indicated by source. 

AMA ( Allyl methacrylate ) is also used as raw materials in a wide range of products and industries including chemical manufacturing, cosmetics, production of metals, etc. Some other applications include food packaging, paper plates, cutlery, small appliances such as roastes, etc. 
AMA ( Allyl methacrylate ) is used as silane coupling agents, which play a vital role in the manufacturing of various composites from inorganic fillers and organic polymers such as minerals, glass, and metals.

AMA ( Allyl methacrylate ) can be obtained by alcoholysis of methyl methacrylate with allyl alcohol in the presence of sodium methylate and hydroquinone , a polymerization inhibitor, or by esterification of the acid with allyl alcohol.
AMA ( Allyl methacrylate ) is a colorless liquid that is sparingly soluble in water. 

AMA ( Allyl methacrylate ) is used for the production of homo- and copolymers. 
The compound is also a very useful starting material for chemical synthesis because addition reactions take place with a large number of organic and inorganic compounds. 

AMA ( Allyl methacrylate ) is used as a co-monomer for hard plastics, crosslinking agents or as a basic product for the production of silanes.
AMA ( Allyl methacrylate ) is an aminomethylpropanol salt of a copolymerof allyl methacrylate and one or more monomers consisting of acrylic acid, methacrylic acid or one of theirsimple esters.

AMA ( Allyl methacrylate ) is an cross-linking agent with methacrylate esters in contact lenses and with alkyl acrylates in pressure-sensitive adhesives; in curable acrylic coatings; for preparing mucilages and thickening agents for aqueous systems. 
AMA ( Allyl methacrylate ) is also used in oil additives as flow improver, in-floor waxes, textile and metal coatings, paint, varnishes, pressure-sensitive adhesives, low temperature caulks, and sealants.

Allyl Methacrylate is water-insoluble, with low volatility clear liquid.
AMA ( Allyl methacrylate ) can be synthesized by the reaction of acrylamide and allyl alcohol under the action of concentrated acid and H2O2. 

AMA ( Allyl methacrylate ) can also be obtained by transesterification of allyl acetate and methyl methacrylate.
AMA ( Allyl methacrylate ) is a very useful starting material for chemical synthesis since it easily undergoes addition reactions with a wide spectrum of organic and inorganic compounds. 

AMA ( Allyl methacrylate ) is used mainly in closed system processing as a co-monomer (rigid plastics) and cross linker (silanes).
AMA ( Allyl methacrylate ) is mainly utilized as a cross-linking agent to increase the hardness of the base material. 

USES:

-Architectural Coatings

-Automotive Coatings

-Construction Coatings

-Industrial Coatings

-Dental Composites

-Optical Polymers

-Photoresists

-UV Inkjet Inks

FEATURES:

-Crosslinking

-Adhesion

-Chemical resistance

-Hardness

-Heat resistance

-Low shrinkage

PHYSICAL PROPERTIES:

-Appearance: colorless

-Physical form: liquid

-Odor: pungent

-Density: 0.930 - 0.940 at 20 °C

-Boiling Point: 144 °C

-Freezing Point: < - 60 °C

-Flash point: 37.8 °C

-Melting Point: < - 60 °C

-Viscosity: 0.72 mPa ･ s at 25 °C

-Vapor Point: 5mmHg at 25 °C

PROPERTIES:

-Melting Point -65 °C

-Boiling Point 59-61 °C43 mm Hg(lit.)

-Flash Point 93 °F

-Molecular Formula C7H10O2

-Molecular Weight 126.15300

-Density 0.938 g/mL at 25 °C(lit.)

SPECIFICATION:

-Melting point: -65 °C

-Color: Clear

-EPA Substance Registry System: AMA ( Allyl methacrylate ) (96-05-9)

-Storage temp.: 2-8°C

-Fp: 93 °F

-Vapor pressure: 4.6 mm Hg ( 20 °C)

-Form: Liquid

-NIST Chemistry Reference: 2-Propenoic acid, 2-methyl-, 2-propenyl ester(96-05-9)

-Density: 0.938 g/mL at 25 °C (lit.)

-Boiling point: 59-61 °C/43 mmHg (lit.)

-Specific Gravity: 0.938

-Water Solubility: 4 g/L (20 ºC)

-refractive index: n20/D 1.436(lit.)

-BRN: 1747406

TECHNICAL INFORMATION:

-Physical State: Liquid

-Storage: Store at 4° C

-Boiling Point: 59-61° C (lit.) at 43 mmHg

-Density: 0.938 g/mL at 25° C (lit.)

-Refractive Index: n20D 1.44 (lit.)

SYNONYM:

Ageflex AMA
allylmethacrylate
2-Propenoic acid, 2-methyl-, 2-propenyl ester
Methacrylic acid, allyl ester
prop-2-enyl 2-methylprop-2-enoate
Allylester kyseliny methakrylove
Methacrylic Acid Allyl Ester
NSC 18597
UNII-G2IG50653Z
prop-2-en-1-yl 2-methylprop-2-enoate
G2IG50653Z
Allyl Methacrylate (stabilized with MEHQ)
DSSTox_CID_1816
DSSTox_RID_76344
DSSTox_GSID_21816
2-Propenoic acid, 2-methyl-, 2-propen-1-yl ester
Allyl 2-methylacrylate
2-Propenoic acid, 2-methyl-, 2-propen-1-yl ester, homopolymer
CAS-96-05-9
25189-05-3
HSDB 5297
EINECS 202-473-0
BRN 1747406
Allylester kyseliny methakrylove 
AI3-37827