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ARMEEN 18D PASTILLES

DESCRIPTION:
Product Line: Surfactants - Cationic and fatty amines
Armeen 18D Pastilles is a distilled octadecylamine.
Armeen 18D Pastilles is a primary amine with an 18 carbon hydrophobic tail. 
Armeen 18D Pastilles is used as a filming amine for mold release and corrosion inhibition applications.
Armeen 18D Pastilles is a distilled, octadecylamine flake derived from vegetable sources. 
Armeen 18D Pastilles is most commonly used as a filming amine but it can also be used as an emulsifier, thickener, and boundary lubricant. 
Armeen 18D Pastilles is well suited as a processing aid for elastomers and provides outstanding mold release properties for rubber manufacturing processes. 
When applied to metal surfaces, Armeen 18D Pastilles forms a protective film that inhibits corrosion and also provides lubrication. 
In addition, Armeen 18D Pastilles can be used as an emulsifier for waxes, pigments, and other hydrophobic materials. 
Armeen 18D Pastilles has broad FDA approvals and can be used in applications that require food contact.

CHEMICAL AND PHYSICAL PROPERTIES OF ARMEEN 18D PASTILLES:    

Amine number: 204 - 211 mg KOH/g
C18 content: 88 - 92 Area%
Color: ≤ 2 Gardner
Iodine value: ≤ 4 g I₂/100 g
Primary Amine: (Mw=269) ≥ 98 %
Secondary + Tertiary Amine: (Mw=521) ≤ 2 %
Water: ≤ 0.5 %
Appearance: White solid
Density: 790 kg/m³ at 60ºC
Flash point: ≥ 150°C
Melting point: 50 - 60°C °C
Odor: Mild ammoniacal
Particle size: 3-5 mm (pastilles)
Viscosity: 7 mPa.s at 60°C
Chemical family: Primary amine
Equivalent weight: 269
Appearance at 25C: Solid
Melting Point (C): 46
Flash Point (C): >150
Vapor Pressure (mm Hg @20C): <0.1
Specific Gravity (C): 0.791(60), 0.784(70)
Chain Length: C18
HLB (Davies Scale 0-40): 8
Viscosity (SSU): 43.5(55), 42.2(65), 39.9(75)
Solubility of H2O% (C): 9.3(65), 7.5(70), 4.0(80)
Specific Heat (BTU/Lb/F): 0.54
pKb in Water: 3.4
Initial Boiling Point (C): 2(166), 8(196), 32(232), 349(760)
Primary Chemistry: Octadecylamine
Storage:
Armeen 18D Pastilles should be stored well below the melting point to maintain the free-flowing form.
Safety and handling:
Upon contact with air reaction of the primary amine with CO₂ can occur giving carbamates and formation of agglomerates.


FEATURES & BENEFITS OF ARMEEN 18D PASTILLES:
Armeen 18D Pastilles is Excellent in mold release applications
Armeen 18D Pastilles Requires lower temperatures
Armeen 18D Pastilles Reduces post mold shrinkage and weight loss and less susceptible to blistering.
Armeen 18D Pastilles Facilitate filler and pigment dispersion in paints and inks: FDA 21 CFR 175.105, 176.210, 173.210, 177.2600, 178.3120, 200.11

Applications OF ARMEEN 18D PASTILLES:
•    Rubber Processing
•    Mold Release
•    Wax Emulsions
•    Pigment Dispersion
•    Hot Melt Adhesives
•    Anti-Corrosion Coatings
•    Metal Coatings


SAFETY INFORMATION ABOUT ARMEEN 18D PASTILLES:
FIRST AID MEASURES:
Description of first aid measures
General Advice If symptoms persist, call a physician. 
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. 
Skin Contact: Wash off immediately with plenty of water for at least 15 minutes. 
If skin irritationpersists,call a physician.
Ingestion: Clean mouth with water and drink afterwards plenty of water. 
Get medical attentionif symptoms occur.
Inhalation Remove to fresh air. 
If not breathing, give artificial respiration. 
Get medical attention if symptoms occur. 
Self-Protection of the First Aider: Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.


FIREFIGHTING MEASURES:
Extinguishing media:
Suitable Extinguishing Media:
Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. 
Special hazards arising from the substance or mixture:
Thermal decomposition can lead to release of irritating gases and vapors. 
Hazardous Combustion Products:
Carbon monoxide (CO), Carbon dioxide (CO2), Sulfur oxides. 
Advice for firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full bprotective gear


ACCIDENTAL RELEASE MEASURES:
Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation. 
Use personal protective equipment as required. 
Avoid dust formation. 
Environmental precautions:
Should not be released into the environment. 
Methods and material for containment and cleaning up:
Sweep up and shovel into suitable containers for disposal. 
Keep in suitable, closed containers for disposal

HANDLING AND STORAGE:
Precautions for safe handling:
Wear personal protective equipment/face protection. 
Ensure adequate ventilation. 
Do not get in eyes, on skin, or on clothing. 
Avoid ingestion and inhalation. 
Avoid dust formation. 
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice. 
Keep away from food, drink and animal feeding stuffs. 
Do not eat, drink or smoke when using this product. 
Remove and wash contaminated clothing and gloves, including the inside, before re-use. 
Wash hands before breaks and after work.
Conditions for safe storage, including any incompatibilities:
Keep in a dry, cool and well-ventilated place. 
Keep container tightly closed.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Control parameters:
Exposure limits:
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by theregionspecific regulatory bodies
Biological limit values:
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specificregulatory bodies
Monitoring methods:
BS EN 14042:2003 Title Identifier: Workplace atmospheres. 
Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. 
MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust.

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