Borane-dimethylamine is used in a nickel-catalyzed reduction of electron-deficient aryl tosylates.
Borane-dimethylamine also serves as a reducing agent in electrolytic deposition of metals, alloys, semiconductors and insulators.
Reagent used in a Ni-catalyzed reduction of electron-deficient aryl tosylates.
CAS: 74-94-2
MF: C2H10BN
MW: 58.92
EINECS: 200-823-7
Synonyms
Borane-dimethylamine complex, 98+%;dimethylamine,compd.withborane(1:1);DimethylamineBorane(DMAB);Dimethylaminoboran;borane, compd. with dimethylamine;dimethylamine, compd. with borane;BORANE-DIMETHYLAMINECOMPLEX(DIMETHYLAMINE-BORANE);Borane, compound with dimethylamine (1:1)
The catalyst is composed of commercially available Ni(PPh3)2Cl2(529621) and PCy3(261971).
Borane-dimethylamine, also known as N-Methylmethanamine, is a reagent that is used in a Ni-catalyzed reduction of electron-deficient aryl tosylates.
Ungraded products are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for human consumption or therapeutic use.
Borane-dimethylamine Chemical Properties
Melting point: 36 °C(lit.)
Boiling point: 59-65°C 12mm
Density: 0,69 g/cm3
Bulk density: 300-350kg/m3
Vapor pressure: <5 hPa (20 °C)
Fp: 110 °F
Storage temp.: Store below +30°C.
Solubility: 120g/l
Form: Flakes or Granules
Color: White to yellow
PH: 8-9 (10g/l, H2O, 20℃)
Water Solubility: 125 g/L (20 ºC)
Sensitive: Air & Moisture Sensitive
Stability: Stable, but water sensitive. Contact with water releases very flammable gases. Incompatible with acids, halogens, oxidizing agents, water.
InChIKey: FTDUHBOCJSQEKS-UHFFFAOYSA-N
CAS DataBase Reference: 74-94-2(CAS DataBase Reference)
NIST Chemistry Reference: Borane-dimethylamine(74-94-2)
EPA Substance Registry System: Borane-dimethylamine(74-94-2)