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Borane morpholine is used in medicine and pharmacology for preparation of antihyperlipimide and resolvent agents.
Borane morpholine is used for preparation of lithium aminoborohydrides, which are air-stable and non-pyrophoric reducing agents.
Borane morpholine is used reduction of imines to amines.
CAS Number: 4856‑95‑5
EC (EINECS) Number: 225‑450‑7
Molecular Formula: C₄H₁₂BNO (morpholine·BH₃)
Molecular Weight: 100.96 g/mol
SYNONYMS:
Morpholineborane, morpholine borane, borane–morpholine complex, borane‑morpholine complex, NSC 93813, borane morphoL, morpholineborohydride, Trihydro(morpholine‑N4)boron, tetrahydro‑p‑oxazine borane, Morpholineborane, NSC 93813, Trihydro(morpholine-N4)boron, Morpholineborane, Trihydro(morpholine-N4)boron, borane;morpholine, (T-4)-Trihydro(morpholine-I masculineN4)boron, morpholineborane, morpholine borane, borane morpholine complex, borane-morpholine complex, c4h12bno, morpholin-boran, borane morpholine, borane, compound with morpholine, boron; morpholine, Borane, compound with morpholine, Morpholine, boron complex, Borane Morpholine coMplex 95%, NSC 93813, Trihydro(morpholine-N4)boron, DIETHYLENE OXIMIDE BORANE, DIETHYLENEIMIDE OXIDE BORANE, Borane morphoL, Borane-morpholine complex, Morpholine-borane, NSC 93813, Morpholineborane, MORPHOLINE BORANE, Morpholine borane, Borane-morpholine complex, Borane morpholine complex, Morpholine, boron complex, TETRAHYDRO-P-OXAZINE BORANE, Trihydro(morpholine-N4)boron, Borane, compound with morpholine
Borane morpholine serves as an efficient reducing agent and is particularly valuable in organic synthesis, where it facilitates the reduction of carbonyl compounds to alcohols.
Its ability to stabilize borane makes Borane morpholine an ideal choice for researchers and industry professionals looking to enhance reaction efficiency and selectivity.
Borane morpholine stands out due to its ease of handling and compatibility with a wide range of substrates, making it a preferred option in laboratories and industrial settings.
Borane morpholine's application in polymer chemistry also highlights its potential in producing advanced materials with tailored properties.
With its broad utility and effectiveness, Borane morpholine is an essential tool for chemists aiming to innovate and optimize their processes.
Borane-morpholine is a solid stabilized borane reagent—valuable in controlled, selective reductions and hydroboration chemistry.
USES and APPLICATIONS of BORANE-MORPHOLINE:
Borane morpholine can be used as reducing agent for aldehydes and ketones.
Borane morpholine is useful in acid media where sodium borohydride is ineffectual because of its instability in acid.
Borane morpholine can be used as a green and efficient reducing agent, mainly used in laboratory research and development and chemical production.
Borane morpholine reduces carbonyl compounds in acidic media.
Borane morpholine is applying metal coatings in PCB production.
Borane morpholine is used in medicine and pharmacology for preparation of antihyperlipimide and resolvent agents.
Borane morpholine is used for preparation of lithium aminoborohydrides, which are air-stable and non-pyrophoric reducing agents.
Borane morpholine is used reduction of imines to amines.
Borane morpholine is used as fogging agents in direct-positive photographic emulsions.
Treatment of polymers to avoid decolouration of Borane morpholinet and undesirable odours.
Borane morpholine isused reduction of cuprum oxide (II) on the surface of metal cuprum to cuprum oxide (I).
Borane morpholine can be used as reducing agent for aldehydes and ketones.
Borane morpholine is useful in acid media where sodium borohydride is ineffectual because of its instability in acid.
Reactant involved in: Borane morpholine is used ethanolysis producing a reducing system.
Borane morpholine is used being a reducing agent for synthesis of Rh nanoparticle / carbon nanotube catalysts.
Borane morpholine is used stereoselective and regioselective reduction of steroidal ketones.
Borane morpholine is used methanolic cleavage.
Additionally, Borane morpholine is utilized in the development of pharmaceuticals and agrochemicals, where precise control over chemical transformations is crucial.
Reducing agent in organic synthesis: Borane-morpholine is used in stereo‑ and regioselective reductions (e.g. aldehydes, ketones, steroidal ketones)
Hydroboration reagent: Borane-morpholine facilitates addition of BH₃ to alkenes → trialkylboranes → alcohols after oxidation
Polymer & materials chemistry: Borane-morpholine is used synthesis of boron‑containing polymers, catalysts (e.g. Rh nanoparticle, carbon nanotube synthesis)
REACTIVITY & APPLICATIONS of BORANE-MORPHOLINE:
Borane-morpholine is a Lewis acid–base adduct of BH₃ stabilized by morpholine.
FUNCTIONS of BORANE-MORPHOLINE:
Functions as a reducing agent, useful for:
*Reducing aldehydes, ketones (including sterols), and select organic functionalities in acid media.
*Ethanolysis reduction systems and nanoparticle catalyst preparation.
*Formulating boron-containing polymers and catalyst precursors.
*Borane morpholine complex is a versatile chemical compound known for its unique properties and applications in various fields.
BENEFITS & PROPERTIES IN USE of BORANE-MORPHOLINE:
*Stabilized borane source:
compared to gaseous BH₃, this adduct is solid, more manageable, easier to weigh and handle
*Selective and mild reactions:
many reductions proceed under milder conditions than strong hydride reagents (e.g. NaBH₄ or LiAlH₄)
*Cleaner by‑products:
morpholine by‑product is volatile and can be removed more easily
PHYSICAL and CHEMICAL PROPERTIES of BORANE-MORPHOLINE:
CAS Number: 4856‑95‑5
EC (EINECS) Number: 225‑450‑7
PubChem CID: 517361
Molecular Formula: C₄H₁₂BNO (morpholine·BH₃)
Molecular Weight: 100.96 g/mol
CAS Registry Number: 4856-95-5
Molecular Formula: C4H12BNO
Molecular Weight: 100.95
EINECS: 225-450-7
Appearance: White crystalline powder
Purity: 99% min
Appearance: White to colorless crystalline powder
Melting Point: 95–99 °C (commonly ~97 °C)
Boiling Point: ~129 °C at 1 atm
Density / Specific Gravity: Not commonly provided
Odor: Slight amine‑like odor
Solubility: Slightly water-soluble; decomposes upon contact with moisture
SMILES: B.C1COCCN1
InChI Key: IFVAHVOGOBRFSP‑UHFFFAOYSA‑N
Molecular Formula: C4H12BNO
Molecular Weight: 100.96
SMILES: B.C1COCCN1
CAS Number: 4856-95-5; 856613-10-0
InChI: InChI=1/C4H9NO.BH3/c1-3-6-4-2-5-1;/h5H,1-4H2;1H3
InChI Key: IFVAHVOGOBRFSP-UHFFFAOYSA-N
CAS Number: 4856-95-5
Purity: ≥ 95% (Assay by titration)
Molecular Formula: C4H12BNO
Molecular Weight: 100.96
MDL Number: MFCD00066736
PubChem ID: 517361
Melting Point: 97 - 99 °C
Appearance: White crystalline powder
Conditions: Store at RT
Assay: 95%
InChI key: IFVAHVOGOBRFSP-UHFFFAOYSA-N
InChI: 1S/C4H9NO.BH3/c1-3-6-4-2-5-1;/h5H,1-4H2;1H3
mp: 97-99 °C (lit.)
Quality Level: 100
Reaction suitability: reagent type: reductant
SMILES string: B.C1COCCN1
CAS: 4856-95-5
Molecular Weight (g/mol): 100.96
MDL Number: MFCD00066736
Synonym: morpholine borane
SMILES: B.C1COCCN1
InChI Key: IFVAHVOGOBRFSP-UHFFFAOYSA-N
Molecular Formula: C4H12BNO
IUPAC Name: morpholine borane
Form: Crystals or powder or crystalline powder
Elemental Analysis: Boron, B: 10.17-11.25% (Theory: 10.71%)
Appearance (Color): White
Assay (special): ≥95.0% (EA)
Elemental Analysis: Nitrogen, N: 13.18-14.57% (Theory: 13.87%)
Elemental Analysis: Hydrogen, H: 11.38-12.58% (Theory: 11.98%)
Elemental Analysis: Carbon, C: 45.21-49.97% (Theory: 47.59%)
Melting Point (clear melt): 92.0-101.0°C
Purity: Min. 95.0 (T)
Size: 5G
Unit: EA
Molecular Formula/Molecular Weight: C4H12BNO=100.96
CAS No: 4856-95-5
Physical State: Solid
Color: White
Melting Point: 97
Condition to Avoid: Moisture Sensitive
Refractive Index: n/a
Specific Gravity: n/a
MDL No: MFCD00066736
SDBS: n/a
MINUM: n/a
PUBCSUB: 87572886
UNSPSC: 12352100
UN No: 2921
Hazard Class: 8
DOT Name: Corrosive solids, flammable, n.o.s.
Pkg Grp: II
TSCA: Yes
Empirical Formula (Hill Notation): C4H12BNO
CAS Number: 4856-95-5
Molecular Weight: 100.96
EC Number: 225-450-7
MDL number: MFCD00066736
UNSPSC Code: 12352005
PubChem Substance ID: 24850854
NACRES: NA.22
Physical state: Chunks
Color: White
Odor: No data available
Melting point/freezing point: Melting point/range: 97 - 99 °C (lit.)
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: No data available
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity:
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: No data available
Partition coefficient: n-octanol/water: No data available
Vapor pressure: No data available
Density: No data available
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information: No data available
CAS Number: 4856-95-5
Molecular Weight: 100.955
Density: N/A
Boiling Point: 128.9 ºC at 760 mmHg
Molecular Formula: C4H12BNO
Melting Point: 97-99 °C (lit.)
MSDS: N/A
Flash Point: -17 ºC
Boiling Point: 128.9 ºC at 760 mmHg
Melting Point: 97-99 °C (lit.)
Molecular Formula: C4H12BNO
Molecular Weight: 100.955
Flash Point: -17 ºC
Exact Mass: 101.101196
PSA: 21.26000
Storage condition: Refrigerator
Water Solubility: MAY DECOMPOSE
CAS: 4856-95-5
EINECS: 225-450-7
InChI: InChI=1/C4H9NO.B.3H/c1-3-6-4-2-5-1;;;;/h5H,1-4H2;;;;/q;+3;3*-1
Molecular Formula: C4H12BNO
Molar Mass: 100.96
Melting Point: 97-99 °C (lit.)
Boiling Point: 128.9 °C at 760 mmHg
Flash Point: 35.6 °C
Water Solubility: MAY DECOMPOSE
Vapor Pressure: 10.4 mmHg at 25 °C
Appearance: solid
Color: White to Almost white
Storage Condition: Refrigerator
Sensitive: Easily absorbing moisture
MDL: MFCD00066736
FIRST AID MEASURES of BORANE-MORPHOLINE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available
ACCIDENTAL RELEASE MEASURES of BORANE-MORPHOLINE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.
FIRE FIGHTING MEASURES of BORANE-MORPHOLINE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.
EXPOSURE CONTROLS/PERSONAL PROTECTION of BORANE-MORPHOLINE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.
HANDLING and STORAGE of BORANE-MORPHOLINE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.
STABILITY and REACTIVITY of BORANE-MORPHOLINE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available
