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BUTYL STEARATE

BUTYL STEARATE

Butyl stearate. It is a fatty acid ester acting as a lubricant. A fatty acid ester that is the butyl ester of stearic acid.

CAS NO: 123-95-5
EC NO: 268-908-1

IUPAC NAME: 
(4-anilino-1-naphthyl){bis[4-(dimethylamino)phenyl]}methanol
butyl octadecanoate
Butyl stearate
n-Butyl Stearate

SYNONYMS:


123-95-5;N-Butyl stearate;Butyl octadecanoate;Octadecanoic acid, butyl ester;Kesscoflex BS;Stearic acid, butyl ester;n-Butyl octadecanoate;Butyl octadecylate;Kessco BS;Stearic Acid n-Butyl Ester;Polycizer 332;Wickenol 122;Witcizer 200;Witcizer 201;Starfol BS-100;Emerest 2325;Tegester butyl stearate;RC plasticizer B-17;Uniflex BYS;Groco 5810;APEX 4;butylstearate;NSC 4820;octadecanoic acid butyl ester;UNII-6Y0AI5605C;6Y0AI5605C;MFCD00026669;BS;Wilmar butyl stearate;FEMA Number 2214;FEMA No. 2214;Fatty acids, C18, Bu esters;HSDB 942;Estrex 1B 54, 1B 55;Stearic acid butyl ester;EINECS 204-666-5;BRN 1792866;n-butylstearate;AI3-00398;(C18) Fatty acid, butyl ester;Kessco BS;Unimate BYS;Uniflex BYS-tech;Oleo-Coll LP;Stearic acid butyl;EINECS 268-908-1;Kemester 5510;Priolube 1451;Witconol 2326;Butyl stearate (NF);ACMC-1BSLH;Radia 7051;Butyl stearate, ~99%;ADK STAB LS-8;Stearic acid-n-butyl ester;SCHEMBL28437;68154-28-9;KSC492E9L;n-Butyl stearate;Butyl stearate;DTXSID5027013;N-Butyl Stearate-Cosmetic Grade;CHEBI:85983;CTK3J2295;FEMA 2214;NSC4820;Butyl stearate, analytical standard;NSC-4820;ANW-18177;LMFA07010795;ZINC60254423;AKOS015901590;KS-0000141Z;BS-14737;FA(22:0);I930;Butyl stearate, technical, 40-60% (GC);DB-041754;FT-0631720;S0077;2783-EP2292593A2;2783-EP2298313A1;2783-EP2311829A1;2783-EP2374792A1;D10681;J-005011;W-204214;Q10442124;n-Butyl stearate (a mixture of stearate and palmitate);Butyl stearate, United States Pharmacopeia (USP) Reference Standard;204-666-5 ;BUTYL OCTADECANOATE;Butyl stearate;Butylstearat ;MFCD00026669 ;Octadecanoic acid, butyl ester ;Stéarate de butyle;stearic acid butyl ester;WI2900000;(3-(Allylcarbamoyl)phenyl)boronic acid;4-04-00-01060 ;ADK STAB LS-8;APEX 4;Butyl octadecylate;butyl stearate, tech.;Emerest 2325;Estrex 1B 54, 1B 55;FEMA 2214;Jsp001599;Kemester 5510;Kessco BS;Kessco BSC;Kesscoflex BS;n-Butyl octadecanoate;N-BUTYL STEARATE;n-butyl stearate 96%;n-Butylstearate;Octadecanoic acid butyl ester;Oleo-Coll LP;Oleoyl sarcosine;Polycizer 332;Priolube 1451;Radia 7051;RC plasticizer B-17;tarfol BS-100;Stearic Acid n-Butyl Ester;Stearic acid, butyl ester;Stearic acid-n-butyl ester;Uniflex BYS;Uniflex BYS-tech;Unimate BYS;Valerohydroxamic acid;Wickenol 122;Wilmar butyl stearate;Witcizer 200;Witcizer 201;Witconol 2326


BUTYL STEARATE

Mol. formula: C22H44O2

Suggested Uses:
1- Acts as a emollient and skin conditioning agent in personal care formulations.
2- Functions as a effective plasticizer in nail varnishes.
3- As a masking agent in fragrances.

Chemical Properties
LOW MELTING SOLID OR LIQUID

Chemical Properties
Butyl stearate has no odor or a faintly fatty odor.

Occurrence
Reported found in fresh apple and boiled mutton.

Uses
Butyl stearate is a stearic acid used in very small quantities in cosmetic preparations as an emulsifier for creams and lotions. It has been shown to cause allergic reactions.

Uses
Solvent, spreading and softening agent in plastics, textiles, cosmetics, rubber industries.

Definition
ChEBI: A fatty acid ester that is the butyl ester of stearic acid.

Preparation
By reacting silver state with n-butyl iodide at 100°C by transesterification of glyceryl tristearate (tristearin) with n-butyl alcohol.

Purification Methods
Acidic impurities are removed by shaking with 0.05M NaOH or a 2% NaHCO3 solution, followed by several water washes, then purified by fractional freezing of the melt and fractional crystallisation from solvents with boiling points below 100o.


APPEARANCE     light yellow liquid or semi-solid
ESTER CONTENT  98.0% min
SAP VALUE      165 -178 (mg KOH/g)
ACID VALUE     0.5 max  (mg KOH/g)
WATER (KF)     0.1% max
IODINE VALUE   2 max
COLOUR, APHA   25 max

Butyl Stearate can be prepared by the reaction of silver stearate with n-butyl iodide at 1 OO°C(11.12) or by the transesterification of glyceryl tristearate (tristearin) with n-butyl alcohol.('2) This ester may also be prepared by the alcoholysis of glycerol stearate (stearin) .

Butyl Stearate, as used in cosmetics, is a liquid mixture of butyl esters consisting of a minimum of 90 percent butyl palmitate and butyl stearate, with lesser amounts of butyl laurate, myristate, pentadecanoate, heptadecanoate, and oleate. 

Butyl Stearate is a stable, colorless, oily liquid. It is resistant to oxidation and undergoes no appreciable degradation when exposed to a temperature of 205°C for 3 hours. At about 19OC, the ester solidifies. Butyl Stearate is slightly soluble to insoluble in water (0.2 percent) and is soluble in acetone, chloroform, ether, alcohol, ketones, ethyl acetate, aromatic and aliphatic hydrocarbons, fats, waxes, mineral oils, and many plasticizer The chemical and physical properties of this compound have been reviewed.

Butyl Stearate is reported to be “compatible” with a number of materials, includ i ng butad iene/styrene rubber, butad ienelacrylonitri le rubber, benzyl cel I ulose, copal esters, cellulose nitrate, cellulose acetate butyrate, cellulose acetate propionate, chlorinated rubber, ester gums, ethyl cellulose, nitrocellulose, polystyrene, and phenolic resins

Butyl Stearate is used as a solvent for dyes in wax polishes, as a spreading and softening agent in plastics, textiles and rubber, as a plasticizer for inks, cellulose acetate butyrate, cellulose nitrate, ethyl cellulose, polystyrene, laminated fiber
products, rubber hydrochloride, chlorinated rubber and cable lacquers, as a lubricant in textiles, molding, metals, and in the extrusion and molding of polyvinylchloride, as a waterproofing agent for concrete, as an emollient in pharmaceuticals, and as an ingredient of carbon paper, inks, and special lubricants and coatings.

USES
*Used as a flavor and solvent for flavors
*as plasticizer for cellulose acetate butyrate, 
*cellulose nitrate, ethyl cellulose,polystyrene,laminated fiber products; 
*as lubricant in extrusion and molding of polyvinyl chloride;
*as emollient in creams, lotions, and lipsticks;
*as solvent, spreading agent, and softening agent in plastics, textiles, cosmetics, and rubber industries;
*to make leather cloth and leather varnishes; in polishes, special lubricants, and coatings; 
*in carbon paper and inks; 
*as damp-proofer for concrete;
*in propellants; as water proofing agent and defoamer.

General description
Butyl stearate is a fatty acid ester, which has application in cosmetics, personal care products, and as an emollient in food industries.

Application
Butyl stearate may be used as an analytical standard for the determination of the analyte in cosmetic products and fruit-based baby foods by various chromatography techniques. It may be used as an internal standard for the determination of fungicides in fruit juice and wine samples by capillary gas chromatography and for the analysis of lysinoalanine in food proteins by gas-liquid chromatography (GLC).

Butyl Stearate is a colorless, oily liquid with several industrial, technical, and cosmetic applications. It is often used in the production of cable lacquers, laminated fiber products, nail varnishes, chlorinated rubber, and PVC copolymers. This version of stearate plasticizers is also used as an emollient in various pharmaceutical or cosmetic products.Like forexample, creams, lotions, and lipstick.


Butyl Stearate is an organic chemical compound belonging to the family of alkyl esters of fatty acids. Butyl stearate is the butyl ester of stearic acid, it is also known by the names such as Octadecanoic acid, Butyl octadecanoate, N-Butyl stearate etc. Butyl Stearate is synthesized by the reaction of stearic acid with butyl alcohol. Butyl stearate has the inimitable properties such as low viscosity and high stability. Owing to its distinguished properties, it forms hydrophobic, non-greasy film when used for skin care. Butyl Stearate is usually in the form of oily liquids or waxy solids. Butyl Stearate is finding its application in various industries as a plasticizer in plastic and polymer processing, as an emollient in cosmetics & personal care products such as skin cream, lotions & lipsticks etc. Butyl Stearate is also gaining significant attraction emulsifying agent or oiling agent in food & beverage industry. Butyl stearate is also finding its applications in spin finishes & textiles, it is also used as lubricants in metalworking, butyl stearate is also used as an additive for Paints and printing inks Butyl stearate can be also used as surfactants and base material for perfumer. Butyl stearate is also gaining attraction as a solvent or oil carriers in agriculture industry.

Title: Butyl Stearate
CAS Registry Number: 123-95-5
CAS Name: Octadecanoic acid butyl ester
Molecular Formula: C22H44O2
Molecular Weight: 340.58
Percent Composition: C 77.58%, H 13.02%, O 9.40%
Line Formula: CH3(CH2)16COOC4H9
Literature References: Prepn from silver stearate and n-butyl iodide: Whitby, J. Chem. Soc. 1926, 1458; from stearic acid and n-butanol: Smith, ibid. 1931, 802. Physical properties: Beilstein vol. 2, Suppl. 3, 1016; Smith, loc. cit.; Ind. Eng. Chem. 32, 880 (1940).
Properties: Crystals from alcohol, propanol, or ether, mp 27°. Also reported as mp 16°. bp 343°. Closed-cup flash pt 160°C (320°F). d2525 0.855-0.875. Slightly sol in water; sol in alcohol, ether.
Melting point: mp 27°; mp 16°
Boiling point: bp 343°
Flash point: flash pt 160°C (320°F)
Density: d2525 0.855-0.875
Use: Solvent, spreading and softening agent in plastics, textiles, cosmetics, rubber industries.

Butyl stearate added as auxiliary agents hardy PVC is widely used in PVC transparent soft board, cable, leather and rolling film. Amount of 5-10%. This product is widely used as an internal lubricant PVC sheet, plate, pipe, pipe fittings, profiles and bottle pellets, shrink film, twist, the amount of 1-3%. As nitrocellulose, ethyl cellulose, plasticizer, when used in coatings, the film can be improved gloss, water resistance and scratch resistance, if this product was dissolved in a solvent-based plasticizer re-use, plasticizing efficiency can be improved. It can also improve polystyrene, vinyl chloride - vinyl acetate copolymer and acrylonitrile-butadiene rubber, and many resins workability and releasability. In addition, the product can be used as a metal foil rolling and spinning lubricants. As a cosmetic additives, as cream. Lipstick products moisturizer. This product is a variety of resin processing lubricant and release agent, widely used in PVC transparent soft and rigid extrusion, injection molding and calendering products and polystyrene products. Also lubricants for metal and fabric, waterproof and lubricants, shoe polish, cosmetic additives. Also be used as nitrocellulose, ethyl fibrous plasticizer and paint film modifier.

It is a highly compatible solvent used in many industrial areas. It is used as a raw material for emulsifiers and lubricating agents in the food industry. In addition, it is found in lubricants, textile chemicals, dye and dye additives, surfactants and perfume-essence ingredients.

Butyl Stearate is used as a solvent, spreading and softening agent in plastics, textiles, cosmetics, rubber industries. Ungraded products supplied by Spectrum are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for human consumption or therapeutic use.

Butyl stearate Cas 123-95-5 - used as finishing agents, lubricants and lubricant additives. Butyl stearate Cas 123-95-5 - used as a plasticizer, food packaging material and as a dye solvent. It acts as a reactant and involved in the preparation of octadecanoic acid methyl ester by reacting with methanol.

Applications:
*Antiperspirants
*Bar Soaps
*Bath Additives
*Deodorants
*Depilatories
*Eye Area Color Cosmetics
*Facial Color Cosmetics
*Facial Skin Care
*Hair Colorants
*Hair Conditioners
*Hand & Body Care
*Lip Care
*Liquid Handsoaps
*Nail Care
*Shaving Products
*Shower Gels/Body Washes
*Styling Aids

Butyl Stearate is a chemical compound which is prepared by reacting stearic acid with an appropriate amount of alcohol. Butyl stearate has the unique properties of low viscosity and is oily in nature. Due to its significant characteristics, Butyl Stearate results in a non-greasy, hydrophobic film when applied to the skin or lips. Butyl Stearate is usually in the form of oily liquids or waxy solids. Its acid value is of maximum 1.0 and the saponification value ranges between 160 to 175. And its specific gravity value is approximately 0.85. To maintain its quality standards, Butyl Stearate is usually stored and maintained away from heat and direct sunlight.

Butyl Stearate has widely being used in various industries. They act as a green chemical alternative to potentially hazardous ingredients, notably personal care, flavor & fragrance, and plastics industries. It acts as an emollient and skin conditioning agent in personal care formulations. It functions as an effective plasticizer in nail varnishes. It also acts as a masking agent in fragrances for the perfume industry. In the metal industry, it has been used as the prime ingredient for cutting oil. Their application includes flavoring, lubrication in plastic production, proofing for concrete production, texturing in ink and in various surfactant systems. Hence these above mentioned critical factors can help drive the demand for Butyl Stearate in various industries, especially in cosmetic industries.

Butyl stearate is an ester of stearic acid and butanol. It is used in the cosmetic industry as a plasticizer in nail varnishes, emollient and skin conditioning agent in personal care formulations, as a masking agent in fragrances. In the food industry, it is used as a flavoring agent and as a defoaming agent in processing beet sugar and yeast.

C17H35COOC4H9 A liquid that solidifies at approximately 19°C; mixes with vegetable oils and is soluble in alcohol and ethers but insoluble in water; used as a lubricant, in polishes, as a plasticizer, and as a dye solvent.A colorless oleaginous material, practically odorless, used as damp-proofing for concrete.

The BUTYL STEARATE molecule contains a total of 68 atom(s). There are 44 Hydrogen atom(s), 22 Carbon atom(s) and 2 Oxygen atom(s). A chemical formula of BUTYL STEARATE can therefore be written as:

C22H44O2

The chemical formula of BUTYL STEARATE shown above is based on the molecular formula indicating the numbers of each type of atom in a molecule without structural information, which is different from the empirical formula which provides the numerical proportions of atoms of each type.

The above chemical formula is the basis of stoichiometry in chemical equations, i.e., the calculation of relative quantities of reactants and products in chemical reactions. The law of conservation of mass dictates that the quantity of each element given in the chemical formula does not change in a chemical reaction. Thus, each side of the chemical equation must represent the same quantity of any particular element based on the chemical formula.

Butyl Stearate is a chemical compound which is prepared by reacting stearic acid with an appropriate amount of alcohol. Butyl stearate has the unique properties of low viscosity and is oily in nature. Due to its significant characteristics, Butyl Stearate results in a non-greasy, hydrophobic film when applied to the skin or lips. Butyl Stearate is usually in the form of oily liquids or waxy solids. Its acid value is of maximum 1.0 and the saponification value ranges between 160 to 175. And its specific gravity value is approximately 0.85. To maintain its quality standards, Butyl Stearate is usually stored and maintained away from heat and direct sunlight.

On the basis of end use, Butyl Stearate market can be segmented into the food industry, beverage industry, cosmetics industry, textile industry, personal care, paper industry and metal industry. The food industry can be further sub-segmented into baked goods, confectionery, desserts, and gelatin. Similarly, beverage industry segment can be further sub-segmented into alcoholic and non-alcoholic beverages. Due to its popularity and large applications in food and cosmetics industry, these two industries holds the largest share in terms of volume sales as compared to other industry.

Butyl Stearate has widely being used in various industries. They act as a green chemical alternative to potentially hazardous ingredients, notably personal care, flavor & fragrance, and plastics industries. It acts as an emollient and skin conditioning agent in personal care formulations. It functions as an effective plasticizer in nail varnishes. It also acts as a masking agent in fragrances for the perfume industry. In the metal industry, it has been used as the prime ingredient for cutting oil. Their application includes flavoring, lubrication in plastic production, proofing for concrete production, texturing in ink and in various surfactant systems. Hence these above mentioned critical factors can help drive the demand for Butyl Stearate in various industries, especially in cosmetic industries.


 

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