BUTYL ZIMATE

Butyl zimate is used as an activator and accelerator in natural and butyl rubber, as well as in natural and synthetic latexes.
Butyl zimate is registered under the REACH Regulation and is manufactured in and/or imported to the European Economic Area, at ≥ 1,000 to < 10,000 tonnes per annum.
Butyl zimate is a dermatological sensitizer and allergen, with sensitivity identified through clinical patch tests.

CAS Number: 136-23-2
EC Number: 205-232-8
Molecular Formula: C18H36N2S4Zn
Molecular Weight: 474.1 g/mol

Synonyms: di-n-Butyldithiocarbamic acid,zinc salt, Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-, Zinc, bis(dibutyldithiocarbamato)-, Aceto zdbd, Bis(dibutyldithiocarbamato)zinc, Butazate, Butazate 50-D, Butyl zimate, Butyl ziram, Carbamic acid, dibutyldithio-, zinc complex, Dibutyldithiocarbamic acid zinc salt, USAF GY-5, Vulcacure, Vulkacit ldb/C, Zimate, butyl, Zinc bibutyldithiocarbamate, Zinc N,N-dibutyldithiocarbamate, Accelerator BZ powder, Butasan, Butasan vulcanization accelerator, Butazin, Nocceler BZ, Octocure ZDB-50, Perkacit ZDBC, Soxinol BZ, ZBC, Zinc bis(dibutyldithiocarbamate), Zinc di-n-butyl dithiocarbamate, bis(dibutyldithiocarbamate)zinc(II), Zinc(II) Dibutyl dithiocarbamate, Zinc bis(dibutyldithiocarbamate), Zinc N,N-dibutylcarbamodithioate, Dibutyldithiocarbamic Acid Zinc(II) Salt, carbamate-BZ, ZDBC (BZ), (Dibutyldithiocarbamato)zinc(II), Accel BZ, Aceto ZDBD, Bis(N,N-dibutyldithiocarbamato)zinc, Bis(dibutyldithiocarbamato)zinc, Butazate, Butazate 50-D, Butyl zimate, Butyl ziram, Carbamic acid, dibutyldithio-, zinc complex, Carbamodithioic acid, dibutyl-, zinc salt, Dibutyldithiocarbamic acid zinc salt, Nocceler BZ, Soxinol BZ, Vulcacure, Vulcacure ZB, Vulkacit LDB, Vulkacit LDB/C, Zimate, butyl, Zinc N,N-dibutyldithiocarbamate, Zinc bis(dibutyldithiocarbamate), Zinc dibutyldithiocarbamate, Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-, Zinc, bis(dibutylcarbamodithioato-kappaS,kappaS')-, (T-4)-, Zinc, bis(dibutyldithiocarbamato)-, [ChemIDplus] ZDBC, [HSDB], Zinc N,N-dibutyldithiocarbamate, Butyl zimate, Di-n-butyldithiocarbamic Acid Zinc Salt, Butasan, Butazate, Butazin, Nocceler BZ, Soxinol BZ, ZBC, Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-, Zinc bis(dibutyldithiocarbamate), NSC-3880, ZINC BIS(DIBUTYLDITHIOCARBAMATE), ZINC DIBUTYLDITHIOCARBAMATE, ZINC DIBUTYLDITHIOCARBAMATE [INCI], ZINC, BIS(DIBUTYLCARBAMODITHIOATO-S,S')-, ZINC, BIS(DIBUTYLDITHIOCARBAMATO)- [HSDB], ZINCDIBUTYLD ITHIOCARBAMATE, 2,6-bis(dibutylamino)-1,3,5,7-tetrathia-4-zincaspiro[3.3]hepta-1,5-diene-1,5-bis(ylium), Accelerator BZ powder, Aceto zdbd, Bis(dibutyldithiocarbamato)zinc, Bis(N,N-dibutylthiocarbamoylthio)zinc, Butasan, Butasan vulcanization accelerator, Butazate, Butazate 50-D, Butazin, Butyl zimate, Butyl ziram, Carbamic acid, dibutyldithio-, zinc complex, di-n-Butyldithiocarbamic acid,zinc salt, Dibutyldithiocarbamic acid zinc salt, Nocceler BZ, Octocure ZDB-50, Perkacit ZDBC, Soxinol BZ, Vulcacure, Vulkacit ldb/C, ZBC, Zimate, butyl, Zinc bibutyldithiocarbamate, Zinc di-n-butyl dithiocarbamate, Zinc dibutyldithiocarbamate, Zinc N,N-dibutyldithiocarbamate, Zinc(II) bis(N,N-diisobutyldithiocarbamate), Zinc, bis(dibutylcarbamodithioato-S,S')-, Zinc, bis(dibutyldithiocarbamato)-, USAF GY-5, (T-4)-Bis(dibutylcarbamodithioato-kappas,kappas')zinc, Bis(dibutyldithiocarbamato)zinc, Dibutyldithiocarbamate zinc salt, Zinc bis(dibutyldithiocarbamate), Zinc bis(dibutyldithiocarbamoyl)disulfide, Zinc bis(dibutyldithiocarbamoyl)disulphide, Zinc bis(dibutylthiocarbamoyl)disulfide, Dibutyldithiocarbamic acid zinc salt, Zinc bis(dibutyldithiocarbamic acid), Zinc bis(dibutylthiocarbamoyl)disulphide, Zinc dibutyldithiocarbamic acid, Zinc di-N-butyldithiocarbamic acid, Butasan, Butazate, Butazin, Butyl Zimate, Butyl Ziram, Nocceler BZ, Soxinol, ZBC, ZDBC, Zinc bis(dibutyldithiocarbamate), Zinc N, N-dibutyldithiocarbamate, Butasan, Butazate, Butazin, Butyl Zimate, Nocceler BZ, Soxinol BZ, ZBC, Zinc dibutyldithiocarbamate, Zinc dibutyldithiocarbamate, 136-23-2, Zinc(II) Dibutyldithiocarbamate, Zinc bis(dibutyldithiocarbamate), zinc;N,N-dibutylcarbamodithioate, DTXSID0021462, Zinc, bis(dibutylcarbamodithioato-kappaS,kappaS')-, (T-4)-, DTXCID501462, Zinc, bis(dibutylcarbamodithioato-.kappa.S,.kappa.S')-, (T-4)-, CAS-136-23-2, Bis(dibutyldithiocarbamato)zinc, zinc bis(dibutylcarbamodithioate), HNM5J934VP, SCHEMBL35745, dibutyldithiocarbamate zinc salt, ZINCDIBUTYLDITHIOCARBAMATE, CHEMBL2373108, BOXSVZNGTQTENJ-UHFFFAOYSA-L, CHEBI:144323, NSC-3880, Tox21_113038, Tox21_202601, NSC-36548, AKOS015839728, zinc bis(dibutylthiocarbamoyl)disulfide, zinc bis(dibutyldithiocarbamoyl)disulfide, Dibutyldithiocarbamic Acid Zinc(II) Salt, NCGC00188440-01, NCGC00260149-01, zinc bis(dibutyldithiocarbamoyl)disulphide, ZINC DIBUTYLDITHIOCARBAMATE [INCI], CS-0152117, D0227, NS00079390, E81950, ZINC, BIS(DIBUTYLCARBAMODITHIOATO-S,S')-, ZINC, BIS(DIBUTYLDITHIOCARBAMATO)- [HSDB], (T-4)-bis(dibutylcarbamodithioato-kappaS,kappaS')zinc, Q27280015, NSC-36548

Butyl zimate is a dithiocarbamate salt that is the zinc salt of dibutyldithiocarbamic acid.
Butyl zimate has a role as an antifungal agrochemical.

Butyl zimate will prevulcanise latex; gives high modulus and transparency.
Butyl zimate has high solubility in rubbers.
Butyl zimate is a chemical compound that forms a complex with fatty acids.

Butyl zimate is found in reaction solutions, where it reacts with hydrochloric acid and boron nitride to form zinc diethyldithiocarbamate.
Butyl zimate is a vulcanization accelerator for natural rubber and latex and a stabilizer for rubber-based adhesive systems, isobutylene-isoprene copolymers and polypropylene.

Butyl zimate is used in a number of rubber and rubber-based materials for food packaging and food handling, e.g. conveyor belts.
Butyl zimate is contact allergens that cross-react in some individuals.
Butyl zimate, like many low-molecular-weight contact allergens, can only trigger an immune response when bound to a protein in the form of an immunogenic protein–hapten complex.

Haptenation of epidermally relevant skin proteins by Butyl zimate has not been reported despite the numerous studies on the disposition and systemic toxicity of Butyl zimate.
Butyl zimate is one of numerous organometallic compounds manufactured.

Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.
Butyl zimate is a white solid with a pleasant odor.

Butyl zimate is a white to cream-colored powder.
Butyl zimate is a dithiocarbamate salt that is the zinc salt of dibutyldithiocarbamic acid.

Butyl zimate has a role as an antifungal agrochemical.
Butyl zimate is a dermatological sensitizer and allergen.

Sensitivity to Butyl zimate may be identified with a clinical patch test.
Butyl zimate is a dithiocarbamate salt and a zinc molecular entity.

Butyl zimate contains a dibutyldithiocarbamate and a zinc(2+).
Butyl zimate is functionally related to a dibutyldithiocarbamic acid.
Butyl zimate is a dermatological sensitizer and allergen.

Sensitivity to Butyl zimate may be identified with a clinical patch test.
Butyl zimate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.

Butyl zimateis used as an activator and accelerator in natural and butyl rubber as well as in natural and synthetic latexes.
Butyl zimate is also used in rubber-based adhesive systems and as a stabilizer in cement.
Further research may identify additional product or industrial usages of Butyl zimate.

Uses of Butyl Zimate:
Butyl zimate is used as an activator and accelerator in natural rubber synthetic latexes.
Butyl zimate is used Antidegradant, and accelerator, natural rubber, butadiene, styrene-butadiene, nitrile-butadiene, butyl rubber, ethylene-propylene-diene terpolymers.

Butyl zimate is used Antioxidant in rubber-based adhesive.
Butyl zimate is used condoms and diaphragms.

Butyl zimate is used cosmetic biocide for skin cleanser and odor prevention.
Butyl zimate is used gloves (household, work, or hospital).

Butyl zimate is used heavy rubber products used in industry.
Butyl zimate is used leather shoes (insoles, adhesives, and linings).

Butyl zimate is used medical devices.
Butyl zimate is used renal dialysis equipment.

Butyl zimate is used rubber in elasticized undergarments and clothing.
Butyl zimate is used rubber pillows and sheets.

Butyl zimate is used rubber shoes (sneakers, tennis shoes, and the like).
Butyl zimate is used sponge makeup applicators and rubber eyelash curlers.

Butyl zimate is used stabilizer in cement.
Butyl zimate is used swim wear.

Butyl zimate is used tires.
Butyl zimate is used Toys.

Butyl zimate belongs to the class of organic compounds known as organic transition metal salts.
These are organic salt compounds containing a transition metal atom in its ionic form.

Butyl zimate is used in Adhesives, Condoms and diaphragms, Disinfectants, repellents, fungicides, and insecticides.
Butyl zimate is used in agriculture, Gloves (household, work, or hospital), Heavy rubber products used in industry, and Leather shoes (insoles, adhesives, linings).

Butyl zimate is used medical devices, Renal dialysis equipment, Rubber in elasticized undergarments and clothing, Rubber pillows and sheets, Rubber shoes (sneakers, tennis shoes, etc.), Soaps and shampoos, Sponge makeup applicators and rubber eyelash curlers, Swim wear, and Tires and toys.
Butyl zimate is used as accelerator (rubber vulcanization, latex dispersions, and cements), ultra-accelerator for lubricating oil additives, and stabilizer in food packaging and handling.

Butyl zimate is used as an absorbent and sample preparation agent in uv spectroscopy.
Butyl zimate is used activator, antidegradant and accelerator for natural rubber, butadiene, styrene-butadiene, nitrile-butadiene, butyl rubber, and ethylene-propylene-diene terpolymers. ICU.

Butyl zimate is a widely used active secondary accelerator for dry rubber.
Butyl zimate can be used as a primary accelerator in latex.
Butyl zimate is used in NR, SBR, NBR, IIR, EPDM and latex industry.

Butyl zimate is used Chemical Synthesis, Plastic, Resin & Rubber, Accelerators, Antioxidants, Polymers, Stabilizer.
Butyl zimate is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Butyl zimate is used in the following products: coating products and adhesives and sealants.
Other release to the environment of Butyl zimate is likely to occur from: indoor use as processing aid and outdoor use as processing aid.

Release to the environment of Butyl zimate can occur from industrial use: of articles where the substances are not intended to be released and where the conditions of use do not promote release.
Other release to the environment of Butyl zimate is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).

Butyl zimate can be found in products with material based on: rubber (e.g. tyres, shoes, toys), plastic (e.g. food packaging and storage, toys, mobile phones) and wood (e.g. floors, furniture, toys).
Butyl zimate is used in the following products: coating products.

Butyl zimate is used in the following areas: building & construction work.
Butyl zimate is used for the manufacture of: furniture.
Other release to the environment of Butyl zimate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use as processing aid.

Butyl zimate is used in the following products: coating products, fillers, putties, plasters, modelling clay, polymers and adhesives and sealants.
Release to the environment of Butyl zimate can occur from industrial use: formulation of mixtures and formulation in materials.

Butyl zimate is used in the following products: adhesives and sealants, coating products and fillers, putties, plasters, modelling clay.
Butyl zimate is used in the following areas: building & construction work.
Butyl zimate is used for the manufacture of: rubber products, textile, leather or fur and machinery and vehicles.

Release to the environment of Butyl zimate can occur from industrial use: in processing aids at industrial sites, as processing aid and in the production of articles.
Release to the environment of Butyl zimate can occur from industrial use: manufacturing of the substance.

Butyl zimate is a vulcanization accelerator for natural rubber and latex and a stabilizer for rubber-based adhesive systems, isobutylene-isoprene copolymers, and polypropylene.

Keywords: di-n-Butyldithiocarbamic acid, zinc salt, Zinc, bis(dibutylcarbamodithioato-S,S')-, (T-4)-, bis(dibutyldithiocarbamato)-, Aceto zdbd, Bis(dibutyldithiocarbamato)zinc, Butazate, Butazate 50-D

Alternative Parents of Butyl Zimate:
Organosulfur compounds
Organopnictogen compounds
Organonitrogen compounds
Hydrocarbon derivatives

Substituents of Butyl Zimate:
Organic transition metal salt
Organic nitrogen compound
Organopnictogen compound
Hydrocarbon derivative
Organosulfur compound
Organonitrogen compound
Aliphatic acyclic compound

Handling And Storage of Butyl Zimate:

Conditions for safe storage, including any incompatibilities:

Storage conditions:
Tightly closed.
Dry.

Stability And Reactivity of Butyl Zimate:

Chemical stability:
Butyl zimate is chemically stable under standard ambient conditions (room temperature).

Possibility of hazardous reactions:
No data available

Conditions to avoid:
no information available

First Aid Measures of Butyl Zimate:

General advice:
Show this material safety data sheet to the doctor in attendance.

If inhaled:
After inhalation:
Fresh air.

In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.

In case of eye contact:

After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.

If swallowed:

After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.

Indication of any immediate medical attention and special treatment needed:
No data available

Fire Fighting Measures of Butyl Zimate:

Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder

Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.

Further information:
Suppress (knock down) gases/vapors/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental Release Measures of Butyl Zimate:

Environmental precautions:
Do not let product enter drains.

Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.

Observe possible material restrictions.
Take up dry.

Dispose of properly.
Clean up affected area.

Exposure Controls/Personal Protection of Butyl Zimate:

Personal protective equipment:

Eye/face protection:
Use equipment for eye protection.
Safety glasses

Skin protection:

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min

Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min

Body Protection:
protective clothing

Respiratory protection:
Recommended Filter type: Filter type P2

Control of environmental exposure:
Do not let product enter drains.

Identifiers of Butyl Zimate:
MDL Number: MFCD00067274
EC Number: 205-232-8
PubChem CID: 5284483
IUPAC Name: Zinc; N,N-dibutylcarbamodithioate
SMILES: CCCCNC(CCCC)C(=S)[S-].CCCCNC(CCCC)C(=S)[S-].[Zn+2]
InChI Identifier: InChI=1S/2C9H19NS2.Zn/c21-3-5-7-10(9(11)12)8-6-4-2;/h23-8H2,1-2H3,(H,11,12);/q;;+2/p-2
InChI Key: BOXSVZNGTQTENJ-UHFFFAOYSA-L
Melting Point: 109°C
Color: White-Yellow
Quantity: 25 g
UN Number: 3077
Formula Weight: 474.12
Percent Purity: ≥98.0% (T)
Physical Form: Crystalline Powder

Chemical Name or Material: Zinc(II) Dibutyldithiocarbamate
Appearance: White powder (estimated)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 104.00 °C @ 760.00 mm Hg (estimated)
Flash Point: 32.00 °F TCC (0.00 °C) (estimated)
CAS registration number: 136-23-2
Unique Ingredient Identifier: HNM5J934VP
Molecular formula: 2C9H18NS2.Zn
International Chemical Identifier (InChI): BOXSVZNGTQTENJ-UHFFFAOYSA-L
SMILES: C([S-])(=S)N(CCCC)CCCC.[Zn+2].C([S-])(=S)N(CCCC)CCCC
Formula: C18H36N2S4Zn
InChI: InChI=1S/2C9H19NS2.Zn/c21-3-5-7-10(9(11)12)8-6-4-2;/h23-8H2,1-2H3,(H,11,12);/q;;+4/p-2

InChIKey: UTKYIUWPTCDQSS-UHFFFAOYSA-L
Molecular Weight: 474.122 g/mol
SMILES: C(N(CCCC)C=1S[Zn]2(SC(N(CCCC)CCCC)=[S+]2)[S+]1)CCC
SPLASH: splash10-05fu-9610500000-14d9eea215477cd6b163
Source of Spectrum: JZ-1992-3347-0
Wiley ID: 1393219
Chemical Formula: C18H36N2S4Zn
Average Molecular Mass: 474.120 g/mol
Monoisotopic Mass: 472.105 g/mol
CAS Registry Number: 136-23-2
IUPAC Name: zinc(2+) ion bis((dibutylcarbamothioyl)sulfanide)
Traditional Name: zinc(2+) ion bis((dibutylcarbamothioyl)sulfanide)
SMILES Representation: [Zn++].CCCCN(CCCC)C([S-])=S.CCCCN(CCCC)C([S-])=S
InChI Identifier: InChI=1S/2C9H19NS2.Zn/c21-3-5-7-10(9(11)12)8-6-4-2;/h23-8H2,1-2H3,(H,11,12);/q;;+2/p-2
InChI Key: BOXSVZNGTQTENJ-UHFFFAOYSA-L

Properties of Butyl Zimate:
Physical State: Powder
Color: White, off-white
Odor: Not available
Melting Point/Freezing Point:
Melting point/range: 104 - 108 °C
Initial Boiling Point and Boiling Range: 318 °C at 1.013 hPa
Flammability (Solid, Gas): Not available
Upper/Lower Flammability or Explosive Limits: Not available
Flash Point: Not available
Autoignition Temperature: Not available
Decomposition Temperature: Not available
pH: Not available
Viscosity:
Kinematic viscosity: Not available;
Dynamic viscosity: Not available
Water Solubility: 0.1 g/l at 25 °C - Insoluble
Partition Coefficient n-Octanol/Water (log Pow): 2.16 at 25 °C

Vapor Pressure: < 0.1 hPa at 25 °C
Density: 1.24 g/cm3 at 20 °C
Relative Density: Not available
Relative Vapor Density: Not available
Particle Characteristics: Not available
Explosive Properties: Not available
Oxidizing Properties: None
Other Safety Information: Not available
Molecular Weight: 474.1 g/mol

Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 4
Rotatable Bond Count: 12
Exact Mass: 472.105276 g/mol
Monoisotopic Mass: 472.105276 g/mol
Topological Polar Surface Area: 72.7 Ų
Heavy Atom Count: 25
Complexity: 112
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 3
Compound Is Canonicalized: Yes

Compound Formula: C18H36N2S4Zn
Molecular Weight: 474.12 g/mol
Appearance: White to very pale yellow powder or crystals
Melting Point: 109°C
Boiling Point: Not applicable (N/A)
Density: Not applicable (N/A)
Solubility in H2O: Insoluble
Exact Mass: 472.105 g/mol
Monoisotopic Mass: 472.105 g/mol
Linear Formula: C18H36N2S4Zn