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BYK P 105

BYK P 105 acts as a wetting and dispersing agent for solvent-borne systems. 
BYK P 105 is a solvent-free, anionic lower molecular weight unsaturated polycarboxylic acid polymer. 
Suitable for medium to high polar systems and particularly effective in preventing flooding of titanium dioxide in combination with other color pigments. 

CAS:    108-31-6
MF:    C4H2O3
MW:    98.06
EINECS:    203-571-6

Synonyms: MALEIC ANHYDRIDE, POWDER, 95%;MALEIC ANHYDRIDE 98+%;MaleicAnhydride>97%;MaleicAnhydrideC4H2O3;MaleicAnhydride(Ma);MALEICANHYDRIDE,REAGENT;2,5-Pyranedione;MALEIC ANHYDRIDE extrapure AR

Offers improved pigment wetting. 
Provides a controlled flocculation of pigments and extenders. 
Prevents flooding / floating and settling, and sagging. 
Enhances protective properties when used in anti-corrosion primers. 
Used in industrial, architectural, wood and furniture, automotive and coil coatings and anti-corrosion systems. 
Also used in amine-neutralized aqueous coatings.
BYK P 105 is an unsaturated polycarboxylic acid polymer and often references maleic anhydride derivative components as a primary raw material/monomer component in its chemical preparation.
BYK P 105 is an organic compound with the chemical formula C4H203. 
BYK P 105 is the acid anhydride of maleic acid and in its pure state it is a colourless or white solid with an acrid odour. 
BYK P 105 is truly a remarkable molecule in that it possesses two types of chemical functionality making it uniquely useful in chemical synthesis and applications.
BYK P 105 is a multifunctional chemical intermediate with applications in several fields of chemical industry. 
BYK P 105's major end use is as feedstock in the production of unsaturated polyester resins (UPR).
These resins are used both in glass-reinforced and in unreinforced applications. 
The UPR end uses includes a wide range of applications in construction, marine and automobile industries.
BYK P 105 is a cyclic dicarboxylic anhydride that is the cyclic anhydride of maleic acid. 
BYK P 105 has a role as an allergen. 
BYK P 105 is a cyclic dicarboxylic anhydride and a member of furans.

BYK P 105 Chemical Properties
Melting point: 51-56 °C (lit.)
Boiling point: 200 °C (lit.)
density: 1.48
bulk density: 700-800kg/m3
vapor density: 3.4 (vs air)
vapor pressure: 0.16 mm Hg ( 20 °C)
refractive index: 1.4688 (estimate)
Fp: 218 °F
storage temp.: Store below +30°C.
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
pka: 0[at 20 ℃]
form: powder
color: White
PH: 0.8 (550g/l, H2O, 20℃)Hydrolysis
Odor: Mild acrid odor.
explosive limit: 1.4-7.1%(V)
Water Solubility: 79 g/100 mL (25 ºC)
Sensitive: Moisture Sensitive
Merck: 14,5704
BRN: 106909
Henry's Law Constant: (atmm3/mol): Not applicable - reacts with water
Exposure limits    ACGIH:TLV-TWA 0.01 mg/m3 (0.0025 ppm),Inhalable fraction and vapor Dermal Sensitizer (DSEN) and Respiratory Sensitizer (RSEN) A4 — Not Classifiable as a Human Carcinogen
OSHA:PEL-TWA 0.25 ppm (1 mg/m3)
NIOSH:REL-TWA 1 mg/m3
Dielectric constant: 51.0(60℃)
Stability: Stable. Combustible. Incompatible with water, strong oxidizing agents, alkali metals, strong bases, amines, most common metals, polymerization catalysts and accelerators.
Cosmetics Ingredients Functions    FILM FORMING
InChI: 1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
InChIKey: FPYJFEHAWHCUMM-UHFFFAOYSA-N
LogP: -2.61 at 20℃
CAS DataBase Reference: 108-31-6(CAS DataBase Reference)
NIST Chemistry Reference: BYK P 105(108-31-6)
EPA Substance Registry System: Maleic anhydride (108-31-6)

Uses    
BYK P 105 is heterocyclic compound used in the manufacture of unsaturated polyester resins. 
BYK P 105 has a wide range of other applications; it is used in synthetic tensides, insecticides, herbicides and fungicides.
BYK P 105 is used in Diels-Alder syntheses (as a dienophile), manufacture of alkyd-type of resins, dye intermediates, pharmaceuticals, agricultural chemicals (maleic hydrazide, malathion), in copolymerization reactions.
Delignified wood esterified by BYK P 105 exhibits higher charge content, superior mass gain, efficient recycling capability of the reaction medium (BYK P 105 could be recycled five times, while TEMPO cannot be recycled), and integrity of the final products (retaining intact geometry vs. complete disintegration) compared to TEMPO-oxidized delignified wood (TEMPO-DW). 
The esterification method mediated by BYK P 105 provides an eco-friendly pathway for modifying wood, serving as a platform for creating diverse materials, potentially offering innovative concepts and insights for wood modification research.

Preparation    
To a flask equipped with a Dean-Stark trap, condenser, and mechanical stirrer is added 116 gm (1.0 mole) of maleic acid and 120 ml of tetrachloroethane. 
The contents are heated, the water (18 ml, 1.0 mole) distilled off as the azeotrope, and the residue distilled under reduced pressure to afford 87.7 gm (89.5%) of the anhydride, b.p. 82-84°C (15 mm), m.p. 53°C. 
The residue remaining in the flask consists of about 10 gm of fumaric acid, m.p. 287°C.
Fumaric and maleic acids both give maleic anhydride on heating. 
Fumaric acid must first be heated to a higher temperature to effect BYK P 105's conversion to maleic acid prior to its dehydration.

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