In the rubber industry, Calcium Salts of Fatty Acids are used as mold-release agents, lubricants, and processing additives.
In pharmaceuticals and cosmetics, Calcium Salts of Fatty Acids may function as tablet lubricants, stabilizers, thickening agents, and consistency regulators.
In powdered products and food applications, certain Calcium Salts of Fatty Acids are used as anti-caking agents to improve powder flow and storage stability.
CAS Number: There is no single CAS number for “calcium salts of fatty acids”.
Representative components include:
Calcium stearate → CAS: 1592-23-0
Calcium palmitate → CAS: 4075-81-4
Calcium oleate → CAS: 25435-02-1
Calcium laurate → CAS: 11064-08-3
EC Number: There is no single EC number for the mixture.
Representative EC numbers:
Calcium stearate → EC: 216-472-8
Calcium palmitate → EC: 223-411-0
Calcium oleate → EC: 247-787-0
Calcium laurate → EC: 234-408-2
Molecular Formula: General structure: (RCOO)2Ca
Where: Ca²⁺ = calcium ion
RCOO⁻ = fatty acid carboxylate (two units per calcium)
Examples:
Calcium stearate: C₃₆H₇₀CaO₄
Calcium palmitate: C₃₂H₆₂CaO₄
Calcium oleate: C₃₆H₆₆CaO₄
Molecular Weight (MW): No single MW exists because composition varies.
Representative values:
Calcium stearate: ~607.0 g/mol
Calcium palmitate: ~591.0 g/mol
Calcium oleate: ~607.0 g/mol
Calcium laurate: ~448.7 g/mol
Typical mixture range: ~450 – 650 g/mol (approx.)
SYNONYMS:
Calcium salts of fatty acids, calcium fatty acid salts, calcium soaps, metallic soaps, calcium carboxylates, calcium alkanoates, calcium stearate, calcium octadecanoate, octadecanoic acid calcium salt, calcium oleate, oleic acid calcium salt, calcium palmitate, hexadecanoic acid calcium salt, fatty acid calcium soaps, calcium surfactants, calcium metallic soaps
Calcium salts of fatty acids, also known as rumen-protected fats or calcium soaps of fatty acids, are compounds formed by reacting free fatty acids with calcium, typically calcium hydroxide.
Calcium Salts of Fatty Acids are used in animal feed formulations as a concentrated energy source.
The manufacturing process involves saponification, where Calcium Salts of Fatty Acids—commonly derived from vegetable oils like palm or soybean oil—are reacted with calcium to produce an insoluble, dry, granular product.
This form allows for easier handling and incorporation into feed and helps prevent rancidity associated with free fats.
Calcium salts of fatty acids, commonly known as calcium soaps, are calcium salts derived from the reaction of calcium ions with fatty acids.
Calcium Salts of Fatty Acids are generally stable, have low solubility in water, and do not readily decompose under normal food storage temperatures.
Calcium Salts of Fatty Acids are regarded as safe when used within regulated limits as they are metabolized similarly to dietary fats.
Calcium salts of fatty acids (also known as "rumen-protected fats" or calcium soaps) are compounds formed by reacting free fatty acids with calcium.
Primarily used as a concentrated energy supplement in livestock diets, Calcium Salts of Fatty Acids bypass ruminal fermentation without disrupting digestion, before being absorbed in the small intestine.
Calcium salts of fatty acids are metallic soaps produced by the reaction of fatty acids with calcium compounds such as calcium hydroxide or calcium oxide.
Calcium Salts of Fatty Acids are generally water-insoluble compounds with excellent lubricating, stabilizing, thickening, and anti-caking properties.
The most common Calcium Salts of Fatty Acids include calcium stearate, calcium palmitate, calcium oleate, and mixed calcium salts derived from vegetable oils, animal fats, or tall oil fatty acids.
Calcium salts of fatty acids belong to the group known as metallic soaps.
Calcium Salts of Fatty Acids are formed by neutralizing long-chain fatty acids with calcium ions.
Due to Calcium Salts of Fatty Acids' hydrophobic structure and high thermal stability, these materials are widely utilized as lubricants, stabilizers, waterproofing agents, release agents, anti-caking additives, and processing aids.
Unlike sodium salts of fatty acids, Calcium Salts of Fatty Acids are generally insoluble in water, which makes them useful in moisture-resistant formulations and waterproof applications.
Calcium Salts of Fatty Acids are commonly manufactured from stearic acid, palmitic acid, oleic acid, or mixed fatty acid streams.
The performance characteristics of Calcium Salts of Fatty Acids depend strongly on the fatty acid chain length, degree of saturation, particle size, purity, and manufacturing process.
Many commercial products are classified as UVCB substances because Calcium Salts of Fatty Acids contain mixtures of fatty acid derivatives from natural sources.
USES and APPLICATIONS of CALCIUM SALTS OF FATTY ACIDS:
Calcium salts of fatty acids are widely used in many industrial sectors because of their lubricating, stabilizing, hydrophobic, and anti-caking properties.
Calcium Salts of Fatty Acids are often used as additives in food processing and as anti-caking agents or flow conditioners in powdered food products.
In the plastics industry, Calcium Salts of Fatty Acids are extensively used as lubricants, acid scavengers, release agents, and heat stabilizers in PVC, polyethylene, polypropylene, and other polymer systems.
Calcium Salts of Fatty Acids improve processing efficiency, reduce friction during extrusion and molding, and prevent materials from sticking to machinery surfaces.
In the rubber industry, Calcium Salts of Fatty Acids are used as mold-release agents, lubricants, and processing additives.
In pharmaceuticals and cosmetics, Calcium Salts of Fatty Acids may function as tablet lubricants, stabilizers, thickening agents, and consistency regulators.
In powdered products and food applications, certain Calcium Salts of Fatty Acids are used as anti-caking agents to improve powder flow and storage stability.
In construction materials, Calcium Salts of Fatty Acids are applied as waterproofing additives in cement, concrete, plaster, and coatings.
Calcium Salts of Fatty Acids' hydrophobic properties help reduce water absorption and improve durability.
Calcium Salts of Fatty Acids are widely used in plastics, lubricants, rubber, pharmaceuticals, food additives, cosmetics, construction materials, and industrial processing.
They are also used in paints, coatings, inks, and greases because of their thickening and stabilizing effects.
In metalworking operations, calcium soaps provide lubrication and corrosion protection.
Calcium Salts of Fatty Acids are additionally utilized in paper processing, textile finishing, mining chemicals, agricultural formulations, and industrial cleaning systems.
Due to their low toxicity, high efficiency, and compatibility with many industrial materials, calcium salts of fatty acids are considered versatile multifunctional additives.
Calcium salts of fatty acids are among the most commercially important metallic soaps used in industrial processing.
Calcium Salts of Fatty Acids' insolubility in water and excellent thermal stability differentiate them from alkali metal soaps such as sodium and potassium fatty acid salts.
Calcium stearate is particularly important in PVC stabilization and plastic lubrication because it neutralizes acidic decomposition products generated during polymer processing.
Calcium oleate and mixed calcium soaps are often used in waterproofing systems and lubricating greases.
-Agricultural & Nutritional Uses of Calcium Salts of Fatty Acids:
Dairy Cattle:
Calcium Salts of Fatty Acids are routinely used in dairy rations to increase the dietary energy density, which improves milk yield and feed efficiency.
Calcium Salts of Fatty Acids can also positively alter the fatty acid profile of the milk.
Beef Cattle:
Supplementation is proven to improve average daily gain (ADG), feed efficiency, and hot carcass weight.
PHYSICAL AND CHEMICAL PROPERTIES of CALCIUM SALTS OF FATTY ACIDS:
• White or cream-colored powder
• Waxy appearance
• Hydrophobic material
• Insoluble in water
• Good thermal resistance
• Excellent lubricating performance
• Anti-caking properties
• Low volatility
• Good chemical stability
• Low odor
• Moisture-resistant
• Good dispersibility
• Surface coating capability
• Foam suppressing characteristics
• Excellent mold-release performance
• Stable under ordinary industrial conditions
• Calcium Salts of Fatty Acids can act as acid scavenger
• Good processing aid properties
• Resistant to hydrolysis under normal conditions
KEY CHARACTERISTICS & PRODUCTION of CALCIUM SALTS OF FATTY ACIDS:
*Manufacturing:
Produced via saponification, where free fatty acids (often derived from palm, soybean, or cottonseed oils) are reacted with calcium oxide or calcium hydroxide.
*Rumen-Inert Properties:
Because Calcium Salts of Fatty Acids form insoluble ionic bonds, they remain largely inert in the neutral pH environment of the rumen.
This prevents Calcium Salts of Fatty Acids from negatively impacting fiber digestion.
*Intestinal Absorption:
When Calcium Salts of Fatty Acids reach the acidic environment of the abomasum (the true stomach, with a pH of ~2.5), the bonds break down, allowing the animal to digest and absorb the fatty acids in the lower gut
BENEFITS of CALCIUM SALTS OF FATTY ACIDS:
• Excellent lubrication properties
• High thermal stability
• Strong water repellency
• Good anti-caking performance
• Effective mold-release capability
• Low toxicity
• Good polymer compatibility
• Calcium Salts of Fatty Acids improve processing efficiency
• Calcium Salts of Fatty Acids reduce friction and wear
• Calcium Salts of Fatty Acids enhance powder flowability
• Environmentally acceptable in many applications
• Moisture-resistant
• Good dispersing ability
• Cost-effective additive system
• Stable during storage and handling
CHARACTERISTICS of CALCIUM SALTS OF FATTY ACIDS:
Calcium salts of fatty acids are highly valued for their lubricating, anti-blocking, anti-caking, hydrophobic, and stabilizing characteristics.
Calcium Salts of Fatty Acids' insolubility in water distinguishes them from sodium soaps and makes them particularly useful in moisture-sensitive systems.
Calcium Salts of Fatty Acids exhibit excellent compatibility with polymers, rubber compounds, powders, and mineral fillers.
Calcium Salts of Fatty Acids also function as acid scavengers and improve processing performance during manufacturing operations.
Calcium Salts of Fatty Acids' metallic soap structure allows them to reduce adhesion between surfaces and improve flow properties in powders and plastics.
Because many Calcium Salts of Fatty Acids are produced from vegetable oils or natural fats, they are often considered environmentally acceptable and relatively low in toxicity.
PHYSICAL and CHEMICAL PROPERTIES of CALCIUM SALTS OF FATTY ACIDS:
Common Commercial Forms
Calcium Stearate
CAS No.: 1592-23-0
EC No.: 216-472-8
Molecular Formula: C36H70CaO4
Molecular Weight: 607.02 g/mol
Calcium Oleate
CAS No.: 142-17-6
EC No.: 205-524-5
Molecular Formula: C36H66CaO4
Molecular Weight: 602.99 g/mol
Calcium Palmitate
CAS No.: 542-05-2
EC No.: 208-798-4
Molecular Formula: C32H62CaO4
Molecular Weight: 550.91 g/mol
Fatty acids, calcium salts
CAS No.: 85251-71-4
EC No.: 286-490-9
Molecular Formula: Variable mixture
Molecular Weight: Variable
Fatty acids, tall-oil, calcium salts
CAS No.: 61790-62-3
EC No.: 263-174-5
Molecular Formula: UVCB mixture
Molecular Weight: Variable
General Appearance: White or off-white powder, granules, flakes, or waxy solid
Odor: Odorless or slight fatty odor
Texture: Waxy, soap-like, smooth powder
Solubility in Water: Insoluble in water
Solubility in Organic Solvents: Slightly soluble in hot alcohols and certain organic solvents
Density: Typically between 1.02–1.15 g/cm³
Melting/Decomposition Point: High thermal stability, generally decomposes at elevated temperatures
Moisture Resistance: Excellent water repellency and hydrophobic behavior
Particle Characteristics: Fine particle size with good dispersibility
Lubricity: Excellent lubricating performance
Volatility: Low volatility under normal conditions
Color: White, cream-colored, or slightly yellowish powder
Foaming Properties: Low foaming characteristics
Surface Properties: Hydrophobic surface coating capability
Thermal Stability: Good resistance to heat and thermal degradation
Flowability: Good powder flow properties
Chemical Nature: Calcium salts of long-chain fatty acids
Chemical Classification: Metallic soaps, calcium carboxylates
Stability: Stable under normal storage and handling conditions
Water Resistance: Highly water-resistant and hydrophobic
Reactivity with Acids: Reacts with strong acids to release free fatty acids
Reactivity with Oxidizers: Incompatible with strong oxidizing agents
Biodegradability: Many grades are biodegradable and derived from renewable sources
Corrosion Characteristics: Generally non-corrosive under standard industrial conditions
Compatibility: Compatible with many polymers, rubbers, coatings, and powders
Acid Scavenging Ability: Can neutralize acidic decomposition products
Lubricating Characteristics: Reduces friction during processing operations
Dispersing Properties: Good dispersing and anti-agglomeration performance
Anti-Caking Properties: Prevents clumping in powder systems
Processing Stability: Maintains stability during extrusion, molding, and blending operations
Hydrolysis Resistance: Resistant to hydrolysis under normal conditions
Combustibility: Combustible at high temperatures or under fire conditions
Decomposition Products: May release carbon oxides and irritating fumes during thermal decomposition
Environmental Characteristics: Low toxicity and environmentally acceptable in many industrial applications
CAS Number: There is no single CAS number for “calcium salts of fatty acids”.
Representative components include:
Calcium stearate → CAS: 1592-23-0
Calcium palmitate → CAS: 4075-81-4
Calcium oleate → CAS: 25435-02-1
Calcium laurate → CAS: 11064-08-3
EC Number: There is no single EC number for the mixture.
Representative EC numbers:
Calcium stearate → EC: 216-472-8
Calcium palmitate → EC: 223-411-0
Calcium oleate → EC: 247-787-0
Calcium laurate → EC: 234-408-2
Molecular Formula: General structure: (RCOO)2Ca
Where: Ca²⁺ = calcium ion
RCOO⁻ = fatty acid carboxylate (two units per calcium)
Examples:
Calcium stearate: C₃₆H₇₀CaO₄
Calcium palmitate: C₃₂H₆₂CaO₄
Calcium oleate: C₃₆H₆₆CaO₄
Molecular Weight (MW): No single MW exists because composition varies.
Representative values:
Calcium stearate: ~607.0 g/mol
Calcium palmitate: ~591.0 g/mol
Calcium oleate: ~607.0 g/mol
Calcium laurate: ~448.7 g/mol
Typical mixture range: ~450 – 650 g/mol (approx.)
FIRST AID MEASURES of CALCIUM SALTS OF FATTY ACIDS:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available
ACCIDENTAL RELEASE MEASURES of CALCIUM SALTS OF FATTY ACIDS:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.
FIRE FIGHTING MEASURES of CALCIUM SALTS OF FATTY ACIDS:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.
EXPOSURE CONTROLS/PERSONAL PROTECTION of CALCIUM SALTS OF FATTY ACIDS:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.
HANDLING and STORAGE of CALCIUM SALTS OF FATTY ACIDS:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.
STABILITY and REACTIVITY of CALCIUM SALTS OF FATTY ACIDS:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available