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COPPER CITRATE

Citric acid, copper salt 

Molecular Formula: C6H8Cu2O7
Molecular Weight: 319.22
CAS Number: 10402-15-0
Linear Formula: Cu2C6H4O7
EC Number:212-752-9

Copper Citrate aids in the absorption of iron, in the formation of red blood cells and the proper bone formation and maintenance.
Copper citrate, also known as cuprocitrol, is an ionic compound of copper and citric acid with the formula Cu3(C6H5O7)2 or Cu3C12H10O14, with a molecular weight of 568.85 g/mol. 
Copper Citrate exists as a seafoam green hemipentahydrate and a sky-blue anhydrous solid.
Copper (citrate) is a dietary supplement that helps activate enzymes that are important to energy metabolism. 
Copper citrate may also facilitate iron absorption to help formulate hemoglobin and red blood cells.
Copper Citrate is generally immediately available in most volumes, including bulk orders. 
 
Description
Green to blue crystals or powder
Copper (citrate) is a dietary supplement that helps activate enzymes that are important to energy metabolism.
Copper Citrate Powder is a green or blue-green crystalline powder, slightly soluble in water, soluble in ammonia and dilute acid, easily soluble in the hot citric acid-alkali solution, soluble in ammonia and dilute acid, slightly soluble in water and cold citrate alkali solution. 
Copper Citrate Powder can be used as a preservative, insecticide, astringent,

Applications
Copper Citrate was used to study the effects of copper on activity and kinetics of free and mineral-immobilized acid phosphatase.
Copper Citrate is used to study the effects of copper on activity and kinetics of free and mineral-immobilized acid phosphatase.
Copper (citrate) – Copper is an essential trace mineral that supports a number of crucial physiological processes.
Copper citrate activates a number of enzymes important to energy metabolism. 
Citric acid, copper salt  is the key mineral in lysyl oxidase, an enzyme that weaves together collagen and elastin. 
Copper assists in the formation of hemoglobin and red blood cells by facilitating iron absorption. 
Citric acid, copper salt is involved in protein metabolism, the production of RNA, and the synthesis of phospholipids used in the formation of myelin sheaths.
Copper Citrate can be used as a dietary ingredient and as a nutrient. 
Copper (citrate) features a highly bioavailable form of the essential trace mineral copper. 
Copper citrate has several important physiological roles including contribution to the protection of cells from oxidative stress and normal function of the immune system.
Essential trace mineral supplement
Citric acid, copper salt helps promote energy metabolism
Citric acid, copper salt  supports numerous physiological processes


Properties
Compound Formula:C12H10Cu3O14
Molecular Weight:568.84
Appearance: Blue to green powder
Melting Point: 350 °C
Boiling Point: N/A
Density    1.667 g/cm3
Solubility in H2O: N/A
Exact Mass: 568.794039
Monoisotopic Mass: 566.795847

Properties (Theoretical)
Compound Formula:C12H10Cu3O14
Molecular Weight:568.84
Appearance: Blue to green powder
Melting Point: 350 °C
Boiling Point: N/A
Density    1.667 g/cm3
Solubility in H2O: N/A
Exact Mass: 568.794039
Monoisotopic Mass: 566.795847

Computed Properties    
Molecular Weight: 319.22    
Hydrogen Bond Donor Count: 4
Hydrogen Bond Acceptor Count:7    
Rotatable Bond Count: 5    
Exact Mass: 317.886197    
Monoisotopic Mass: 317.886197    
Topological Polar Surface Area: 132 Ų
Heavy Atom Count: 15    
Formal Charge:4    
Complexity: 227    
Isotope Atom Count: 0    
Defined Atom Stereocenter Count: 0    
Undefined Atom Stereocenter Count: 0    
Defined Bond Stereocenter Count: 0    
Undefined Bond Stereocenter Count: 0    
Covalently-Bonded Unit Count: 3    
Compound Is Canonicalized: Yes

Chemical Identifiers
Linear Formula: Cu2C6H4O7
MDL Number: N/A
EC No.    212-752-9
Beilstein/Reaxys No.    N/A
Pubchem CID: 6451521
IUPAC Name: tricopper; 2-hydroxypropane-1,2,3-tricarboxylate

Physical Properties:
Assay:    95.00 to 100.00
Boiling Point:    309.60 °C. @ 760.00 mm Hg (est)
Vapor Pressure:    0.000057 mmHg @ 25.00 °C. (est)
Flash Point:    311.00 °F. 

Chemical Properties
Copper citrate is soluble in alkaline citrate solutions.
The hydrated salt will lose its water of crystallization at 100 °C, turning from green to blue.
When heated more strongly, the salt decomposes, leaving behind solid copper particles. 
When heated under vacuum, the resulting residue is claimed to be pyrophoric.

CHEMICAL INFORMATION
Appearance:Blue/Green Powder
Molecular Weight:342.18
Formula:Cu2C6H4O7.1.5H2O
EEC No:212-752-9
Customs Tariff No:2918 15 00

Physical Properties
Copper citrate is a blueish solid, soluble in water.

SPECIFICATIONS & PROPERTIES    
Min. Purity Spec:97%
Physical Form (at 20°C):Green to blue-green powder
Melting Point: >300°C
Long-Term Storage: Store long-term in a cool, dry place

Safety
Copper citrate has low toxicity, though copper ions are harmful if consumed in large quantities.

Storage
Copper citrate should be kept in closed bottles, or air tight sealed ones if you want the anhydrous form.

Disposal
Copper citrate should be disposed of just any other copper compound. 
Which is reduction to metallic copper followed by recycling. 
Although if the amount you hae is very small, you may flush it down the drain with lots of water.


Hazard statement(s)
H315 Causes skin irritation.
H318 Causes serious eye damage.

Precautionary statement(s) 
Prevention
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P264 Wash all exposed external body areas thoroughly after handling.
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. 
Remove contact lenses, if present and easy to do. 
Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Description of first aid measures
Eye Contact: Generally not applicable.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation: If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. 
Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. 
Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

Methods and material for containment and cleaning up
Minor Spills
Clean up all spills immediately.
Secure load if safe to do so.
Bundle/collect recoverable product.
Collect remaining material in containers with covers for disposal.

Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Prevent spillage from entering drains or water ways.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal.
Wash area and prevent runoff into drains or waterways.
If contamination of drains or waterways occurs, advise emergency services.
Clean up all spills immediately.
Wear protective clothing, safety glasses, dust mask, gloves.
Secure load if safe to do so. 
Bundle/collect recoverable product.
Use dry clean up procedures and avoid generating dust.
Vacuum up (consider explosion-proof machines designed to be grounded during storage and use).
Water may be used to prevent dusting.
Collect remaining material in containers with covers for disposal.
Flush spill area with water.

Method for Preparing
Disclosed is a method for preparing copper citrate, comprising the following steps: raw material preparation – preparation of an aqueous citric acid solution – neutralization reaction – material concentration – centrifugal dehydration – drying. 
The present invention prepares a finished product by means of reaction of edible citric acid and copper carbonate or copper oxide, and then material concentration, centrifugal dehydration and drying, without using a catalyst. 
Therefore has a simple process, low energy consumption, no pollution, and low costs.

Alternative Names
Citric acid, copper salt 
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, copper salt
Citrate de cuivre(2+) (2:3) [French]
Copper citrate
Copper(2+) 2-hydroxy-1,2,3-propanetricarboxylate (3:2) 
Copper(2+) 2-hydroxypropane-1,2,3-tricarboxylate (3:2)
dicopper
cuprocitrol
copper(i)citrate
dicopper citrate
Copper(Ⅱ) Citrate
COPPER (II) CITRATE
dicupric citric acid
Copper Citrate Hydrate
2-Hydroxy-1, 2, 3-propanetricarboxylic Acid Copper Salt


 

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