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DIMORPHOLINODIETHYL ETHER

CAS Number: 6425-39-4
EC Number: 229-194-7 
Molecular Weight: 244.33 g/mol
Molecular Formula: C12H24N2O3
IUPAC Name: 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine
DESCRIPTION:
4,4′-(Oxydi-2,1-ethanediyl)bismorpholine (DMDEE) is an amine based catalyst that is also known as dimorpholinodiethyl ether. 
Dimorpholinodiethyl ether can act as a catalyst for blowing reactions and facilitates the process of polymeric curing.
Dimorpholinodiethyl ether is a reactive chemical agent that has been used as a sealant for the insulation and maintenance of joints. 
Dimorpholinodiethyl ether reacts with water vapor or moisture in the air, which causes it to harden. 
Dimorpholinodiethyl ether is also known as DMDE and has been used in analytical chemistry as an optimal reagent for reactions with high resistance. 
Dimorpholinodiethyl ether is a divalent hydrocarbon molecule with two hydroxy groups on its backbone. 
The reaction products of DMDE are viscosity and reaction solution. 
Dimorpholinodiethyl ether can be used in coatings due to its reactivity.


Chemical Structure Description:

A chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together. 
The Dimorpholinodiethyl ether molecule contains a total of 42 bond(s).
There are 18 non-H bond(s), 6 rotatable bond(s), 2 six-membered ring(s), 2 tertiary amine(s) (aliphatic) and 3 ether(s) (aliphatic).
The 2D chemical structure image of Dimorpholinodiethyl ether is also called skeletal formula, which is the standard notation for organic molecules. 
The carbon atoms in the chemical structure of Dimorpholinodiethyl ether are implied to be located at the corner(s) and hydrogen atoms attached to carbon atoms are not indicated – each carbon atom is considered to be associated with enough hydrogen atoms to provide the carbon atom with four bonds.

The 3D chemical structure image of Dimorpholinodiethyl ether is based on the ball-and-stick model which displays both the three-dimensional position of the atoms and the bonds between them. 
The radius of the spheres is therefore smaller than the rod lengths in order to provide a clearer view of the atoms and bonds throughout the chemical structure model of Dimorpholinodiethyl ether.


APPLICATIONS OF DIMORPHOLINODIETHYL ETHER:
Dimorpholinodiethyl ether is Catalyst for flexible polyester foams, molded foams, and moisture-cured foams and coatings. 
Dimorpholinodiethyl ether is Good blowing catalyst that does not cause cross-linking.
DMDEE can be used as a property modifier for 3-nitribenzonitrile (3-NDN) which can be further used in matrix assisted ionization vacuum analysis (MAIV). 
Dimorpholinodiethyl ether can also be used as catalyst for formation of polyurethane foams, adhesives and polypropylene glycol (PPG) incorporated fumed silica.
Dimorpholinodiethyl ether is used as catalysts in order to design the profile of the reactions and the final properties of the product in polyurethane systems. 
The properties needed for different industries can be achieved by using different amine or metal based catalysts.
Dimorpholinodiethyl ether can be used in flexible polyurethane, rigid polyurethane, and elastomer industries.

CAS Number: 6425-39-4
EC Number: 229-194-7 
Molecular Formula: C12H24N2O3

Molecular Weight: 244.33 g/mol
IUPAC Name: 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine


CHEMICAL AND PHYSICAL PROPERTIES OF DIMORPHOLINODIETHYL ETHER:
Assay: 97%
refractive index: n20/D 1.484 (lit.)
bp:309 °C (lit.)
density: 1.06 g/mL at 25 °C (lit.)
PSA:34.2
XLogP3:-0.6
Appearance:Liquid
Density:1.0682 g/cm3 @ Temp: 20 °C
Boiling Point: 176-182 °C @ Press: 8 Torr
Flash Point: 295 °F
Molecular Weight:    244.33    
XLogP3-AA:    -0.6    
Hydrogen Bond Donor Count:    0    
Hydrogen Bond Acceptor Count:    5    
Rotatable Bond Count:    6    
Exact Mass:    244.17869263    
Monoisotopic Mass:    244.17869263    
Topological Polar Surface Area:    34.2 Ų    
Heavy Atom Count:    17    
Formal Charge:    0
Complexity:    172    
Isotope Atom Count:    0    
Defined Atom Stereocenter Count:    0    
Undefined Atom Stereocenter Count:    0    
Defined Bond Stereocenter Count:    0    
Undefined Bond Stereocenter Count:    0    
Covalently-Bonded Unit Count:    1    
Compound Is Canonicalized:    Yes

CAS Number: 6425-39-4
EC Number: 229-194-7 
Molecular Weight: 244.33 g/mol
Molecular Formula: C12H24N2O3
IUPAC Name: 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine

SAFETY INFORMATION ABOUT DIMORPHOLINODIETHYL ETHER:
FIRST AID MEASURES:
Description of first aid measures
General Advice If symptoms persist, call a physician. 
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. 
Skin Contact: Wash off immediately with plenty of water for at least 15 minutes. 
If skin irritationpersists,call a physician.
Ingestion: Clean mouth with water and drink afterwards plenty of water. 
Get medical attentionif symptoms occur.
Inhalation Remove to fresh air. 
If not breathing, give artificial respiration. 
Get medical attention if symptoms occur. 
Self-Protection of the First Aider: Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.


FIREFIGHTING MEASURES:
Extinguishing media:
Suitable Extinguishing Media:
Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. 
Special hazards arising from the substance or mixture:
Thermal decomposition can lead to release of irritating gases and vapors. 
Hazardous Combustion Products:
Carbon monoxide (CO), Carbon dioxide (CO2), Sulfur oxides. 
Advice for firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full bprotective gear


ACCIDENTAL RELEASE MEASURES:
Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation. 
Use personal protective equipment as required. 
Avoid dust formation. 
Environmental precautions:
Should not be released into the environment. 
Methods and material for containment and cleaning up:
Sweep up and shovel into suitable containers for disposal. 
Keep in suitable, closed containers for disposal

HANDLING AND STORAGE:
Precautions for safe handling:
Wear personal protective equipment/face protection. 
Ensure adequate ventilation. 
Do not get in eyes, on skin, or on clothing. 
Avoid ingestion and inhalation. 
Avoid dust formation. 
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice. 
Keep away from food, drink and animal feeding stuffs. 
Do not eat, drink or smoke when using this product. 
Remove and wash contaminated clothing and gloves, including the inside, before re-use. 
Wash hands before breaks and after work.
Conditions for safe storage, including any incompatibilities:
Keep in a dry, cool and well-ventilated place. 
Keep container tightly closed.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Control parameters:
Exposure limits:
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by theregionspecific regulatory bodies
Biological limit values:
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specificregulatory bodies
Monitoring methods:
BS EN 14042:2003 Title Identifier: Workplace atmospheres. 
Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. 
MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust.

CAS Number: 6425-39-4
EC Number: 229-194-7 
Molecular Weight: 244.33 g/mol
Molecular Formula: C12H24N2O3
IUPAC Name: 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine

SYNONYMS OF DIMORPHOLINODIETHYL ETHER:

2,2'-dimorpholinyldiethyl ether
2,2'-Dimorpholinyldiethyl-ether
4,4'-(Oxydi-2,1-ethandiyl)dimorpholin [German] [ACD/IUPAC Name]
4,4'-(Oxydi-2,1-ethanediyl)bismorpholine
4,4'-(Oxydi-2,1-ethanediyl)dimorpholine [ACD/IUPAC Name]
4,4'-(Oxydi-2,1-éthanediyl)dimorpholine [French] [ACD/IUPAC Name]
4,4'-(Oxydiethane-2,1-diyl)dimorpholine
4,4'-(oxydiethylene)bis(morpholine)
4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine
6425-39-4 [RN]
Dimorpholinodiethyl ether
MFCD00072740 [MDL number]
Morpholine, 4,4'-(oxydi-2,1-ethanediyl)bis- [ACD/Index Name]
[6425-39-4] [RN]
2,2'-Dimorpholinodiethyl ether
2,2-DIMORPHOLINODIETHYL ETHER
2,2-dimorpholinodiethylether
2,2'-Dimorpholinodiethylether (en)
2-methyl-1-(4-pyridyl)piperidin-4-one;1-(Pyridin-4-ylmethyl)piperidin-4-one
2-methyl-1-pyridin-4-yl-4-piperidinone
2-morpholin-4-yl-1-(2-morpholin-4-ylethoxy)ethane
4, 4'-(Oxydiethylene)bis[morpholine]
4,4'-(Oxybis(ethane-2,1-diyl))dimorpholine
4,4'-(OXYDIETHYLENE)DIMORPHOLINE
4,4′-(Oxydi-2,1-ethanediyl)bismorpholine
4-{2-[2-(MORPHOLIN-4-YL)ETHOXY]ETHYL}MORPHOLINE
Bis(2-morpholinoethyl) Ether
bis(2-morpholinoethyl) ether (dmdee)
Bis(2-morpholinoethyl)Ether
Bis(morpholinoethyl) ether
BIS[2-(N-MORPHOLINO)ETHYL]ETHER
Bis-morpholino-diethylether
Dimorpholino Diethyl Ether
Morpholine, 4, 4'-(oxydiethylene)di-
Morpholine, 4,4'- (oxydi-2,1-ethanediyl)bis-
Morpholine, 4,4'-(oxydiethylene)di-
N,N'-dibutylcarbamimidothioic acid 2-aminoethyl ester; sulfuric acid
β,β'-Dimorpholinodiethyl ether
β,β'-Dimorpholinodiethyl ether

Depositor-Supplied Synonyms:
6425-39-4

Morpholine, 4,4'-(oxydi-2,1-ethanediyl)bis-

2,2-Dimorpholinodiethylether

Bis(2-morpholinoethyl) Ether

4,4'-(Oxybis(ethane-2,1-diyl))dimorpholine

Dimorpholinodiethyl ether

4,4'-(Oxydiethylene)bis(morpholine)

2,2'-Dimorpholinodiethyl ether

2,2'-Dimorpholinyldiethyl ether

4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine

Bis(morpholinoethyl)ether

UNII-5BH27U8GG4

5BH27U8GG4

4,4'-(Oxydiethylene)bis[morpholine]

Morpholine, 4,4'-(oxydiethylene)di-

2,2'-Dimorpholinyldiethyl-ether

EINECS 229-194-7

NSC 28749

DMDEE

Bis-morpholino-diethylether

EC 229-194-7

DSSTox_CID_22170

DSSTox_RID_79943

DSSTox_GSID_42170

SCHEMBL111438

bis-(2-morpholinoethyl) ether

CHEMBL3187951

DTXSID9042170

4,4'-(Oxydiethylene)dimorpholine

Morpholine,4'-(oxydiethylene)di-

Bis[2-(N-morpholino)ethyl] ether

NSC28749

Tox21_301312

AC-374

MFCD00072740

NSC-28749

ZINC22000396

AKOS015915238

NCGC00255846-01

.beta.,.beta.'-Dimorpholinodiethyl ether

AS-15429

4,4'-(oxydiethane-2,1-diyl)dimorpholine

CAS-6425-39-4

DB-054635

Morpholine,4'-(oxydi-2,1-ethanediyl)bis-

CS-0077139

FT-0636148

4,4'-(3-Oxapentane-1,5-diyl)bismorpholine

Bis(2-morpholinoethyl) ether (DMDEE), 97%

4,4'-(Oxybis(ethane-2,1-diyl))dimorpholine

D78314

4,4'-(Oxydi-2,1-ethanediyl)bismorpholine, 97%

4,4'-(2,2'-oxybis(ethane-2,1-diyl))dimorpholine

Q21034660


 

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