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DIPROPYLENE GLYCOL METHYL ETHER

DIPROPYLENE GLYCOL METHYL ETHER

Di(propylene glycol) methyl ether is an organic solvent with a variety of industrial and commercial uses. It finds use as a less volatile alternative to propylene glycol methyl ether and other glycol ethers. The commercial product is typically a mixture of four isomers.

CAS NO: 34590-94-8
EC NO: 252-104-2

SYNONYMS:
Dipropylene glycol methyl ether;2-(2-methoxypropoxy)propan-1-ol;13588-28-8;1-Propanol, 2-(2-methoxypropoxy)-;2-(2-methoxypropoxy)propanol;2-(2-METHOXYPROPOXY)-1-PROPANOL;2-(2-methoxy-propoxy)-propan-1-ol;Glycol Ether DPM;ACMC-1AH7V;SCHEMBL16073;12002-25-4;Glycol Ether DPM Reagent Grade;dipropyleneglycol monomethyl ether;DTXSID80864425;MFCD19707082;NCGC00090688-04;BS-15252;FT-0625302;31276-EP2272849A1;31276-EP2274983A1;31276-EP2308857A1;31276-EP2308858A1;31276-EP2311816A1;31276-EP2311817A1;31276-EP2371809A1;31276-EP2380568A1;J-019668;J-520393;Q2954819
;1-Propanol, 2-(2-methoxypropoxy)- [ACD/Index Name];2-(2-Methoxypropoxy)-1-propanol [ACD/IUPAC Name];2-(2-Methoxypropoxy)-1-propanol [German] [ACD/IUPAC Name];2-(2-Méthoxypropoxy)-1-propanol [French] [ACD/IUPAC Name];2-(2-Methoxypropoxy)propan-1-ol;252-104-2 [EINECS];34590-94-8 [RN];37286-64-9 [RN];DIPROPYLENE GLYCOL METHYL ETHER;Dipropylene glycol monomethyl ether;Q1Y1&O1Y1&O1 [WLN];(2-Methoxymethylethoxy)propanol;1(or 2)-(2-Methoxymethylethoxy)propanol;1,4-Dimethyl-3,6-dioxa-1-heptanol;2-(2-Methoxypropoxy)propanol;Acrosolve DPM;Arcosolv DPM;Arcosolv DPM (Salt/Mix);Bis(2-(methoxypropyl) ether;BS-15252(PROPYLENE GLYCOL) METHYL ETHER,99%,PURE,MI XTURE OF ISOMERS;Dipropylene glycol monomethyl ether (Salt/Mix);Dipropylene glycol, monomethyl ether;dowanol 50b;Dowanol DPM;Dowanol-50B;DPGME;DPGME (Salt/Mix);Glycol Ether DPM;Glycol Ether DPM Reagent Grade;Glysolv DPM;Kino-red;methoxypropoxypropanol(mixture of isomers);MFCD19707082;OXYBISPROPANOL METHYL ETHER;PPG-2 methyl ether;propan-1-ol, 2-(2-methoxypropoxy)-;Propanol, 1(or 2)-(2-methoxymethylethoxy)-;Ucar solvent 2LM;(2-methoxymethylethoxy)-propano;1-(2-methoxy-1-methylethoxy)-2-propanol;1-(2-methoxyisopropoxy)-2-propanol;(or2)-(2-methoxymethylethoxy)-propano;1(or2)-(2-methoxymethylethoxy)-Propanol;Di(propylene glycol) methyl ether,99%,mixtureof isomers;DPM;DOWANOL(R) DPM

DIPROPYLENE GLYCOL METHYL ETHER

Dipropylene Glycol Methyl Ether is a colourless, viscous, practically non-toxic and slightly hygroscopic liquid; melting point -78 C, boiling point 231 C, specific gravity 1.023. It is a isomer mixture of 1,1'-Oxybis(2-propanol) (cas no.108-61-2), 2-(2-Hydroxypropoxy)-1-propanol (106-62-7) and 2,2'-Oxybis(1-propanol) (110-98-5). Dipropylene glycol Methyl Ether is miscible in water, alcohols, esters and almost organic solvents and various vegetable oils. It is produced during the manufacture of propylene glycol from propylene oxide along with tripropylene glycol and higher glycols. Dipropylene Glycol Methyl Ether is used as a solvent, coupling agent and chemical intermediate. Dipropylene glycol Methyl Ether is used as a component in the production of unsaturated polyester resins, alkyd resins, polyurethane polyols, textile auxiliaries and Dibenzoate plasticisers. It is an ingredient of cutting oils, functional fluids, industrial soaps, agricultural insecticidal formulations, defoamers, cosmetics and fragrances. It is used an additive for carburettor fuels as a lubricant and anti-freezing agent. Dipropylene glycol Methyl Ether is used as a solvent for printing inks, cellulose acetate, nitrocellulose, lacquers and coatings. In the refinery industry, it is used used as an extraction solvent to extract aromatics.Dipropylene Glycol Methyl Ether is a colourless, viscous, practically non-toxic and slightly hygroscopic liquid; melting point -78 C, boiling point 231 C, specific gravity 1.023. It is a isomer mixture of 1,1'-Oxybis(2-propanol) (cas no.108-61-2), 2-(2-Hydroxypropoxy)-1-propanol (106-62-7) and 2,2'-Oxybis(1-propanol) (110-98-5). Dipropylene glycol Methyl Ether is miscible in water, alcohols, esters and almost organic solvents and various vegetable oils. It is produced during the manufacture of propylene glycol from propylene oxide along with tripropylene glycol and higher glycols. Dipropylene Glycol Methyl Ether is used as a solvent, coupling agent and chemical intermediate. Dipropylene glycol  Methyl Ether is used as a component in the production of unsaturated polyester resins, alkyd resins, polyurethane polyols, textile auxiliaries and Dibenzoate plasticisers. It is an ingredient of cutting oils, functional fluids, industrial soaps, agricultural insecticidal formulations, defoamers, cosmetics and fragrances. It is used an additive for carburettor fuels as a lubricant and anti-freezing agent. Dipropylene glycol Methyl Ether is used as a solvent for printing inks, cellulose acetate, nitrocellulose, lacquers and coatings. In the refinery industry, it is used used as an extraction solvent to extract aromatics.

History
Dipropylene glycol methyl ether  is one of the most commonly used propylene glycol ethers in industry and is discussed in a recently published NEG/NIOSH document. Dipropylene glycol methyl ether is a collective term describing a mixture of structural isomers. The method specifies collection of the vapors on activated charcoal, desorption of the charcoal with carbon disulfide, and analysis by GC using flame ionization detection.

Dipropylene glycol methyl ether is used as a solvent for paints, lacquers, resins, dyes, oil/greases, cleaners and cellulose and as a heat-transfer agent. It is frequently used as a substitute for the more toxic DEGME (diethylene glycol methyl ether). 

1.1.4 Physical properties 
 
CAS number:             34590-94-8 (unspecified isomer)
molecular weight:       148.2
melting point:              -80°C
boiling point:               189.6°C
flash point:                  85°C (185°F)
vapor pressure:           0.05 kPa at 25°C
vapor density:             5.14 (air=1)
saturation concentration:510 ppm at 25°C
liquid density:             0.948 (25°C/4°C)
description:                clear, colorless liquid
odor:                          sweet, ether-like
solubility:                   completely miscible with water, VM&P naphtha, acetone, ethanol, benzene, carbon tetrachloride, ether, methanol, monochlorobenzene, and petroleum ether
molecular formula:     C7H16O3
structural formula:     (Note: Dipropylene glycol methyl ether is a mixture of structural isomers. Also, each isomer has two asymmetrical carbon atoms, thus configurational isomers can exist. The numbers in parentheses are approximate percentages by weight of each isomer found in the Dipropylene glycol methyl ether used in this evaluation. The abbreviations in the brackets are used in chromatograms in this method.)

Dipropylene glycol methyl ether  is a clear, colorless, combustible liquid with a slight ether odor. It is completely soluble in water, and has moderate volatility.Dipropylene glycol methyl ether is a propylene oxide-based, or P-series, glycol ether.

What is Dipropylene glycol methyl ether?
Dipropylene glycol methyl ether is a glycol ether based on propylene oxide and methanol. It is a speciality solvent having a bi-functional nature (ether-alcohol). It is a clear liquid with an ether-like odour.

How is Dipropylene glycol methyl ether Used?
It is used as an intermediate and in formulations in industrial, professional or consumer applications. Mainly in surface coatings and printing inks and paints, cleaners and agrochemical formulations. 

Dipropylene glycol methyl ether is not flammable, but a combustible liquid with a flashpoint of 1670.
Dipropylene glycol  methyl ether is of low toxicity towards aquatic organisms. It is completely miscible with water, biodegradable and not expected to bio-accumulate. 

USES
*Dipropylene glycol methyl ether is used in the manufacture of a wide variety of industrial arid commercial
*Products including paints, varnishes, inks and cleaners. 
*Dipropylene glycol  methyl ether is used as a solvent in
*The manufacture of water-based coatings and as a coalescing agent for water-based
*Paints and inks. Dipropylene glycol methyl ether is also an intermediate in the production of dipropylene glycol
*Methyl ether acetate Dipropylene glycol methyl ether. It is widely used in industrial, commercial, automotive and household cleaners. 
*Consumer products containing Dipropylene glycol methyl ether include: glass,
*Surface, and all-purpose cleaners; floor polish and carpet cleaners; paints and
*Paintbrush cleaners; inks and dyes; rust remover and aluminum brightener; and
*Cosmetic agents and their residues in packaging. Most products contain levels of
*Dipropylene glycol methyl ether between 1-10%, although some industrial products may have levels as high as 50%.


Dipropylene glycol methyl ether is a mid-to slow evaporating solvent. This hydrophilic solvent has 100% water solubility and is ideally suited as a coupling agent in a wide range of solvent systems. Dipropylene glycol methyl ether glycol ether has a higher flash point than propylene glycol methyl ether (PM) making it easier to handle, store, and ship. More broadly, its hydrophilic nature makes it an ideal coupling aid in water reducible coatings, and cleaning applications. Dipropylene glycol methyl ether glycol ethers intermediate evaporation rate allow it to be used in a potentially wider range of systems than many other solvents.

USES FOR  Dipropylene glycol methyl ether

*Coupling agent (often in blends) for water-based dilutable coatings.
*Fragrance carrier for reed diffusers
*Active solvent for solvent-based coatings.
*Coupling agent and solvent in household and industrial cleaners, grease and paint removers, metal cleaners, and hard surface cleaners.
*Tail solvent for solvent-based gravure and flexographic printing inks.
*Primary solvent in solvent-based silk screen printing inks.
*Coupling agent in solvent blends for water-based gravure, flexographic, and silk screen printing inks.
*Coupling agent and solvent for vat dyeing fabrics.
*Stabilizer for agricultural herbicides.
*Coalescent for floor polishes and finishes
*Properties of Dipropylene glycol methyl ether:

Formula: CH3O[CH2CH(CH­3)O]2H
CAS No: 34590-94-8
Molar mass: 148.2 g mol-1
Density: 0.951 g/cm, liquid
Boiling Point: 190 C
Viscosity: 3.7 cP at 25 C

Clear colorless liquid with a mild ethereal odor in moderate concentrations. May be a lachrymator as is the chemically related propylene glycol methyl ether.
Dipropylene glycol methyl ether is a clear, colourless liquid with a faint ether-like odour. It is soluble in water and has moderate volatility.
Dipropylene glycol methyl is produced by reacting propylene oxide with methanol using a catalyst. It is a mixture of four structural isomers: 1-(2-methoxypropoxy)propanol-2, 1-(2-methoxy-1-methylethoxy)propanol-1, 2-(2-methoxypropoxy)propanol-1 and 2-(2-methoxy-1-methylethoxy)propanol-1.

Applications of Dipropylene Glycol Methyl Ether
Dipropylene glycol methyl ether is primarily used as a solvent in paints, varnishes, printing inks and strippers and in coatings for automotive and architectural applications, wood and coil coatings and metal finishing. It is also used as a coalescent agent in water-based paints and inks where it serves to promote polymer fusion during the drying process, as a chemical building block for the production of dipropylene glycol monomethyl ether acetate, and as a chemical additive in the oil and drilling industry.
It is found in a wide range of household and industrial cleaners including all-purpose cleaners, glass and other surface cleaners, paint brush cleaners, disinfectants and carpet cleaners. It is also used as a coupling agent in fabric dyes; as a solvent, coupler, emollient and stabilizer in cosmetic products; and as a stabilizer in pesticides and herbicides.

Storage and Handling
Dipropylene glycol methyl ether should be stored in a cool, well-ventilated place away from sources of ignition and static discharge. It must be isolated from incompatible materials such as strong oxidizing and reducing agents, alkali metals and nitrides.
Dipropylene glycol methyl ether is a mild irritant to the skin and eyes. Excessive inhalation may cause irritation to the respiratory tract and drowsiness. Such risks should be managed by engineering controls, adequate ventilation and by the use of approved personal protective equipment including gloves, clothing and safety goggles and the use of respirators where appropriate to the task being carried out. All handling should be carried out in a chemical fume hood.

Uses and Functions
Dipropylene glycol methyl ether is a powerful solvent for a vast range of organic compounds. It is used as a solvent in the manufacture of water-based coatings and Dipropylene glycol methyl ether is also used as a coalescing agent for water based paints and inks. Dipropylene glycol methyl ether is an ingredient in a wide variety of industrial products including cleaning agents, cosmetic agents, detergent/wetting agents, sanitary/disinfectant cleaners, solvent for paints/varnished/inks, and stripper/degreasers. Dipropylene glycol methyl ether  is also used in a wide variety of household and commercial cleaning products including glass, surface, paintbrush, carpet, and all-purpose cleaners, floor polish, industrial degreasers, aluminium brighteners, and rust removers. It is also used in chemicals for the oil production and drilling industry. In the U.S. in 1999, Dipropylene glycol methyl ether  was used as follows: 58% paints/coatings/inks, 28% cleaners, 10% Dipropylene glycol methyl ether  acetate production, and 3 % miscellaneous production .

Dipropylene glycol methyl ether is used in a variety of domestic, commercial, and industrial cleaners. The majority of these products may contain less than 1%-5% Dipropylene glycol methyl ether, however, some products contain as much as 10-25%.

*Chemical Properties
Dipropylene glycol monomethyl ether is colorless liquid with a mild, pleasant odor. Because of its structure it is completely miscible with water and a wide variety of organic substances, and has the combined solubility characteristics of an alcohol, on ether and a hydrocarbon. It is used in formulations of brake fluids, lacquers, paints, varnishes, dye and ink solvents, wood stains, textile processes, dry cleaning soaps and cleaning compounds.*Uses
As solvent for automotive fluids, cleaners, dyes, coatings, inks, waxes, adhesives, agricultural products, insect repellents, and cosmetics; chemical intermediate.

*Uses
Dipropylene glycol methyl ether is often used in combination with propylene glycol in cosmetics.

*Uses
Solvent for nitrocellulose and synthetic resins

*General Description
Colorless liquid with a weak odor .

*Air & Water Reactions
Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Miscible with water.

*Reactivity Profile
Dipropylene glycol methyl ether may react violently with strong oxidizing agents. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. May initiate the polymerization of isocyanates and epoxides.

Trade name: Dipropylene glycol methyl ether
Chemical name of the compound: (2-methoxymethylethoxy)propanol
Synonyms: methoxydipropanol, Dipropylene glycol monomethyl ether.
Chemical and physical properties: Colorless liquid with faint etheric scent, water soluble.
Application: Cleaning agents, agrochemistry.
Health safety: May cause skin irritation and infection. May be harmful to air passages and cause headache and vertigo. May have negative influence on fertility and be harmful for children in the wombs.

Dipropylene glycol methyl ether . It acts as a solvent. Reduces coating temperature, speeds up cohesion and keeps coatings in good condition. Suitable for benzene propylene emulsion, propylene alkene acid emulsion and emulsion paints. Used as anti-ice liquid in soft printing inks and silk printing inks. Applications include electrophoresis paints.
Dipropylene glycol methyl ether  is a clear, colorless liquid with a slight ether odor. Dipropylene glycol methyl ether is completely soluble in water and has moderate volatility.Dipropylene glycol methyl ether is used as a solvent, coupling agent, and coalescing agent. It is often formulated into latex coatings, water reducible coatings, and cleaners. Dipropylene glycol methyl ether is also used as a chemical building block in the manufacture of other products. Some specific applications are household and industrial cleaners, grease and paint removers, metal cleaners, hard surface cleaners, printing ink solvents, fabric dye coupling agents, cosmetics, and herbicide stabilizers.

Dipropylene glycol monomethyl ether (also known as Methoxy Propoxy Propanol, Oxybispropanol, dipropylene glycol methyl ether, DPM, and Dowanol DPM) is a propylene oxide-based, or P series, glycol ether and has the formula C7H16O3. 
It  is a clear, colourless, viscous liquid which has a slight ether odour.  It is completely soluble in water and is miscible with a number of organic solvents, for example, ethanol, carbon tetrachloride, benzene, petroleum ether, and monochlorobenzene.  It is also practically non- toxic, and is hygroscopic, and thus lends itself well to commercial and industrial use.

Uses
Dipropylene glycol methyl ether is a very useful industrial and commercial chemical.  One of its main commercial uses is as a solvent for paints, varnishes, inks, strippers, and degreasers.  It is also utilised as a coalescing agent for water-based paints and inks where it promotes polymer fusing during the drying process.  It is also a component of wood and coil coatings, as well as coatings used in the automotive industry, industrial maintainence, and metal finishing.  It is also a component of hydraulic fluids and industrial degreasers and is a chemical additive in the oil production and drilling industry.

Dipropylene glycol methyl ether  is a useful chemical building block in the manufacture of other products as it reacts with acids to form esters, oxidising agents to form aldehydes or carboxylic acids, alkali metals to form alcoholates, and aldehydes to form acetals.  It is this flexibility that supports the use of Dipropylene glycol methyl ether across a range of industries and Dipropylene glycol methyl ether  is, therefore, a component of many household items that people use every day.  It is found in ceiling and wall paints, and in many common cleaners including glass and surface cleaners, paint-brush cleaners, all-purpose cleaners, carpet cleaners, and disinfectant cleaners.  It is also found in cosmetics where it provides emoillient properties and product stabilisation.  It is also found in floor polish and aluminium polish, leather and textile dyes, rust removers, and pescticides where it acts as a stabiliser.

Dipropylene glycol methyl ether acetate is a clear, colorless to a yellow liquid organic chemical compound with moderate evaporation rate and sweet odor. It is a propylene oxide-based P-series glycol ether acetate. Dipropylene glycol methyl ether acetate is used in an industrial solvent and coalescing agent. As a solvent, dipropylene glycol methyl ether acetate is dissolved in the resins to various typed of surface coatings such as paints, inks, lacquers, among others. Moreover, the common uses of dipropylene glycol methyl ether acetate as household and industrial cleaners, Inks, automotive and industrial coatings, among others. The dipropylene glycol methyl ether acetate consumption is primarily attributing by the growing p-series glycol consumption across the globe. Several factors such as low toxic and safe for health as compared to other propylene glycol ether remains to contribute in the market growth of dipropylene glycol methyl ether acetate across the globe.

Mid-to slow evaporating solvent. Has 100% water solubility and is ideally suited as a coupling agent in a wide range of solvent systems. Has a higher flash point than Dipropylene glycol methyl ether glycol ether making it easier to handle, store, and ship. Often incorporated into latex emulsion coatings; can be used to prevent shocking (coagulation of emulsion) when hydrophobic solvents are used. More broadly, its hydrophilic nature makes Dipropylene glycol methyl ether an ideal coupling aid in water reducible coatings, and cleaning applications. Used with cleaners because they offer an extensive combination of basic physical and performance properties for cleaning formulations. The intermediate evaporation rate allow Dipropylene glycol methyl ether to be used in a potentially wider range of systems than many other solvents.

Uses of Dipropylene glycol methyl ether:
Cleaners, Resins, Coating formulation and application
Industrial, automotive and architectural coatings
Benefits of Dipropylene glycol methyl ether:
Versatile, Wide range of applications, Extensive combination of physical and performance properties

Product Description of Dipropylene glycol methyl ether
Dipropylene glycol methyl ether glycol ether is a mid-to slow evaporating solvent. This hydrophilic solvent has 100% water solubility and is ideally suited as a coupling agent in a wide range of solvent systems. Dipropylene glycol methyl ether glycol ether has a higher flash point than DOWANOL PM glycol ether making it easier to handle, store, and ship. Often incorporated into latex emulsion coatings Dipropylene glycol methyl ether glycol ether can be used to prevent shocking (coagulation of emulsion) when hydrophobic solvents are used. More broadly, its hydrophilic nature makes it an ideal coupling aid in water reducible coatings, and cleaning applications. Dipropylene glycol methyl ether glycol ether’s intermediate evaporation rate allow it to be used in a potentially wider range of systems than many other solvents.

USES of Dipropylene glycol methyl ether
• Coupling agent (often in blends) for water-based dilutable coatings.
• Active solvent for solvent-based coatings.
• Coupling agent and solvent in household and industrial cleaners, grease and paint removers, metal cleaners, and hard surface cleaners.
• Tail solvent for solvent-based gravure and flexographic printing inks.
• Primary solvent in solvent-based silk screen printing inks.
• Coupling agent in solvent blends for water-based gravure, flexographic, and Silk screen, printing inks.
• Coupling agent and solvent for vat dyeing fabrics.
• Mutual solvent, coupling agent, and emollient in cosmetic formulations.
• Stabilizer for agricultural herbicides.
• Coalescent for floor polishes and finishes.
• Features of Dipropylene glycol methyl ether
• Powerful solvency
• Moderate evaporation rate
• Low viscosity
• High dilution ratio
• Low surface tension
• Coupling ability
• Wide range of applications

Dipropylene glycol methyl ether is a dipropylene glycol methyl ether. Used as coupling agent (often in blends) for water-based dilutable coatings, active solvent for solvent-based coatings, tail solvent for solvent-based gravure and flexographic printing inks, primary solvent in solvent- based silk screen printing inks, coupling agent in solvent blends for water-based gravure, flexographic, and silk screen printing inks. Dipropylene glycol methyl ether offers moderate evaporation rate, very good coupling abilities and low viscosity. Dipropylene glycol methyl ether Exhibits high dilution rate and low surface tension.

What is Dipropylene glycol methyl ether?
Dipropylene glycol methyl ether (also known as Methoxy Propoxy Propanol, Oxybispropanol, dipropylene glycol methyl ether, DPM, and Dipropylene glycol monomethyl ether) is a propylene oxide-based/P series glycol ether and has the formula C7H16O3. Dipropylene glycol methyl ether is a clear, colourless, viscous liquid which has a slight ether odour. Dipropylene glycol methyl ether is completely soluble in water and is miscible with a number of organic solvents, for example ethanol, carbon tetrachloride, benzene, petroleum ether and monochlorobenzene. Dipropylene glycol methyl ether is also practically non- toxic and hygroscopic, and thus lends itself well to commercial and industrial use.

How is Dipropylene glycol methyl ether produced?
Dipropylene glycol methyl ether (dipropylene glycol monomethyl ether) is produced by the reaction of propylene oxide with methanol using a catalyst.

How is Dipropylene glycol methyl ether stored and distributed?
Dipropylene glycol methyl ether is stored in mild steel and /or stainless steel tanks and/or drums and can be transported by bulk vessels or tank trucks. Dipropylene glycol methyl ether should be stored away from heat and sources of ignition in a cool and well-ventilated area. Dipropylene glycol methyl ether has a specific gravity of 0.95 and a flashpoint of 75oC (closed cup) and is not regulated for any form of transport.
 

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