PRODUCTS

EMULAN OP 25

Molecular Formula: C26H50O10
Molecular Weight: 522.7

Emulan OP 25
Emulan OP 25 acts as a high-performance oil in water type of emulsifier.
Emulan OP 25 offers stabilization of emulsions, dispersions and latices against thermal, mechanical and chemical effects.
Emulan OP 25 can be used alone or in combination with anionic emulifiers such as Emulphor OPS 25 or with cationic emulsifiers in emulsion polymerization processes.
Emulan OP 25 used in emulsion polymerization processes for many different types of monomer such as acrylic esters, styrene and vinyl compounds (with 1-5% addition level).
Also, Emulan OP 25 used for emulsifying ester waxes and fatty acids (with 5-15% addition level) and disperse systems (with 0.5-5% addition level).

Uses of Emulan OP 25
Special emulsifier for the manufacture of emulsion polymers, especially for vinylacetate or acrylic homopolymers and copolymers.
On account of its chemical composition, EXOSEL OPS 25 combines the advantages of non-ionic and anionic emulsifiers, and can therefore be used as the sole emulsifier for emulsion polymerization.
Composition Alkyl aryl polyglycol ether sulphate, sodium salt
Specification Anionic surfactant 29 - 31 %
Sodium chlorid < 0.5 %
Sodium sulphate < 1.0 %
pH-value (5 %) 7.0 - 8.0
Solid content Min 29%

Use Special emulsifier for the manufacture of emulsion polymers, especially for vinylacetate or acrylic homopolymers and copolymers.
On account of its chemical composition, EXOSEL OPS 25 combines the advantages of non-ionic and anionic emulsifiers, and can therefore be used as the sole emulsifier for emulsion polymerization.
Composition Alkyl aryl polyglycol ether sulphate, sodium salt Specification Anionic surfactant 29 - 31 %
Sodium chlorid < 0.5 %
Sodium sulphate < 1.0 %
pH-value (5 %) 7.0 - 8.0
Solid content Min 29%

Computed Properties of Emulan OP 25
Molecular Weight: 522.7
XLogP3-AA: 2.5
Hydrogen Bond Donor Count: 3
Hydrogen Bond Acceptor Count: 10
Rotatable Bond Count: 26
Exact Mass: 522.34039779
Monoisotopic Mass :522.34039779
Topological Polar Surface Area: 133 Å²
Heavy Atom Count: 36
Formal Charge: 0
Complexity: 507
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 4
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Chemical nature of Emulan OP 25
Emulan OP 25 types are nonionic surfactants.
Emulan OP 25 are made from a saturated iso-C13 alcohol.
Emulan OP 25 conform to the following structural formula.
RO(CH2CH2O)xH
R = iso-C13 H27
x = 3, 5, 6, 6.5, 7, 8, 10, 12, 15 or 20
The numeric code in the product name indicates the degree of ethoxylation.
Emulan OP 25 consists of ca. 90
Emulan OP 25and ca. 10 % water.
Emulan OP 25 consists of ca. 85
Emulan OP 25 and ca. 15 % water.
Emulan OP 25 consists of ca.
Emulan OP 25 and ca. 15 % water.
Emulan OP 25 is a special mixture of Lutensol TO 3 and Lutensol TO 8
with an active content of ca. 90 % and a water content of ca. 10 %.
Emulan OP 25 is a mixture of Lutensol TO 5 and Lutensol TO 65.
Classification according to German chemicals legislation based on EU.
Directive 67/548/EEC
(8) = Harmful
(10) = Irritant

Emulan OP 25 types are manufactured by causing the iso-C13 oxo alcohol to react with ethylene oxide in stoichiometric proportions.
The ethoxylation temperature is kept as low as possible.
This, combined with the high purity of the feedstocks, ensures that high-performance products with low toxicity are obtained.

Properties of Emulan OP 25
Emulan OP 25 is cloudy liquids at 23 °C, which tend to form a sediment.
They become clear at 50 °C.
Emulan OP 25 is clear liquids at 23 °C.
Emulan OP 25 is soft, slightly yellowish pastes.

Applications of Emulan OP 25
The Emulan types can be used to prepare oil-in-water and water-in-oilemulsions.
Individual products can usually be classified as being oil-in-water or water-in-oil emulsifiers, but it is often difficult to allocate combina-tions of different emulsifiers to either of these categories.
Emulan OP 25 is also difficultto categorize emulsions that deviate from the norm in that, for instance,they consist of more than two phases.
Some of the products in the Emulan range can also be used to dispersesolids such as waxes, polymers or rubber latex in water, and to stabilizeaqueous dispersions.
Dispersions of this type are employed as impregnat-ing resins, lubricants, polishes and protective coatings, and they can beused to dedust powders.
The choice of emulsifier plays a large part in determining the stability ofemulsions.
The nature of the hydrophilic and lipophilic components of theemulsifier molecule and the proportions of hydrophilic and lipophilicgroups determine their performance and the applications open to them.
Oil-in-water emulsions are usually obtained if the emulsifier molecule ispredominantly hydrophilic, and water-in-oil emulsions are obtained if theemulsifier molecule is predominantly hydrophobic

The ratio between the two parts of the molecule is expressed by thehydrophilic lipophilic balance (HLB).
The hydrophilic lipophilicbalance is a useful practical guide to the applications open to differentemulsifiers, but the final choice of emulsifier always depends on the resultsof practical tests in the laboratory.
The usual method is to use a combination of two or more emulsifiers,because this approach offers greater scope.
The Emulan types have theadvantage that they are compatible with each other, with cationic andanionic emulsifiers, and with many other substances.
Emulsions preparedwith emulsifiers from the Emulan range are largely insensitive to variationsin temperature.
They are largely unaffected by the presence of soil and, toa lesser extent, electrolytes.
As with all other nonionic emulsifiers, the performance of the Emulan typescan be affected by tannins, other substances of a phenolic nature, andcomplex acids such as phosphotungstic acid and its salts.

Product Information of Emulan OP 25
Application ID: 2393/KOLNP/2009
Invention Field CHEMICAL
Date of Application: 2009-06-29
Publication Number: 29/2009
Publication Type: INA
Ipc Classification. C10M 169/04
International Application No: PCT/US2007/087143
International Filing Date: 2007-12-12
Priority Country: EUROPEAN UNION
Priority Date: EUROPEAN UNION06025688.0
Examination Date: 2010-12-08

Pharmacology and Biochemistry of Emulan OP 25
MeSH Pharmacological Classification
Excipients
Usually inert substances added to a prescription in order to provide suitable consistency to the dosage form.
These include binders, matrix, base or diluent in pills, tablets, creams, salves, etc.

Medical Subject Headings
Surface-Active Agents
Agents that modify interfacial tension of water; usually substances that have one lipophilic and one hydrophilic group in the molecule; includes soaps, detergents, emulsifiers, dispersing and wetting agents, and several groups of antiseptics.

Uses of Emulan OP 25
EMULSIFIER IN COSMETICS, TEXTILE FINISHES, & BAKED GOODS
IN OINTMENTS /POLYETHYLENE GLYCOL OINTMENT WITH SORBITAN MONOPALMITATE/
SURFACTANT; DISPERSING AGENTS; SHORTENINGS & BAKED GOODS; FLAVORING AGENTS; FOAMING & DEFOAMING AGENTS /POLYSORBATE/
EMULSIFIERS IN FEEDS, MILK REPLACERS, PESTICIDES, VITAMINS, PARENTERALS, VACCINES, ORAL PHARMACEUTICALS, INTRAMAMMARY & ASSORTED TOPICALS /POLYSORBATES/

Depositor-Supplied Synonyms of Emulan OP 25
Emulan OP 25
POLYOXYETHYLENE SORBITAN MONOPALMITATE
9005-66-7
2-[(2R)-2-[(2R,3R,4R)-3,4-bis(2-hydroxyethoxy)oxolan-2-yl]-2-(2-hydroxyethoxy)ethoxy]ethyl dodecanoate
Crillet 2
Glycosperse p-20
Crill 7
Durfax 60
Radiasurf 145
Emsorb 6910
Polyoxyethylene 20 sorbitan monopalmitate
Tween(R) 40
Nissan Nonion PT-221
UNII-4NR71FN0IA
UNII-STI11B5A2X
4NR71FN0IA
Sorbimacrogol palmitate 300
STI11B5A2X
CCRIS 701
Sorbitan polyethoxy monopalmitate
HSDB 1928
Ethoxylated sorbitan monopalmitate
Sorbitan, monohexadecanoate, poly(oxy-1,2-ethanediyl) derivs.
Polysorbate 40 [USAN:INN:BAN:NF]
Polyethylene glycol sorbitan monopalmitate
Polyoxyethylene (80) sorbitan monopalmitate
Sorbitan, monopalmitate polyoxyethylene deriv.
Sorbitan monopalmitate polyethylene glycol ether
Sorbitan, monopalmitate, polyoxyethylene derivs
Polyethylene glycol (80) sorbitan monopalmitatey
Polyethylene glycol-sorbitan monopalmitate adduct