PRODUCTS

IONOL 75

IONOL 75 is 2, 6-ditert-butyl (1, 1-dimethylethyl)-4-methylphenol.
IONOL 75 is an antioxidant with a good cost performance ratio for the use in refinery streams, gasoline and aviation fuels.
IONOL 75 is 100% active antioxidant and is a mixture of butylated phenols which contains a minimum of 75% 2,6-di-tert.-butylphenol and a maximum of 25 % other butylated phenols.

CAS Number: 128-39-2
EC Number: 204-884-0
IUPAC Name: 2,6-Di-tert-butylphenol
Chemical Formula: C14H22O

Other names: 2,6 Di T Butyl 4 Methylphenol, 2,6 Di Tert Butyl 4 Methylphenol, 2,6 Di Tert Butyl P Cresol, 2,6-bis(1,1-dimethylethyl)-4-methylphenol, 2,6-di-t-butyl-4-methylphenol, 2,6-di-tert-butyl-4-methylphenol, 2,6-di-tert-butyl-p-cresol, 4 Methyl 2,6 Ditertbutylphenol, 4-methyl-2,6-ditertbutylphenol, Bht, Butylhydroxytoluene, Di Tert Butyl Methylphenol, Di-tert-butyl-methylphenol, Dibunol, Hydroxytoluene, Butylated, Ionol, Ionol (bht), 2,6-di-tert-butyl-4-methylphenol, 128-37-0, Butylhydroxytoluene, 2,6-di-tert-butyl-p-cresol, 2,6-di-t-butyl-4-methylphenol, Ionol, Bht, Dbpc, Dibunol, Stavox, Ionol Cp, Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-, Impruvol, Kerabit, Topanol, Dalpac, Deenax, Ionole, Vianol, Antioxidant Kb, 3,5-di-tert-butyl-4-hydroxytoluene, 2,6-ditert-butyl-4-methylphenol, Antioxidant 4k, Sumilizer Bht, Topanol O, Topanol Oc, Vanlube Pc, Antioxidant Dbpc, Sustane Bht, Tenamene 3, Vanlube Pcx, Antioxidant 29, Antioxidant 30, Nonox Tbc, Tenox Bht, Chemanox 11, Ionol 1, Agidol, Catalin Cao-3, Advastab 401, Ionol (antioxidant), Buks, Parabar 441, Paranox 441, 2,6-di-tert-butyl-4-cresol, Catalin Antioxydant 1, Antrancine 8, Butylated Hydroxytoluol, Vulkanox Kb, Di-tert-butyl-p-cresol, 2,6-bis(1,1-dimethylethyl)-4-methylphenol, Dibutylated Hydroxytoluene, Ional, Ao 4k, Cao 1, Cao 3, Di-tert-butyl-p-methylphenol, Fema No. 2184, O-di-tert-butyl-p-methylphenol, 4-methyl-2,6-tert-butylphenol, 2,6-di-tert-butyl-1-hydroxy-4-methylbenzene, 2,6-di-tert-butyl-p-methylphenol, Ao 29, Nci-c03598, 2,6-ditert-butyl-4-methyl-phenol, 2,6-di-t-butyl-p-cresol, 4-methyl-2,6-di-tert-butylphenol, Butyl Hydroxy Toluene, 2,6-di-terc.butyl-p-kresol, 4-hydroxy-3,5-di-tert-butyltoluene, P 21, Bht(food Grade), 4-methyl-2,6-di-terc. Butylfenol, 2,6-di-tert-butyl-4-methyl-phenol, 1-hydroxy-4-methyl-2,6-di-tert-butylbenzene, Di-tert-butylcresol, Dbpc(technical Grade), E321, P-cresol, 2,6-di-tert-butyl-, Nsc-6347, Chembl146, 2,6-ditertiary-butyl-p-cresol, Ins No.321, Chebi:34247, Ins-321, 1p9d0z171k, Butylated Hydroxytoluene (e 321), 2,6-di-tert-butyl-4-methyl Phenol, Ncgc00091761-03, Tonarol, Dsstox_cid_216, Antioxidant Mpj, E-321, Antioxidant 4, Toxolan P, Alkofen Bp, Swanox Bht, Tenamen 3, Antox Qt, Antioxidant 264, Dsstox_rid_75440, Agidol 1, Dsstox_gsid_20216, Bht (food Grade), Butylated Hydroxytoluene (nf), Antioxidant T 501, Nocrac 200, Butylated Hydroxytoluene (bht), Caswell No. 291a, Dbpc (technical Grade), Butylated Hydroxytoluene [nf], Annulex Bht, Aox 4k, Aox 4, Butylhydroxytoluenum, Mfcd00011644, Cas-128-37-0, Butylohydroksytoluenu, Ccris 103, Butylohydroksytoluenu [polish], Ionol Cp-antioxidant, Di-tert-butyl-p-cresol (van), Hsdb 1147, Bht 264, Nsc 6347, Einecs 204-881-4, 2,6-di-terc.butyl-p-kresol [czech], Epa Pesticide Chemical Code 022105, 2,6-di-tert-butyl-4-methylhydroxybenzene, Popol, Unii-1p9d0z171k, Ai3-19683, 4-methyl-2,6-di-terc. Butylfenol [czech], Lowinox Bht, Nipanox Bht, Bht Swanox, Bht, Food Grade, 4-methyl-2,6-di-t-butyl-phenol, Ionol Bht, Ralox Bht, 2, Food Grade, Butylated Hydroxytoluene [ban:nf], 3im, Dibutyl-para-cresol, 2,6-bis(tert-butyl)-4-methylphenol, Butylated-hydroxytoluene, Spectrum_001790, Bht Fcc/nf, Specplus_000768, Methyldi-tert-butylphenol, Spectrum3_001849, Spectrum5_001612, Bht [inci], Hydagen Deo (salt/mix), Bht [fcc], Ec 204-881-4, 2,6-di-butyl-para-cresol, 2.6-di-t-butyl-p-cresol, Schembl3950, 2,6-ditert-butyl-p-cresol, P-cresol,6-di-tert-butyl-, Di-tert-butylparamethylphenol, Bspbio_003238, Kbioss_002281, 2,6-di-tert.butyl-p-cresol, Di-tert-butyl-4-methylphenol, Mls000069425, Bidd:er0031, Divk1c_006864, Spectrum1600716, 2,6-bis-tert-butyl-p-cresol, 2,6-di-tert-butyl-paracresol, Bht (butylated Hydroxytoluene), 2,6-di-tert. Butyl-p-cresol, 2,6-di-tert.-butyl-p-cresol, 2,6-di-tert-butyl-para-cresol, 2,6-di-tert-butyl-methylphenol, 2,6-ditertbutyl-4-methylphenol, Dtxsid2020216, 2,6-di-t Butyl-4-methylphenol, 2.6-di-t-butyl-4-methylphenol, Fema 2184, Kbio1_001808, Kbio2_002280, Kbio2_004848, Kbio2_007416, Kbio3_002738, 2,6-di-tert-butyl-4-methylenol, 2,6-di-tert-butyl-4methylphenol, 2,6-di-tert-butyl4-methylphenol, 2,6-di-tertbutyl-4-methylphenol, 2,6-ditert.butyl-4-methylphenol, Butylated Hydroxyl Toluene (bht), Nsc6347, 2,6-di(tert-butyl)hydroxytoluene, 2,6-di(t-butyl)-4-methylphenol, 2,6-di-t- Butyl-4-methylphenol, 2,6-di-t-butyl 4-methyl Phenol, 2,6-di-t-butyl-4-methyl Phenol, 2,6-di-t-butyl-4-methyl-phenol, 3,5-di-t-butyl-4-hydroxytoluene, Hms2091e21, Hms2231m22, Hms3369g17, Hms3750m21, Pharmakon1600-01600716, 2,1-dimethylethyl)-4-methylphenol, 2,6-di-tert-butyl 4-methylphenol, 2,6-di-tert-butyl-4 Methylphenol, 2,6-di-tert-butyl4-methyl Phenol, 2,6-di-tert.butyl-4-methylphenol, 2,6-ditert.-butyl-4-methylphenol, 2.6-di-tert-butyl-4-methylphenol, 4-methyl-2,6-di-tert.butylphenol, 2,6-di-ter-butyl-4-methyl-phenol, 2,6-di-tert.-butyl4-methylphenol, 2,6-ditertiarybutyl-4-methylphenol, 2.6-di- T-butyl- 4-methylphenol, Amy40200, Hy-y0172, Str04334, Zinc1481993, 2,6 -di-tert-butyl-4-methylphenol, 2,6-di(tert-butyl)-4-methylphenol, 2,6-di-tert-butyl-p-cresol, 8ci, 2,6-di-tert.-butyl-4-methylphenol, Tox21_113537, Tox21_201093, Tox21_303408, 2,6-di-tert-butyl-p-cresol (bht), 2,6-di-tert-butyl-para-methylphenol, Bdbm50079507, Butylated Hydroxytoluene [ii], Butylated Hydroxytoluene [mi], Nsc759563, S6202, Stl277184, 2,6-di-tert. Butyl-4-methyl Phenol, 2,6-di-(tert-butyl)-4-methylphenol, Akos000269037, Tox21_113537_1, Butylated Hydroxytoluene [fhfi], Butylated Hydroxytoluene [hsdb], Butylated Hydroxytoluene [inci], Butylated Hydroxytoluene [jkdm], Butylated Hydroxytoluene [vii], Butylated Hydroxytoluene [wme], Butylated Hydroxytoluene [wpf], Gtpl3439, Ks-0015, Mcule-7508486604, Ncgc00091761-01, Ncgc00091761-02, Ncgc00091761-04, Ncgc00256301-01, Ncgc00256301-02, Ncgc00256301-03, Ncgc00256301-04, 2,6-ditert.butyl-4-methyl Phenol, 2,6-di-tert-butyl 4-methylphenol, 2,6-di-tert.-butyl-4-methylphenol, 2,6-ditert.butyl-4-methylphenol, 4-methyl-2,6-ditert.butylphenol, 6-di-ter-butyl-4-methyl-phenol, 6-tert-butyl-4-methylphenol, Ncgc00256301-01, Ncgc00256301-02, Ncgc00256301-03, Ncgc00256301-04, Ncgc00256301-05, Ncgc00256301-06, Ncgc00256301-07, Ncgc00256301-08

The content of C15H240 shall not be less than 98.5% calculated as anhydrous.
IONOL 75 is easily soluble in kerosene, oil and gasoline.
IONOL 75 conforms to the requirements of British Defense Standard 91/91, listed as RDE/A/609.

Also IONOL antioxidants have shown to increase the useful life of many industrial oils, reducing equipment downtime.
Applications include hydraulic fluids, transformer oils, spinning oils and metal rolling and cutting fluids.

IONOL antioxidants are excellent stabilizers for all grades of kerosene based Jet A1 fuel for civil and military use.
The concentration needed to protect and stabilize aviation fuels is also defined by these international specifications.
For example, DERD 2494 specifies an addition level in the range of 17.0 – 24.0 mg/L for hydrotreated fuels.

Uses of IONOL 75:
IONOL 75 is an oil-soluble antioxidant widely used at home and abroad.
Although IONOL 75 is toxic, IONOL 75 has strong antioxidant ability, good heat resistance and stability, no specific odor, no color reaction of metal ions, and low price, only 1/8~1/5 of BHA.

Generally used in conjunction with BHA, and citric acid or other organic acids as a synergist.
China's provisions can be used for edible oil, fried food, biscuits, instant noodles, nuts canned, dry fish products, the maximum use of 0. 2g/kg.
IONOL 75 also has a certain antibacterial effect, but weaker than BHA.

Properties of IONOL 75:
IONOL 75 is colorless, white or off-white crystal or crystalline powder.
IONOL 75 is easily soluble in acetone, soluble in ethanol, insoluble in water and propylene glycol.

Molecular Weight: 220.35 g/mol
Molecular Formula: C15H24O
XLogP3: 5.3
Hydrogen Bond Donor Count: 1

Hydrogen Bond Acceptor Count: 1
Rotatable Bond Count: 2
Exact Mass: 220.182715385 g/mol
Monoisotopic Mass: 220.182715385 g/mol

Topological Polar Surface Area: 20.2 Å²
Heavy Atom Count: 16
Complexity: 207
Covalently Bonded Unit Count: 1

Density: 1.048
Melting Point: 69-73°C(lit.)
Boling Point: 265°C(lit.)
Flash Point: 127 °C

Freezing point:
The freezing point of IONOL 75 (General 0613) is 69~70°C.

Absorption coefficient
Take IONOL 75, precision weighing, plus ethanol dissolution and quantitative dilution to make a solution containing about 50mg per lm l, according to UV-visible spectrophotometry (General Rule 0 @ 1), the absorbance was measured at a wavelength of 278nm, and the absorption coefficient (dish) was 80. 0 to 90. 0.

Nature of IONOL 75:
IONOL 75 is colorless crystal or white crystalline powder, odorless, tasteless.
Soluble in ethanol (25%,25 ° C), acetone (40%), benzene (40%), soybean oil, cottonseed oil, insoluble in water, glycerol, propylene glycol.
Light, thermal stability, heating can be volatilized with water vapor, the metal ion does not change color.

Preparation Method of IONOL 75:
p-cresol and tert-butyl alcohol are dissolved by heating, and phosphoric acid is used as catalyst to react at a certain temperature.
The reaction product is washed with sodium hydroxide solution to alkaline first, then washed with water to neutral, and finally distilled, recrystallization provides dibutyl hydroxytoluene.
Or isobutylene mixed with cresol and concentrated sulfuric acid, reaction at a certain temperature for a certain time, and the crude product is neutralized, and then the crude product is dissolved in ethanol, adding thiourea, hot filtration, spin drying, obtained by drying.

Differential Diagnosis of IONOL 75:
In the chromatogram recorded under the content determination item, the retention time of the main peak of the test solution should be consistent with the retention time of the main peak of the reference solution.
The infrared absorption spectrum of IONOL 75 should be consistent with that of the reference product (General rule 0402).