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IONOL K65

IONOL K65 is a high quality antioxidant, with a typical purity 99.8 %. 
IONOL K65 is an antioxidant with a good cost performance ratio for the use in refinery streams, gasoline and aviation fuels. 
IONOL K65 is an oil-soluble antioxidant widely used at home and abroad. 

CAS Number: 188364-50-3
Molecular Formula: C29H48O2
Molecular Weight:428.69022

IONOL 220, IONOL 103, IONOL 135 and IONOL 99 are highly effective antioxidants for multigrade Iubricants, automatic transmission fluids, differential fluids and turbine oils.

Also IONOL antioxidants have shown to increase the useful life of many industrial oils, reducing equipment downtime. 
Applications include hydraulic fluids, transformer oils, spinning oils and metal rolling and cutting fluids.

IONOL antioxidants are excellent stabilizers for all grades of kerosene based Jet A1 fuel for civil and military use. 
The concentration needed to protect and stabilize aviation fuels is also defined by these international specifications. 
For example, DERD 2494 specifies an addition level in the range of 17.0 – 24.0 mg/L for hydrotreated fuels.

Uses of IONOL K65:

Lubricants:
The continual development and improvement of the internal combustion engine has made increasing demands on Iubricants. 
Increasing Crankcase oil temperatures and increasing longevity of vehicles in general require ever higher performance and stability from lubricating oils to prevent oxidation.

Oxidation contributes to piston ring sticking, formation of sludge within the oil, and an overall breakdown of the viscosity characteristics of the lubricant. 
As free radical scavengers, one IONOL molecule can inhibit and help prevent the oxidation of many oil molecules, extending the useful life of lubricants and transmission fluids.

Polymer, Elastomers & Rubbers:
Oxidation is an important limiting factor in all thermoplastics and thermosetting resins. 
IONOL K65 effects include adverse colour change, loss of flexibility, loss of tensile strength and elongation, reduced impact resistance, cracking and other surface deterioration. 
Oxidation can also affect the molecular weight of a polymer, which in turn affects IONOL K65 other properties.

The oxidation of latex and rubber compounds can have different effects, depending on the type of polymer involved. 
Problems include adverse colour changes, loss of flexibility, loss of tensile strength and reduced impact resistance, ageing, cracking and other surface deterioration.

IONOL products are widely used in polyols for flexible polyurethane foams, where IONOL K65 protects the polyol during production and long-term storage, as well as preventing scorching during the formation of the polyurethane foam. 
Furthermore, IONOL products are also used in the production of colourless stabilized polyolefins as well as PVC and PVB films.

IONOL antioxidants are widely used in most natural and synthetic lattices and rubbers.

Biodiesel:
The IONOL BF range – 100% active, no harm approved stabilizers with superior performance.

In every phase of IONOL K65 lifecycle, from manufacturing to storage to combustion in the engine, biodiesel is subjected to oxidative influences. 
The process starts with degradation reactions that cause undesired polymers, aggressive acids and peroxides. 
Due to IONOL K65 natural composition, biodiesel ages a lot faster than fossil diesel and IONOL K65 use-by date is very often exceeded by the time the biofuel finally makes IONOL K65 to the end-user.

The international biodiesel norms, (e.g. EN 14214 or ASTM D 6751) demand the adherence to the specified oxidation stability. 
The global specifications for fossil diesel (e.g. EN 590 or ASTM D 975) clearly prescribe that only in-spec biodiesel may be blended with fossil diesel.

Leather, Coatings and Inks:
During the process of tanning, fat is dissolved from the animal skin. 
Further on in the process, the “wet-blue” has to pick up fat again. 

These fats, made from different native fats, are called fat liquors. 
IONOL Technical Grade, IONOL CPC or IONOL 135 are used to stabilize the feed stock of the fat liquors.

The addition of either IONOL Technical Grade, IONOL CPC or IONOL 135 helps maintain overnight stability, reduce run-resistance and improve gloss and hard drying properties in most general-purpose printing inks. 
IONOL Technical Grade or IONOL CPC in lithographic inks also prevents skin formation and even promotes drying.

Chemical Stability

Conditions Contributing to Instability:
Presence of incompatible materials.
IONOL K65 is considered stable.

Storage Incompatibility:
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminium, copper and brass alloys in storage and process equipment.

Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.

Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. 
Many of them form metal salts that tend toward detonation by rather mild shock.

Safety and Handling of IONOL K65:

Safety Statements:
Moderately toxic by ingestion and skin contact. 
A severe skin irritant. 
When heated to decomposition IONOL K65 emits acrid smoke and irritating vapors.

First Aid Measures of IONOL K65:

Swallowed:
For advice, contact a poisons information center or a doctor at once.
Urgent hospital treatment is likely to be needed.

Eye:
If IONOL K65 comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.

Skin:
If skin or hair contact occurs:
Immediately flush body and clothes with large amounts of water, using safety shower if available.
Quickly remove all contaminated clothing, including footwear.

Inhaled:
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. 
Keep warm and rested.

Fire Fighting Measures of IONOL K65:
Vapor Pressure (mmHg): 19.952 (130 C)
Upper Explosive Limit (%): Not available.
Specific Gravity (water=1): 0.917
Lower Explosive Limit (%): Not available.

Extinguishing Media:
Foam.
Dry chemical powder.

Fire Fighting:
Alert Emergency Responders and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 800 metres in all directions.

General Fire Hazards/hazardous Combustible Products:
Combustible.
Slight fire hazard when exposed to heat or flame.

Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material.
May emit corrosive fumes.

Fire Incompatibility:
Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorine etc. as ignition may result.

Personal Protection:

Glasses:
Full face- shield.

Gloves.

Respirator:
Type A-P Filter of sufficient capacity

Accidental Release Measures of IONOL K65:

Minor Spills:
Drains for storage or use areas should have retention basins for ph adjustments and dilution of spills before discharge or disposal of material.
Check regularly for spills and leaks.

Clean up all spills immediately.
Avoid breathing vapors and contact with skin and eyes.

Major Spills:
Clear area of personnel and move upwind.
Alert Emergency Responders and tell them location and nature of hazard.

Identifiers of IONOL K65:
CAS Number: 188364-50-3
Molecular Formula: C29H48O2
Molecular Weight:428.69022

Inchi: InChI=1S/C29H48O2/c1-7-22(19(2)3)11-10-20(4)26-14-15-27-23(9-8-16-29(26,27)6)12-13-24-17-25(30)18-28(31)21(24)5/h12-13,19-20,22,25-28,30-31H,5,7-11,14-18H2,1-4,6H3/b23-12+,24-13-/t20-,22-,25+,26-,27+,28-,29-/m1/s1
Canonical Smiles: CC[C@@]([H])(C(C)C)CC[C@@]([C@@]1([C@@]2([C@]([H])(/C(=C(/C(=C3C([C@@](O)([H])C[C@](O)([H])C3)=C)/[H])[H])/CCC2)CC1)C)[H])([H])C
Isomers Smiles: CC[C@@]([H])(C(C)C)CC[C@@]([C@@]1([C@@]2([C@]([H])(/C(=C(/C(=C3C([C@@](O)([H])C[C@](O)([H])C3)=C)/[H])[H])/CCC2)CC1)C)[H])([H])C

Other IONOL Products:
IONOL CP
IONOL 75
IONOL 75S30
IONOL 75T30
IONOL BS35
IONOL BT45
IONOL BF200
IONOL BF350
IONOL BF1000
IONOL K72
IONOL K78
IONOL K98
IONOL 99
IONOL 103
IONOL 135
IONOL 220
IONOL 220 AH
IONOL PET FOOD
IONOL AQUA 50
IONOL CPS
IONOL CP MOLTEN
IONOL 175N
IONOL 175N PLUS
IONOL FEED 501
IONOL FEED 101
IONOL 200N
IONOL CPF
IONOL CPA
IONOL CPC
IONOL CPD
IONOL FEED 502
IONOL CP
IONOL CPA FLAKES
IONOL LC
IONOL BHT TECHNICAL GRADE
IONOL BHT TECHNICAL FLAKES
 

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