PRODUCTS

IRON ACETYLACETONATE

Iron acetylacetonate is used moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
Iron acetylacetonate is used as a precatalyst and reagent in organic chemistry.
Iron acetylacetonate acts as a precursor for highly crystalline (Zn, Fe)Fe2O4.

CAS Number: 14024-18-1
EC Number: 237-853-5
MDL Number: MFCD00000020
Molecular Formula: C₁₅H₂₁FeO₆
Molecular Weight: 353.17 g/mol

SYNONYMS:
Tris(2,4-dioxopentan-3-ido-κ2O,O′)iron, Iron(III) acetylacetonate, Iron(III) tris(2,4-pentanedionato), Fe(acac)3, Ferric acetylacetonate, Iron(III) acetylacetonate, Iron acetylacetonate, Nasemu Iron, Iron tris(acetoacetonate), Iron tris(acetylacetonate), Acetope Fe(II), (Acetylacetonato)iron(III), Tris(acetylacetone)iron, Tris(actylacetone)iron, Tris(actylacetonato) iron, Ferric tris(acetylacetonate), Iron acetylacetonate (VAN), Iron triacetylacetonate, Ferric triacetylacetonate, Iron tris(2,4-pentanedioate), Tris(acetylacetonato)iron, Iron tris(2,4-pentanedionato), Iron(3+) acetylacetonate, Ferric tris(acetoacetonate), 118BHF260P, Iron, tris(2,4-pentanedionato)-, EINECS 237-853-5, Tris(pentane-2,4-dionato)iron(II), NSC 43622, Tris(2,4-pentanedionato)iron, AI3-60038, Iron, tris(2,4-pentanedionato-O,O')-, hydrate, NSC-43622, Iron, tris(2,4-pentanedionato-kappaO2,kappaO4)-, (OC-6-11)-, DTXSID3051707, Tris(2,4pentanedionato)iron, Iron tris(2,4pentanedioate), Iron tris(2,4pentanedionato), Iron(III) 2,4pentanedionate, Iron, tris(2,4pentanedionato), Tris(pentane2,4dionato)iron(II), Iron, tris(2,4pentanedionatoO,O'), (OC611), Iron, tris(2,4pentanedionatokappaO,kappaO'), (OC611), Iron, tris(2,4pentanedionatokappaO2,kappaO4), (OC611), Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)-, dtxcid3030262, 14024-18-1, Fe(acac)3, Iron(III) 2,4-pentanedionate, iron(III) acetyl acetonate, tris (acetylacetonato) iron, (Acetylacetonato) iron(III), UNII-118BHF260P, STR08397, AKOS037655921, iron(3+);(Z)-4-oxopent-2-en-2-olate, Iron(III) acetylacetonate, Trace metals grade, iron(3+) ion tris((2Z)-4-oxopent-2-en-2-olate), 2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate, Iron-III-acetylacetonate, Ironchelat, Iron tris-acetylacetonat, Ferriacetylacetonat, Tris-(2.4-pentanedionato)-iron (III), Fe(acac)3, Iron(III) 2,4-pentanedionate, Tris(2,4-pentanedionato)iron(III), Tris(acetylacetonato) iron(III), Trisacetylacetonato iron(III), Iron tris(acetylacetonate), Ferric acetyl acetonate, Iron Acetylacetonate, 2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric triacetylacetonate, Iron(III) 2,4-pentanedionate, 2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Ferric(III) acetylacetonate, Acetylacetone iron(III) salt, Tris(2,4-pentanedionato)iron(III), Fe(acac)3,IRON(III) ACETYLACETONATE,IRON ACETYLACETONATE,TRIS(2,4-PENTANEDIONATO)IRON(III),acetonate,nasemuiron,Fe (III)-AA,acetopefe(ii),Iron(III) acetyL,Ironpentanedionate, FeAcac, Fe(Acac)3, (Acetylacetonato)iron(III), Ferric acetylacetonate, Ferric tris(acetoacetonate), Ferric tris(acetylacetonate), Iron acetylacetonate, Iron triacetylacetonate, Iron tris(2,4-pentanedionate), Iron tris(acetoacetonate), Iron tris(acetylacetonate), Iron(3+) acetylacetonate, Iron(III) acetylacetonate, Iron(III) tris(2,4-pentanedionate), Tris(2,4-pentanedionato)iron, Tris(acetylacetonato)iron, Tris(acetylacetone)iron, Iron, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-, (Acetylacetonato)iron(iii), Iron, tris(2,4-pentanedionato)-, Ferric acetylacetonate, Ferric tris(acetoacetonate), Iron acetylacetonate, Iron triacetylacetonate, Iron tris(acetoacetonate), Iron tris(acetylacetonate), Iron tris(2,4-pentanedionate), Iron(iii) acetylacetonate, Iron(3+) acetylacetonate, Tris(acetylacetonato)iron, Tris(acetylacetone)iron, Tris(2,4-pentanedionato)iron, Iron(III) 2,4-pentanedionate, Ferric(III) acetylacetonate, Ferric triacetylacetonate, Acetope Fe(II), Nacem Iron, NSC 43622, tris(pentane-2,4-dionato)iron(II),

Iron acetylacetonate is a iron source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and Metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds).
Iron acetylacetonate, Ferric acetylacetonate, often abbreviated Fe(acac)3, is a ferric coordination complex featuring acetylacetonate (acac) ligands.

Iron acetylacetonate has been examined as a precatalyst and reagent in organic chemistry.
Iron acetylacetonate is a ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates.

Iron acetylacetonate is a red air-stable solid that dissolves in nonpolar organic solvents.
Iron acetylacetonate is a catalyst used in Grignard reactions with acid chlorides to give ketones.
MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Iron acetylacetonate is an organometallic compound that comprises iron and acetylacetone, an organic compound featuring a ketone group.
Iron acetylacetonate finds application in polymer synthesis, and it has been the subject of research as a potential catalyst for carbon dioxide reduction.

Iron acetylacetonate, also known as Fe(acac)₂, ferrous acetylacetonate, or 2,4-pentanedione iron(II) derivative, is a red to brown powder with the molecular formula C₁₀H₁₄FeO₄ and a molecular weight of 254.06 g/mol.
Iron acetylacetonate is stable under normal conditions but is sensitive to moisture.

To preserve its integrity and reactivity, Iron acetylacetonate should be stored in dry, air-tight containers.
Iron acetylacetonate has a melting point of approximately 210°C, making it suitable for processes that involve moderate to high temperatures.
Iron acetylacetonate, Fe(acac)₂, or iron(II) acetylacetonate, is a versatile and reactive compound commonly used in catalysis, thin-film deposition, and material synthesis.

Its high purity and reactivity make Iron acetylacetonate valuable in advanced industrial processes, though care must be taken to handle it safely due to its hazardous nature.
Iron acetylacetonate is an Iron source that is soluble in organic solvents as an organometallic compound.

Iron acetylacetonate, commonly abbreviated as Fe(acac)₃, is a coordination complex where an iron(III) ion is chelated by three acetylacetonate ligands.
Iron acetylacetonate is notable for its stability and solubility in organic solvents, making it valuable in various industrial and research applications.

Iron acetylacetonate, often abbreviated Fe(acac)3, is a ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates.
Iron acetylacetonate is a red air-stable solid that dissolves in nonpolar organic solvents.

USES and APPLICATIONS of IRON ACETYLACETONATE:
Iron acetylacetonate can be used as a catalyst in preparation, degradation, and calcification of biodegradable polyurethane foams for bone graft substitutes.
Thermal decomposition of Iron acetylacetonate in triethylene glycol has being used in the synthesis of water-stable magnetite nanoparticles for clinical MRI and magnetic hyperthermia applications.

Iron acetylacetonate is used chemical Synthesis of Monodisperse Magnetic Nanoparticles.
Iron acetylacetonate has been enhanced for catalytic efficiency.
Iron acetylacetonate is widely used in various chemical applications, particularly in catalysis and material science.

Iron acetylacetonate is often used as a precursor in the synthesis of other iron-containing compounds and materials, particularly in the deposition of thin films via chemical vapor deposition (CVD) and atomic layer deposition (ALD) processes.
Iron acetylacetonate is also employed as a catalyst in organic reactions, where its reactivity and stability contribute to efficient chemical transformations.

The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring, because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures via the use of chemical vapor deposition (CVD) and laser evaporation techniques.

The numerous commercial applications for Iron include primary colorant in glass and ceramics, catalyst, basis for low-grade magnets and because of its magnetic properties is used extensively in memory tape.
Iron acetylacetonate is used lewis-acidic catalyst for chlorination.

Iron acetylacetonate is used lewis-acidic catalyst for polymerization reactions.
Iron acetylacetonate is used catalyst for chemical synthesis.
Iron acetylacetonate is used lewis-acidic catalyst for Grignard reactions.

Iron acetylacetonate is used lewis-acidic catalyst for cross-coupling reactions.
Iron acetylacetonate is utilized in various fields due to its chemical properties.
Catalysis: Iron acetylacetonate serves as a catalyst or catalyst precursor in organic synthesis and polymerization reactions.

Material Science: Iron acetylacetonate is used in the preparation of magnetic materials and as a precursor for iron oxide nanoparticles.
Analytical Chemistry: Iron acetylacetonate is employed in spectroscopic studies due to its distinct electronic properties.
Chemical Vapor Deposition (CVD): Iron acetylacetonate acts as a precursor in the deposition of iron-containing films.

-Applications of Iron acetylacetonate:
Chemical Synthesis of Monodisperse Magnetic Nanoparticles.

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
Iron acetylacetonate may be used as a precursor for the synthesis of water-soluble magnetite nanoparticles, which may find applications in the area of magnetic hyperthermia treatment.

✅ BENEFITS AND CHARACTERISTICS OF IRON ACETYLACETONATE:
*Thermal Stability:
Iron acetylacetonate maintains integrity under elevated temperatures, making it suitable for high-temperature applications.

*Solubility:
Iron acetylacetonate's solubility in various organic solvents allows for versatility in different chemical processes.

*Magnetic Properties:
Iron acetylacetonate exhibits paramagnetic behavior, useful in magnetic studies and applications.

CHEMICAL PROPERTIES OF IRON ACETYLACETONATE:
Iron acetylacetonate is dark red powder or Red-orange orthorhombic crystal, slightly soluble in water and heptane, easily soluble in ethanol, benzene, chloroform, acetone and ether.
Iron acetylacetonate is solubility at 25°C: water 0.16, methanol 9.5, toluene 21.3, benzene 52.5.

PREPARATION OF IRON ACETYLACETONATE:
Iron acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent.
Iron acetylacetonate is an excellent quencher of triplet states.

PURIFICATION METHODS OF IRON ACETYLACETONATE:
When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr.
However, when recrystallised from EtOH or Et2O it has m 179o.
Recrystallisation from absolute EtOH gives material with m 159.5o.
Dry it for 1 hour at 120oC.

PREPARATION OF IRON ACETYLACETONATE:
Iron acetylacetonate is prepared by treating freshly precipitated Fe(OH)3 with acetylacetone.
Fe(OH)3 + 3 HC5H7O2 → Fe(C5H7O2)3 + 3 H2O

STRUCTURE AND PROPERTIES OF IRON ACETYLACETONATE:
Iron acetylacetonate is an octahedral complex with six equivalent Fe-O bonds with bond distances of about 2.00 Å.
The regular geometry is consistent with a high-spin Fe3+ core with sp3d2 hybridization.

As the metal orbitals are all evenly occupied Iron acetylacetonate is not subject to Jahn-Teller distortions and thus adopts a D3 molecular symmetry.
In contrast, the related metal acetylacetonate Mn(acac)3 adopts a more distorted octahedral structure.
The 5 unpaired d-electrons also result in the complex being paramagnetic, with a magnetic moment of 5.90 μB.

Iron acetylacetonate possesses helical chirality.
The Δ- and Λ-enantiomers slowly inter-convert via Bailar and Ray–Dutt twists.
The rate of interconversion is sufficiently slow to allow Iron acetylacetonate's enantiomers to be partially resolved.

REACTIONS OF IRON ACETYLACETONATE:
Iron acetylacetonate has been examined as a precatalyst and reagent in organic chemistry, although the active iron-containing species is usually unidentified in these processes.

In one instance, Iron acetylacetonate was shown to promote cross-coupling a diene to an olefin.
Iron acetylacetonate catalyzes the dimerization of isoprene to a mixture of 1,5-dimethyl-1,5-cyclooctadiene and 2,5-dimethyl-1,5-cyclooctadiene.

Iron acetylacetonate also catalyzes the ring-opening polymerization of 1,3-benzoxazine.
Beyond the area of polymerization, Iron acetylacetonate has been found to catalyze the reaction of N-sulfonyl oxaziridines with olefins to form 1,3-oxazolidine products.

PHYSICAL and CHEMICAL PROPERTIES of IRON ACETYLACETONATE:
Chemical Name: Iron(III) acetylacetonate
CAS Number: 14024-18-1
EC Number: 237-853-5
Molecular Formula: C₁₅H₂₁FeO₆
Molecular Weight: 353.17 g/mol
PubChem CID: 5483663
Appearance: Red to dark red crystalline powder
Density: Approximately 1.348 g/cm³
Melting Point: 180–183 °C (decomposes upon melting)
Solubility:
Water: Slightly soluble (approximately 2 g/L)

Organic Solvents: Soluble in ethanol, acetone, benzene, and other organic solvents
Stability: Air-stable under standard conditions
Chemical formula: Fe(C5H7O2)3
Molar mass: 353.17 g/mol
Appearance: Red Solid
Density: 1.348 g/cm³
Melting point: 180 to 181 °C (356 to 358 °F; 453 to 454 K)
Boiling point: decomposes
Solubility in water: 2 g/L
Molecular Weight: 353.17 g/mol

Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 3
Exact Mass: 353.068749 Da
Monoisotopic Mass: 353.068749 Da
Topological Polar Surface Area: 120 Å²
Heavy Atom Count: 22
Formal Charge: 0

Complexity: 90.4
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 3
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 4
Compound Is Canonicalized: Yes

Linear Formula: Fe(C5H7O2)3
CAS Number: 14024-18-1
Molecular Weight: 353.17
Beilstein: 4157960
EC Number: 237-853-5
MDL number: MFCD00000020
UNSPSC Code: 12352103
PubChem Substance ID: 24894833

NACRES: NA.23
CAS: 14024-18-1
IUPAC Name: iron(3+) tris((2Z)-4-oxopent-2-en-2-olate)
Molecular Formula: C15H21FeO6
InChI Key: AQBLLJNPHDIAPN-LNTINUHCSA-K
SMILES: [Fe+3].CC([O-])=CC(C)=O.CC([O-])=CC(C)=O.CC([O-])=CC(C)=O
Molecular Weight (g/mol): 353.17
Synonym: iron(3+) tris((2Z)-4-oxopent-2-en-2-olate)
MDL Number: MFCD00000020

Appearance (Form): Powder or crystals
Infrared spectrum: Conforms
Titration Iodometric: >=99.0 %
Appearance (Color): Dark orange to dark red
Physical state: powder
Color: dark red
Odor: No data available

Melting point/freezing point:
Melting point/range: 180 - 182 °C - dec.
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: No data available
Autoignition temperature: 160 °C
Decomposition temperature: No data available
pH: No data available

Viscosity:
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: 2 g/l at 20 °C
Partition coefficient: n-octanol/water: No data available
Vapor pressure: No data available
Density: 5,24 g/cm3 at 25 °C - lit.
Relative density: No data available
Relative vapor density: No data available

Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: none
Other safety information: No data available
CBNumber: CB8677712
Molecular Formula: C15H21FeO6
Molecular Weight: 353.17
MDL Number: MFCD00000020

MOL File: 14024-18-1.mol
Melting point: 180-182 °C (dec.)(lit.)
Boiling point: 110°C 2mm
Density: 5.24 g/mL at 25 °C(lit.)
bulk density: 500kg/m3
vapor pressure: 2.6 hPa (110 °C)
storage temp.: Store below +30°C.

solubility: Soluble in toluene.
form: Powder
color: Red
Specific Gravity: 5.24
Water Solubility: 2 g/L (20 ºC)
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
BRN: 4157960
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3

Stability: Stable.
Incompatible with strong bases, strong oxidizing agents.
LogP: 0.4 at 20℃
EWG's Food Scores: 1
FDA UNII: 118BHF260P
NIST Chemistry Reference: Iron tris(acetylacetonate)(14024-18-1)
EPA Substance Registry System: Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1)
UNSPSC Code: 12352103
NACRES: NA.23

CAS number: 14024-18-1
EC number: 237-853-5
Hill Formula: C₁₅H₂₁FeO₆
Molar Mass: 353.18 g/mol
HS Code: 2914 19 29
Density: 1.36 g/cm3
Melting Point: 182 - 185 °C
Vapor pressure: 2.6 hPa (110 °C)
Bulk density: 500 kg/m3
Solubility: 1.7 g/l

Appearance: Crystalline powder
Physical State: Solid
Solubility: Soluble in water (2 mg/ml at 20° C), ethanol, chloroform, dichloromethane, and acetone.
Storage: Store at room temperature
Melting Point: 180-182° C (dec.)
Density: 5.24 g/cm3 at 25° C
Refractive Index: n20D ~1.45 (Predicted)

FIRST AID MEASURES of IRON ACETYLACETONATE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of IRON ACETYLACETONATE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of IRON ACETYLACETONATE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of IRON ACETYLACETONATE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of IRON ACETYLACETONATE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.

STABILITY and REACTIVITY of IRON ACETYLACETONATE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available