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ISOBUTANOL

CAS NUMBER: 78-83-1

EC NUMBER: 201-148-0

MOLECULAR FORMULA: (CH3)2CHCH2OH

MOLECULAR WEIGHT: 74.12

 


Isobutanol is a 4-carbon branched-chain alcohol used as a raw material for coating resins, Isobutyl acrylate, isobutyl acetate, isobutyl methacrylate, and paint thinners.
Isobutanol acts as a solvent. 

Isobutanol is produced directly from fermentation of starch, sugar, sugar cane juice, molasses and hemicellulose. 
Isobutanol is used in adhesives.

Isobutanol is an organic compound with the formula (CH3)2CHCH2OH (sometimes represented as i-BuOH). 
This colorless, flammable liquid with a characteristic smell is mainly used as a solvent either directly or as its esters. 

Isobutanols isomers, the other butanols, include n-butanol, 2-butanol, and tert-butanol, all of which are important industrially.
Isobutanol appears as a clear colorless liquid with a sweet odor.

Flash point 85 - 100°F. 
Less dense than water. 

Vapors heavier than air.
Isobutanol is an alkyl alcohol that is propan-1-ol substituted by a methyl group. 

Isobutanol is a primary alcohol and an alkyl alcohol. 
Isobutanol derives from a hydride of an isobutane.

Isobutanol is a medium boiling, slow evaporating, colorless liquid that is useful in organic synthesis, as a chemical intermediate and as a solvent in coating applications. 
Isobutanol is similar in properties to n-butyl alcohol and may be used as a supplement or replacement for it in many applications. 

As a latent solvent in lacquers and ambient-cured enamels, isobutanol is effective in reducing the viscosities of many formulations while simultaneously promoting flow and leveling. 
Isobutanol is also used as an etherification alcohol in the manufacture of amino resins that are used as curing agents in baking and physical-drying finishes.

Isobutanol, also known as isopropyl alcohol, 2-methyl propanol is a colorless alcohol flammable liquid. 
Isobutanol is one of the main ingredients of fresh tea leaves, black tea and green tea to produce the wonderful aroma with the molecular weight of 74.12, boiling point of 107.66 ℃, relative density of 0.8016 (20/4 ℃), refractive index of 1.3959 and a flash point of 37 ℃. 

Isobutanol is fully dissolved in alcohol and ether, slightly soluble in water. 
Isobutanols vapor can form an explosive mixture with air; the explosion limit is 2.4% (volume). 

Isobutanol can form addition compounds (CaCl2 • 3C4H10O) with calcium chloride. 
Isobutanol can be obtained by the distillation of the by-product of methanol and can also be derived from distillation of crude fusel oil. 

Using Industrial carbonyl cobalt as a catalyst, making propylene and carbon monoxide and hydrogen mixture react at 110~140 ° C, 2.0265 × 107~3.0397 × 107Pa to generate butyraldehyde and isobutyraldehyde, and then via catalytic hydrogenation, separation can obtain isobutanol. 
Isobutanol is used in the manufacture of petroleum additives, antioxidants, plasticizers, synthetic rubber, artificial musk, fruit oil and synthetic drugs and also used as solvents and chemical reagents.

Isobutanol is a kind of colorless transparent liquid with a special smell, soluble in water, and fully dissolved in ethanol and ether.
Isobutyl alcohol has a disagreeable odor. 
Isobutanol is may be prepared from isobutylene; by reduction of isobutyraldehyde with sodium amalgam or in the presence of a catalyst; by fermentation of isobutyraldehyde; isolated during fermentation of carbohydrates.

 

 


USES OF ISOBUTANOL:

Isobutanol is used in organic synthesis, as a latent solvent in paints and lacquers, an intermediate for coating resins, in paint removers, liquid chromatography, and some flavor concentrations.
Isobutanol is also used as: solvent (textile industry and production of paints and lacquers), extraction agent in production of medicines, component of anti-icing mixtures and anti-corrosion additives.

Isobutanol can be used in a variety of ways, e.g. as a feedstock in the production of isobutyl acetate or as a varnish remover.
Isobutanol is widely used in the productionof isobutyl acetate for lacquers, isobutylphthalate for plasticizers; as a solvent forplastics, textiles, oils, and perfumes; and asa paint remover.
 

-formulation & (re)packaging of substances and mixtures 

-coatings (paints, ink, toners, adhesives) 

-cleaning agents  

-lubricants 

-metal working fluids / rolling oils

-Process solvents

-Protective coatings

-Water treatment industrial

-Wood coatings

 

-For analysis reagents, chromatography reagents, solvents and extraction agent.

-As raw materials for the organic synthesis, and also act as a superior solvent.

-Isobutanol is raw materials for organic synthesis. It mainly used in the synthesis of isobutyronitrile, an intermediate for diazinon.

-As raw materials of organic synthesis, isobutanol is used in the manufacture of petroleum additives, antioxidants, 2, 6-butylated hydroxytoluene, isobutyl acetate (paint solvents), plasticizers, synthetic rubber, artificial musk, fruit oil and synthetic drugs. It can also be used to purify strontium, barium and lithium salts and other chemical reagents and used as a superior solvent.

-Extraction solvent.

 

 

USAGE AREAS OF ISOBUTANOL:


-production

-use as a semi-finished product

-preparation and (re-) packing substances and mixtures

-distribution of substances

-use in coatings (paints, inks, toners, adhesives)

-use in cleaning agents

-use in lubricants

-fluids for treatment of metals / rolling mill oils

-use in laboratories

-use as a consumer product for daily care or disinfection

 

 


APPLICATIONS OF ISOBUTANOL:

The uses of isobutanol and n-butanol are similar.
Isobutanols are often used interchangeably. 

The main applications are as varnishes and precursors to esters, which are useful solvents, e.g. isobutyl acetate. Isobutyl esters of phthalic, adipic, and related dicarboxylic acids are common plasticizers.
Isobutanol is also a component of some biofuels.

Isobutanol is used as a raw material for coating resins, Isobutyl acrylate, isobutyl acetate, isobutyl methacrylate, and paint thinners.
On the other hand, Isobutanol is widely used as a solvent because many organic materials are soluble in it.
Isobutanol can be used as a suitable blending agent

 

-Architectural coatings

-Auto OEM

-Auto plastics

-Auto refinish

-Furniture

-General industrial coatings

-Graphic arts

-Hard surface care
 
-Industrial fuel imeds

-Packaging components non food contact

-Paints & coatings

 

 


PHYSICAL AND CHEMICAL PROPERTIES OF ISOBUTANOL:


-Formula: C4H10O / (CH3)2CHCH2OH

-Molecular mass: 74.1

-Boiling point: 108°C

-Melting point: -108°C

-Relative density (water = 1): 0.80

-Solubility in water, g/100ml at 20°C: 8.7

-Relative vapour density (air = 1): 2.55

-Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02

-Flash point: 28°C c.c.

-Auto-ignition temperature: 415°C

-Explosive limits, vol% in air: 1.7-10.9

-Octanol/water partition coefficient as log Pow: 0.8  

 

 


FEATURES OF ISOBUTANOL:

-Excellent reactivity as an intermediate

-Improves flow and gloss in cellulose lacquers and amino baking finishes

-Inert Food use with limitations

-Inert Nonfood use

-Latent solvent in cellulose lacquers

-Non HAP

-Non SARA

-Readily biodegradable

-Slow evaporation rate

 

 

CHARACTERISTICS OF ISOBUTANOL:

Isobutanol (IBA), also called isobutyl alcohol, is a 4-carbon branched-chain alcohol.
Isobutanol is hardly soluble in water, but is soluble in almost all organic solvents.
Isobutanol has very low-level impurities and may be used as a raw material for a wide variety of chemicals.

 

 

PRODUCTION OF ISOBUTANOL:

Isobutanol is produced by the carbonylation of propylene.
The reaction is catalyzed by cobalt or rhodium complexes. 

The resulting aldehydes are hydrogenated to the alcohols, which are then separated. 
In Reppe carbonylation, the same products are obtained, but the hydrogenation is effected by the water-gas shift reaction.

 

 

STORAGE OF ISOBUTANOL:

Fireproof. 
Separated from strong oxidants and aluminium

 


SYNONYM:

2-Methylpropan-1-ol
78-83-1
1-Propanol, 2-methyl-
1-Hydroxymethylpropane
Isopropylcarbinol
i-Butyl alcohol
Iso-butyl alcohol
2-Methylpropyl alcohol
Isobutylalkohol
2-Methylpropanol
Alcool isobutylique
2-Methyl propanol
i-Butanol
Fermentation butyl alcohol
iso-butanol
RCRA waste number U140
2-Methylpropanol-1
Isopropyl carbitol
NSC 5708
UNII-56F9Z98TEM
MFCD00004740
Methyl-2 propanol-1
iso-C4H9OH
2-methyl-1-propanyl alcohol

 

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