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Isobutyl methacrylate is a colorless liquid with a flash point of 120°F.
When heated to high temperatures it may release acrid smoke and fumes.
If Isobutyl methacrylate is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization.
If the polymerization takes place inside a container, the container may violently rupture.
CAS Number: 97-86-9
EC Number: 202-613-0
IUPAC Name: 2-methylpropyl 2-methylprop-2-enoate
Molecular Formula : C8H14O2
Other names: 97-86-9, 2-methylpropyl 2-methylprop-2-enoate, 2-Propenoic acid, 2-methyl-, 2-methylpropyl ester, Methacrylic acid, isobutyl ester, Isobutyl 2-methyl-2-propenoate, 2-METHYLPROPYL METHACRYLATE, Methacrylic Acid Isobutyl Ester, NSC 18607, Isobutylester kyseliny methakrylove, Isobutyl .alpha.-methacrylate, Isobutyl .alpha.-methylacrylate, DTXSID3025461, V11534UYZ0, MFCD00008931, NSC-18607, Isobutyl Methacrylate (stabilized with HQ), Isobutyl 2-methylacrylate, DTXCID505461, Isobutyl alpha-methacrylate, CAS-97-86-9, Isobutyl alpha-methylacrylate, CCRIS 4829, HSDB 5312, EINECS 202-613-0, UN2283, 2-Methylpropyl 2-methyl-2-propenoate, BRN 1747595, Propenoic acid, 2-methyl, isobutyl ester, UNII-V11534UYZ0, Isobutylester kyseliny methakrylove [Czech], isobutyl 2-methylprop-2-enoate, Blemmer IBMA, Isobutylmethacrylate, i-butyl methacrylate, iso-butyl methacrylate, EC 202-613-0, Isobutyl 2-methylacrylate #, Isobutyl methacrylate, 97%, SCHEMBL24562, MLS002152907, SCHEMBL5098395, SCHEMBL6046949, Isobutyl methacrylate, inhibited, CHEMBL1453087, HMS3039B08, NSC18607, ISOBUTYL METHACRYLATE [HSDB], Tox21_201568, Tox21_303327, BBL010919, MFCD00084435, STK801852, AKOS005622614, UN 2283, NCGC00091087-01, NCGC00091087-02, NCGC00256982-01, NCGC00259117-01, WLN: 1Y1 & 1OVY1 & U1, SMR001224512, VS-02749, Isobutyl Methacrylate, (stabilized with HQ), M0132, NS00001412, Q27291392, Isobutyl methacrylate, inhibited [UN2283] [Flammable liquid], InChI=1/C8H14O2/c1-6(2)5-10-8(9)7(3)4/h6H,3,5H2,1-2,4H
The vapors of Isobutyl methacrylate are heavier than air.
Isobutyl methacrylate may be irritating to skin and eyes and produce a narcotic effect.
Isobutyl methacrylate is used in making acrylic resins.
Use and Manufacturing of Iso Butyl Methacrylate
Used as a monomer for acrylic resins, in hydrogel contact lenses, and as a water repellant for concrete; [HSDB]
Monomer for acrylic resins
In hydrogel contact lenses
Concrete can be made water repellent by the polymerization of vinyl monomers on the surface.
Polymerization of Iso Butyl Methacrylate
Exposure to heat, light, peroxide activators, catalysts or storage without air contact may result in exothermic polymerization.
If the permissible storage period or storage temperature is noticeably exceeded, exothermic polymerization may occur.
Produe Method of Iso Butyl Methacrylate
Isobutyl methacrylate is produced by the esterification ortransesterification of isobutyl alcohol with either methacrylicacid or methyl methacrylate.
Industry Uses of Iso Butyl Methacrylate
Intermediates
Lubricants and lubricant additives
Plasticizers
Consumer Uses of Iso Butyl Methacrylate
Paints and coatings
Household Products of Iso Butyl Methacrylate
Household & Commercial/Institutional Products
Information on 1 consumer products that contain Isobutyl methacrylate in the following categories is provided:
-Hobby/Craft
Isobutyl methacrylate (IBMA) is an ester of Methacrylic acid and is used as a raw material component in the synthesis of polymers.
Isobutyl methacrylate (IBMA) is a functional monomer consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group.
Isobutyl methacrylate (IBMA) forms homopolymers and copolymers which can be obtained with acrylic acid and its salts, amides, and esters, as well as methacrylates, acrylonitrile, maleic esters, butadiene, and other monomers.
Isobutyl methacrylate (IBMA) easily entering into the reaction of accession with a wide range of organic and inorganic substances, is used for the synthesis of organic low molecular weight substances.
Features & Benefits of Iso Butyl Methacrylate:
Hydrophobicity
Adhesion
Water resistance
Low-temperature performance
Toughness
Weatherability
Applications areas of Iso Butyl Methacrylate:
Isobutyl methacrylate (IBMA) can be used to produce organic glass, synthetic resins, rubbers, and varnishes, finishing textile fabrics, and Isobutyl methacrylate is also used in adhesive and as a polymeric plasticizer for harder resins.
Isobutyl methacrylate (IBMA) is applied in the production of:
Coating resins
Textiles treating agents
Lubricating oil additives
Adhesives
Surface preparation agents
Many of the other
Storage & Handling of Iso Butyl Methacrylate:
Isobutyl methacrylate (IBMA) is stored in an airtight aluminum container or stainless steel container in a covered fireproof warehouse at a temperature not exceeding 25 °C.
Isobutyl methacrylate is allowed to store butyl methacrylate in a hermetically sealed steel container.
Isobutyl methacrylate (IBMA) is transported by road and rail in covered vehicles and in aluminum and special steel road and rail tanks in accordance with the rules for the carriage of goods in force on this type of transport.
Isobutyl methacrylate (IBMA) in bottles and steel containers is transported only by road.
Isobutyl methacrylate is allowed to transport the product in steel containers in open vehicles.
By rail, butyl methacrylate in barrels is transported by wagon shipments.
The degree (level) of filling of tanks is calculated taking into account the full use of their capacity and volume expansion of the product with a possible temperature difference along the route.
General Description of Iso Butyl Methacrylate
Isobutyl methacrylate is a colorless liquid with a flash point of 120°F.
When heated to high temperatures Iso Butyl Methacrylate may release acrid smoke and fumes.
If Iso Butyl Methacrylate is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization.
If the polymerization takes place inside a container, the container may violently rupture.
The vapors are heavier than air.
Iso Butyl Methacrylate may be irritating to skin and eyes and produce a narcotic effect.
Iso Butyl Methacrylate is used in making acrylic resins.
Isobutyl methacrylate is a colorless and moderately flammable liquid.
IBMA, or isobutyl methacrylate, is a methacrylate ester of methacrylic acid and isobutanol.
Isobutyl methacrylate is a colorless liquid, and soluble in water at room temperature.
When heated, Isobutyl methacrylate will easily polymerize.
Isobutyl methacrylate is one of the monomer building blocks for acrylic resins, which are widely used in paints, coatings, adhesives, and plastics.
Uses
Plastic industry: used in the manufacture of containing active hydroxyl acrylic resin.
Coatings with epoxy resin, diisocyanate and melamine formaldehyde resin configuration used for preparing a two-component coating.
In oil industry as additives for lubricating oil washing.
In electronics industry used as electron microscope to take off the water.
Textile industry used in the manufacture of adhesive fabric.
Used as chemical reagents in analytical chemistry.
In addition, also used for water immiscible embedding agent, used in the synthesis of medical polymer materials, thermosetting coatings and adhesives.
Isobutyl methacrylate (IBMA) is monomer for acrylic resins.
Isobutyl methacrylate (IBMA) is produced by the esterification or transesterification of isobutyl alcohol with either methacrylic acid or methyl methacrylate.
Isobutyl methacrylate (IBMA) is flammable.
Isobutyl methacrylate (IBMA) is sensitive to heat, air and light.
Isobutyl methacrylate (IBMA) is an ester.
Esters react with acids to liberate heat along with alcohols and acids.
Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products.
Heat is also generated by the interaction of esters with caustic solutions.
Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Isobutyl methacrylate (IBMA) polymerizes readily.
As an organic synthetical monomer isobutyl methacrylate is used as resin, plastic, coating, printing ink, adhesive, lube oil additive dentistry material, fiber treating compound and paper coating agent.
Isobutyl Methacrylate is used in making acrylic resins.
Ungraded products supplied by Spectrum are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for human consumption or therapeutic use.
Isobutyl methacrylate (IBMA) is a synthetic polymer that is used in the manufacture of paints, coatings, sealants, adhesives, and other products.
The particle size of Isobutyl methacrylate (IBMA) can be controlled by adjusting the monomer feed rate.
Isobutyl methacrylate (IBMA) can be activated by heating to form a thermoreversible gel.
Isobutyl methacrylate (IBMA) has been shown to have minimal toxicity when tested in Sprague-Dawley rats.
TRANSPORTATION AND STORAGE of Iso Butyl Methacrylate
Avoid shine rain and high temperature in transportation.
Store the products in cool, shady and ventilated conditions, keep far away from fire.
6 months from date of delivery at a maximum storage temperature of 30℃.
Precautionary Statements of Iso Butyl Methacrylate
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Contaminated work clothing should not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces.
Keep container tightly closed
Ground/bond container and receiving equipment
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Use explosion-proof electrical/ventilating/lighting equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool.
First Aid of Iso Butyl Methacrylate
EYES: First check the victim for contact lenses and remove if present.
Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.
IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.
Gently wash all affected skin areas thoroughly with soap and water.
If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.
If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.
Provide proper respiratory protection to rescuers entering an unknown atmosphere.
Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING.
If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.
Be prepared to transport the victim to a hospital if advised by a physician.
If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.
DO NOT INDUCE VOMITING.
IMMEDIATELY transport the victim to a hospital.
Hazard classification & labelling of Iso Butyl Methacrylate
Warning! According to the harmonised classification and labelling (ATP13) approved by the European Union, this substance is a flammable liquid and vapour, causes skin irritation, may cause an allergic skin reaction and may cause respiratory irritation.
About Iso Butyl Methacrylate
Iso Butyl Methacrylate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 10 000 to < 100 000 tonnes per annum.
Iso Butyl Methacrylate is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.
Formulation or re-packing of Iso Butyl Methacrylate
Iso Butyl Methacrylate is used in the following products: polymers.
Release to the environment of Iso Butyl Methacrylate can occur from industrial use: formulation of mixtures and formulation in materials.
Iso Butyl Methacrylate is used in the following products: polymers.
Iso Butyl Methacrylate is used in the following areas: offshore mining.
Iso Butyl Methacrylate is used for the manufacture of: plastic products.
Release to the environment of Iso Butyl Methacrylate can occur from industrial use: for thermoplastic manufacture, in the production of articles and as an intermediate step in further manufacturing of another substance (use of intermediates).
Manufacture of Iso Butyl Methacrylate
Release to the environment of Iso Butyl Methacrylate can occur from industrial use: manufacturing of the substance.
Isobutyl methacrylate is a colorless liquid with a flash point of 120 °F. When heated to high temperatures it may release acrid smoke and fumes. If it is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization. If the polymerization takes place inside a container, the container may violently rupture. The vapors are heavier than air. Isobutyl methacrylate may be irritating to skin and eyes and produce a narcotic effect. Isobutyl methacrylate is used in making acrylic resins.
