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K-FLEX 850S
CAS-Number: Chemical Name: Weight%:
120-55-8 Diethylene glycol dibenzoate 65-<75
27138-31-4 Dipropylene glycol dibenzoate 15-<20
K-Flex 850S is a blend of diethylene glycol dibenzoate and dipropylene glycol dibenzoate
K-Flex 850S is non-phthalate, low-VOC plasticizer.
The composition of K-Flex 850S of classic dibenzoate plasticizers is optimized for waterborne latex applications.
K-Flex 850S – Classic dibenzoate blend based on DEGDB and DPGDB optimized for waterborne latex applications.
K-Flex 850S - Blend of dipropylene glycol/diethylene glycol dibenzoates, abbreviated 850S.
K-Flex 850S - a commercial diblend of diethylene glycol a d dipropylene glycol dibenzoates (DEG/DPG DB).
Benzoate plasticizers include dibenzoates and monobenzoates, such as diethylene glycol dibenzoate (DEGDB) and dipropylene glycol dibenzoate (DPGDB) esters that have been used in a wide variety of polymer applications, including in the vinyl industry.
DEGDB is an excellent plasticizer, but due to its high freeze point, blends with DPGDB were also developed to capitalize on the utility and lower cost of DEGDB.
Several years ago a blend of DEGDB, DPGDB and triethylene glycol dibenzoate (TEGDB) was introduced as a high solvating dibenzoate blend.
More recently, a new dibenzoate triblend was introduced as a low VOC plasticizer/coalescent for use in plastisols, adhesives, architectural paint and coatings, and polishes, among other applications.
This triblend, comprising DEGDB, DPGDB and 1,2-propylene glycol dibenzoate (PGDB) in various ratios and sold as K-FLEX 975P, has been found to be very versatile for a variety of applications, based on its broad range of compatibilities with polymers utilized in the coatings industry (for example, in vinyl acrylic, acrylic and styrene acrylic types) and possesses good solvating properties and low volatility.
Its performance properties compare favorably to traditional high solvating phthalate plasticizers as well as traditional benzoate ester plasticizers.
Results set forth herein show the triblend to be a high solvating plasticizer that enhances the performance properties of 1,2-cyclohexane dicarboxylate esters, such as 1,2-cyclohexane dicarboxylic acid diisononyl ester, commercially available through a number of manufacturers.
Monobenzoate esters known to be useful as plasticizers include: isodecyl benzoate, isononyl benzoate, and 2-ethylhexyl benzoate.
The use of 2-ethylhexyl benzoate in a blend with DEGDB and diethylene glycol monobenzoate is described.
The use of isononyl esters of benzoic acid as film-forming agents in compositions such as emulsion paints, mortars, plasters, adhesives, and varnishes.
The K-Flex dibenzoate plasticiser product line contains a variety of high solvating dibenzoate plasticisers for PVC applications.
K-Flex 850P and K-Flex 975P have found broad utility as fast fusers in numerous applications and have served as tools for formulators to increase fusion speed, compatibility, and performance when switching from traditional phthalates to the less compatible phthalate alternatives.
In addition, the K-Flex plasticisers impart exceptional stain and extraction resistance, especially versus oily solvents.
As little as 15% DOTP can be offset using K-Flex 850P or K-Flex .
The plasticizer of focus is propylene glycol dibenzoate (K-FLEX PG).
When blended with two traditional dibenzoates, it is part of a product called K-FLEX 975P, diethyl phthalate plasticizer.
Diethyl phthalate (C12H14O4), or DEP is a diethyl ester of phthalic acid.
DEP is used as a plasticizer in consumer goods, including plastic packaging films, cosmetics, solvent for fragrances, a surface lubricant in food and pharmaceutical packaging, and in tubing used for medical purposes.
K-FLEX plasticizers optimize manufacturing processes and the properties of end-products.
They are highly compatible with polar polymers in water-based adhesive systems and they improve the film formation of paints and coatings.
In PVC production, the fast-gelling dibenzoates can speed up processes, helping formulators achieve greater efficiency.
K-FLEX plasticizers have become standard plasticizers for adhesive products.
They improve the processability of many polar polymers used in water-based latex and hot-melt adhesives.
They further lower the glass transition temperature of the binder and thus enhance its adhesiveness.
K-FLEX plasticizers are mainly used in protective coatings such as underbody protection and seam sealers.
They are more effective at gelling PVC than common standard plasticizers.
As a result, they allow shorter cycle times or lower processing temperatures, making production more efficient.
In paints and coatings, K-FLEX dibenzoates are excellent at increasing film-formation, even at lower temperatures.
This means that polymers become solid at a certain temperature and no longer flow together, which impairs film-formation.
Plasticizers ensure that this temperature, the so-called minimum film formation temperature, can be reduced.
Thus, these products can even be processed at room temperature.
K-FLEX dibenzoates are the go-to alternative to volatile solvents.
The K-FLEX line of low-volatile coalescing agents is highly compatible with the typical polymeric binders used in these applications, such as acrylates, vinyl and styrene acrylates, polyvinyl acetate and ethylene vinyl acetate.
K-FLEX coalescing agents help produce paints and coatings with a superior surface appearance and high durability.
In order to create a paper surface that could be used in packaging, for example, additives are needed.
They enhance the coating process and improve the resulting products.
K-FLEX products for coating paper and cardboard are safe for use in packaging with food contact.
K-FLEX products provide optimum performance in sealants and joint compounds.
This includes articles based on polyacrylates, polyvinyl acetate, their copolymers and silane-terminated sealants.
For reactive polyurethane applications, low hydroxyl dibenzoates have been developed to ensure consistency in the production of shelf-stable sealants.
In polysulfide sealants, the dibenzoates serve as an alternative to phthalates, which have been used up to now.
K-FLEX dibenzoates are known for their excellent gelling properties in a wide range of polymers, including PVC.
As additional plasticizers, they can supplement moderately-gelling standard plasticizers.
In both cases, this results in lower processing temperatures and/or shorter processing times.
The flexible PVC products produced show better stain resistance and create high wear-proof surfaces.
Typical applications are floor and wall coverings, artificial leather and gloves.
Nail care and depilatory waxes are just some of the personal care products that our additives are used for.
Personal care is one field where our products with a low ecological footprint are truly appreciated.
K-FLEX plasticizers are an excellent phthalate-free solution for formulators looking to satisfy both legislative requirements and consumer demand.
K-FLEX plasticizers offer equal or superior performance over other recognized plasticizers and coalescents in a wide range of applications including adhesives, caulks, sealants, coatings, and vinyl/plastisol applications
USES and APPLICATIONS of K-FLEX 850S:
-Adhesives:
Putty
-Adhesives:
Water-based Latex Adhesives
-Paper:
Paper Coating
-Sealant:
Polysulphide Sealants
-Adhesives:
Putty:
Effective and economical plasticizer; vehicle used in peroxide paste for putty
-Graphic Arts & Printing:
Flexographic Ink
-Adhesives:
Water-based Latex Adhesives:
Highly recommended, low VOC plasticizer for water-based latex adhesives
-Paints & Coatings:
Concrete and Metal Primer, Exterior Latex Paint, Industrial Coatings, Interior Latex Paint, Lacquers – Nitrocellulosic & Acrylic, and Special Purpose Coatings
-Graphic Arts & Printing:
Flexographic Ink:
Highly recommended, low VOC coalescent for flexographic inks and waterborne OPV applications
-Paints & Coatings:
*Concrete and Metal Primer:
Highly recommended coalescent for direct-to-metal coatings
*Exterior Latex Paint:
Highly recommended coalescent for exterior latex paints
*Floor Polish:
Recommended, non-phthalate plasticizer for floor polish applications, allowing reduced TBEP loading and improved gloss development between consecutive coats, leveling, recoatability, hardness development, removeability, and resistance to soiling, water spots, and powdering
*Industrial Coatings:
Highly recommended, low VOC coalescent for industrial coatings applications
*Interior Latex Paint:
Highly recommended coalescent for interior latex paints
*Lacquers – Nitrocellulosic & Acrylic:
Effective, low VOC coalescent for nitrocellulosic and acrylic lacquers
*Special Purpose Coatings:
Highly recommended, low VOC coalescent for special purpose coatings applications
-Paper:
Paper Coating:
Highly recommended, low VOC coalescent for paper coatings
-Sealant: Polysulfide Sealants:
General plasticizer with excellent compatibility for polysulfide sealants
-K-Flex 850S achieves excellent performance and compatibility in waterborne adhesives, latex caulks, and polysulfide & reactive sealants, including acrylic, VAE, PVAc, STPE, and STPU type chemistries.
-K-Flex 850S is suitable for food contact- and pressure sensitive adhesives.
-K-Flex 850S provides excellent performance properties, such as wet tack, extended open times, chalk point/Tg suppression, reduced set times, and strong viscosity response of the base emulsion to the plasticizer (demonstrating compatibility and allowing flexibility).
-K-Flex 850S is optimized for performance, compatibility and economy in waterborne latex applications.
-K-Flex 850S is very effective for hot melt adhesives and putty.
-K-Flex 850S is a viable option for food packaging adhesives.
-K-Flex 850S is label-free grade.
-K-Flex 850S is a dibenzoate plasticizer optimized for performance, compatibility, and economy in waterborne latex applications.
-K-Flex 850S is a very effective, low-VOC choice for waterborne adhesives, as well as hot melt adhesives and putty.
-With FDA approvals for direct food contact, K-Flex 850S is a viable option for food packaging adhesives.
-In both VAE an PVAc emulsions, K-Flex 850S provides excellent performance properties, such as wet tack, extended open times, chalk point/Tg suppression, reduced set times, and strong viscosity response of the base emulsion to the plasticizer (demonstrating compatibility and allowing flexibility).
-K-Flex 850S can also be used in direct-to-metal and corrosion resistant coatings, where it demonstrates notable hardness development and salt fog resistance.
-K-Flex 850S is not recommended for PVC applications.
-The composition of K-Flex 850S of classic dibenzoate plasticizers is optimized for waterborne latex applications.
-K-Flex 850S is a classic dibenzoate blend based on DEGDB and DPGDB optimized for waterborne latex applications.
-In coatings, K-Flex 850S is low in VOCs to assist the formulator on issues of VOC reduction.
-Other applications of K-Flex 850S include use in acrylic systems.
-A low VOC blend of dibenzoates optimized for use in waterborne latex applications.
-K-Flex 850S is widely used in the industry because of the excellent combination of efficiency, economy and performance benefits it provides to the formulator.
-Highly solvated water-based adhesives are often use K-FLEX 850S.
-K-Flex 850S has full FDA approvals for adhesives and was created to maximize on efficiency and cost effectiveness.
-In coatings K-Flex 850S is low in VOC to assist the formulator on issues of VOC reduction.
-K-Flex 850S is not recommended for PVC applications; however, K-Flex 850S can be used in other applications such as polysulphide sealants
-K-Flex 850S is economical to use and tailored to provide good handling and excellent compatibility in waterborne systems.
-K-Flex 850S is highly recommended for direct-to-metal coatings such as primers, interior and exterior latex paints, floor polishes, and industrial and protective coatings.
-K-Flex 850S is also effective in nitrocellulosic and acrylic lacquers.
-K-Flex 850S is used as plasticizer , adhesive material.
-K-Flex 850S - optimized for waterborne latex applications.
-In coatings, K-Flex 850S is low in VOCs to assist the formulator on issues of VOC reduction.
-Other applications of K-Flex 850S include use in polysulphide & acrylic systems.
-Dibenzoate plasticizers such as K-Flex 850S provide strong viscosity response of the base emulsion to the plasticizer, demonstrating compatibility and allowing flexibility.
-In coatings, K-Flex 850S is low in VOCs to assist the formulator on issues of VOC reduction.
-K-Flex 850S is not recommended for PVC applications.
-In the EU, K-Flex 850S is label-free.
-K-Flex 850S and other K-FLEX dibenzoate products offer benefits in manufacturing, due to their high compatibility with a wide range of polymers and systems, providing:
● Excellent viscosity response and chalk point/Tg depression,
● Extended open/reduced set times,
● Improved wet tack, and
● Improved dry resistance to oil, grease, and water.
-In latex adhesives, dibenzoate plasticizers such as K-Flex 850S provide excellent performance in both VAE and PVAc emulsions when compared to other commercially available alternatives.
-A value-added blend of traditional dibenzoate plasticizers optimized for waterborne applications.
-Very effective low-VOC choice for waterborne adhesives and latex caulks.
-K-Flex 850S – Classic dibenzoate blend based on DEGDB and DPGDB optimized for waterborne latex applications.
-K-FLEX produces flexible elastomeric foam, polyethylene and mineral wool insulating pipes and sheets.
Self-adhesive versions are also available.
A variety of product types, from tubing to flat sheeting, is available with specific technical characteristics for individual applications.
Whenever applied outdoors K-FLEX products must be covered or clad for UV and wheater protection (e.g. Aluminum, steel, K-FLEX AL CLAD, K-FLEX IC CLAD or K-FLEX IN CLAD)
Where the tubing has to be cut for applications purposes, its thermal insulating characteristics are maintained using the proper K-FLEX glue.
With large diameter pipes or conduits, insulation is carried out using elastomeric sheets cut to size.
-K-FLEX recommends that fitting has to be carried out to the highest possible standards to optimise the insulation effectiveness
-K-FLEX ADHESIVES:
K-FLEX provides different types of adhesive:
K-414 for the most common civil application K-420 recomended for high performance insulation in both civil and oil&gas project K-425 recomended for high temperature insulation with SOLAR HT insulation product.
-K-FLEX THINNER:
It is recommended that surfaces to be insulated should first be cleaned with K-FLEX thinner, which is suitable for use with K-FLEX glue.
The glue will adhere perfectly to surfaces cleaned with the proprietory thinner.
K-FLEX thinner can also be used to clean tools (brush, spatula, etc.).
-K-FLEX FINISH:
K-FLEX finish is an acrylic paint that can be diluted in water to protect insulation both indoors and outdoors.
The paint is environmentally safe and odorless, making it particularly suitable for use in confined spaces.
It gives a professional, durable finish.
It dries rapidly, and provides excellent coverage.
When used as a primer, subsequent layers of white paint retain their color even in dark surroundings.
Colors are fade resistant.
-K90 ELBOWS and “TEES”:
A useful accessories pre-cut in the thickness and diameter required.
-K-FLEX INSULATED PIPE SUPPORTS:
Specifically designed to ensure that thickness of the insulating material is absolutely correct, especially in the fixing points.
-K-FLEX ADHESIVE INSULATING TAPE:
Special, 3mm thick, selfadhesive, 5 cm wide insulating tape for covering gaps or sealing insulated sections.
-K-FLEX GLUE DISPENSER:
It facilitates the glueing of the surface avoiding the continuous dipping of the brush in the can.
The controlled flow of the adhesive allows proper and regular quantity on the surface to glue.
PHYSICAL and CHEMICAL PROPERTIES of K-FLEX 850S:
Color (APHA): 40
Density, ASTM D1475, 25°C g/ml: 1.14
Density, ASTM D1475 ,25°C lbs/gal: 9.6
Flash Point, ASTM D92, °C: 193
Freeze Point, °C: 14
Glass Point, by DSC, °C: -55
Moisture Content, %: 0.02
Refractive Index, 25°C: 1.5361
Solubility, in water, %: 0.55
Solubility Parameter, Small’s Hildebrands: 9.8
Specific Gravity, 25/25°C: 1.14
Surface Tension, ASTM D1331, 25°C, dynes/cm: 45.0
Viscocity, Brookfield RVT, 20 RPMs at 25°C, cps and mPa.S: 72
Viscosity, Kinematic, 25deg;C, cSt: 63
VOC, ASTM D2369, %: 2.2
Form: Liquid
pH: Not Available
Appearance: Colorless to light yellow
Relative density: 1.14
Odor: Slight aromatic
Partition coefficient (noctanol/water): >3 - <4
Odor threshold: Not Available
% Volatile by weight: 2.2%
Solubility in water: Negligible
VOC: 2.2% ASTM D2369
Evaporation rate: Slower than n-butyl acetate
Boiling point °C: >330 °C @ 760 mm Hg (extrapolated)
Vapor pressure: 0.0000903 mm Hg @ 25°C (extrapolated)
Boiling point °F: >626 °F @ 760 mm Hg (extrapolated)
Vapor density: Heavier than air
Flash point: 193°C (379°F) ASTM D-92
Viscosity: 63 mm2/s @ 25°C
Auto-ignition temperature: Not Available
Melting point/Freezing point: 14 °C (57 °F)
Flammability (solid, gas): Not Applicable (liquid)
Oxidizing properties: Not oxidizing
Flammability or explosive limits: LFL/LEL: Not Available
Explosive properties: Not explosive
UFL/UEL: Not Available
Decomposition temperature: Not Available
Surface tension: 45 dynes/cm @ 25°C (ASTM D1331)
FIRST AID MEASURES of K-FLEX 850S:
-Description of first aid measures:
*Eye contact:
Any material that contacts the eye should be washed out immediately with water.
Get medical attention if symptoms occur.
*Skin contact:
Wash the affected area thoroughly with plenty of soap and water.
Get medical attention if symptoms occur.
*Inhalation:
If affected, remove to fresh air.
Get medical attention if symptoms occur.
*Ingestion:
Do not induce vomiting.
Rinse out the mouth with water.
Get medical attention immediately.
*Protection of first aid responders:
Wear proper personal protective clothing and equipment.
-Indication of any immediate medical attention and special treatment needed:
Treat symptomatically.
ACCIDENTAL RELEASE MEASURES of K-FLEX 850S:
-Environmental precautions:
Do not flush liquid into public sewer, water systems or surface waters.
-Methods and material for containment and cleaning up:
Wear proper personal protective clothing and equipment.
Absorb spill with an inert material.
Change contaminated clothing and launder before reuse.
FIRE FIGHTING MEASURES of K-FLEX 850S:
-Extinguishing media:
*Suitable:
Use water spray, ABC dry chemical, foam or carbon dioxide.
Water or foam may cause frothing.
Use water to keep fire-exposed containers cool.
Water spray may be used to flush spills away from exposures.
*Unsuitable:
None known.
EXPOSURE CONTROLS/PERSONAL PROTECTION of K-FLEX 850S:
-Exposure controls:
--Individual protection measures, such as personal protective equipment:
*Eye/face protection:
Wear eye protection.
*Skin and body protection:
Use good laboratory/workplace procedures including personal protective clothing:
labcoat, safety glasses and protective gloves.
*Respiratory protection:
Respiratory protection is not needed with proper ventilation.
*Further information:
Eyewash fountains and safety showers are recommended in the work area.
HANDLING and STORAGE of K-FLEX 850S:
-Precautions for safe handling:
As with any chemical product, use good laboratory/workplace procedures.
Wash thoroughly after handling this product.
Always wash up before eating, smoking or using the facilities.
Wash contaminated clothing before reuse.
-Conditions for safe storage, including any incompatibilities:
Store cool and dry, under well-ventilated conditions.
Do not store in open, unlabeled or mislabeled containers.
Keep container closed when not in use.
Do not reuse empty container without commercial cleaning or reconditioning.
STABILITY and REACTIVITY of K-FLEX 850S:
-Reactivity:
None known.
-Chemical stability:
This product is stable.
-Possibility of hazardous reactions:
Hazardous polymerization will not occur.
