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MAA (METHACRYLIC ACID)


CAS NO:79-41-4
EC NO:201-204-4

MAA (Methacrylic Acid)  is an organic compound. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. 
MAA (Methacrylic Acid)  is soluble in warm water and miscible with most organic solvents. 
MAA (Methacrylic Acid)  is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate (MMA) and poly(methyl methacrylate) (PMMA). MAA (Methacrylic Acid)  occurs naturally in small amounts in the oil of Roman chamomile.

Properties:
Chemical formula:    C4H6O2
Molar mass:    86.09 g/mol
Appearance:    Colorless liquid or solid
Odor:    Acrid, repulsive
Density:    1.015 g/cm3
Melting point:    14 to 15 °C (57 to 59 °F; 287 to 288 K)
Boiling point:    161 °C (322 °F; 434 K)
Solubility in water:    9% (25 °C)
Vapor pressure:    0.7 mmHg (20 °C)

Production
In the most common route, methacrylic acid is prepared from acetone cyanohydrin, which is converted to methacrylamide sulfate using sulfuric acid. This derivative in turn is hydrolyzed to methacrylic acid, or esterified to methyl methacrylate in one step. In the second route, isobutylene or tert-butanol are oxidized to methacrolein, then methacrylic acid. Methacrolein for this purpose can also be obtained from formaldehyde and ethylene. Isobutyric acid can also be dehydrogenated to methacrylic acid.

MAA (Methacrylic Acid)  can also be prepared by decarboxylation of itaconic acid, citraconic acid, and mesaconic acid. Such green precursors are not of commercial value. 
MAA (Methacrylic Acid)  is, however, obtained by boiling citra- or meso-brompyrotartaric acids with alkalis.

Uses
MAA (Methacrylic Acid)  is used in some nail primers to help acrylic nails adhere to the nail plate.

Mainly used in paints, adhesives, and leather treatment agents, methacrylic acid is also used as a raw material in the manufacture of ion-exchange resins.

Applications:
-Paint
-Adhesive
-Fiber processing agent
-Rubber modifier
-Leather treatment
-Paper processing agent
-Lubricant additive
-Cement mixing agent

MAA (Methacrylic Acid) is a functional monomer, an unsaturated monocarboxylic acid. 
MAA (Methacrylic Acid) reacts as a vinyl compound and as a carboxylic acid. 
MAA (Methacrylic Acid) easily undergoes polymerization and addition reactions. The copolymers of Methacrylic Acid (MAA) can be prepared with acrylic and methacrylic esters, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, ethylene, and other monomers.

Product Type: Methacrylate Monomer

Features & Benefits:
-Adhesive ability
-Hydrophilic
-Water solubility
-Required rheological properties

Applications areas:
Polymethacrylic Acid (PMAA) and Methacrylic Acid (MAA) copolymers are used in pulp and paper, paint and varnish, textile, medicine, in the petrochemical field and oil production as binders, film-forming agents, thickeners, adhesives, drilling reagents, dressing preparations, etc.
MAA (Methacrylic Acid) copolymers are used in the manufacture of ion exchange resins and superabsorbents.
MAA (Methacrylic Acid) is used to synthesize its esters and salts.

MAA (Methacrylic Acid) is applied in the production of:
-Coatings
-Pulp & Paper
-Paint & Varnishes
-Adhesives & Sealants
-Leather & Textile
-Film-forming agents
-Thickeners
-Lubricants
-Materials used in medicine
-Plastics
-Oilfield
-Drilling agents
-Dressing preparations

MAA (Methacrylic Acid) is a polymerizable, unsaturated, monocarboxylic acid functional monomer. In copolymers, low levels (≤5%) of MAA (Methacrylic Acid) improve latex stability, adhesive properties,  wettability and pigment dispersion, as well as allowing for post-crosslinking reactions. At higher levels of MAA, copolymers are used as thickening agents and rheology modifiers, paper coatings, personal care products, oil field chemicals, processing agents and water-soluble polymers.  

MAA (Methacrylic Acid) is a clear, colorless liquid with a molecular weight of 86.06 g/mol, a freeze point of ca. 14 °C, a boiling point of 161 °C, and a viscosity of 1.5.

MAA (Methacrylic Acid) is used in copolymers to enhance performance in adhesives, caulks, sealants, paint, coatings, varnishes, printing inks, and textile finishes. Higher levels of MAA (Methacrylic Acid) are used in copolymers for applications such as thickeners, dispersants, wetting agents, and flocculants.  Virtually all acrylic copolymers produced commercially contain one of two key monomers - MAA or GAA.  

MAA (Methacrylic Acid) is formed via the acetone cyanohydrin (ACH) route to manufacture MMA and is used in many applications, which include the production of speciality methacrylates for automotive coatings, in cement modifiers, NBR latex for disposable synthetic rubber gloves and in vinyl ester resins. 

MAA (Methacrylic Acid) contributes a number of additional beneficial properties including surface adhesion, toughness and chemical resistance.
MAA (Methacrylic Acid) appears as a clear colorless liquid (or low-melting solid) with a pungent odor. Corrosive to metals and tissue. Flash point 170°F. Melting point 61°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Less dense than water. Vapors heavier than air. Used to make plastics.

MAA (Methacrylic Acid), stabilized appears as a clear colorless liquid with a pungent odor. Corrosive to metals and tissue. Combustible. Flash point 170°F. Melting point 61°F. May polymerize if contaminated or heated. If polymerization takes place inside a closed container, the container may violently rupture. Less dense than water and is soluble in water. Vapors heavier than air. Used to make plastics.

MAA (Methacrylic Acid) is an alpha,beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position is substituted by a methyl group. 
MAA (Methacrylic Acid) derives from an acrylic acid. 
MAA (Methacrylic Acid) is a conjugate acid of a methacrylate.

Industry Uses:
-Adhesives and sealant chemicals
-Functional fluids (open systems)
-Intermediates
-Paint additives and coating additives not described by other categories
-Pharmaceutical and Medicine manufacturing
-Photosensitive chemicals
-Viscosity adjustors

Consumer Uses:
-Paints and coatings

Industry Processing Sectors:
-All other basic organic chemical manufacturing
-Paint and coating manufacturing
-Pharmaceutical and medicine manufacturing
-Plastic material and resin manufacturing
-Wholesale and retail trade

MAA (Methacrylic Acid), is an organic compound.
This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor.
MAA (Methacrylic Acid) is soluble in warm water and miscible with most organic solvents.
MAA (Methacrylic Acid) is produced industrially on a large scale as a precursor to its esters,
especially methyl methacrylate (MMA) and poly(methyl methacrylate) (PMMA).
The methacrylates have numerous uses, most notably
in the manufacture of polymers with trade names such as Lucite and Plexiglas.
MAA (Methacrylic Acid) occurs naturally in small amounts in the oil of Roman chamomile.

Uses
Textile processing : Sizing
Leather technology : Binding, Tanning agent
Ion-exchange resins : Water treatment
Cosmetics : Thickening agent, Suspending agent
Oil-well drilling : Drilling-mud additive, Anti-caking agent
Paper industry : Filler-retention aid
Industrial-waste treatments : Suspending agent, Flocculating agent
Transportation : Skid-proof tires
Rubber industry : Creaming of latex
Agriculture : Solid conditioners
Others : Coating, Adhesive

MAA (Methacrylic Acid) is a colorless liquid or crystals with an unpleasant odor. MAA (Methacrylic Acid) reacts with strong oxidizing agents and is water soluble.

MAA (Methacrylic Acid) is used in plastic sheets, molded and extruded products, modifiers, and harder components of copolymers with acrylates for similar applications. 
MAA (Methacrylic Acid) is favored for its hardness, flexibility, clarity, color compatibility, toughness, internal plasticization, and weatherability.

MAA (Methacrylic Acid) is a carboxylic acid with the chemical formula C4H6O2. The substance occurs as a colorless liquid or, in the solid state, colorless.

MAA (Methacrylic Acid) is an organic compound. 
MAA (Methacrylic Acid) is a monofunctional methacrylayte monomer. 
MAA (Methacrylic Acid) is used as a starting material for the production of its esters, especially methyl methacrylate and poly methyl methacrylate (PMMA)

MAA (Methacrylic Acid) is a colorless liquid.

About MAA (Methacrylic Acid)
Helpful information
MAA (Methacrylic Acid) is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 100 000 to < 1 000 000 tonnes per annum.

MAA (Methacrylic Acid) is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Consumer Uses
MAA (Methacrylic Acid) is used in the following products: adhesives and sealants.
Other release to the environment of MAA (Methacrylic Acid) is likely to occur from: outdoor use, indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters).

Article service life
Other release to the environment of MAA (Methacrylic Acid) is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
MAA (Methacrylic Acid) can be found in complex articles, with no release intended: vehicles, machinery, mechanical appliances and electrical/electronic products (e.g. computers, cameras, lamps, refrigerators, washing machines) and electrical batteries and accumulators.
MAA (Methacrylic Acid) can be found in products with material based on: plastic (e.g. food packaging and storage, toys, mobile phones), rubber (e.g. tyres, shoes, toys), stone, plaster, cement, glass or ceramic (e.g. dishes, pots/pans, food storage containers, construction and isolation material), fabrics, textiles and apparel (e.g. clothing, mattress, curtains or carpets, textile toys), leather (e.g. gloves, shoes, purses, furniture), metal (e.g. cutlery, pots, toys, jewellery), paper (e.g. tissues, feminine hygiene products, nappies, books, magazines, wallpaper) and wood (e.g. floors, furniture, toys).

Widespread uses by professional workers
MAA (Methacrylic Acid) is used in the following products: inks and toners, coating products, polymers, adhesives and sealants, non-metal-surface treatment products, paper chemicals and dyes and washing & cleaning products.
MAA (Methacrylic Acid) has an industrial use resulting in manufacture of another substance (use of intermediates).
MAA (Methacrylic Acid) is used in the following areas: building & construction work, printing and recorded media reproduction and scientific research and development.
MAA (Methacrylic Acid) is used for the manufacture of: , plastic products and electrical, electronic and optical equipment.
Other release to the environment of MAA (Methacrylic Acid) is likely to occur from: outdoor use and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).

Formulation or re-packing
MAA (Methacrylic Acid) is used in the following products: polymers, non-metal-surface treatment products, inks and toners, laboratory chemicals, paper chemicals and dyes and washing & cleaning products.
MAA (Methacrylic Acid) has an industrial use resulting in manufacture of another substance (use of intermediates).
Release to the environment of MAA (Methacrylic Acid) can occur from industrial use: formulation of mixtures and formulation in materials.

Uses at industrial sites
MAA (Methacrylic Acid) is used in the following products: polymers, coating products, inks and toners and adhesives and sealants.
MAA (Methacrylic Acid) has an industrial use resulting in manufacture of another substance (use of intermediates).
MAA (Methacrylic Acid) is used for the manufacture of: chemicals and plastic products.
Release to the environment of MAA (Methacrylic Acid) can occur from industrial use: for thermoplastic manufacture, as an intermediate step in further manufacturing of another substance (use of intermediates) and in the production of articles.

Manufacture
Release to the environment of MAA (Methacrylic Acid) can occur from industrial use: manufacturing of the substance, in processing aids at industrial sites, in the production of articles, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, for thermoplastic manufacture, as processing aid and of substances in closed systems with minimal release.

IUPAC names:
2- methylpropenoic acid
2-methyl-2-propenic acid
2-Methyl-2-propenoic acid
2-methylacrylic acid
2-Methylprop-2-enoic acid
2-methylprop-2-enoic acid
2-methylprop-2-enoic acid
2-methylpropenic acid
2-methylpropenoic acid
2-Propenoic acid, 2-methyl-
MAA
Methacrylic acid
methacrylic acid
Methacrylic Acid
Methacrylic acid
methacrylic acid
Methacrylic Acid (stabilized with MEHQ)
METHACRYLIC ACID(38780)
methacrylic acid; 2-methylpropenoic acid
Methacrylsäure
methyacrylate acid
methyl propenoate
sodium 2-methylprop-2-enoate

SYNONYMS:
2-METHACRYLIC ACID
2-METHYLACRYLIC ACID
2-METHYLPROPENOIC ACID
MAA
METHACRYLIC ACID
PROPYLENE-2-CARBOXYLIC ACID
RARECHEM AL BO 0090
.alpha.-Methylacrylicacid
2-Methyl-2-propenoic acid
2-methyl-2-Propenoicacid
2-Methyl-2-propensαure
2-methyl-acrylicaci
2-methylene-propionicaci
2-methylenepropionicacid
2-Methylpropencicacid
2-Propenoicacid,2-methyl-
acidemethacrylique
acidemethacrylique(french)
acidometacrilico
Acrylic acid, 2-methyl-
15802-18-3 [RN]
1719937 [Beilstein]
201-204-4 [EINECS]
2-Methacrylic acid
2-Methylene propionic acid
2-methylprop-2-enoic acid
2-methylpropenoic acid
2-Propenoic acid, 2-methyl- [ACD/Index Name]
2-Propenoic acid, 2-methyl-, endo-
79-41-4 [RN]
Acide methacrylique [French]
Acide méthacrylique [French] [ACD/IUPAC Name]
Acido metacrilico [Spanish]
a-Methylacrylic Acid
Kyselina methakrylova [Czech]
Methacrylic acid [ACD/IUPAC Name]
Methacrylsäure [German] [ACD/IUPAC Name]
MFCD00002651 [MDL number]
MFCD00002701 [MDL number]


 

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