MANGANESE SULPHATE

Manganese sulphate usually refers to the inorganic compound with the formula MnSO4·H2O. 
Manganese sulphate can also be made by mixing potassium permanganate with sodium bisulfate and hydrogen peroxide.
Manganese sulphate is a metal sulfate in which the metal component is manganese in the +2 oxidation state. 

CAS Number  : 7785-87-7 
EC Number   : 232-089-9
ECHA InfoCard     : 100.029.172 
PubChem CID     : 24580
ChemSpider     : 22984
Chemical formula : MnSO4
Molecular Weight : 151.00
Density             : 3.25 g/cm3
Melting point     : 710 °C 
Boiling point     : 850 °C 
 
This pale pink deliquescent solid is a commercially significant manganese(II) salt. 
Approximately 260,000 tonnes of Manganese sulphate were produced worldwide in 2005. 
Manganese sulphate is the precursor to manganese metal and many other chemical compounds. 
Manganese-deficient soil is remediated with this salt.

Structure of Manganese sulphate
Like many metal sulfates, Manganese sulphate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. 
All of these salts dissolve in water to give faintly pink solutions of the aquo complex [Mn(H2O)6]2+. 
The structure of MnSO4·H2O has been determined by X-ray crystallography . 
The tetrahydrate also features Mn(II) in an O6 coordination sphere provided by bridging two sulfate anions and four aquo ligands.

Applications and production of Manganese sulphate
Typically, manganese ores are purified by their conversion to Manganese sulphate. 
Treatment of aqueous solutions of the sulfate with sodium carbonate leads to precipitation of manganese carbonate, which can be calcined to give the oxides MnOx. 
In the laboratory, Manganese sulphate can be made by treating manganese dioxide with sulfur dioxide:

MnO2 + SO2 + H2O → MnSO4(H2O)

Manganese sulphate is a by-product of various industrially significant oxidations that use manganese dioxide, including the manufacture of hydroquinone and anisaldehyde.

Electrolysis of Manganese sulphate
Electrolysis of Manganese sulphate reverses the above reaction yielding manganese dioxide, which is called EMD for electrolytic manganese dioxide. 
Alternatively oxidation of Manganese sulphate with potassium permanganate yields the so-called chemical manganese dioxide (CMD). 
These materials, especially EMD, are used in dry-cell batteries.

Natural occurrence of Manganese sulphate
Manganese sulphate minerals are very rare in nature and always occur as hydrates. 
The monohydrate is called szmikite; the tetrahydrate is called ilesite; the pentahydrate is called jōkokuite; the hexahydrate, the most rare, is called chvaleticeite; and the heptahydrate is called mallardite.

Manganese sulphate has a role as a nutraceutical. 
Manganese sulphate is a metal sulfate and a manganese molecular entity. 
Manganese sulphate contains a manganese(2+).

Manganese sulphate  is a sulfate of manganese. 
Manganese sulphate  is the precursor to manganese metal and many chemical compounds, such as manganese dioxide. 
Manganese sulphate  is a naturally occurring metal with the symbol Mn and the atomic number 25. 
Manganese sulphate  does not occur naturally in its pure form, but is found in many types of rocks in combination with other substances such as oxygen, sulfur, or chlorine. 
Manganese sulphate  occurs naturally in most foods and small amounts are needed to stay healthy, as manganese ions act as cofactors for a number of enzymes.

Definition and Usage Area of Manganese sulphate :
Manganese sulphate  is the inorganic compound with the formula MnSO4. 
This colorless moist solid is a commercially important manganese (II) salt. 
In 2005, approximately 260M kg/y was produced in the world. 

Manganese sulphate  is the precursor of manganese metal and many chemical compounds. 
Manganese sulphate  are corrected with this salt.
Like many metal sulfates, Manganese sulphate  forms various hydrates such as monohydrate, tetrahydrate, pentahydrate, heptahydrate. 
The most common of these is monohydrate. 
These are all pale pink in color.

The chemical formula of MnSO4 contains about 32% Mn of Manganese sulphate. 
This colorless moist solid is a commercially important manganese (II) salt. 
In 2005, the importance of its production has been recognized and its production has become widespread. 
Manganese sulphate is the precursor of manganese metal and many chemical compounds. 
Manganese sulphate has a wide variety of hydrate structure.

Production and Reactions of Manganese sulphate

Manganese sulphate is obtained by reduction of manganese with chloride in acidic medium.
MnO2 4 HCl? MnCl2 Cl2 2 H2O MnO2 2 NaCl 2 H2SO4? MnSO4 Na2SO4 2 H2O Cl2

Usage areas of Manganese sulphate

Agriculture
Manganese sulphate plays an important role in the work of many enzymes in plants. 
Manganese sulphate has been determined that it has a duty to activate about 30-35 enzymes.
Manganese sulphate is used as the participation of soil in appropriate amounts for this purpose.
Manganese sulphate also increases the resistance of the plant against cold.

Chemistry
Manganese sulphate is used in reduction-oxidation (redox) reactions in chemical industry. 
Manganese sulphate is also used in the production of electrolyte manganese.

Ceramic
This sector is used in the manufacture and disinfection of porcelain.

Paint
Manganese sulphate is used as a drying agent in varnishes and colored materials in the paint sector.

Manganese sulphate is the inorganic compound with the formula MnSO4. 
Manganese sulphate is a light pink moisture-melting solid, commercially important manganese(II) salt. 
Manganese sulphate is the precursor of manganese metal and many other chemical compounds. 

Manganese-deficient soil is removed with this salt.
Like many metal sulfates, Manganese sulphate forms various hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. All these salts dissolve in water to give 2+ pale pink solutions of aquo complex [Mn (H2O) 6].
Manganese sulphate minerals are very rare in nature and always exist as hydrates.

Sectors of Manganese sulphate used 
-In animal feed
-As a fertilizer in the agricultural sector
-In the battery manufacturing industry
-In drinking water treatment
-steel industry
-Aluminum and manganese alloys

Usage areas  of Manganese Sulphate
-Manganese, which is necessary for the healthy growth of pasture animals, is used as a supplement in case of deficiency in animals, chemical products containing manganese sulphate.
-Manganese sulphate is used in the fertilizer contents used to eliminate manganese deficiency in calcareous soils and alkaline soils.
-Manganese Sulphate is used in the purification of drinking water.
-Manganese Sulphate is used in steel making to increase its durability.
-Manganese Sulphate is used to prevent corrosion of manganese and aluminum-containing alloys.
-Manganese Sulphate is a byproduct of various industrially important oxidations used in manganese dioxide, including the production of hydroquinone and anisaldehyde.
-Electrolysis of Manganese Sulphate yields manganese dioxide, called EMD for electrolytic manganese dioxide. 
Alternatively, oxidation of manganese sulfate with potassium permanganate gives the chemical manganese dioxide (CMD). 
These materials, especially EMD, are used in dry cell batteries.

APPLICATION of Manganese Sulphate
Manganese Sulphate is mainly used for making dryer of ink and paint, catalyst of synthetic fatty acid, manganese compound, electrolyze metallic manganese, dyeing manganese oxide, and for printing/dyeing paper making, porcelain/ceramic paint, medicine and other industries. 
Manganese Sulphate can cure the disease caused by manganese insufficiency, such as growth badness, short bone, loose bone, slow growth. etc.

Benefits of Using Manganese Sulphate
-Used to alleviate deficiencies commonly found in Northland, the West Coast and in peat soils
-Applied to soils or as a foliar application for cereal production where a history of manganese deficiency exists
-Provides manganese to the crop immediately because it is readily soluble

First aid measures of Manganese Sulphate

Following inhalation :
Provide fresh air. 
In all cases of doubt, or when symptoms persist, seek medical advice.

Following skin contact :
Rinse skin with water/shower. 
In all cases of doubt, or when symptoms persist, seek medical advice.

Following eye contact : 
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.

Following ingestion : 
Rinse mouth. 
Call a doctor if you feel unwell.

Substance identity

EC / List no.: 232-089-9
CAS no.: 7785-87-7
Mol. formula: MnO4S

Hazard classification & labelling of Manganese sulphate
Warning! According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is toxic to aquatic life with long lasting effects and may cause damage to organs through prolonged or repeated exposure.
Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance causes serious eye damage.

About Manganese sulphate
Manganese sulphate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 10 000 to < 100 000 tonnes per annum.
Manganese sulphate is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Consumer Uses of Manganese sulphate
Manganese sulphate is used in the following products: fertilisers, coating products and non-metal-surface treatment products.
Other release to the environment of Manganese sulphate is likely to occur from: outdoor use and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).

Article service life of Manganese sulphate
Other release to the environment of Manganese sulphate is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials), indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment), outdoor use in long-life materials with high release rate (e.g. tyres, treated wooden products, treated textile and fabric, brake pads in trucks or cars, sanding of buildings (bridges, facades) or vehicles (ships)), indoor use in long-life materials with high release rate (e.g. release from fabrics, textiles during washing, removal of indoor paints) and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners). 

Manganese sulphate can be found in products with material based on: stone, plaster, cement, glass or ceramic (e.g. dishes, pots/pans, food storage containers, construction and isolation material), fabrics, textiles and apparel (e.g. clothing, mattress, curtains or carpets, textile toys), wood (e.g. floors, furniture, toys), leather (e.g. gloves, shoes, purses, furniture) and paper (e.g. tissues, feminine hygiene products, nappies, books, magazines, wallpaper).

Widespread uses by professional workers of Manganese sulphate
Manganese sulphate is used in the following products: fertilisers, coating products, leather treatment products, non-metal-surface treatment products, textile treatment products and dyes, water treatment chemicals and inks and toners.
Manganese sulphate is used in the following areas: agriculture, forestry and fishing, building & construction work and formulation of mixtures and/or re-packaging.
Manganese sulphate is used for the manufacture of: textile, leather or fur, mineral products (e.g. plasters, cement), pulp, paper and paper products, chemicals and furniture.
Other release to the environment of Manganese sulphate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.

Formulation or re-packing of Manganese sulphate
Manganese sulphate is used in the following products: fertilisers, leather treatment products, coating products, non-metal-surface treatment products, inks and toners, textile treatment products and dyes and water treatment chemicals.
Release to the environment of Manganese sulphate can occur from industrial use: formulation of mixtures and formulation in materials.
Other release to the environment of Manganese sulphate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and indoor use in long-life materials with high release rate (e.g. release from fabrics, textiles during washing, removal of indoor paints).

Uses at industrial sites of Manganese sulphate
Manganese sulphate is used in the following products: fertilisers, textile treatment products and dyes, coating products, non-metal-surface treatment products, leather treatment products, water treatment chemicals, pH regulators and water treatment products, plant protection products, cosmetics and personal care products, metals and water softeners.
Manganese sulphate is used in the following areas: agriculture, forestry and fishing, formulation of mixtures and/or re-packaging and building & construction work.
Manganese sulphate is used for the manufacture of: chemicals, textile, leather or fur, plastic products, mineral products (e.g. plasters, cement) and pulp, paper and paper products.
Release to the environment of Manganese sulphate can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, in processing aids at industrial sites and formulation of mixtures.
Other release to the environment of Manganese sulphate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).

Manufacture of Manganese sulphate
Release to the environment of Manganese sulphate can occur from industrial use: manufacturing of the substance.

Synonyms:
Manganese sulphate
Sulfuric acid, manganese(2+) salt (1:1)
manganese sulphate
mangaanisulfaatti (fi)
Mangaansulfaat (et)
mangaansulfaat (nl)
mangano sulfatas (lt)
manganov sulfat (hr)
manganov sulfat (sl)
mangansulfat (da)
Mangansulfat (de)
mangansulfat (no)
mangansulfat (sv)
mangāna sulfāts (lv)
siarczan(VI) manganu(II) (pl)
solfato di manganese (it)
sulfat de mangan (ro)
sulfate de manganèse (fr)
sulfato de manganeso (es)
sulfato de manganés (pt)
síran manganatý (cs)
síran mangánatý (sk)
θειϊκό μαγγάνιο (el)
мaнганов сулфат (bg)mangán-szulfát (hu)
Sulfuric acid, manganese(2+) salt (1:1)
GFU Manganese sulphate C_L
Mangan(II)sulfat monohydrat
Manganese (2+) sulfate
manganese (2+) sulfate
Manganese (II) sulphate
manganese (II) sulphate (monohydrate)
manganese (II) sulphate monohydrate
manganese (II) sulphate-1-water
Manganese sulfate
manganese sulfate
Manganese Sulfate
Manganese sulfate
MANGANESE SULPHATE
Manganese Sulphate
Manganese sulphate
manganese sulphate
Manganese Sulphate
Manganese sulphate
manganese sulphate
manganese sulphate anhydrous
manganese sulphate monohydrate
manganese(2)sulfate hydrate (1:1:1)
manganese(2+) ion sulfate
Manganese(2+) sulfate
manganese(2+) sulfate
manganese(2+) sulphate
manganese(2+);sulfate
manganese(2+);sulfate;hydrate
Manganese(2+);sulphate
manganese(2+)sulphate
Manganese(II) sulfate
manganese(II) sulfate
Manganese(II) sulfate hydrate
Manganese(II) sulphate
Manganese(II)sulfate 1-hydrate
Manganese(II)Sulphate
Manganeses(II)sulphate
Manganeso(II) Sulfato 1-hidrato
sulfate manganese
sulfato de manganeso, sulfato de manganeso monohidratado
Sulfuric acid, manganese(2+) salt (1 1), monohydrate
MANGANESE SULPHATE
manganese sulphate
Techmangam
ZM Grow
025-003-00-4
10034-96-5
139939-61-0
139939-61-0
32916-06-6
32916-06-6
36474-32-5
36474-32-5
7487-89-0
7487-89-0
7785-87-7
Manganese sulphate
Manganese(II) sulfate
7785-87-7
Manganous sulfate
Manganese(2+) sulfate
Manganese monosulfate
Manganese sulfate anhydrous
Manganese sulfate (1:1)
MnSO4
10124-55-7
manganese(2+);sulfate
Manganese(2+) sulfate (1:1)
IGA15S9H40
Sorba-spray Mn
Man-Gro
Sorba-Spray Manganese
Sulfuric acid, manganese salt
Manganese sulfate (MnSO4)
Sulfato de manganeso
CCRIS 6916
HSDB 2187
NCI C61143
EINECS 232-089-9
UNII-IGA15S9H40
Sulfuric acid, manganese (II) salt (1:1)
Manganese(II) sulfate (1:1)
EINECS 233-342-6
Manganese(II)sulfate
manganese(II) sulphate
manganese(2+) sulphate
EC 232-089-9
MANGANESE SULFATE [MI]
DTXSID9044160
CHEBI:86360
Manganese(II) sulfate (MnSO4)
Manganese (II )sulfate anhydrous
MANGANOUS SULFATE ANHYDROUS
MANGANESE SULFATE [WHO-DD]
MANGANESE SULPHATE ANHYDROUS
MANGANESE SULFATE, ANHYDROUS
MANGANESE SULFATE (ANHYDROUS)
MANGANI(II) SULFAS ANHYDRICUS
AKOS015904462
MANGANESE (AS SULFATE) [VANDF]
MANGANESE(2+) SULPHATE (1:1)
MANGANESE SULFATE ANHYDROUS [HSDB]
FT-0628155
M3394
Q409393
J-521672
Manganese(II) sulfate [Wiki]
232-089-9 [EINECS]
7785-87-7 [RN]
IGA15S9H40
Mangan(2+)sulfat [German] [ACD/IUPAC Name]
Manganese monosulfate
manganese sulfate
Manganese sulfate anhydrous
Manganese sulphate
Manganese(2+) sulfate [ACD/IUPAC Name]
Sulfate de manganèse(2+) [French] [ACD/IUPAC Name]
Sulfuric acid, manganese salt
[7785-87-7] [RN]
10034-96-5 [RN]
10101-68-5 [RN]
139939-61-0 [RN]
15244-36-7 [RN]
32916-06-6 [RN]
7487-89-0 [RN]
C039798
dimanganese tris(sulphate)
Dimanganese trisulfate
EINECS 232-089-9
MANGANESE (II) SULFATE
Manganese (II) Sulphate
MANGANESE SULFATE (1:1)
manganese sulfate (MnSO4)
Manganese Sulfate Mono ACS USP FCC
Manganese sulfic acid
Manganese sulphic acid
manganese(+2) cation sulfate
manganese(2+) ion sulfate
Manganese(2+) sulfate (1:1)
manganese(2+) sulphate
manganese(2+);sulfate
Manganese(II) sulfate (1:1)
Manganese(II) sulfate (MnSO4)
MANGANESE(II) SULFATE|MANGANESE(2+) SULFATE
manganese(II) sulphate
manganesesulphate
Manganic sulfate
Manganous sulfate
Manganous sulfate,feeded
Manganous sulphate,anhydrous
MANGANOUSSULFATE
Man-Gro
MFCD00003464
MFCD00149159 [MDL number]
MnSO4
Sorba-Spray Manganese
Sorba-spray Mn
Sulfuric acid manganese(2+) salt (1:1)
Sulfuric acid, manganese (II) salt (1:1) (8CI)
SULFURIC ACID, MANGANESE(2+) SALT
Sulfuric acid, manganese(2+) salt (1:1)
Sulfuric acid, manganese(3+) salt (3:2)
SULFURIC ACID, MANGANESE(II) SALT
UNII:IGA15S9H40
UNII-IGA15S9H40
硫酸锰 [Chinese]