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MERGAL BIT 20

MERGAL BIT 20 is an effective broad-spectrum liquid preservative designed to inhibit the growth of micro-organisms such as bacteria, yeast, and fungi in aqueous based formulations


Mergal BIT 20 by Troy Corporation acts as a biocide. Based on BIT chemistry and compatible over a wide pH range. 
Mergal BIT 20 is heat stable and formaldehyde-free. 
Mergal BIT 20 offers high pH formulations and is compatible with amines as well as amine containing additives. 
Mergal BIT 20 is designed to inhibit the growth of microorganisms such as bacteria, yeast, and fungi in aqueous based formulations.


MERGAL BIT20
For Industrial Use Only As A Microbiostat Preservative Intended To Protect Adhesives, Building And Construction Compositions, Emulsion Paint And Coatings, Inks, Lattices, Leather Processing Solutions, Metalworking Fluids, Mineral Slurries And Dispersions, Oil Recovery Systems, Paper Coatings, Pesticide Formulations, Polymer Emulsions, Textile Spin-Finish And Coatings, Car Care Products Including Car Washes, Car Waxes And Silicone Emulsions, Home Care Cleaning Products Including Floor Cleaners, Floor Waxes, Floor Polishes And Surface Cleaners, Laundry Additives Including Liquid Laundry Detergents, Fabric Softeners And Stain Removers.
ACTIVE INGREDIENT: ....................................... % Weight
1,2-Benzisothiazolin-3(2H)-one ............................. 19.18%
INERT INGREDIENTS ............................................. 80.82%
TOTAL ................................................................... 100.00% 


GENERAL INFORMATION
APPLICATION RATE: Mergal BIT20 is an effective preservative for most aqueous applications. 
Mergal BIT20 is used in aqueous or water-containing products and systems to control growth of bacteria and fungi. 
Use rates are in percentage by weight and refer to the product Mergal BIT20. 
In order to determine the most cost effective use level for Mergal BIT20 in a given use, field trials are suggested.

GENERAL RECOMMENDATIONS: For protection against bacterial attack, a concentration within the range of 0.02 – 0.35% of this product is almost invariably sufficient.
The control of mold growth, particularly on paste products of high solids content, may occasionally demand dosages above 0.25%. 
In dilute fluid systems, spoilage is usually controlled with dosages not greater than 0.09%.

The use rate is 0.05 – 0.25% wt/wt in the following products: Adhesives, Building and Construction Compositions, Emulsion Paint and Coatings, Inks, Lattices, Leather Processing Solutions, Metalworking Fluids, Mineral Slurries and Dispersions, Paper Coatings, Pesticide Formulations, Polymer Emulsions, Textile Spin-Finish and Coatings.

Mergal BIT20 is approved for adhesives used in food packaging and food contact paper and paperboard coatings. 

Use of Mergal BIT 20 must not exceed 0.21 mg/in2 (0.0326 mg/cm2) of finished paper and paperboard intended for contact with dry foods and 0.11 mg/in2 (0.0168 mg/cm2) of finished paper and paperboard intended for contact with aqueous and fatty foods.
Oil Recovery Systems: Drilling fluids, packer fluids, completion fluids: Polysaccharide fluid loss control agents and thickeners such as starch, guar, and xanthan gum at a use rate of 0.05 – 0.15% on fluid weight or 1.5 – 4.5% on the dry polysaccharide eight. 
Subsurface injection waters such as polymer and micellar/polymer waterfloods: Thickeners such as polysaccharides and xanthan gum at a use rate of 0.05 – 0.15% on the solution weight. . 

GENERAL INFORMATION
APPLICATION RATE: Mergal BIT20 is an effective preservative for most aqueous applications. 
Mergal BIT20 is used in aqueous or water-containing products and systems to control growth of bacteria and fungi. Use rates are in percentage by weight and refer to the product Mergal BIT20. 
In order to determine the most cost effective use level for Mergal BIT20 in a given use, field trials are suggested.
The use rate is 0.05 – 0.3% wt/wt in the following products: Car Washes, Car Waxes And Silicone Emulsions, Home Care Cleaning Products Including Floor Cleaners, Floor Waxes, Floor Polishes And Surface Cleaners, Laundry Additives Including Liquid Laundry Detergents, Fabric Softeners And Stain Removers. 

Mergal BIT20 is an effective broad-spectrum, liquid preservative designed to inhibit the growth of microorganisms such as bacteria, yeast, and fungi in aqueous based formulations.


GENERAL INFORMATION
APPLICATION RATE: Mergal BIT20 is an effective preservative for most aqueous applications.
Mergal BIT20 is suggested for use in aqueous or water-containing products and systems to control growth of bacteria and fungi. 
In order to determine the most cost effective use level for Mergal BIT20 in a given use, field trials are suggested.

GENERAL RECOMMENDATIONS: For protection against bacterial attack, a concentration within the range of 0.02 – 0.35% of this product is almost invariably sufficient. 
The control of mold growth,particularly on paste products of high solids content, may occasionally demand dosages above 0.25%. 
In dilute fluid systems, spoilage is usually controlled with dosages not greater than 0.09%.
The use rate is 0.05-0.35% wt/wt of Mergal BIT20 in the following products: Adhesives,
Building and Construction Compositions, Emulsion Paint and Coatings, Inks, Latices, Leather
Processing Solutions, Metalworking Fluids, Mineral Slurries and Dispersions, Paper Coatings,
Pesticide Formulations, Polymer Emulsions, Textile Spin-Finish And Coatings.
Mergal BIT20 is approved for adhesives used in food packaging and food contact paper and paperboard coating. 
Use of Mergal BIT20 must not exceed 0.21 mg/in2(0.0326 mg/cm2) offinished paper and paperboard intended for contact with dry foods and 0.11 mg/in2(0.0168mg/cm2) of finished paper and paperboard intended for contact with aqueous and fatty foods.

OIL RECOVERY SYSTEMS: Drilling fluids, packer fluids, completion fluids. 
Polysaccharide fluid loss control agents and thickeners such as starch, guar, and xanthan gum-0.05-0.15% on fluid weight or 1.5-4.5 on the dry polysaccharide weight. 
Subsurface injection waters such as polymer and micellar/polymer waterfloods: Thickeners such as xanthan gum and polysaccharides-0.05-0.15% on solution weight.

 SUPPLEMENTAL DOSING:
Depending on the nature/severity of the contamination, if analysis indicates a loss of active ingredient and further microbial control is necessary, product may be dosed with additional microbiocide at a level to ensure that the final use-dilution product will not exceed the maximum concentration indicated

METALWORKING FLUID ADDITIVES DIVISION
MERGAL BIT 20
EPA Registration No. 5383-121

 
Description

Application/ Use
Highlights

Physical Properties

Antimicrobial Activity
 
Water dilutable soluble oil, semi-synthetic and synthetic metalworking fluid systems are highly susceptible to the growth of microorganisms. 
Microbial contamination can result in slime generation, gas formation, malodors and the reduction or drift of pH in the fluid concentrate and the working dilution. 
This contamination can diminish fluid performance and system efficiency, which can increase costs, decrease tool life, reduce productivity and cause machine shut-down. 
The use of Mergal BIT20, a proven high quality preservative to control biodeterioration, will help maintain product functionality and increase the life of the metalworking fluid.

For use in concentrates during manufacturing and in post addition applications.


•    Cost effective
•    Excellent pH stability
•    Formaldehyde free
•    Broad spectrum of activity
•    Outstanding stability in the presence of amines or high heat
•    Ease of incorporation
•    Excellent freeze-thaw stability, low freezing point
•    Long-term efficacy

The following are typical properties of Mergal BIT 20; they are not to be considered product specifications.
Active Ingredient, 1,2-Benzisothiazolin-3-one:    19.3%
Appearance:    Clear liquid
Specific Gravity, 25°C:    1.13
Lbs/Gal:    9.42 (approx.)
Viscosity (Brookfield), 25°C:    400
pH (10% aqueous room temperature solution):    ~12
Flash Point (ASTM D3278-96)    >94°C (>200°F)
Solubility:    Soluble in water at use dilutions

Gram Negative Bacteria    
Gram Positive Bacteria

Proteus vulgaris    
Bacillus subtilis
 
Desulfovibrio desulfuricans    
Staphylococcus aureus
 
Enterobacter aerogenes    
Streptococcus faecalis 
Escherichia coli
Pseudomonas aeruginosa
 
 
Function/ Activity
Formulating Considerations
Regulatory Considerations
Environmental Effects
 
Mergal BIT20 is a liquid, organic broad spectrum preservative designed for use in both the concentrate and working dilutions of soluble oil, semi-synthetic and synthetic metalworking fluid systems which may be subject to microbial degradation.


Mergal BIT20, at appropriate use levels in both laboratory and field evaluations, inhibits the growth of microorganisms. 
Products protected with Mergal BIT20 can generally resist the long-term, repeated challenge of microorganisms.

When used in metalworking fluid concentrates and working dilutions at application use levels of up to 0.15% (max.), based on the weight of the working dilution, Mergal BIT20 will protect against a broad range of gram positive and gram negative bacteria and other microorganisms. 
The level of Mergal BIT20 required for optimum effectiveness is dependant on the composition and end use application of your specific product formulation. 
Mergal BIT20 may be used in systems with commonly used fungicides such as Troyshield LA33, Troyshield FX20 and Troyshield FX40. 
Customers are encouraged to check for compatibility and stability in their formulated systems.


Acute Oral Effects:
LD50 (oral, rat, female) – 1020 mg/kg

Acute Skin Effects:
LD50 (dermal, rabbit) > 2000 mg/kg. Moderate irritation (rabbit). 
This product is not a skin sensitizer.

Acute Eye Effects:
Severe irritation and corrosive (rabbit). 
Corneal damage may be irreversible if not washed from eyes promptly.
Acute Inhalation Effects:
LD50 (rate, 4 hr.) – 0.57 mg/l.

Subchronic Effects and Other Studies
Additional data is available on request from the Troy Chemical Corporation on active ingredient and other hazardous components.


Ecotoxicity
This product is moderately toxic to fish. Do not apply directly to water or wetlands. Do not contaminate water when disposing of equipment washwaters.
Data on the active ingredient, 1,2,-Benzisothiazolin-3-one (BIT), is as follows: LC50 (rainbow trout, 96 hr flow-through): 1.3-1.6 mg/kg.
LC50 (water flea, 48 hr flow-through): 1.5-3.3 mg/kg.

Environmental Fate
1,2,-Benzisothiazolin-3-one (BIT) is hydrolytically stable (half-life >30 days), but breaks down fairly quickly in aerobic soils (half-life <24 hours in sandy loam soil). 
Its low Kow (20 at 25°C) indicates that it is unlikely to bioaccumulate in aquatic organisms.
 
Chemical Inventories

Labeling

Handling, Storage, Health And Safety

Shipping And
 
This product, or its components, are listed on, or are exempt from:

Country    Agency    CAS or Other Identification Number
United States    TSCA    2634-33-5 (CAS No.)
United States    EPA    5383-121
Canada    DSL    2634-33-5 (CAS No.)
Europe    EINECS    220-120-9
Switzerland    SWISS    G-6729
Australia    AICS    2634-33-5 (CAS No.)
Korea    ECL    2634-33-5 (CAS No.)
Korea    ECL Serial No.    KE-02680
Japan    ENCS    2634-33-5 (CAS No.)
Japan    MITI No.    9-1845
Philippines    PICCS    2634-33-5 (CAS No.)
China    IECSC    2634-33-5 (CAS No.)

HAZARDS TO HUMANS AND DOMESTIC ANIMALS. 
DANGER: Corrosive. 
Causes irreversible eye damage. 
Harmful if swallowed, inhaled, or, absorbed through skin. 
Do not get in eyes, on skin or on clothing. 
Avoid breathing vapor or spray mist. Wear goggles, face shield, or safety glasses. 
Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. 
Remove and wash contaminated clothing before reuse.


Avoid contact with skin, eyes, or clothing. 
Avoid breathing vapor or mist. 
Wash thoroughly after handling. 
Keep container tightly closed. 
Use only with adequate ventilation. 
Store away from incompatible substances in a cool dry, ventilated area. 
Do not store near food or feed.
Observe all Federal, State and Local regulations when storing or disposing of this substance. 
Shelf Life: 24 Months
Emergency Overview: Mergal BIT20 is a clear liquid with a slight odor. 
Corrosive liquid. May cause irreversible damage to the eyes. 
May cause moderate skin and respiratory irritation. 
This material is moderately toxic to fish. Avoid contamination of streams and sewers.

Mergal BIT 20 is packaged in:
 
Packaging         
Shipping Container    Net Weight
Pail    45 lbs/20.5 kg
 
Drums    100 lbs/45.4 kg
Drums    441 lbs/200.5 kg
 

 
DOT
Shipping Name    UN3266, Corrosive liquid, inorganic, basic, n.o.s. (Sodium hydroxide)
8 PG lll, ERG# 154
Labels Required    Corrosive

IATA
Shipping Name    UN3266, Corrosive liquid, inorganic, basic, n.o.s. (Sodium hydroxide)
8 PG lll, ERG# 8L
Labels Required    Corrosive
IMDG
Shipping Name    UN3266, Corrosive liquid, inorganic, basic, n.o.s. (Sodium hydroxide)
8 PG lll, EMS# F-A, S-B
Labels Required    Corrosive

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