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METHYLENE BİS(THIOCYANATE)


Methylene bis(thiocyanate) is a member of the class of thiocyanates that is methane in which two of the hycrogens have been replaced by thiocyanato groups.


CAS NO: 6317-18-6
EC NO: 228-652-3


IUPAC NAMES:
Dithiocyanatomethan
METHYLENE BIS(THIOCYANATE)
Methylene bis(thiocyanate)
methylene bis(thiocyanate)
Methylene Dithiocyanate
Methylene dithiocyanate
methylene dithiocyanate
thiocyanatomethyl thiocyanate
{[(cyanosulfanyl)methyl]sulfanyl}carbonitrile


SYNONYMS:
methylene dithiocyanate, methylene bis thiocyanate, methylenedithiocyanate, proxel mb, methylenedirhodanide, thiocyanic acid, methylene ester, nalfloc n 206, methylenedirhodanid, methylenethiocyanate,dithiocyanatomethane;Dithiocyanatomethane;MethyleneBisthiocyanate;Methylenedithiocyanate; Methylene bis(thiocyanate)
Amerstat 282
Antiblu 3737
Busan 110
Cytox
Dithiocyanatomethane
Methylendirhodanid
Methylendithiokyanat
Methylene bis(thiocyanate)
Methylene dithiocyanate
Methylene ester OF thiocyanic acid
Amerstat 282; Antiblu 3737; Busan 110; cp17879; Methane, dithiocyanato-; Methylendirhodanid; methylendirhodanid(czech); Methylendithiokyanat
CP 17879; Methane, dithiocyanato-; Methylendirhodanid [Czech]; Methylendithiokyanat [Czech]; Methylene bis(thiocyanate); Methylene dithiocyanate; Methylene thiocyanate; Methylenebis(thiocyanate); Methylenedirhodanid [German]; Methylenedirhodanide; Nalco D-1994; Nalfloc N 206; Proxel MB; Thiocyanic acid, methylene ester; V 709; [ChemIDplus] Organiclear, Methylene bisthiocyanate; [Hawley] UN2811
bis(thiocyanate) de methylene;Acide thiocyanique, éther de méthylène;Dithiocyanate de méthylène;methylene bis(thiocyanate);Thiocyanic acid, methylene ester;Methylene dithiocyanate;CP 17879;Methylendirhodanid;METHYLENDIRHODANID (CZECH);Methylendithiokyanat;METHYLENE BISTHIOCYANATE;Methylenebis(thiocyanate);Methylenedirhodanid;METHYLENEDIRHODANID (GERMAN);METHYLENEDIRHODANIDE;NALFLOC N 206;PROXEL MB;V 709.
Methylene bis(thiocyanate)
Methylene Bisthiocyanate
MTC
methanediyl bis(thiocyanate)
Methylenedithiocyanate
methylene bisthiocyanate


METHYLENE BİS(THIOCYANATE)


Methylene Bis Thiocyanate is non-metallic organosulfur biocide. It possesses excellent fungicidal, algaecidal, and bactericidal properties. It can be formulated for convenient use as a solution in many organic solvents or as an aqueous dispersion. It is a crystalline solid thus avoiding dusting. It is stable across wide range of pH and shows a very rapid kill against microbial species.


MBT can increase oil production by reducing oil layer contamination and preventing clay form expanding and disinfecting. MBT can also be used to protect packing paper from moulding, cooling water, and removes marine organisms from marine liners.


MBT has good effects of anti-corrosion germicide and algaecide for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and ink.


MBT 1% emulsion is a broad-spectrum and safe agricultural germicide, with good effects against diseases of rice and wheat.


 


Applications:


Aquapharm MBT has excellent penetration properties which make it suitable for preservation of wood and leather.
It is recommended for leather processing at pre-tanning stage where high levels of bacterial and fungal contaminants are present.
It is also used for prevention of mould and sapstain for stored timber before converting them into finished goods.
It is used in the preservation of paints, adhesives, synthetic polymer lattices and latex emulsions
Anti-microbial treatment of water thinned product, thickeners and slurries.
Oil well brines and drilling muds.


Appearance        Pale yellow crystalline solid
Active Content        99%(Solid)
Melting point oC        105


Background
Methylene bis(thiocyanate) (MBT) is a microbiocidal agent mainly used in industrial water cooling systems and paper mills as an inhibitor of algae, fungi, and bacteria.


Methylene bis(thiocyanate) is used as a microbiocide/microbiostat, fungicide/fungistat, algicide, and disinfectant. End-use products are formulated as a soluble concentrate/liquid, a ready-to-use liquid, and a soluble concentrate/solid. Methylene bis(thiocyanate) is employed in water cooling systems, paint manufacturing, metalworking cutting fluids, pulp and paper mills, oil drilling/mud packing fluids, leather processing, wood pressure treatments (forest products), wood protection treatments to buildings/products, and latex paints (in-can). The chemical is applied by applicator rolls; brush; chemical pump; dip tank; drip-feed device; metering pump; paintbrush; roller; sprayer; sprinkler can; or from a tank.


* For uses as a wood pressure treatment to forest products;
* For uses in leather processing liquors, leather processing, and leather
* products;
* For application as a dip for leather products and for wood
* preservation, including removal of products from the dip;
* For painting with a roller; and
* For painting with a sprayer.


MBT is a light yellow acicular crystalline chemical. MBT melting point is 100-104℃, sight soluble in other organic solvents, soluble in water at the degree of 0.4%, and stable under acid conditions.
MBT is an efficient, broad-spectrum germicide & algaecide & displaying strong extermination effects against Germs, Fungus, and Algae existing in circulating water. MBT maintains long-term effects and is applicable to broad pH value and temperature ranges. Using 3-4ppm MBT kills over 90% of nitrosation germs, sulfate reducing germs, colon bacillus, anti-nitrosation germs and many other types of germs. MBT liquid is stable, and MBT can decompose shortly in application. MBT has analysis method and is easy for monitoring, so MBT is safe for discharge.


MBT can increase oil production by reducing oil layer contamination, preventing clay form expanding, and disinfecting. MBT can also be used to protect packing paper from going molding, treat circulating cooling water, and remove marine organisms from marine liners. MBT has excellent effects of anti-corrosion, germicide and algaecide for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and ink.


MBT 1% emulsion is a kind of efficient, broad-spectrum and safe agricultural germicide, having good effects against diseases of rice and wheat. Within the recommended quantity, MBT is safe to rice seed and increases germination percentage. As MBT is an organic thiocyano germicide, it can solve the problem of anti-pesticide property developed by the widely used absorbing germicides. Whenused in treating rice seed, MBT does not need pre soaking or after-washing. MBT can be used directly in germination and seeding.


MBT also can be made of safe fish medicine to prevent many kinds of fish disease. MBT is a good disinfectant in the water for various breed aquatics.


Methylene bis(thiocyanate) is a member of the class of thiocyanates that is methane in which two of the hycrogens have been replaced by thiocyanato groups.


Methylene bis(thiocyanate) is used as a biocide for the control of various pathogens and algae in industrial water systems and as a fungicide for the control of surface moulds and sapstain fungi on wood.


Methylene bis(thiocyanate) has a role as a fungicide and an antibacterial agent.


Methylene bis(thiocyanate) is used as a microbiocide/microbiostat, fungicide/fungistat, algicide, and disinfectant.End-use products are formulated as a soluble concentrate/liquid, a ready-to-use liquid, and a soluble concentrate/solid.


Methylene bis(thiocyanate) is employed in water cooling systems, paint manufacturing, metalworking cutting fluids, pulp and paper mills, oil drilling/mud packing fluids, leather processing, wood pressure treatments (forest products), wood protection treatments to buildings/products, and latex paints (in-can).


Methylene bis(thiocyanate) is applied by applicator rolls; brush; chemical pump; dip tank; drip-feed device; metering pump; paintbrush; roller; sprayer; sprinkler can; or from a tank.


USES
METHYLENE BIS(THIOCYANATE) is used for wood pressure treatment to forest products;


METHYLENE BIS(THIOCYANATE) is used for leather processing liquors, leather processing, and leather products;
METHYLENE BIS(THIOCYANATE) is used for application as a dip for leather products and for wood preservation, including removal of products from the dip;


METHYLENE BIS(THIOCYANATE) is used for painting with a roller; and For painting with a sprayer.


Methylene Bis Thiocyanate is non-metallic organosulfur biocide. It possesses excellent fungicidal, algaecide, and bactericidal properties. It can be formulated for convenient use as a solution in many organic solvents or as an aqueous dispersion. It is a crystalline solid thus avoiding dusting. It is stable across a wide range of pH and shows a very rapid kill against microbial species.


Methylene Bis Thiocyanate can increase oil production by reducing oil layer contamination and preventing clay form expanding and disinfecting. Methylene Bis Thiocyanate can also be used to protect packing paper from moulding, cooling water, and removes marine organisms from marine liners.


Methylene Bis Thiocyanate has good effects of anti-corrosion germicide and algaecide for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and ink.


Methylene Bis Thiocyanate 1% emulsion is a broad-spectrum and safe agricultural germicide, with good effects against diseases of rice and wheat.


Applications:


Methylene Bis Thiocyanate has excellent penetration properties which make it suitable for preservation of wood and leather.
It is recommended for leather processing at the pre-tanning stage where high levels of bacterial and fungal contaminants are present.
It is also used for prevention of mould and sapstain for stored timber before converting them into finished goods.
It is used in the preservation of paints, adhesives, synthetic polymer lattices and latex emulsions
Anti-microbial treatment of water thinned product, thickeners and slurries.
Oil well brines and drilling muds.


Methylene bis(thiocyanate) is a light yellow acicular crystalline chemical. Methylene bis(thiocyanate) melting point is 100-104℃, sight soluble in other organic solvents, soluble in water at the degree of 0.4%, and stable under acid conditions.
Methylene bis(thiocyanate) is an efficient, broad-spectrum germicide & algaecide & displaying strong extermination effects against Germs, Fungus, and Algae existing in circulating water. 
Methylene bis(thiocyanate) maintains long-term effects and is applicable to broad pH value and temperature ranges.
Using 3-4ppm Methylene bis(thiocyanate) kills over 90% of nitrosation germs, sulfate reducing germs, colon bacillus, anti-nitrosation germs and many other types of germs.
Methylene bis(thiocyanate) liquid is stable, and MBT can decompose shortly in application. MBT has analysis method and is easy for monitoring, so Methylene bis(thiocyanate) is safe for discharge.


Methylene bis(thiocyanate) can increase oil production by reducing oil layer contamination, preventing clay form expanding, and disinfecting.


Methylene dithiocyanate can also be used to protect packing paper from going molding, treat circulating cooling water, and remove marine organisms from marine liners.


Methylene dithiocyanate has excellent effects of anti-corrosion, germicide and algaecide for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and ink.


Methylene bis(thiocyanate) 1% emulsion is a kind of efficient, broad-spectrum and safe agricultural germicide, having good effects against diseases of rice and wheat.
Within the recommended quantity, MBT is safe to rice seed and increases germination percentage.


As Methylene dithiocyanate is an organic thiocyano germicide, it can solve the problem of anti-pesticide property developed by the widely used absorbing germicides.
Whenused in treating rice seed, MBT does not need presoaking or after-washing. MBT can be used directly in germination and seeding.


Methylene bis(thiocyanate) also can be made of safe fish medicine to prevent many kinds of fish disease.


Methylene bis(thiocyanate) is a good disinfectant in the water for various breed aquatics.


Methylene bis(thiocyanate) (MBT) is a microbiocidal agent mainly used in industrial water cooling systems and paper mills as an inhibitor of algae, fungi, and bacteria.


Appearance        Pale Yellow free-flowing powder / Crystals
Melting Point        101 deg c. Min.
Assay        98% Min.
Moisture        0.5% Max.
Acetone Insolubles        1.0% Max.
Inorganic Salts        1.0% Max.


Uses:
Methylene bis thiocyanate is an efficient, broad-spectrum germicide & algaecide & displaying strong extermination effects against germs, fungus, and algae existing in circulating water. MBT biocide maintains long-term effects and is applicable to broad pH values and temperature ranges. Using 3-4ppm methylene bis thiocyanate kills over 90% of nitrosation germs, sulfate-reducing germs, colon bacillus, anti-nitrosation germs, and many other types of germs. Methylene bis thiocyanate liquid is stable, and methylene bis thiocyanate can decompose shortly in an application. MBT biocide has an analysis method and is easy to monitoring, so methylene bis thiocyanate is safe for discharge.


Methylene bis thiocyanate can increase oil production by reducing oil layer contamination, preventing clay from expanding and disinfecting. Methylene bis thiocyanate can also be used to protect packing paper from going molding, treat circulating cooling water, and remove marine organisms from marine liners. Methylene bis thiocyanate has excellent effects of anti-corrosion, germicide, and algaecide for electrical materials, bamboo and woodenware, coatings, rubber, canvas, glue, and ink.


Methylene bis thiocyanate 1% emulsion is a kind of efficient, broad-spectrum, and safe agricultural germicide, having good effects against diseases of rice and wheat. Within the recommended quantity, methylene bis thiocyanate is safe for rice seed and increases germination percentage. As methylene bis thiocyanate is an organic thiocyano germicide, it can solve the problem of anti-pesticide property developed by the widely used absorbing germicides. When used in treating rice seed, methylene bis thiocyanate does not need presoaking or after-washing. Methylene bis thiocyanate can be used directly in germination and seeding.


The MBT biocide also can be made of safe fish medicine to prevent many kinds of fish disease. Methylene bis thiocyanate is a good disinfectant in the water for various breed aquatics.


Methylene Bis(Thiocyanate) is a light yellow acicular crystalline chemical. Melting point: 100-104℃. The MBT biocide is slightly soluble in other organic solvents, soluble in water (0.4%), and stable under acid conditions.


Methylene bis(thiocyanate) is used in formulating biocides. It is used as a antifouling agent,preservatives for coatings, slurries and to control microbial fouling in paper mills,oil field and leather process.It is also used in water treatment process.


Formula: C9H6N2S3
Molecular Weight: 238.35
Specification: TCMTB 60%; 30%
Appearance: amber transparent liquid
PH(1%Water Solution): 3-6
Proportion (2 0℃): 1.10±0.05 g/cm3
USE: It can be effectively used in water treatment, leather processing and coatings.


Chemical Properties
yellow crystalline powder


Uses
Methylene bis(thiocyanate) emulsion is used as bactericide.


General Description
Yellow to light orange-colored mass or yellow powder.


Air & Water Reactions
May be sensitive to prolonged exposure to air. Decomposes in water (not vigorously) and more rapidly in boiling water.


Reactivity Profile
Methylene bis(thiocyanate) reacts vigorously with strong bases and strong oxidizing agents such as hydrogen peroxide. Hydrolyzes slowly with water at boiling temperatures and reacts slowly and exothermically with aqueous acids .


Methylene Bis Thiocyanate is a light yellow acicular crystalline chemical. Its melting point is 100-104 , sight soluble in other organic solvents, soluble in water at the degree of 0.4%, and stable under acid conditions.


USAGE:
Methylene Bis Thiocyanate can increase oil production by reducing oil layer contamination, preventing clay form expanding and disinfecting. It can also be used to protect packing paper from going molding, treat circulatin cooling water, and removes marine organisms
from marine liners. It has excellent effects of anti-corrosion germicide and algaecide
for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and
ink


Methylene Bis Thiocyanate 1% emulsion is a kind of efficient, broad-spectrum and safe agricultural germicide, having good effects against diseases of rice and wheat. Within the
recommended quantity, it is safe to rice seed and increases germination percentage.
As it is an organic thiocyano germicide, it can solve the problem of anti-pesticide
property developed by the widely used absorbing germicides. When used in treating
rice seed, it does not need pre-soaking or after-washing. It can be used directly in
germination and seeding.


DESCRIPTION
Methylene Bis Thiocyanate is a light yellow acicular crystalline chemical. Its melting
point is 100-104℃, sight soluble in other organic solvents, soluble in water at the
degree of 0.4%, and stable under acid conditions.


SPECIFICATION:
Appearance Pale Yellow free flowing powder / Crystals
Melting Point 101°C minimum
Assay 98% minimum
Moisture 0.5% maximum
Acetone Insolubles 1.0% maximum
Inorganic Salts 1.0% maximum


APPLICATIONS:
1. Control of microbial activity in cooling water systems.
2. Control of slime in Pulp & Paper Manufacturing.
3. Preservation of paints, adhesives, synthetic polymer lattices and latex emulsions.
4. Anti-microbial treatment of water thinned products, thickeners and slurries.
5. Preservation of wood and wood products.
6. Preservation of Leather and Leather products.
7. Oil well brines and drilling mud.


Methylene Bis(thiocyanate) is used in formulating biocides. It is used as a preservatives for coatings, slurries and to control microbial fouling in paper mills , oil field and leather process. It is used  in water treatment process.


Methylene bis(thiocyanate) is a member of the class of thiocyanates that is methane in which two of the hycrogens have been replaced by thiocyanato groups. Used as a biocide for the control of various pathogens and algae in industrial water systems and as a fungicide for the control of surface moulds and sapstain fungi on wood. It has a role as a fungicide and an antibacterial agent.


Methylenebis(thiocyanate) appears as yellow to light orange-colored mass or yellow powder.


USES


* General adhesives and binding agents for a variety of uses        
* Type of pesticide used to destroy or inhibit the growth of disease-causing mechanisms, can be impregnated into clothing        
* General construction (as opposed to those things labeled building_construction); i.e. when source only indicates 'construction,' construction of roads, or engineering         
* General disinfectants/sanitizing agnets, disinfectants related to drugs (modified by 'drug'), and disinfectants used in drinking water, or animal feed (modified by 'drinking_water' and 'feed')         
* Related to animals (but non-veterinary) e.g., animal husbandry, farming of animals/animal production, raising of animals for food or fur, animal feed, products for household pets
* General flavoring agents used in foods, including condiments and seasonings        
* Includes food packaging, paper plates, cutlery, small appliances such as roasters, etc.; does not include facilities that manufacture food                
* Related to metals - manufacturing of metals, casting of metals, production of metals, surface treatment of metals, etc
* Non-metallic mineral products and their manufacture        
* Related to the manufcturing of pulp or paper products, or paper products in general        
* Textiles used for clothing or furniture upholstery, processes related to textiles (e.g. softeners, antiwrinkle agents), or the processing/manufacturing of textiles         
* Various types of paint for various uses, modifiers included when more information is known        
* Substances used for preventing, destroying or mitigating pests
* Pesticide for non agricultural use
* Includes preservatives used in cosmetics, film, wood preserving agents, foods, etc (note food preservatives are also indicated as food_additive)        
* Type of pesticide to prevent the growth of slime        
* Related to photography, film, photographic equipment, photographic laboraties, photochemicals, and developing of photographs        
* Includes preservatives used in cosmetics, film, wood preserving agents, foods, etc (note food preservatives are also indicated as food_additive)        
* Surface treatments for metals, hardening agents, corrosion inhibitors, polishing agents, rust inhibitors, water repellants, etc (surfaces to be applied to often not indicated in source description)


Methylene bis(thiocyanate) is an important organic intermediate. It is used in agrochemical, pharmaceutical and dyestuff field. It is also used to control slime in pulp and paper manufacturing, preservation of paints, adhesives, synthetic polymer lattices and latex emulsions, anti-microbial treatment of water thinned products, thickeners and slurries, preservation of wood and wood products, preservation of Leather and Leather products and in oil well brines and drilling mud.


Used against wood rot, termites, mildew, and decay; [Hawley] Powerful action against slime-forming bacteria, spore formers, and fungi; Used in paper mills and water cooling systems;


Methylene dithiocyanate Usage


1. Fungicide


2. It can be used for the treatment of rice and wheat seeds after being made into emulsifiable concentrate. It can control the bacteria, fungi and nematode diseases. It is also an efficient and broad-spectrum bactericidal algaecide.


3. Used to manufacture rubber products such as cables, wires and tires. Efficient, broad-spectrum bactericidal algaecide


Items                                    Standard                                                        Results
Appearance           Pale Yellow Free Flowing Powder Crystals                 Acceptance
Melting point                      101℃min                                                           101
Assay                                  98%min                                                             98.3
Moisture                          1.0%max                                                          0.61
Acetone Insolubles              0.5%max                                                         0.43
Inorganic Salts                 0.5%max                                            0.42
PH(0.5% Solution)                         5-7                                                         6.0
Conclusion        The results conforms with enterprise standards


Methylene dithiocyanate(CAS 6317-18-6), alias MBT or Methylene bis(thiocyanate), is broadly effective and environment-friendly fungicide, which can be used to against many bacteria, fungi, yeast and algae. Methylene dithiocyanate is pale yellow crystalline powder, decomposes in water, slightly soluble in organic solvents.


Methylene bis(thiocyanate)  can be used as industrial anti-mildew agent, it has good anti-mildew, antisepsis and sterilization effect in bamboo and wood products, electrical materials, coating, rubber, leather, canvas, pulp and ink, etc.


Methylene bis(thiocyanate)  displays strong extermination effects against germs, fungus, and algae existing in circulating water. It has long-term effects and is applicable to broad PH value and temperature ranges. 3-4 ppm Methylene bis(thiocyanate)  kills over 90% of nitrosation germs, sulfate reducing germs, colon bacillus, anti-nitrosation germs and many other types of germs. Methylene bis(thiocyanate) liquid is stable, and it can decompose shortly in application. It has analysis method and is easy for monitoring, so it is safe for discharge.


Application of Methylene bis(thiocyanate) 


Methylene bis(thiocyanate)  can reduce oil layer contamination to increase oil production. It can also be used to protect packing paper from going molding, treat circulating cooling water, and remove marine organisms from marine liners. It also has excellent effects of anti-corrosion, germicide and algaecide for electrical materials, bamboo and wooden ware, coatings, rubber, canvas, glue and ink.


As a pesticide, Methylene bis(thiocyanate)  can be prepared into 10% Methylene bis(thiocyanate)  emulsion. It is an efficient, broad-spectrum and safe fungicide for crops. It is good for the disease of rice disease, dry point nematodes disease, network spot disease, and stem smut, and it has good effect on other diseases caused by bacterial fungi and nematode worms. Methylene bis(thiocyanate)  also can be made of safe fish medicine to prevent many kinds of fish disease. It is a good disinfectant in the water for various breed aquatics.

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