PRODUCTS

METHYLENE BISMORPHOLINE

Methylene Bismorpholine is used as a curing agent in epoxy resins and as a stabilizer in industrial chemical formulations.
Methylene Bismorpholine enhances the properties and longevity of cured materials.
Methylene Bismorpholine is a highly effective biocide specifically developed for metalworking fluids (MWFs), such as cutting oils, coolants, and lubricants.

CAS Number: 5625-90-1
EC Number: 227-062-3
MDL Number: MFCD00023369
Molecular Formula: C9H18N2O2
Molecular Weight: 186.25 g/mol

SYNONYMS:
N,N-Dimorpholinomethane, Morpholine,4,4-methylenebis-, Bis(4-morpholinyl)methane, N,N'-Methylenebismorpholine, 4,4'-methanediyldimorpholine, 4,4-methylenebis-Morpholine, N,N-Methylene-bis-morpholine, N,N'-Dimorpholinomethane, 4-(Morpholin-4-ylMethyl)Morpholine, Conncide MW, SIDCHEM LB 69, DIMORPHOLINOMETHONE, DIMORPHOLINOMETHANE, bismorpholinomethane, bis(morpholino-)methan, MORPHOLINE44METHYLENEDI, BIS-(MORPHOLINE-)METHANE, 44METHYLENEBISMORPHOLINE, N,N'-DIMORPHOLINOMETHANE, 4,4'-methylenedi-morpholin, 4,4'-methylenedimorpholine, bis(morpholino-)methan, bismorpholinomethane, N,N'-Methylenebismorpholine, DIMORPHOLINOMETHANE, DIMORPHOLINOMETHONE, N,N-Dimorpholinomethane, Morpholine, 4,4′-methylenebis-, Bis(4-morpholinyl)methane, N,N′-Methylenebismorpholine, 4,4′-methanediyldimorpholine, 4,4-methylenebis-Morpholine, DIMORPHOLINOMETHANE, DIMORPHOLINOMETHONE, bismorpholinomethane, bis(morpholino-)methane, N,N'-DIMORPHOLINOMETHANE, 4,4’-methylenedi-morpholin, 4,4’-methylenedimorpholine, N,N'-Dimorpholinomethane, N,N´-Methylene bismorpholine, Bis (morpholino-) methan, Bismorpholino methane, 4,4-Methylenedimorpholine, Morpholine, 4,4-methylenedi-, N,N'-Methylene-bis-morpholine, Methylenebistetrahydro-1,4-oxazine, Methylenebisoxazine, Dimorpholinomethan, Bismorpholinomethan

Methylene Bismorpholine is a low toxicity and water-based biocide developed for use in metal working concentrates.
Methylene Bismorpholine is effective against a wide range of microorganisms including gram positive and gram negative bacteria, yeast and fungi.
Microorganisms grow at a rapid rate and without use of the correct biocide, numbers can increase dramatically.

Methylene Bismorpholine is a chemical compound from the group of nitrogen - oxygen heterocycles.
Methylene Bismorpholine, with the CAS number 5625-90-1, is an organic compound characterized by its morpholine functional groups.
Methylene Bismorpholine typically appears as a colorless to pale yellow liquid or solid, depending on the temperature and purity.

Methylene Bismorpholine has a relatively low toxicity profile, but like many chemical substances, it should be handled with care to avoid skin and eye irritation.
Methylene Bismorpholine's reactivity is primarily attributed to the presence of the morpholine rings, which can participate in various chemical reactions, including cross-linking processes in polymer chemistry.

Overall, Methylene Bismorpholine is valued for its functional properties in the production of durable and resilient materials.
Sexual fungicide, Methylene Bismorpholine has good solubility, suitable for oil and water based systems.
In addition to the bactericidal effect, Methylene Bismorpholine also has a certain anti-rust effect of black metal.

Methylene Bismorpholine is a new generation of broad spectrum and low toxicity developed for water-based metalworking fluids
Sexual fungicide, Methylene Bismorpholine has good solubility, suitable for oil and water based systems.

In addition to the bactericidal effect, Methylene Bismorpholine also has a certain anti-rust effect of black metal.
Methylene Bismorpholine is effective against both gram-negative and Gram-positive bacteria.

USES and APPLICATIONS of METHYLENE BISMORPHOLINE:
Methylene Bismorpholine is known for its role as a hardener or curing agent in epoxy resins and is often utilized in various industrial applications due to its ability to enhance the mechanical properties of materials.
Methylene Bismorpholine exhibits good solubility in water and organic solvents, making it versatile for different formulations.

Methylene Bismorpholine serves as a broad-spectrum biocide/preservative, particularly in water-based metalworking fluids (MWF)—protecting against bacteria and fungi.
Typical in-can usage of Methylene Bismorpholine: ~0.15% w/w in MWF; recommended addition: 2–3% in concentrate, 0.1–0.2% (1–2 ‰) in working liquid.

Methylene Bismorpholine offers advantages such as low toxicity, mild odor, low irritation, and good formulation compatibility and stability in fluids
Methylene Bismorpholine was previously approved for use as a biocide in the EEA and/or Switzerland, and this approval has now expired, for: product preservation, preservation for working / cutting fluids.

Metal cutting fluid bactericide Methylene Bismorpholine is a slow-release bactericide with a broad spectrum and high efficiency and a certain gas-phase sterilization ability.
Methylene Bismorpholine is suitable for inhibiting the growth and reproduction of microorganisms in various humid environments, preventing the generation of putrefaction and foul odors, and ensuring safe operation of the system.

Methylene Bismorpholine is employed as intermediate for pharmaceutical.
Methylene Bismorpholine is used as a curing agent in epoxy resins and as a stabilizer in industrial chemical formulations.
Methylene Bismorpholine enhances the properties and longevity of cured materials.

Methylene Bismorpholine is a highly effective biocide specifically developed for metalworking fluids (MWFs), such as cutting oils, coolants, and lubricants.
Methylene Bismorpholine is renowned for its broad-spectrum antimicrobial properties, making it an ideal solution for the control of bacteria, fungi, and algae that can cause contamination in industrial fluids.

As a mildly toxic and environmentally friendly agent, Methylene Bismorpholine is a key choice for industries where safety and sustainability are paramount.
Broad-Spectrum Efficacy: Methylene Bismorpholine effectively controls a wide range of microorganisms, including bacteria, fungi, and algae, that can degrade the quality and performance of metalworking fluids.

Mild Skin Irritation: Unlike other biocides, Methylene Bismorpholine has minimal skin irritation, making it safer for operators handling metalworking fluids in manufacturing environments.
Environmentally Friendly: Methylene Bismorpholine is considered an eco-friendly solution because of its lower toxicity compared to traditional biocides, helping to minimize the environmental impact of its use.

Long-Lasting Effectiveness: Methylene Bismorpholine provides long-lasting microbial control at recommended concentrations, ensuring that metalworking fluids remain clean and effective throughout their use.
Cost-Effective and Efficient: With its broad-spectrum activity and effective dosing, Methylene Bismorpholine is an economical solution for controlling microbial contamination, reducing the need for frequent reapplication.

Methylene Bismorpholine is a formaldehyde-releasing preservative and is used as a component of metalworking fluids.
Methylene Bismorpholine is a useful reagent for electron-rich heterocycles (pyrroles, indoles) and active methylene compounds in the presence of trifluoroacetic acid.

-Strong Compatibility:
Methylene Bismorpholine is highly compatible with a variety of metalworking fluid formulations, including concentrates and ready-to-use solutions.
This flexibility makes Methylene Bismorpholine suitable for diverse applications in industries like automotive, aerospace, and precision machining.

-Oilfield Desulfurization uses of Methylene Bismorpholine:
Methylene Bismorpholine is an effective biocide used in oilfield desulfurization processes to control microbial growth.
Sulfur compounds in oilfields often promote the growth of microbes, leading to corrosion and quality degradation of the extracted oil.

Methylene Bismorpholine’s broad-spectrum antimicrobial action helps prevent the proliferation of bacteria, fungi, and other microbes in the oil, reducing the impact of sulfur compounds and improving the overall efficiency of the desulfurization process.
This ensures the smooth operation of oilfield equipment and enhances the quality of extracted oil.

-Water Treatment uses of Methylene Bismorpholine:
Methylene Bismorpholine is widely used in water treatment systems, including industrial wastewater, circulating water systems, and municipal wastewater treatment.
In these processes, Methylene Bismorpholine acts as a powerful biocide to control the growth of bacteria, fungi, and algae.

Its broad-spectrum antimicrobial properties help prevent biofouling, ensuring water quality and reducing maintenance costs.
The use of Methylene Bismorpholine also contributes to the efficiency of water treatment processes by keeping microbial contamination at bay and preventing the corrosion of system components.

-Metalworking Fluids uses of Methylene Bismorpholine:
In metalworking, Methylene Bismorpholine is commonly used in metalworking fluids (MWFs), such as cutting fluids and coolants, to prevent microbial growth.
Metalworking fluids are highly susceptible to microbial contamination due to their aqueous nature and the presence of organic matter.

Methylene Bismorpholine effectively inhibits the growth of bacteria, fungi, and yeasts in these fluids, preventing foul odors, sludge formation, and corrosion.
This not only extends the service life of the metalworking fluid but also ensures a cleaner and more efficient machining process.

-Coatings uses of Methylene Bismorpholine:
In the coatings and paints industry, Methylene Bismorpholine is used as an antimicrobial and anti-fungal agent.
Methylene Bismorpholine helps prevent the growth of mold and bacteria in paints, ensuring the quality of the product during storage and application.

In environments with high humidity or moisture, Methylene Bismorpholine enhances the durability and performance of coatings by protecting them from microbial degradation.
This makes Methylene Bismorpholine particularly useful for coatings used in damp or humid conditions, such as those applied in marine or industrial environments.

-Lubricants uses of Methylene Bismorpholine:
Methylene Bismorpholine is also used in lubricants to prevent microbial contamination.
In lubricating oils, the growth of bacteria and fungi can lead to system failures and corrosion of mechanical parts.

Methylene Bismorpholine’s biocidal properties help ensure that lubricants remain free from microbial growth, extending the life of the lubricant and the machinery it protects.
This is especially important for industrial machinery and automotive systems where the performance and stability of lubricants are critical.

-Leather Anti-fungal Protection uses of Methylene Bismorpholine:
In the leather industry, Methylene Bismorpholine is used to prevent fungal and bacterial contamination in leather products, especially in humid and wet environments.

Leather, being organic, is highly prone to microbial growth, which can lead to deterioration, unpleasant odors, and discoloration.
By applying Methylene Bismorpholine, manufacturers can protect leather goods, such as shoes, bags, and furniture, from microbial damage, thereby extending their lifespan and preserving their quality.

-Pulp and Paper Industry uses of Methylene Bismorpholine:
In the pulp and paper industry, Methylene Bismorpholine is used to inhibit microbial growth in the pulp slurry.
In this industry, the moist conditions are ideal for the proliferation of bacteria and fungi, which can lead to the spoilage of pulp, paper, and equipment.

Methylene Bismorpholine’s antimicrobial properties ensure that the pulp remains free from microbial contamination, helping improve the quality of the final paper product and prolonging the life of production equipment.
Methylene Bismorpholine is especially useful in preventing mold and mildew, which can affect the quality of paper and cause production delays.

-Adhesives uses of Methylene Bismorpholine:
In adhesive formulations, Methylene Bismorpholine serves as a biocide to prevent microbial contamination.
Adhesives are often used in environments where moisture is present, making them susceptible to microbial growth.

Methylene Bismorpholine helps protect adhesives from mold and bacteria, ensuring that they maintain their effectiveness and stability over time.
This is particularly important in applications such as packaging, construction, and automotive industries, where the quality and durability of adhesives are paramount.

-Organic synthesis uses of Methylene Bismorpholine:
Methylene Bismorpholine, as an important intermediate raw material, plays a key role in organic synthesis reactions.
Methylene Bismorpholine can participate in a variety of chemical reactions to generate compounds with specific structures and functions.

-Oil additives uses of Methylene Bismorpholine:
Methylene Bismorpholine has excellent oil solubility and solubility balance, making it ideal for oil additives.
Methylene Bismorpholine improves oil stability and performance and extends oil life.

-Biocide uses of Methylene Bismorpholine:
Methylene Bismorpholine is a broad-spectrum bactericide that inhibits and kills microorganisms such as bacteria, fungi and yeasts.
Methylene Bismorpholine can be used in emulsions, semi-synthetic and fully synthetic metalworking fluids, coatings, paper, adhesives, etc.
Methylene Bismorpholine prevents the growth of moulds and bacteria in humid environments.

-Recommended for use of Methylene Bismorpholine as metal working fluid;
*Multifunctional components: bactericidal against bacteria;
*Methylene Bismorpholine is a bactericide widely used in metal working fluids.
*Methylene Bismorpholine can be added Concentrate, but not recommended for field maintenance;

*Methylene Bismorpholine has been successfully applied as a killer in water-based metalworking fluids and diesel oil Bactericide.
*Methylene Bismorpholine is more stable in concentrates than BK To be sure;
*Methylene Bismorpholineis particularly stable and long-lasting in concentrates, with a half-life of 5-8 1 month;

-Methylene Bismorpholine which is a biocide that is used in metal cutting fluids.
Below some more details about biocides MBM:
*Biocidal properties:
Methylene Bismorpholine is effective against a wide range of microorganisms, including bacteria and fungi.
Methylene Bismorpholine works by disrupting the cell membranes and metabolic processes of these organisms, which can lead to their death.

*Metal cutting fluids:
Methylene Bismorpholine is used in metal cutting fluids to prevent the growth of microorganisms that can cause corrosion, fouling, and degradation of the cutting fluid.
These microorganisms can also cause health and safety concerns for workers who come into contact with the cutting fluid.

*Environmental safety:
Methylene Bismorpholine is considered to be relatively safe for the environment compared to other biocides.
Methylene Bismorpholine has a low toxicity and is biodegradable, which means that it can break down into harmless substances over time.

*Regulatory compliance:
Methylene Bismorpholine is approved for use by regulatory agencies such as the U.S. Environmental Protection Agency (EPA) and the European Chemicals Agency (ECHA).
These agencies have established guidelines for the safe use of Methylene Bismorpholine in metal cutting fluids.

EXTRACTION OF METHYLENE BISMORPHOLINE:
Methylene Bismorpholine can be obtained by reacting formaldehyde with morpholine.

PHYSICAL and CHEMICAL PROPERTIES of METHYLENE BISMORPHOLINE:
Chemical Formula: C9H18N2O2
Molecular Weight: 186.25 g/mol
CAS Number: 5625-90-1
EC Number: 227-062-3
Appearance: Colorless to light yellow liquid; slightly amine-like odor
Density: 1.04 g/cm³
Melting Point: 18–21 °C
Boiling Point: 122–124 °C at 12 mmHg; ~265 °C at 760 mmHg
Flash Point: 77.6 °C
Vapor Pressure: 0.00935 mmHg at 25 °C (~0.625 Pa)
Water Solubility: Soluble in water; fully miscible between 10–30 °C, pH 5–9

pKa: 6.91 ± 0.10 (Predicted)
Refractive Index: 1.4790 (estimated)
Storage Conditions: 2–8 °C
SMILES: C(N1CCOCC1)N1CCOCC1
InChI: InChI=1S/C9H18N2O2/c1-5-12-6-2-10(1)9-11-3-7-13-8-4-11/h1-9H2
InChIKey: MIFZZKZNMWTHJK-UHFFFAOYSA-N
IUPAC Name: 4-(morpholin-4-ylmethyl)morpholine
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 4
Rotatable Bond Count: 2
Topological Polar Surface Area: 24.9 Å²

Heavy Atom Count: 13
Formal Charge: 0
Exact Mass: 186.137 g/mol
Monoisotopic Mass: 186.137 g/mol
XLogP3: -0.3
Complexity: 127
Covalently-Bonded Unit Count: 1
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Compound Is Canonicalized: Yes
Function: Biocide
Applications: Specialty chemicals, biocide use

FIRST AID MEASURES of METHYLENE BISMORPHOLINE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of METHYLENE BISMORPHOLINE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of METHYLENE BISMORPHOLINE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of METHYLENE BISMORPHOLINE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of METHYLENE BISMORPHOLINE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.

STABILITY and REACTIVITY of METHYLENE BISMORPHOLINE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available