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METHYLENE CHLORIDE

 

 

Methylene chloride is used solvent for manufacturing film, polycarbonate etc.
Methylene chloride is used raw materials for fluorocarbon production, and Urethane foam.
Methylene chloride's volatility and ability to dissolve a wide range of organic compounds makes it a useful solvent for many chemical processes.


CAS Number: 75-09-2
EC Number / EINECS: 200-838-9
IUPAC Name: Dichloromethane
Molecular Formula: CH₂Cl₂
Molecular Weight: 84.93 g/mol

SYNONYMS:
DICHLOROMETHANE, Methylene chloride, 75-09-2, Methylene dichloride, Methane, dichloro-, Methylene bichloride, Methane dichloride, Solaesthin, Solmethine, Narkotil, Aerothene MM, Freon 30, Metylenu chlorek, Chlorure de methylene, Metaclen, CH2Cl2, Soleana VDA, Khladon 30, F 30 (chlorocarbon), Methylenum chloratum, R30 (refrigerant), RCRA waste number U080, Caswell No. 568, NCI-C50102, HCC 30, DTXSID0020868, Chloride, Methylene, Bichloride, Methylene, Dichloride, Methylene, CCRIS 392, UN 1593, EPA Pesticide Chemical Code 042004, NSC-406122, BRN 1730800, 588X2YUY0A, AI3-01773, DTXCID40868, CHEBI:15767, NSC406122, RefChem:6698, dichloromethane, methylene chloride, 200-838-9, Dichlormethan, dichloro-methane, R 30, dichlormethane, Methoklone, Salesthin, dichloro methane, Chlorodorm D, NSC 406122, F 30, Methylene chloride [NF], Dichloromethane, HPLC Grade, Dichloromethane (Methylenechloride), MFCD00000881, Methylene chloride (NF), Dichloromethane(Methylene Chloride), Metylenu chlorek [Polish], Methylene chloride, Dichloromethane, DCM, HSDB 66, Chlorure de methylene [French], EINECS 200-838-9, UN1593, DICHLOROMETHANE, NF, RCRA waste no. U080, DICHLOROMETHANE, ACS, dichioromethane, dichlormetane, dichloromeihane, dichlorometan, dichlorometane, dichloromethan, dichoromethane, dicloromethane, methylenchoride, metylenchloride, UNII-588X2YUY0A, Methylenchlorid, Driverit, Nevolin, dichlor-methane, dichlorometliane, dichlorornethane, dicliloromethane, methylenchloride, methylenechlorid, methYIenechlorid, di-chloromethane, dichloromethane-, methlyenechloride, methylenechloride, methlene chloride, methyene chloride, methylen chloride, methylene chlorie, methylene cloride, metylenе chloride, Methylene choride, mehtylene chloride, methlyene chloride, methylene,chloride, methylene-chloride, dichloro -methane, dichloro- methane, methylenedichloride, Distillex DS3, Dichloromethane, ACS reagent, >=99.5%, contains 40-150 ppm amylene as stabilizer, M-clean D, methyl ene chloride, MeCl2, methylene di chloride, N,N-methylenechloride, dichloromethane radical, Methylene chloride ACS, Cl2CH2, H2CCl2, Desflurane EP Impurity E, Dichloromethane, anhydrous, SCHEMBL493, Dichloromethane, for HPLC, EC 200-838-9, NCIMech_000221, SCHEMBL9639, WLN: G1G, 4-01-00-00035 (Beilstein Handbook Reference), Dichloromethane, >=99.9%, CHEMBL45967, DICHLOROMETHANE [IARC], SCHEMBL135285, Dichloromethane, AR, >=99%, SCHEMBL8546647, Dichloromethane (Peptide Grade), DICHLOROMETHANE [MART.], METHYLENE CHLORIDE [II], METHYLENE CHLORIDE [MI], METHYLENE CHLORIDE [FCC], SCHEMBL18247337, METHYLENE CHLORIDE [HSDB], Dichloromethane, LR, >=99.5%, Dichloromethane, purification grade, METHYLENE CHLORIDE [VANDF], Dichloromethane, analytical standard, Dichloromethane, Environmental Grade, METHYLENE CHLORIDE [USP-RS], Tox21_202526, MSK000662, STL264204, AKOS009031498, InChI=1/CH2Cl2/c2-1-3/h1H, Dichloromethane [UN1593] [Poison], Dichloromethane, ACS reagent, 99.5%, CAS-75-09-2, Dichloromethane, for HPLC, >=99.7%, Dichloromethane, Spectrophotometric Grade, METHYLENE CHLORIDE [EP MONOGRAPH], MSK000662-1000E, NCGC00091504-01, NCGC00260075-01, Dichloromethane, Guaranteed Reagent Grade, Dichloromethane 100 microg/mL in Methanol, Dichloromethane, suitable for PCB analysis, DESFLURANE IMPURITY E [EP IMPURITY], Dichloromethane 1000 microg/mL in Methanol, D0529, D3478, M0629, NS00004151, Dichloromethane, 99%, stabilized with ethanol, Dichloromethane, for HPLC, >=99.8% (GC), Dichloromethane, SAJ first grade, >=99.0%, Dichloromethane, Selectophore(TM), >=99.5%, C02271, D02330, Dichloromethane, analytical standard, stabilized, Dichloromethane, JIS special grade, >=99.0%, Dichloromethane, stabilised with Amylene, >99.8%, F600015, L023970, Q421748, Q425210, Dichloromethane Solution in Ethyl acetate, 1000ug/mL, Dichloromethane, 99%, stab. with ca. 50ppm amylene, Methylene Chloride HPLC grade Stabilized with Amylene, Dichloromethane, glass distilled HRGC/HPLC trace grade, Dichloromethane, TLC high-purity grade, >=99.8% (GC), Dichloromethane HPLC, UV/IR, min. 99.8%, isocratic grade, Dichloromethane, special, 99.9%, contains 40-60 ppm Amylene, Dichloromethane, for HPLC, >=99.8%, contains amylene as stabilizer, Dichloromethane, Selectophore(TM), >=99.5% (GC), inhibitor-free, Dichloromethane, technical grade, 95%, contains 40-60 ppm Amylene, Methylene chloride, European Pharmacopoeia (EP) Reference Standard, Dichloromethane, puriss. p.a., ACS reagent, reag. 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ISO, reag. Ph. Eur., 99.8%, contains 40-60 ppm Amylene, M.C, Residual Solvent Class 2 - Methylene chloride, United States Pharmacopeia (USP) Reference Standard, Dichloromethane, Methylene bichloride, Methylene chloride gas, Methylene dichloride, Solmethine, Narkotil, Solaesthin, Di-clo, Refrigerant-30, Freon-30, R-30, DCM, MDC, Methane, dichloro-, Aerothene MM, Dichloromethane, Freon 30, Methylene dichloride, Narkotil, Solaesthin, Solmethine, CH2Cl2, Methane dichloride, Methylene bichloride, Chlorure de methylene, Metylenu chlorek, NCI-C50102, R 30, Rcra waste number U080, UN 1593, Methoklone, Salesthin, F 30, F 30 (chlorocarbon), HCC 30, Khladon 30, Metaclen, NSC 406122, Soleana VDA, Dichloromethane, DCM, Methylenum chloratum, NCI-C50102

Methylene chloride (CH2Cl2), also known as dichloromethane, is one example of a class of chemicals known as chlorinated hydrocarbons.
Methylene chloride is a volatile, colorless liquid that has a chloroform-like odor.
Methylene chloride has a boiling point of 104 deg. F and a vapor pressure of 350 mm at 68 deg. F (20 deg. C).


Methylene chloride is mainly released into the environment during its production and use.
Methylene chloride, which is also called Dichloromethane, is a volatile chemical that is produced and imported into the United States, with use estimated at over 260 million pounds per year.


Methylene chloride is registered under the REACH Regulation and is manufactured in and/or imported to the European Economic Area, at ≥ 100 000 tonnes per annum.
Methylene chloride is one of the most stable aliphatic saturated chlorinated hydrocarbon compounds.


Methylene chloride, also known as dichloromethane (DCM), is a solvent frequently used in various consumer, commercial, and research applications.
Methylene Chloride (also known as Dichloromethane) has long been used in the manufacture of adhesives.


Methylene chloride's main purpose is that of a solvent, helping to dissolve many types of plastic and resin polymers found in adhesives such as acrylics, polyurethanes and PVC.
This helps with creating a uniform adhesive structure and texture and can increase final bond strength.


Methylene chloride is an organic solvent that is practically nonflammable, has strong solvency and high stability.
Methylene chloride is often found in products used for solvent welding of plastics.
This is a process whereby pieces of plastic are joined after they have been clamped together.


The solvent-based adhesive, Methylene chloride, can be applied along the gap between the parts, and due to its very low viscosity, quickly wicks (seeps) into the joint and starts to melt the two pieces of plastic together.
Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula CH2Cl2.


Methylene chloride, also called dichloromethane, is a volatile, colorless liquid with a chloroform-like odor.
Methylene chloride is used in various industrial processes, in many different industries including paint stripping, pharmaceutical manufacturing, paint remover manufacturing, and metal cleaning and degreasing.


The most common means of exposure to methylene chloride is inhalation and skin exposure.
Methylene chloride is highly volatile and nonflammable, and among chlorinated solvents, it demonstrates excellent solubility for fats and oils.
Methylene chloride, also known as dichloromethane or DCM, is a solvent used in paint strippers and other products.


Methylene chloride has been linked to cancer, cognitive impairment, and immediate death by asphyxiation.
If you need to remove paint or a coating, make sure to avoid products containing methylene chloride and other toxic chemicals like N-methylpyrrolidone (NMP).


Methylene chloride, also known as dichloromethane and methylene dichloride, is a clear, colorless liquid with a slightly sweet scent that is primarily used as an industrial solvent and as a potent paint stripper and paint thinner.
Methylene chloride is a colorless liquid with a mild, sweet odor.


Another name for Methylene chloride is dichloromethane.
Methylene chloride does not occur naturally in the environment.
Methylene chloride appears as a colorless liquid with a sweet, penetrating, ether-like odor.


Methylene chloride is noncombustible.
Methylene chloride is a member of the class of chloromethanes that is methane in which two of the hydrogens have been replaced by chlorine.
Methylene chloride is a dense, non-flammable colourless liquid at room temperature (b.p. 40℃, d = 1.33) which is immiscible with water.


Methylene chloride is a member of chloromethanes and a volatile organic compound.
Methylene Chloride has been reported in Garcinia mangostana, Biflustra perfragilis, and Cynara cardunculus with data available.


Methylene Chloride is a clear, colorless, nonflammable, volatile liquid chlorinated hydrocarbon with a sweet, pleasant smell and emits highly toxic fumes of phosgene when heated to decomposition.
Diluent for colour additives and inks for marking fruit and vegetables.


The output of these processes is a mixture of methyl chloride, dichloromethane, chloroform, and carbon tetrachloride.
These compounds are separated by distillation.
Methylene chloride has been shown to exhibit anti-tumor, anti-proliferative, analgesic, anti-fungal and antibiotic functions.


Methylene chloride belongs to the family of Organochlorides.
These are organic compounds containing a chlorine atom.
Methylene chloride is a chlorinated hydrocarbon that has been used as an inhalation anesthetic and acts as a narcotic in high concentrations.

USES and APPLICATIONS of METHYLENE CHLORIDE:
Methylene chloride is used as an aerosol solvent in the production of pharmaceuticals and as a degreasing agent in electronics and manufacturing industries.
Methylene chloride is used by consumers, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.


Methylene chloride is used in the following products: adhesives and sealants, plant protection products, washing & cleaning products, biocides (e.g. disinfectants, pest control products) and coating products.
Other release to the environment of Methylene chloride is likely to occur from: indoor use as processing aid and outdoor use as processing aid.


Methylene chloride is used in the following products: coating products, washing & cleaning products, adhesives and sealants, biocides (e.g. disinfectants, pest control products) and plant protection products.
Methylene chloride is used in the following areas: scientific research and development and agriculture, forestry and fishing.


Other release to the environment of Methylene chloride is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use as processing aid.
Methylene chloride is used in the following products: adhesives and sealants and coating products.


Release to the environment of Methylene chloride can occur from industrial use: formulation of mixtures.
Methylene chloride is used in the following products: washing & cleaning products, extraction agents, adhesives and sealants, coating products and heat transfer fluids.


Methylene chloride has an industrial use resulting in manufacture of another substance (use of intermediates).
Methylene chloride is used for the manufacture of: chemicals, textile, leather or fur, plastic products and rubber products.


Release to the environment of Methylene chloride can occur from industrial use: in processing aids at industrial sites, as an intermediate step in further manufacturing of another substance (use of intermediates) and of substances in closed systems with minimal release.
Release to the environment of Methylene chloride can occur from industrial use: manufacturing of the substance.


Main uses of Methylene chloride: Metal cleaning, printed circuit board cleaning, paint remover, adhesive solvents, urethane foam auxiliary blowing agents, manufacturing solvents such as polycarbonate resin.
Methylene chloride has been used for paint and furniture stripping, as an extraction solvent in pharmaceutical manufacturing, as a solvent for metal cleaning and degreasing, and as a solvent in spray adhesive and urethane foam blowing.


Methylene chloride is widely used in various applications such as resin manufacturing solvents and paint release agents.
Furthermore, because of its low boiling point, Methylene chloride is also suitable as a solvent and an extractant for organic intermediates.
Applications of Methylene chloride: Metal degreasing cleaning, and Reaction solvents for medical and agrochemical production.


Methylene chloride is used solvent for manufacturing film, polycarbonate etc.
Methylene chloride is used raw materials for fluorocarbon production, and Urethane foam.
Methylene chloride's volatility and ability to dissolve a wide range of organic compounds makes it a useful solvent for many chemical processes.


In the past Methylene chloride was used to decaffeinate coffee and tea, though it has mostly been replaced by extraction using supercritical CO2, as well as to prepare extracts of hops and other flavourings.
Methylene chloride's volatility has led to its use as an aerosol spray propellant and as a blowing agent for polyurethane foams.


This colorless, volatile liquid, Methylene chloride, with a chloroform-like, sweet odor is widely used as a solvent.
Although Methylene chloride is not miscible with water, it is slightly polar and miscible with many organic solvents.
Methylene chloride chemically welds certain plastics.


For example, Methylene chloride is used to seal the casing of electric meters.
Often sold as a main component of plastic welding adhesives, Methylene chloride is also used extensively by model building hobbyists for joining plastic components together.


Methylene chloride is commonly referred to as "Di-clo".
Methylene chloride is used in the garment printing industry for removal of heat-sealed garment transfers.


Methylene chloride is used in the material testing field of civil engineering; specifically it is used during the testing of bituminous materials as a solvent to separate the binder from the aggregate of an asphalt or macadam to allow the testing of the materials.
Methylene chloride has been used as the principal component of various paint and lacquer strippers, although its use is now restricted in the EU and many such products now use benzyl alcohol as a safer alternative.


Consequently, methylene chloride is used in a broad array of applications as a paint remover, urethane foaming agent, and also as a reaction solvent for producing polycarbonate resin and photographic film.
Owing to the above mentioned properties solubility, methylene chloride is also widely used for cleaning metals.


General applications of Methylene chloride: Reaction solvent for producing polycarbonate resin, Extracting solvent for pharmaceuticals and agricultural chemicals, Paint remover, Material for adhesive agents, and Urethane foaming agent.
Occurrence/Use of Methylene chloride: Solvent; paint stripper, degreaser; extraction agent for flavorings and to decaffeinate coffee and tea; aerosol propellant and blowing agent for polyurethane foams; manufacture of pharmaceuticals, film coatings, and electronics.


Methylene chloride is primarily used as a solvent in paint removers.
Methylene chloride is predominantly used as a solvent.
Methylene chloride is used as an industrial solvent and as a paint stripper.


Methylene chloride may also be found in some aerosol and pesticide products and is used in the manufacture of photographic film.
Methylene chloride is used as a solvent and paint remover.
Methylene chloride is widely used as a solvent, a paint stripper, and for the removal of caffeine from coffee and tea.


Methylene chloride has a role as a polar aprotic solvent, a carcinogenic agent and a refrigerant.
Methylene chloride is also used in aerosol formulations, as a solvent in the manufacture of pharmaceuticals, as a degreasing agent, in electronics manufacturing and as an ethane foam blowing agent.


Methylene chloride is used as an extraction solvent in the preparation of decaffeinated coffee, hop extracts and spice oleoresins.
Methylene chloride's primary use is as a solvent in manufacturing and food technology.


-Specialized uses of Methylene chloride:
Methylene chloride's low boiling point allows the chemical to function in a heat engine that can extract mechanical energy from small temperature differences.
An example of a Methylene chloride heat engine is the drinking bird.

The toy works at room temperature.
Methylene chloride is also used as the fluid in jukebox displays and holiday bubble lights that have a colored bubbling tube above a lamp as a source of heat and a small amount of rock salt to provide thermal mass and a nucleation site for the phase changing solvent.

USES & BENEFITS of METHYLENE CHLORIDE:
Methylene chloride is most prominently used industrially — in the production of paint strippers, pharmaceuticals and process solvents.
Methylene chloride also is used in the following industrial settings:


*Food and Beverage Manufacturing
Methylene chloride is used as an extraction solvent in the food and beverage manufacturing industry.
For example, methylene chloride can be used to remove caffeine from unroasted coffee beans and tea leaves, to make decaffeinated coffee and tea.
Methylene chloride also is used in processing spices, creating hops extract for beer and other flavorings for the food and beverage industries.


*Transportation Industry
Methylene chloride can be used to degrease metal surfaces and parts, such as airplane components and railroad tracks and equipment.
Lubricating and degreasing products used in automotive products, for example in gasket removal and for prepping metal parts for a new gasket, could contain methylene chloride.

Automotive specialists use a vapor methylene chloride degreasing process to remove oils and grease from car transistor parts, diesel motors and aircraft components and spacecraft assemblies.
Modern vapor degreasing techniques that rely on methylene chloride enable metal parts in transportation systems to be cleaned quickly and safely.


*Medical Applications
In laboratories, methylene chloride is used to extract chemicals from plants or foods for medicine such as steroids, antibiotics and vitamins.
Medical equipment can be quickly and efficiently cleaned with methylene chloride cleaners without causing corrosion problems or damage to heat-sensitive parts.


*Household Uses
Methylene chloride is a solvent found in paint and varnish strippers that are used to remove paint or varnish coatings from a variety of surfaces.
Methylene chloride is also used in bathtub refinishing.

OCCURRENCE of METHYLENE CHLORIDE:
Natural sources of Methylene chloride include oceanic sources, macroalgae, wetlands, and volcanoes.
However, the majority of Methylene chloride in the environment is the result of industrial emissions.

PRODUCTION of METHYLENE CHLORIDE:
Methylene chloride is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C.
At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products.
In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993.

CH4 + Cl2 → CH3Cl + HCl
CH3Cl + Cl2 → CH2Cl2 + HCl
CH2Cl2 + Cl2 → CHCl3 + HCl
CHCl3 + Cl2 → CCl4 + HCl

The output of these processes is a mixture of chloromethane, dichloromethane, chloroform, and carbon tetrachloride as well as hydrogen chloride as a byproduct.
These compounds are separated by distillation.

Methylene chloride was first prepared in 1839 by the French chemist Henri Victor Regnault (1810–1878), who isolated it from a mixture of chloromethane and chlorine that had been exposed to sunlight.

CHEMICAL REACTIONS of METHYLENE CHLORIDE:
Methylene chloride is widely used as a solvent in part because it is relatively inert.
Methylene chloride does participate in reactions with certain strong nucleophiles however.

Tert-butyllithium deprotonates DCM:
H2CCl2 + RLi → HCCl2Li + RH

Methyllithium reacts with methylene chloride to give chlorocarbene:
CH2Cl2 + CH3Li → CHCl + CH4 + LiCl

Although Methylene chloride is a common solvent in organic chemistry laboratories and is commonly assumed to be inert, it does react with some amines and triazoles.
Tertiary amines can react with Methylene chloride to form quaternary chloromethyl chloride salts via the Menshutkin reaction.

Secondary amines can react with Methylene chloride to yield an equilibrium of iminium chlorides and chloromethyl chlorides, which can react with a second equivalent of the secondary amine to form aminals.

At increased temperatures, pyridines including DMAP, react with Methylene chloride to form methylene bispyridinium dichlorides.
Hydroxybenzotriazole and related reagents used in peptide coupling react with Methylene chloride in the presence of triethylamine, forming acetals.

HOW IS METHYLENE CHLORIDE USED?
Methylene chloride is a solvent used in a variety of industries and applications, such as adhesives, paint and coating products, pharmaceuticals, metal cleaning, chemical processing, and aerosols.

Methylene chloride is manufactured using AGC’s proprietary production method as “Asahi Chloromethane,” a methane-based chlorine derivative with a carbon number of 1.
Methylene chloride offers high degreasing performance and stability and has a low boiling point, so it can be ideal for cleaning parts that are adversely affected by heat, as well as for organic synthetic solvents and extraction solvents.

SPECIAL CHARACTERISTICS of METHYLENE CHLORIDE:
Colorless and volatile liquid.
Nonflammable.
Methylene chloride has excellent solubility compared to other chlorinated solvents.

KEY POINTS/OVERVIEW of METHYLENE CHLORIDE:
Methylene chloride is used to process spices and hops and to extract caffeine from coffee beans and tea leaves.
In the automotive industry, Methylene chloride serves as a lubricant or degreaser.
Lab technicians use Methylene chloride to extract other chemicals from plants for use in steroids, antibiotics and vitamins.

PHYSICAL and CHEMICAL PROPERTIES of METHYLENE CHLORIDE:
Molecular Weight: 96.08 g/mol
XLogP3: 0.4
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 1
Exact Mass: 96.021129366 Da
Monoisotopic Mass: 96.021129366 Da
Topological Polar Surface Area: 30.2 Ų
Heavy Atom Count: 7
Formal Charge: 0

Complexity: 70.5
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
Flash Point: None, but can form flammable vapor-air mixtures above ≈100 °C

Autoignition Temperature: 556 °C
Explosive Limits: 13%-23%
Chemical Formula: CH2Cl2
Molar Mass: 84.93 g·mol−1
Appearance: Colorless liquid
Odor: Faint, minty, chloroform-like
Density: 1.3266 g/cm3 (20 °C)
Melting Point: −96.7 °C

Boiling Point: 39.6 °C
Decomposition Temperature: 720 °C
Solubility in Water: 25.6 g/L (15 °C), 17.5 g/L (25 °C), 15.8 g/L (30 °C), 5.2 g/L (60 °C)
Solubility: Miscible in ethyl acetate, alcohol, hexanes, benzene, CCl4, diethyl ether, CHCl3
Log P: 1.19
Vapor Pressure: 0.13 kPa (−70.5 °C), 2 kPa (−40 °C), 19.3 kPa (0 °C), 57.3 kPa (25 °C), 79.99 kPa (35 °C)
Henry's Law Constant: 3.25 L·atm/mol
Magnetic Susceptibility: −46.6·10−6 cm3/mol

Refractive Index: 1.4244 (20 °C)
Viscosity: 0.43 cP (20 °C), 0.413 cP (25 °C)
Dipole Moment: 1.6 D
Heat Capacity: 102.3 J/(mol·K)
Std Molar Entropy: 174.5 J/(mol·K)
Std Enthalpy of Formation: −124.3 kJ/mol
Std Enthalpy of Combustion: −454.0 kJ/mol

FIRST AID MEASURES of METHYLENE CHLORIDE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation: 
Fresh air.
*In case of skin contact: 
Take off immediately all contaminated clothing. 
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact: 
Rinse out with plenty of water. 
Call in ophthalmologist. 
Remove contact lenses.
*If swallowed:
After swallowing: 
Immediately make victim drink water (two glasses at most). 
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of METHYLENE CHLORIDE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains. 
Collect, bind, and pump off spills. 
Observe possible material restrictions. 
Take up dry. 
Dispose of properly. 
Clean up affected area.

FIRE FIGHTING MEASURES of METHYLENE CHLORIDE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2) 
Foam 
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of METHYLENE CHLORIDE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection. 
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A 
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of METHYLENE CHLORIDE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed. 
Dry.

STABILITY and REACTIVITY of METHYLENE CHLORIDE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available

 
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