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CAS: 143-28-2
Oleyl alcohol /ˈoʊliˌɪl, ˈoʊliəl/,[1] or cis-9-octadecen-1-ol, is an unsaturated fatty alcohol with the molecular formula C18H36O or the condensed structural formula CH3(CH2)7-CH=CH-(CH2)8OH. It is a colorless oil, mainly used in cosmetics.
Synonyms:
(Z) -9-Oktadeken-1-ol etoksillenmiş, Oleth-5, Oleil alkolün polioksietilen glikol eteri, PEG 5 Oleyl alkol, Polioksi Oleyl Alkol; OLEYL ALCOHOL; (Z)-octadec-9-en-1-ol; 143-28-2; cis-9-Octadecen-1-ol; Ocenol; Dermaffine; Lancol; Novol; Oceol; Oleol; Satol; Oleic alcohol; Oleo alcohol; Crodacol-O; Conditioner 1; Loxanol M; Atalco O; Siponol OC; Sipol O; (Z)-9-Octadecen-1-ol; (Z)-Octadec-9-enol; Cachalot O-1; Cachalot O-3; Cachalot O-8; H.D. eutanol; HD-Ocenol K; Loxanol 95; Unjecol 50; Unjecol 70; Unjecol 90; Oleoyl alcohol; Olive alcohol; Cachalot O-15; Crodacol A.10; Unjecol 110; HD oleyl alcohol CG; cis-9-Octadecenyl alcohol; Adol 34; HD-Ocenol 90/95; HD oleyl alcohol 70/75; (9Z)-octadec-9-en-1-ol; Witcohol 85; Witcohol 90; 9-Octadecen-1-ol, (Z)-; Adol 320; Adol 330; Adol 340; cis-octadecen-1-ol; 9-Octadecen-1-ol; (Z)-9-octadecenol; Oleylalcohol; HD-Eutanol; Octadec-9Z-enol; cis-9-octadecenol; UNII-172F2WN8DV; (9Z)-9-Octadecen-1-ol; 9Z-Octadecen-1-ol; Oleyl alcohol (NF); Oleyl alcohol [NF]; ( Z)-9-octadecenol; Witcohol 85 (TN); 9-Octadecen-1-ol, (9Z)-Polyoxyl 10 oleyl ether; MFCD00002993; 9-Octadecen-1-ol, cis-172F2WN8DV; CHEBI:73504; 0leyl alcohol; 9-Octadecenol; Oleyl alcohol, ca. 60%, technical; Poly(oxy-1,2-ethanediyl), alpha-((Z)-9-octadecenyl)-omega-hydroxy-; cis-Oleyl alcohol; HSDB 6484; EINECS 205-597-3; NSC 10999; AI3-07620; Lipocol O; C18H36O; Anjecol 90N; Unjecol 90N; (Z)-oleyl alcohol; Anjecol 90NR; Unjecol 90NR; Francol OA-95; Fancol OA-95; cis 9 octadecen-1-ol; cis-9-0ctadecen-1-ol; 9(Z)-Octadecen-1-ol; HD-Echelon 90/95; cis-octadec-9-en-1-ol; DSSTox_CID_2010; Octadeca-9-cis-en-1-ol; EC 205-597-3; cis-.DELTA.9-Octadecenol; HD-Ocenol 90/95 V; SCHEMBL5668; (Z)-octadeca; 9-en-1-ol; DSSTox_RID_76459; DSSTox_GSID_22010; (9Z)-9-Octadecen-1-ol #; Octadec-9-en-1-ol, (Z)-; CHEMBL2105350; DTXSID0022010; Oleyl alcohol, >=99% (GC); Oleyl alcohol, analytical standard; cis-Laquo deltaRaquo 9-Octadecenol; NSC10999; ZINC8214634; Tox21_200111; (9Z)-9-Octadecen-1-ol, 85%; 7025AA; LMFA05000213; NSC-10999; Oleyl alcohol, technical grade, 85%; Oleyl alcohol, technical, ~60% (GC); NCGC00164365-01; CAS-143-28-2; DB-007794; O0058; D05245; Q7086489; W-109512; 3164D881-7E14-4979-9E60-58DDC0468323; Oleyl alcohol, United States Pharmacopeia (USP) Reference Standard
It can be produced by the hydrogenation of oleic acid esters by Bouveault–Blanc reduction, which avoids reduction of the C=C group (as would occur with usual catalytic hydrogenation). The required oleate esters are obtained from beef fat, fish oil, and, in particular, olive oil (from which it gains its name). The original procedure was reported by Louis Bouveault in 1904] and subsequently refined.
It has uses as a nonionic surfactant, emulsifier, emollient and thickener in skin creams, lotions and many other cosmetic products including shampoos and hair conditioners. It has also been investigated as a carrier for delivering medications through the skin or mucus membranes; particularly the lungs.
Industry Uses
Paint additives and coating additives not described by other categories
Consumer Uses
Lubricants and greases
Photographic supplies, film, and photo chemicals
Oleth-5 is in products to clean scalp and hair by helping water to mix with oil and dirt so that they can be rinsed away. Oleth-5 also helps to form emulsions by reducing the surface tension of the substances to be emulsified and help ingredients to dissolve in liquids.
• Stable emulsions for various degrees of water hardness and a wide variety of conditions. • Foam controlling emulsifiers, co-emulsifiers and solubilizers. • Multifunctional stabilizers (highlighted in Kao Metalworking Toolbox summary of application benefits). • Easy handling and formulating. • Environmentally friendly.
• Longer fluid lifetimes. • Lower maintenance costs and increased productivity thanks to clean fluids. • Formulations for high pressure and high speed machining. • Improved lubricity and extreme pressure/anti-wear (EP/AW) performance for increased tool lifetimes. • Mild labeling and environmentally friendly metalworking fluids.
Unlike standard Oleth-5 products, it is a narrow range ethoxylate resulting in a clear liquid product which can be processed cold. it is an excellent emulsifier and solubilizer. excellent solubility in many oils. nonionic emulsifier and co-emulsifier.
Clear hair gels and facial toners due to excellent solubilizing activity. HLB is 9, if a higher HLB value is needed in the final application, combine with another liquid nonionic product like undeceth-8 which has an HLB value of 13.
Both nonionic emulsifiers and specialized products, for example self emulsifying blooming bath oils, leave on and rinse off hair conditioners or hair dye emulsions are easily and succesfully made
It belongs to nonionic surfactants from the group of ethoxylated fatty alcohols (INCI name: Oleth 5). The product is available in straw to light yellow liquid form. The product is naturally produced from raw materials, making it highly biodegradable. Another advantage is the low content of free ethylene oxide and 1,4-dioxane.
Product advantages:
natural, easily biodegradable product,
good dispersing and solubilizer,
O / W emulsifier,
improves the rheological properties of washing preparations in the presence of anionic surfactants and electrolytes,
suitable for use in oxidizing, reducing environments and hard water,
it does not corrode metals.
Applications:
body care products,
washing products,
industrial cleaning,
industrial applications.
Alkyl polyglycol ether recommended for a number of skin and hair care systems.
Applications
Bath, Shower & Soaps
Antiperspirants & Deodorants
Eye Colour
Face Colour
Hair Colour
Hair Relaxing / Permanent Waves
Lip Colour
Shaving / Hair Removal
Styling
Functions
Dispersing Agents
Pigment Wetters
Solubilisers
Emulsifiers
Gelling Agents
Surfactants / Detergents
Oleth-5, are polyethylene glycol ethers of oleyl alcohol in which the number in the name is the average number of ethylene oxide units. In cosmetics and personal care products, the Oleth ingredients are used in the formulation of skin care products, makeup and hair care products.
The Oleth ingredients clean skin and hair by helping water to mix with oil and dirt so that they can be rinsed away. These ingredients also help to form emulsions by reducing the surface tension of the substances to be emulsified and help ingredients to dissolve in liquids in which they would not normally dissolve.
The Oleth ingredients are polyethylene glycol ethers of oleyl alcohol. Their physical from ranges from liquids to waxy solids. The water solublity of the Oleth ingredients increases as the content of ethylene oxide increases.
Definition and Structure Oleth -5 is the polyethylene glycol (PEG) ethers of oleyl alcohol (q.v.) that confonn to the formula shown in ,
.
Oleyl Alcohol is a mixture of fatty alcohols that consists primarily of the straight-chain unsaturated 9- n-octadecenol Oleths are identified in Japan as polyoxyethylene oleyl ether (Rempe and Santucci 1992). Chemical and Physical Properties The Oleth family has a broad range of properties depending on the degree of polymerization of the PEG segment. The physical forms of these ingredients range from liquids to waxy solids. Compounds with 1-5 moles of ethylene oxide are soluble in oil and many hydrocarbons. Solubility in water increases with the content of ethylene oxide.
Cosmetic The Oleths are surfactants used as emulsifying, cleansing, and solubilizing agents.
Concentration of use values are no longer reported to the FDA by the cosmetic industry. However, data provided to the FDA in 1984 indicated that the highest concentration used was 25 %. At this concentration, Oleth-2 and Oleth-10 were used in tonics, dressings, and other hair grooming aids, Oleth-10 were used in blushers, and Oleth-20 was used in colognes/toilet waters. Recent data submitted directly by CTFA indicated that Oleths are used at concentrations up to 12%. The data indicated the following maximum concentrations of use for specific Oleths in particular formulations: Oleth-2 up to 12% (hair styling gel), Oleth-10 between 0.2-6.0% (various formulations, used at 6% in sachets), Oleth-16 up to 5%, and Oleth-20 up to 12% (various formulations) International Oleths are listed in the Comprehensive Licensing Standards of Cosmetics by Category (CLS) and must conform to the specifications of the Japanese Standards of Cosmetic Ingredients (Yakuji Nippo, Ltd. 1994). They can be used in all CLS categories without restrictions. Noncosmetic Oleths are used for their emulsifying, wetting, antistatic, solubilizing, defoaming, detergent, and lubricating properties in pharmaceutical and industrial applications.
Consumer Uses
This substance is used in the following products: washing & cleaning products, biocides (e.g. disinfectants, pest control products), coating products, fertilisers, anti-freeze products, fillers, putties, plasters, modelling clay, finger paints, lubricants and greases and polishes and waxes. Release to the environment of this substance can occur from industrial use: industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal). Other release to the environment of this substance is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment) and indoor use in long-life materials with high release rate (e.g. release from fabrics, textiles during washing, removal of indoor paints).
Article service life
Release to the environment of this substance can occur from industrial use: in processing aids at industrial sites, in the production of articles and industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal).
Other release to the environment of this substance is likely to occur from: outdoor use, indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
This substance can be found in products with material based on: stone, plaster, cement, glass or ceramic (e.g. dishes, pots/pans, food storage containers, construction and isolation material) and plastic (e.g. food packaging and storage, toys, mobile phones).
This substance is used in the following products: lubricants and greases, biocides (e.g. disinfectants, pest control products), coating products and fillers, putties, plasters, modelling clay.
This substance is used in the following areas: building & construction work and agriculture, forestry and fishing.
This substance is used for the manufacture of: machinery and vehicles, rubber products, plastic products, mineral products (e.g. plasters, cement), furniture and fabricated metal products.
Release to the environment of this substance can occur from industrial use: industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal), in processing aids at industrial sites and in the production of articles.
Other release to the environment of this substance is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
Formulation or re-packing
This substance is used in the following products: pH regulators and water treatment products, laboratory chemicals, lubricants and greases and polymers.
This substance has an industrial use resulting in manufacture of another substance (use of intermediates).
Release to the environment of this substance can occur from industrial use: formulation of mixtures, formulation in materials, as an intermediate step in further manufacturing of another substance (use of intermediates), manufacturing of the substance, in processing aids at industrial sites, in the production of articles, as processing aid, for thermoplastic manufacture, as processing aid and of substances in closed systems with minimal release.
This substance is used in the following products: fillers, putties, plasters, modelling clay, lubricants and greases, adhesives and sealants, non-metal-surface treatment products, pH regulators and water treatment products and coating products.
This substance is used in the following areas: building & construction work and mining.
This substance is used for the manufacture of: chemicals, mineral products (e.g. plasters, cement), machinery and vehicles, textile, leather or fur, pulp, paper and paper products and furniture.
Release to the environment of this substance can occur from industrial use: in processing aids at industrial sites, in the production of articles, industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal) and as an intermediate step in further manufacturing of another substance (use of intermediates).
Other release to the environment of this substance is likely to occur from: outdoor use and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).
Release to the environment of this substance can occur from industrial use: manufacturing of the substance, formulation of mixtures, formulation in materials, in processing aids at industrial sites, in the production of articles, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, for thermoplastic manufacture, as processing aid, of substances in closed systems with minimal release and industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal).
Consumer Uses
This substance is used in the following products: washing & cleaning products, plant protection products, lubricants and greases, air care products, polishes and waxes and fertilisers.
Other release to the environment of this substance is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.
Other release to the environment of this substance is likely to occur from: indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment), outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials), outdoor use in long-life materials with high release rate (e.g. tyres, treated wooden products, treated textile and fabric, brake pads in trucks or cars, sanding of buildings (bridges, facades) or vehicles (ships)) and indoor use in long-life materials with high release rate (e.g. release from fabrics, textiles during washing, removal of indoor paints). This substance can be found in complex articles, with no release intended: vehicles. This substance is intended to be released from scented: clothes.
This substance is used in the following products: washing & cleaning products and polishes and waxes.
This substance is used in the following areas: agriculture, forestry and fishing.
This substance is used for the manufacture of: machinery and vehicles and fabricated metal products.
Other release to the environment of this substance is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.
Formulation or re-packing
This substance is used in the following products: washing & cleaning products, lubricants and greases, metal working fluids, textile treatment products and dyes and fertilisers.
Release to the environment of this substance can occur from industrial use: formulation of mixtures and as an intermediate step in further manufacturing of another substance (use of intermediates).
Uses at industrial sites
This substance is used in the following products: washing & cleaning products, metal surface treatment products, lubricants and greases and textile treatment products and dyes.
This substance is used in the following areas: formulation of mixtures and/or re-packaging.
This substance is used for the manufacture of: machinery and vehicles, fabricated metal products, textile, leather or fur and plastic products.
Release to the environment of this substance can occur from industrial use: in processing aids at industrial sites.
Manufacture
Release to the environment of this substance can occur from industrial use: manufacturing of the substance and as an intermediate step in further manufacturing of another substance (use of intermediates).
IUPAC
Aduxol HDOC
Alcohols, C16-18 (even numbered) and C18 unsaturated, ethoxylated < 2.5 EO
Alcohols, C16-18 (even numbered) and C18:1 unsaturated, ethoxylated
Alcohols, C16-18 (even numbered) and C18:1 unsaturated, ethoxylated, 3-10 EO
Alcohols, C16-18 and C18 unsatd., ethoxylated
Alcohols, C16-18 and C18-unsatd., ethoxylated
Alcohols, C16-18 and C18-unsatd., ethoxylated
Alcohols, C16-18 and C18-unsatd., ethoxylated (1 - 2.5 mol EO)
Alcohols, C16-18 and C18-unsatd., ethoxylated (<=2.5 moles EO)
Alcohols, C16-18 and C18-unsatd., ethoxylated (CTS)
Alcohols, C16-18 and C18-unsatd., ethoxylated < 2.5 EO
(9Z)-octadec-9-en-1-ol
(Z)-octadec-9-en-1-ol
(Z)-octadec-9-enol
(Z)-octadec-9-enol
(Z)-Octdec-9-en-1-ol
9-Octadecen-1-ol, (9Z)-
octadec-9-en-1-ol
Oleyl Alcohol
Oleyl alcohol
TRADE
FAEO C16-18/18:1 + 10EO; 10-EO
FAEO C16-18/18:1 + 11EO; 11-EO
FAEO C16-18/18:1 + 12.5EO; 12,5-EO
Eumulgin ET 5 L; 5-EO
Eumulgin ET 5 V; 5-EO
Eumulgin ET 5; 5-EO
FAEO C16-18/18:1 + 6.5EO; 6,5-EO
FAEO C16-18/18:1 + 6EO; 6-EO
FAEO C16-18/18:1 + 7EO; 7-EO
ROFANOL 50/55 V
Rofanol 50/55 V
ROFANOL 60/65 V
Rofanol 60/65 V
ROFANOL 70/75 V
Rofanol 70/75 V
ROFANOL 80/85 V
Rofanol 80/85 V
ROFANOL 90/95 V
Rofanol 90/95 V
