PARMETOL MBX

DESCRIPTION:
Parmetol MBX is an aqueous formulation of 1,2-benzisothiazolin-3(2H)-one (BIT), 2-Methyl-2H-isothiazol-3-one (MIT) and Bis(3- aminopropyl)dodecylamin (BDA).
Parmetol MBX is a fast-acting 2 in 1 in-can preservative based on a synergistic combination of benzisothiazolone (BIT), methylisothiazolone (MIT) and laurylamine dipropylenediamine (BDA) with a broad spectrum of efficacy.

COMPOSITION OF PARMETOL MBX:
Benzisothiazolone (BIT):
Molecular formula: C7H5NOS
Molecular weight: 151.18 g/mol
CAS name: 1,2-benzisothiazol-3(2H)-one
CAS no.: 2634-33-5
INCI name: Benzisothiazolinone
EINECS name: 1,2-benzisothiazol-3(2H)-one
EINECS no.: 220-120-9

Methylisothiazolone (MIT):
Molecular formula : C4H5NOS
Molecular weight : 115.15 g/mol
CAS name: 2-methyl-2H-isothiazol-3-one
CAS no.: 2682-20-4
INCI name: Methylisothiazolinone
EINECS name: 2-methyl-2H-isothiazol-3-one
EINECS no.: 220-239-6
Laurylamine Dipropylenediamine (BDA):
Molecular formula: C18H41N3
Molecular weight: 299 g/mol
CAS name: N-3-Aminopropyl-N-dodecyl1,3-propanediamine
CAS no.: 2372-82-9
INCI name: Laurylamine
Dipropylenediamine
EINECS name: N-(3-Aminopropyl)-Ndodecylpropane-1,3-diamine
EINECS no.: 219-145-8

FIELDS OF APPLICATION OF PARMETOL MBX:
Germ count monitoring by using mikrocount combi. 
For exact dosing guidelines please consult your coolant (metal working fluid) supplier.
Use biocides safely. 
Always read the label and product information before use.
RECOMMENDED DOSAGE:
Sanitation:
2.0 - 4.0 g/kg Addition to be made directly into the central coolant (metal working fluid) system.
Post treatment:
1.0 - 2.0 g/kg Addition to be made directly into the central coolant (metal working fluid) system.
INDICATIONS FOR USE:
Solubility(ies): Fully soluble in water
Recommended use pH range: 3 - 10
Maximum use temperature: max. 80 °C
Additional advice:
Aldehydes should be avoided as they cause decomposition of the active substances. 
When adding parmetol MBX , it should be added at a point with good turbulence in order to ensure good distribution in the system. 
Before refilling the plant, system cleaning is recommended (e.g. with grotanol FF 1 N). 
Cleaning of equipment is possible by rinsing with water.

BENEFITS OF PARMETOL MBX:
PARMETOL MBX is Immediately acting preservative with longterm protection
PARMETOL MBX provides Fast germ count reduction e.g. for contaminated process water
PARMETOL MBX provides Production hygiene integrated in-can preservative
PARMETOL MBX is Synergistic working combination of benzisothiazolone (BIT), methylisothiazolon (MIT) and bis(3-aminopropyl)dodecylamine (BDA)
PARMETOL MBX is Approved for Ecolabel, e.g. "European Flower" or "Nordic Ecolabel
PARMETOL MBX is Smart combination of actives
PARMETOL MBX is Broad, balanced efficacy against bacteria, yeasts and moulds  
PARMETOL MBX is Free of AOX, VOC, CMI/MI, formaldehyde releasers and other aldehydes
PARMETOL MBX based on BDA, a fast-acting amine, and MIT/BIT, responsible for in-can preservation, kills bacteria, yeasts and moulds within process water or raw materials in only a few minutes. 
At the same time PARMETOL MBX offers a long-term protection ensuring a well preserved finished product.

Only one dose of parmetol MBX at the very beginning of the production process is necessary to prevent or to minimise the effect of contamination during the whole manufacturing process.
Parmetol  MBX provides safer manufacturing procedures and provides the opportunity to eliminate quarantine time, product recalls and downtime issues; reduces blocking of filling lines by contaminated products.
Parmetol MBX allows for sustainable use of raw materials due to low use concentrations.
As a result, parmetol MBX complies with the standards of various ecolabels.
No H317-/EU H208-labelling of products containing < 2 % / < 0.2 % (from 6/2015) of parmetol® MBX.

Parmetol MBX-Concept:
There are various sources of microbial contamination in a manufacturing process: stagnant water in pipes may contain bacterial counts >106 cfu/ml. 
In addition serious sources of contamination are raw materials or other subsequently added components. 
What is the common approach for these problems?
A single “quick-killer” is used to treat the contaminated process water and raw materials. 
In most cases the in-can preservative to ensure a long-term preservation is added within the last
production step of the product.
Parmetol MBX-Concept requires the addition of the whole biocide concentration at the very beginning of the production process. 
Enabled due to the outstanding stability and short-term efficacy, parmetol® MBX guarantees for:
• A highly effective biocide for pre-contaminated process water
• A security buffer for contaminated raw materials
• Long-term in-can preservation

INDICATIONS FOR USE OF PARMETOL MBX:
Parmetol MBX is a water soluble, light yellow to orange liquid with a characteristic odour.

Use concentrations:
Household products: 0.05 – 0.4 %
Wet wipes: 0.05 – 0.2 %
Paints and coatings: 0.1 – 0.4 %
Adhesives: 0.1 – 0.4 %
Polymer dispersions: 0.1 – 0.4 %
Metalworking (emulsion): 0.1 – 0.4 %
Legionella pneumophila efficacy: ≥0.1 %

Technical properties:
pH-range for application: 3 - 10
Max. manufacturing temperature: 80 °C

Physical-chemical data for PARMETOL MBX:
Colour: light yellow - orange
Form: liquid
Odour: characteristic
Density (20 °C): 1.009-1.021 g/cm3
Refractive index: 1.345 -1.357
Initial boiling point: ca. 100 °C
Flash point (ISO 2719): > 100 °C
Flow time (DIN 53211, 20 °C): < 15 s
Water solubility (20 °C): in all proportions
VOC Content to Directive 2004/42/EC : none
pH (concentrate): approx. 8 - 9

TYPES OF PARMETOL MBX:
Preservatives for products during storage:
PARMETOL MBX is used for the preservation of manufactured products, other than foodstuffs, feedingstuffs, cosmetics or medicinal products or medical devices by the control of microbial deterioration to ensure their shelf life. 
PARMETOL MBX is used as preservatives for the storage or use of rodenticide, insecticide or other baits.
Slimicides:
PARMETOL MBX is used for the prevention or control of slime growth on materials, equipment and structures, used in industrial processes, e.g. on wood and paper pulp, porous sand strata in oil extraction.
Working or cutting fluid preservatives:
PARMETOL MBX is used control microbial deterioration in fluids used for working or cutting metal, glass or other materials.

Type of Contamination:    Bacteria, Moulds, Yeasts
pH-Range:    0 - 14
Temperature:    < 80°C
Function: Biocide, Anti-Microbial Agent
Chemical Family: Isothiazolones, Diamines
Labeling Claims: Formaldehyde-free, VOC-free, Solvent-free

IDENTIFICATION & FUNCTIONALITY OF PARMETOL MBX:
Chemical Family: Diamines,Isothiazolones
CASE Ingredients Functions:Antimicrobial Agent,
Biocide
Fluids & Lubricants Functions:Biocide,Microbial Control 
Technologies: CASE Ingredients,Fluids & Lubricants
Product Families:
CASE Ingredients — Additives,Microbial Control & Preservation,Fluids & Lubricants — Additives,
Lubricant Protective Additives,
Active Ingredients: BDA | BIT | MIT
Free of the following: Formaldehyde | Solvents | VOC
Labeling Claims: Formaldehyde-free, Solvent-free,VOC-free
Applications & Uses:
Markets: Adhesives & Sealants,Industrial,Paints & Coatings
Applications:
Industrial — Chemical & Industrial Manufacturing,Fluids & Lubricants,Industrial — Leather & Textiles,Leather Manufacturing,Textile Manufacturing,Industrial — Oil, Gas & Mining,Exploration &Upstream,Adhesives & Sealants — Other Adhesives & Sealants Applications,Paints & Coatings — Other Paints & Coatings Applications,Industrial — Paper & Pulp,Other Paper & Pulp Applications,
Fluids & Lubricants Type: Metalworking Fluids
Fluids & Lubricants End Use: Metalworking Fluids
Domains: Adhesive industry | Construction industry | Gypsum, plaster and mortar | Laundry and cleaning agents | Lubricant/coolants | Metalworking | Paint and coatings industry | Paper manufacture | Technical suspension/emulsion | Textile and leather industry

Material compatibility
Concentrate:
In the material compatibility tests with the concentrate of parmetol MBX high-alloyed stainless steel (e. g. 1.4571), steel, nitrile rubber, fluorinated rubber, natural rubber, polyethylene, polyvinylchloride (hard) and polystyrene proved to be suitable materials for handling the undiluted product. 
Copper, brass, zinc, sealants and plastics other than mentioned should not be used.
Dilutions:
The behaviour of parmetol MBX in 0.2 % aqueous solution with regard to material compatibility of metals and plastics was not significantly different from that of tap water. 
A slight incompatibility with brass was determined.
Storage:
Store in original container. 
Keep away from frost, heat and direct sunlight.
Shelf life:
18 months at recommended storage conditions. 
Product specification is valid for the whole shelf life.
Environmental information:
Parmetol  MBX contains only biodegradable components. 
Dilutions of parmetol MBX do not normally interfere with the operation of waste water treatment plants. 
schülke has DIN EN ISO 9001 and EN ISO 14001 certification and has a validated environmental management system in accordance with the Eco Audit Regulation (Reg. No. D-150-00003).
The canisters and drums used by schülke are made of polyethylene (HDPE) and are labelled accordingly. 
The 1000 kg containers are affiliated to a recycling system that guarantees free pick-up and sensible utilisation of used containers throughout Europe. 
The labels are made of polyethylene (PE). 
Our packaging materials contain no PVC  and are recyclable. 
Samples of our products are supplied together with extensive information and are supported by personal advice.

SAFETY INFORMATION ABOUT PARMETOL MBX:
First aid measures:
Description of first aid measures:
General advice : Take off all contaminated clothing immediately.
If inhaled : If breathed in, move person into fresh air.
If symptoms persist, call a physician.
In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Call a physician immediately.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Call a physician immediately.
If swallowed : Do NOT induce vomiting.
Rinse mouth with water.
Give small amounts of water to drink.
Obtain medical attention.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media : Water
Dry powder:
Foam
Carbon dioxide (CO2)
Special hazards arising from the substance or mixture:
Advice for firefighters:
Further information : Standard procedure for chemical fires.

Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment.
Environmental precautions:
Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
Methods and material for containment and cleaning up:
Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust)

Handling and storage:
Precautions for safe handling:
Advice on safe handling : Handle and open container with care.
Advice on protection against fire and explosion: No special protective measures against fire required.
Hygiene measures : Take off all contaminated clothing immediately.
Conditions for safe storage, including any incompatibilities:
Requirements for storage areas and containers: Store in original container.
Further information on storage conditions: Keep away from heat. Keep away from direct sunlight. Keep container tightly closed. 
Advice on common storage : Keep away from food and drink.

Exposure controls/personal protection:
Control parameters:
Contains no substances with occupational exposure limit values.
Exposure controls:
Personal protective equipment:
Eye protection : Safety glasses with side-shields
Hand protection : Impervious glovesSplash protection: disposable nitrile rubber gloves e.g. Dermatril (layer thickness: 0.11 mm) made by KCL or gloves from other manufacturers offering the same protection.
Prolonged contact: Butyl rubber gloves e.g. Butoject (>480 Min., layer thickness: 0.70 mm) made by KCL or gloves from other manufacturers offering the same protection.
Skin and body protection : Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemicalprotection suit ( according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
Respiratory protection : In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit.
Protective measures : Avoid contact with skin and eyes.

Stability and reactivity
Reactivity:
Stable under recommended storage conditions.
Chemical stability:
No decomposition if stored normally.
Conditions to avoid : Protect from frost, heat and sunlight.
Disposal considerations:
Waste treatment methods:
Product : Dispose of as hazardous waste in compliance with local and national regulations.
The product should not be allowed to enter drains, water courses or the soil.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Waste key for the unused product(Group): The waste producer itself must, in consultation with the appropriate authorities and a waste disposal company, obtain a waste code from the EWC (European Waste Catalogue)