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PHOSPHONOBUTANE TRICARBOXYLIC ACID

Phosphonobutane tricarboxylic acid is a very effective scale inhibitor used in various industrial applications. 
Due to Phosphonobutane tricarboxylic acid's higher performance properties it is a very cost effective inhibitor compared to standard Phosphonates such as HEDP/ATMP. 
Phosphonobutane tricarboxylic acid is mainly due to superior stability to chlorine, bleach and bromine. 

CAS:    37971-36-1
MF:    C7H11O9P
MW:    270.13
EINECS:    253-733-5

In cooling water Phosphonobutane tricarboxylic acid performs well at high PH or temperatures. 
Phosphonobutane tricarboxylic acid further shows high effectiveness in high alkaline solutions such as industrial cleaners.

Applications
Cooling water systems / industrial water treatment
Industrial detergents
Disinfectants
Liquid dishwashing concentrates
Metal surface treatment as corrosion inhibitor for steel
Retardant in concrete
Sequestering agent in textile auxiliaries

Phosphonobutane tricarboxylic acid is a high efficient agent as scale and corrosion inhibitor. 
Phosphonobutane tricarboxylic acid is the excellent stabilizer for zinc salt. 
Phosphonobutane tricarboxylic acid is widely used in circulating cool water system and oilfield refill water system as scale and corrosion inhibitor, suitable to composite with zinc salt and copolymer.
Phosphonobutane tricarboxylic acid, with its excellence stability against chlorine, high temperatures and high alkali conditions, is used as scale and corrosion inhibitor and as stabilizer for Zinc salts and Calcium salts in aqueous systems.

Phosphonobutane tricarboxylic acid has low phosphoric content. 
Phosphonobutane tricarboxylic acid has structural features of both phosphoric acid and carboxylic acid groups, which enable its excellent scale and corrosion inhibition properties. 
Phosphonobutane tricarboxylic acid's antiscalant property under high temperature is far better than that of organophosphines. 
Phosphonobutane tricarboxylic acid can improve zinc salt solubility, has good chlorine oxidation tolerance, and good composite synergy. 
Phosphonobutane tricarboxylic acid is used as a corrosion inhibitor in boiler feed water. 
Phosphonobutane tricarboxylic acid also has important applications as a chemical intermediate in insecticides, dry cleaning soaps, gas absorbents, rubber chemicals and plasticizers.

Whether Phosphonobutane tricarboxylic acid belongs to an environmentally-friendly scale inhibitor or not, many customers have this question when purchasing. 
Before determining whether Phosphonobutane tricarboxylic acid acid is an environmentally friendly scale inhibitor, it is necessary to talk about the types of scale inhibitors.

So far, the types of scale inhibitors that are widely used in the water treatment industry are mainly the following. 
Organic phosphine scale inhibitor (phosphorus), organic phosphonate scale inhibitor (phosphorus), compound scale inhibitor, environmental scale inhibitor (PESA, PASP, etc.), low phosphorus-containing scale inhibitor (such as PBTCA).

Among the organic phosphine type scale inhibitors, Phosphonobutane tricarboxylic acid is one of the lowest scale inhibitors. 
The reason is that Phosphonobutane tricarboxylic acid's structural characteristics contain only one phosphorus element in the molecular formula. 
At the same time, Phosphonobutane tricarboxylic acid chemical has the characteristics of phosphonic acid and a carboxylic acid, which has good scale inhibition and corrosion inhibition performance and is much better than other organic phosphonic acid scale inhibitors.

Phosphonobutane tricarboxylic acid has low phosphorus content and is ideal for scale inhibition. Within the foreseeable range, Phosphonobutane tricarboxylic acid acid is still the main product in water treatment chemicals and can be used as a compound or as a separate ingredient.

As the country’s environmental requirements become more stringent, the use of more water treatment agents with higher phosphorus content is limited. 
Phosphonobutane tricarboxylic acid acid meets national environmental requirements. 
Phosphonobutane tricarboxylic acid is relatively affordable and is a good choice for most companies.

Phosphonobutane tricarboxylic acid is well known that organic phosphine water treatment agents are the most widely used in monomer water treatment agents. 
Faced with more environmental pressures, water treatment agents are moving towards diversification. 
For example, compounding, copolymer, polymer, and other water treatment agents are more targeted when used.
The full name of Phosphonobutane tricarboxylic acid is 2-phosphonobutane-1 2 4-tricarboxylic acids.
The advantages of 2-phosphonic butane-1 2 4-tricarboxylic acid are as follows.

Good chemical stability, not easy to decompose, high-temperature resistance, strong acid, and alkali resistance and oxidant resistance. 
Phosphonobutane tricarboxylic acid is used together with oxidizing biocides such as sodium hypochlorite and chlorine.
Phosphonobutane tricarboxylic acid has a much higher tolerance for Ca2+. 
Phosphonobutane tricarboxylic acid is used under the conditions of high hardness, high alkali, high temperature, high pH and high concentration. 

Phosphonobutane tricarboxylic acid can still achieve a good scale inhibition effect.
Phosphonobutane tricarboxylic acid has a high solubility in zinc salts and good stability. 
Phosphonobutane tricarboxylic acid can be combined with zinc salt to obtain a very good corrosion inhibition effect.
Phosphonobutane tricarboxylic acid has low phosphorus content (only 11-15%), and it has a low dosage and is not subject to environmental emissions. 
Phosphonobutane tricarboxylic acid is one of the more advanced circulating cooling water treatment chemicals in China.

Among the organic phosphine water treatment agents, Phosphonobutane tricarboxylic acid is one of the most suitable organic phosphine monomers for environmentally friendly scale inhibitors due to its own characteristics and low phosphorus content. 
Phosphonobutane tricarboxylic acid acid has the structural properties common to phosphonic acids and carboxylic acids.

Therefore, Phosphonobutane tricarboxylic acid is relatively superior to other organic phosphonic acids, and it has excellent scale inhibition and corrosion inhibition properties. 
At the same time, Phosphonobutane tricarboxylic acid chemical is resistant to high temperature and high alkali, and its scale inhibition performance at high temperature is much higher than other commonly used organic phosphines. 
Phosphonobutane tricarboxylic acid is also used as a special corrosion and scale inhibitor for high temperature.

Phosphonobutane tricarboxylic acid is the most widely used in the combination of high-efficiency corrosion and scale inhibitors. 
Phosphonobutane tricarboxylic acid is one of the best performance products among all known scale inhibitors. 
At the same time, Phosphonobutane tricarboxylic acid has functional diversity. 
For example, Phosphonobutane tricarboxylic acid can also be used as a stabilizer for zinc salts. 
In addition, Phosphonobutane tricarboxylic acid can also be used as a chelating agent and metal cleaner in the washing industry.

Phosphonobutane tricarboxylic acid is currently mainly used for corrosion and scale inhibition of circulating cooling water systems and oilfield refill systems. 
Phosphonobutane tricarboxylic acid acid is compounded with zinc salt and copolymer during use and is used for high temperature, high alkali, high hardness water quality.

Phosphonobutane tricarboxylic acid Chemical Properties
Boiling point: 545.2±60.0 °C(Predicted)
Density: 1.25 (50% aq.)
Vapor pressure: 0Pa at 25℃
Solubility: Completely miscible in water
pka: 1.14±0.10(Predicted)
Form: clear liquid
Color: Colorless to Light yellow
Water Solubility: 909g/L at 20℃
InChIKey: SZHQPBJEOCHCKM-UHFFFAOYSA-N
LogP: -1.66 at 25℃
CAS DataBase Reference: 37971-36-1(CAS DataBase Reference)
EPA Substance Registry System: Phosphonobutane tricarboxylic acid (37971-36-1)

Phosphonobutane tricarboxylic acid corrosion inhibitor is very useful just as both equal antiscalants as well as corrosion inhibitors. 
Due to the truth of Phosphonobutane tricarboxylic acid's structural function of carboxylic acid and phosphoric acid. 
The Phosphonobutane tricarboxylic acid antiscalant is steady and good performance within the situation of high hardness, temp, pH value, and then listed matter concentration.

While ordinarily establishing with many other organophosphates, Phosphonobutane tricarboxylic acid as well broadly works jointly with zinc salts which solubility it’s going to rise. 
Phosphonobutane tricarboxylic acid antiscalant is able to raise zinc sodium solubility. 
Phosphonobutane tricarboxylic acid also provide a bigger tolerance to oxidation chemicals such as chlorine or bromine in the system.

Use
As being a good inhibitor to both the scale and corrosion, Phosphonobutane tricarboxylic acid corrosion inhibitor is definitely the great stabilizer for zinc sodium. 
Phosphonobutane tricarboxylic acid can be commonly applied to the re-filling system and circulated cooling system for oil areas, metal mills, and also mines. 
Phosphonobutane tricarboxylic acid antiscalant can be utilized within conditions of, high hardness, high alkali, and high concentration index. 
In addition, Phosphonobutane tricarboxylic acid is used in order to chelate steel ions in lavation and also detergent fields as steel detergent. 
In pH 7-10, 5-15 mg/L is usually recommended if only Phosphonobutane tricarboxylic acid.

Phosphonobutane tricarboxylic acid corrosion inhibitor is normally applied along with the zinc sodium, copolymer, organophosphine, imidazole, and also other water treatment chemicals. 
While used by itself, the actual dosage of 5-15 mg/l is normally recommended.
The original reaction of Phosphonobutane tricarboxylic acid corrosion inhibitor production is normally between dialkyl phosphite (generally dimethyl phosphate in China) and also maleic acid dimethyl ester using a common catalyst. 
Tetraalkyl ester of phosphonosuccinic acid forms along with quickly responded together with methyl acrylate. 
The next thereupon saponification outputs Phosphonobutane tricarboxylic acid.

Water treatment:
One of the most important applications of Phosphonobutane tricarboxylic acid is in water purification. 
Phosphonobutane tricarboxylic acid is used as an anti-corrosion and antiscalant in industrial units. 
Water used in cooling systems and other industrial equipment contains hardening agents and impurities such as calcium carbonate and copper ions. 
These impurities cause many problems, including sedimentation in pipes and other paths that deal with water, and also cause corrosion in the system.

Amino trimethylene phosphonic acid (ATMP) and Etidronic acid  (HEDP) also have this capability, but there are two barriers to using these substances: Limitations in the solubility of their salts and their low resistance to oxidizing agents

Anticorrosion and antiscalants:
Phosphonobutane tricarboxylic acid has more power than other phosphonates as an anti-corrosion and anti-scaling agent. 
Phosphonobutane tricarboxylic acid can be used to control the deposition of calcium carbonate. 
In addition, Phosphonobutane tricarboxylic acid is very useful in harsh conditions and very high temperatures, and with high alkalinity.

Cooling systems and industrial water treatment units:
In systems where water plays a key role as a cooling agent, the presence of substances such as calcium ions causes deposits inside the equipment, which blocks the passage of water and makes the system inefficient. 
The best way to solve this problem is to use antiscalants such as Phosphonobutane tricarboxylic acid.

Industrial detergents:
One of the most important applications of phosphates is in the production of detergents. 
The use of these materials has the following advantages: reducing hardness and preventing the formation of sediment and dispersion of contaminants and controlling their deposition.

Synonyms
2-PHOSPHONOBUTANE-1,2,4-TRICARBOXYLIC ACID
37971-36-1
PBTC
1,2,4-Butanetricarboxylic acid, 2-phosphono-
2-Phosphono-1,2,4-butanetricarboxylic acid
2-Phosophonobutane-1,2,4-tricarboxylic acid
2-Phosphonobutane-1,2,4-tricarbonic acid
EINECS 253-733-5
phosphonobutanetricarboxylic acid
EC 253-733-5
3-Carboxy-3-phosphonohexanedioic Acid
306P37319L
40372-66-5
Q-200319
C7H11O9P
2-Phosphono butane-1,2,4-tricarboxylic acid
UNII-306P37319L
BAYHIBIT AM
MAYOQUEST 2100
DEQUEST 7000
SCHEMBL22514
DTXSID4027999
MFCD01940753
AKOS007930701
DB-049222
CS-0451914
FT-0613352
P1857
Butanetricarboxylic acid, 2-phosphono-1,2,4-
PHOSPHONOBUTANETRICARBOXYLIC ACID [INCI]
(S)-2-phosphonobutane-1,2,4-tricarboxylic acid
971P361
A823953
Q27255925
2-Phosphonobutane-1,2,4-tricarboxylic acid 50% in water
2- Phosphonobutane -1,2,4-tricarboxylic acid, tetra sodium salt
2-Phosphonobutane-1,2,4-tricarboxylic acid (ca. 50% in water)

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