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PHOTOMER 4017 (HDDA) is a commercial trade name for 1,6-Hexanediol diacrylate (HDDA). Produced by IGM Resins, PHOTOMER 4017 is a low-viscosity, difunctional reactive monomer used primarily as a diluent and crosslinker in UV and Electron Beam (EB) curable coatings, inks, adhesives, and photopolymers.
PHOTOMER 4017 (HDDA) is a difunctional acrylate ester monomer used in the manufacture of polymers.
CAS No.13048-33-4
Chemical Name: Hexamethylene diacrylate
CBNumber: CB1114704
Molecular Formula: C12H18O4
Molecular Weight: 226.27
MDL Number: MFCD00008631
MOL File: 13048-33-4.mol
Synonyms: 1,2-Bisacryloyloxyhexane, 1,6-HDDA, 1,6-Hexamethylene diacrylate, 1,6-Hexamethylenediol diacrylate, 1,6-Hexandiol diacrylate, 1,6-Hexanediyl diacrylate, 1,6-Hexenediol diacrylate, 1,6-Hexyleneglycol diacrylate, Hexamethylene acrylate, Hexamethylene diacrylate, Hexamethylenediol diacrylate, Hexamethyleneglycol diacrylate, Hexaneglycol diacrylate, Hexylene-1,6-diacrylate
Photomer 4017 by IGM Resins is hexanediol diacrylate (HDDA) monomer.
Photomer 4017 exhibits moderate shrinkage profile and good cutting power.
Photomer 4017 possesses outstanding solvency characteristics with high viscosity urethane and epoxy oligomers.
Photomer 4017 offers good flexibility, adhesion, leveling and weatherbility coupled with good chemical-, water- and abrasion resistance.
Photomer 4017 is used in flexible vinyl, UV curable adhesive formulations based on acrylates.
Photomer 4017 is recommended for use in graphic arts, adhesives and electronics.
The shelf life of Photomer 4017 (HDDA) is 12 months.
PHOTOMER 4017 (HDDA) is a low viscosity diluent for UV and EB radiation curable lacquers and pigmented coatings, used in paper and board coatings, wood finishes vinyl flooring and flexible vinyl.
PHOTOMER 4017 (HDDA) is particularly useful for use in ultraviolet light cure applications.
Furthermore, PHOTOMER 4017 (HDDA) is also used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.
Like other acrylate monomers PHOTOMER 4017 (HDDA) is usually supplied with a radical inhibitor such as hydroquinone added.
1,6-Hexanediol diacrylate is a di-functional monomer commonly used in the polymer industry for producing various types of polymers.
Photomer 4017 (HDDA) is a viscous liquid, that is often used as a crosslinking agent in radical polymerization reactions.
Additionally, Photomer 4017 (HDDA) also finds use in various fields such as coatings, adhesives, 3D printing, medical devices, and textiles due to its excellent polymerization properties and versatility.
1,6-Hexanediol diacrylate emerges as a multifaceted acrylate monomer, finding wide-ranging utilization across diverse applications.
Photomer 4017 (HDDA) proves instrumental in the synthesis of polymer materials, contributing to the formulation of coatings, adhesives, and sealants.
This compound′s versatility makes Photomer 4017 (HDDA) a cornerstone in various industries, where its properties play a pivotal role in creating functional and durable products.
Preparation
The material is prepared by acid-catalyzed esterification of 1,6-hexanediol with acrylic acid.
Physical description
Clear yellow liquid with a mild ester-like odor.
Good weather resistance
One of the monomers with better weather resistance.
Application :
Photomer 4017 has low viscosity, low volatilization and fast curing properties, and can be used in an be used for wood coatings, PVC coatings, plastic coatings, metal coatings, offset printing inks, flexographic printing, screen printing, overprint varnishes,etc.
Good plastic adhesion.
This product has certain adhesion to most plastics, such as ABS, PMMA, PC, ABS+PC, etc.
Strong dilution.
Photomer 4017 (HDDA) has stronger dilution ability than TPGDA, DPGDA, TMPTA and other traditional bulk monomers.
Application :
1,6-Hexanediol diacrylate can be used as:
A monomer for the synthesis of poly(1,6-hexanediol diacrylate) (PHDA)-based polymer microspheres and bifunctional microcapsules.
The resulting PHDA-based polymer embedded with TiO2 nanoparticles finds uses in various potential applications in fields such as sensing, drug delivery, and photonics.
A sensitizer in the UV-curable inks commonly used in the printing industry.
A cross-linking agent in conjunction with a photocatalytic system to modify cellulose material.
The resulting crosslinked cellulose material finds uses in various potential applications such as paper manufacturing, textiles, and biomedical devices.
A monomer in the synthesis of polyurethane acrylate (PUA) which is used to produce polymer electrolytes for use in lithium batteries.
1,6-Hexanedioldiacrylate can be used as a starting material to synthesize:
A resin (copolymer of 1,6-hexanediol diacrylate and styrene) by suspension polymerization, which is applicable in the preparation of hydrophobic peptide sequences.
Monodispersed poly(HDDA)/TiO2 microspheres, applicable in the degradation of methylene blue.
Applications & Uses
1-Markets: Adhesives & Sealants, Consumer Goods, Paints & Coatings
2-Applications:
Consumer Goods — Appliances & Electronics
Paints & Coatings — Building & Construction
Wood Coatings & Finishes
Paints & Coatings — Industrial Coatings
Industrial Coatings,
Metal Coatings
Adhesives & Sealants — Other Adhesives & Sealants Applications
Consumer Goods — Stationery, Art & Office Supplies
3-Compatible Substrates & Surfaces: Glass, Metal, Paper,Plastics, Wood
4-Cure Method: Radiation Cure
5-Adhesive & Sealant Type: Radiation Curable Adhesive
6-Coating Type: Radiation Curable Coating
7-Ink & Toner Type: Radiation Curable Ink
Other uses
As the molecule has acrylic functionality, Photomer 4017 (HDDA) is capable of undergoing the Michael reaction with an amine.
This allows Photomer 4017 (HDDA) use in epoxy chemistry where its use speeds up the cure time considerably.
Key Characteristics & Properties
Appearance: Clear, colorless to pale yellow liquid with a characteristic acrylic odor.
Viscosity: Very low, typically ranging from 8–12 mPa·s at 25 °C.
Functionality: Difunctional (contains two reactive acrylate groups), allowing it to form tight, crosslinked polymer networks.
Performance: Provides excellent cutting power, good flexibility, chemical/water resistance, and a moderate shrinkage profile.
Industrial Applications
Because of its ability to dramatically lower the viscosity of formulations without sacrificing the physical integrity of the cured product, Photomer 4017 is widely used in:
UV/EB Curable Coatings: Clear lacquers and pigmented coatings for wood finishes, paper, board, and vinyl flooring.
Printing Inks: High-speed, radiation-curable inks.
3D Printing & Adhesives: Acts as a key reactive diluent in photopolymer resins and industrial bonding agents.
Electronics: Used in solder mask inks and conformal coatings.
Safety and Handling
Like many acrylate monomers, Photomer 4017 can cause skin and eye irritation.
Prolonged or repeated exposure may lead to allergic contact dermatitis.
Proper Personal Protective Equipment (PPE), including gloves and safety glasses, and adequate ventilation are required during handling.
Storage :
Being kept in dry, clean warehouse with well ventilation.
Avoid exposing to light and heating.
Protecting the product from leakage, rain and insolation during transportation.
Melting point: 6°C
Boiling point: 295°C
Density: 1.01 g/mL at 25 °C (lit.)
vapor density: >1 (vs air)
vapor pressure: <0.01 mm Hg ( 20 °C)
refractive index: n20/D 1.456(lit.)
Flash point: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: Chlroform (Slightly), DMSO (Slightly)
form:Liquid
color: Colourless
Specific Gravity: 1.01
Odor: Mild ester-like odor
Viscosity: 9 cp (25C)
Water Solubility: Slightly miscible with water.
Freezing Point: 6
Sensitive: Hygroscopic
Stability: Light Sensitive
InChI: 1S/C12H18O4/c1-3-11(13)15-9-7-5-6-8-10-16-12(14)4-2/h3-4H,1-2,5-10H2
InChIKey : FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP: 2.81 at 25℃
CAS DataBase Reference: 13048-33-4(CAS DataBase Reference)
FDA UNII: FY751V5MMY
NIST Chemistry Reference: Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System: 1,6-Hexanediol diacrylate (13048-33-4)
UNSPSC Code: 12162002
NACRES: NA.23
