PRODUCTS

POLYETHOXYLATED TALLOW AMINE

Polyethoxylated tallow amine is used primarily as emulsifiers and wetting agents for agrochemical formulations, such as pesticides and herbicides (e.g. glyphosate).
Polyethoxylated tallow amine is used as an ingredient in drilling fluids and corrosion inhibitors.
Polyethoxylated tallow amine is used primarily as emulsifiers and wetting agents for agrochemical formulations, such as pesticides.

CAS Number: 61791-26-2
EC Number: 500-153-8
Molecular Formula: Variable (dependent on ethoxylation degree)
Molecular Weight: Not specified

SYNONYMS:
Polyoxyethylene tallow amine, POEA, Tallow amine ethoxylate, PEG tallow amine, Ethomeen, Noramox, MON-0818, Ethokem, Frigate, NE-1808

Polyethoxylated tallow amine (also polyoxyethylene tallowamine, POE-tallowamine) refers to a range of non-ionic surfactants derived from animal fats (tallow).
Polyethoxylated tallow amine are a class of polyethoxylated amines (POEAs).

The abbreviation 'POEA' is often erroneously used to refer to polyethoxylated tallow amine.
Polyethoxylated tallow amine (POE-tallowamine) is a class of synthetic surfactants widely used in a variety of pesticides, especially in glyphosate-based herbicide formulations (1–3).

Polyethoxylated tallow amine can improve the plant coverage and penetration of glyphosate through surface tissues.
Polyethoxylated tallow amine is derived from animal fats based fatty acids via the nitrile process.
Polyethoxylated tallow amine is obtained as mixtures of C12-C18 hydrocarbons, which in turn are derived from the abundant fatty acids in animal fat.

The main source of Polyethoxylated tallow amine is from animal fats, but vegetable based tallow is also available and both can be ethoxylated to give non-ionic surfactants having similar properties.
Polyethoxylated tallow amine (61791-26-2) are generally used in agriculture formulation for pesticides and as corrosion inhibitors.

Polyethoxylated tallow amine functions as wetting agent, solubilizer in textile processing, anti-corrosion agent in oil & gas, and adjuvant in agrochemicals.
For example, Polyethoxylated tallow amine -2EO is used in agricultural formulations.

Polyethoxylated tallow amine can be used alone or in combination with other surfactants.
Polyethoxylated tallow amine (also polyoxyethylene tallowamine, POE-tallowamine) refers to a range of non-ionic surfactants derived from animal fats (tallow).

Polyethoxylated tallow amine are a class of polyethoxylated amines (POEAs).
The abbreviation 'POEA' is often erroneously used to refer to Polyethoxylated tallow amine.
Polyethoxylated tallow amine, specifically the variant known as POE (15) tallow amine, is a non-ionic surfactant derived from animal fats, particularly tallow.

Polyethoxylated tallow amine belongs to a class of compounds known as polyethoxylated amines, which are characterized by the addition of ethylene oxide to fatty amines.
The "15" in its name indicates that Polyethoxylated tallow amine contains approximately 15 ethylene oxide units.

Polyethoxylated tallow amine is primarily used as an emulsifier and wetting agent in various applications, particularly in agrochemical formulations like pesticides and herbicides, including glyphosate-based products.

USES and APPLICATIONS of POLYETHOXYLATED TALLOW AMINE:
Polyethoxylated tallow amine is primarily used as a non-ionic surfactant in herbicide formulations to enhance the efficacy of active ingredients.
Polyethoxylated tallow amine promotes the penetration of herbicides into plant cuticles, improving their effectiveness.

Additionally, polyethoxylated tallow amine is utilized in various industrial applications, including as an emulsifier, thickener, antistatic agent, and corrosion inhibitor.
Polyethoxylated tallow amine is also employed in personal care products, cleaners, and as an acid degreaser in industrial settings.

Polyethoxylated tallow amine are used primarily as emulsifiers and wetting agents for agrochemical formulations, such as pesticides and herbicides (e.g. glyphosate).
Application of Polyethoxylated tallow amine in Agriculture: Glyphosate-based Herbicides

Specific Scientific Field uses of Polyethoxylated tallow amine: This application falls under the field of Agriculture.
Polyethoxylated tallow amine is a class of synthetic surfactants widely used in a variety of pesticides, especially in glyphosate-based herbicide formulations.

Polyethoxylated tallow amine can improve the plant coverage and penetration of glyphosate through surface tissues.
Application of Polyethoxylated tallow amine in Industrial Manufacturing: Surfactant and Emulsifier
Specific Scientific Field: This application falls under the field of Industrial Manufacturing.

Polyethoxylated tallow amine is commonly used as a surfactant and emulsifier in various industries, including personal care, agriculture, and oilfield applications.
Polyethoxylated tallow amine is known for its excellent wetting, dispersing, and solubilizing properties, making it suitable for use in formulations such as detergents, fabric softeners, and herbicides.

Polyethoxylated tallow amine is often used as an ingredient in personal care products such as shampoos, shower gels, and conditioners.
Polyethoxylated tallow amine helps increase the consistency of these products and improves their lubricity and foaming properties.
Polyethoxylated tallow amine is used primarily as emulsifiers and wetting agents for agrochemical formulations, such as pesticides and herbicides (e.g. glyphosate).

Tallow amine 15 EO, a type of Polyethoxylated tallow amine, is used in formulations for textile aids.
Polyethoxylated tallow amine is used to obtain effects such as an oil-in-water emulsifier, moisturizer, emulsifier for quaternary ammonium compounds in water used in softeners, lubricants and anti-static agents for spinning, equalizer for polyamide and polyester dyeing and detergent for washing dyed articles.

Application of Polyethoxylated tallow amine in Oilfield: Drilling Fluids and Corrosion Inhibitors
Specific Scientific Field uses of Polyethoxylated tallow amine: This application falls under the field of Oilfield Operations.
Polyethoxylated tallow amine is used as an ingredient in drilling fluids and corrosion inhibitors.

Polyethoxylated tallow amine is known for its excellent wetting, dispersing, and solubilizing properties, making it suitable for use in these formulations.
Polyethoxylated tallow amine is used primarily as emulsifiers and wetting agents for agrochemical formulations, such as pesticides.

COMPOSITION AND USE OF POLYETHOXYLATED TALLOW AMINE:
The polyethoxylated tallow amine used as a surfactant is referred to in the literature as MON 0139 or polyoxyethyleneamine (POEA).
Polyethoxylated tallow amine is contained in the herbicide Roundup.

A Polyethoxylated tallow amine (CAS No. 61791-26-2) is on the United States Environmental Protection Agency List 3 of Inert Ingredients of Pesticides.

Polyethoxylated tallow amine concentrations range from <1% in ready-to-use glyphosate formulations to 21% in concentrates.
Polyethoxylated tallow amine constitutes 15% of Roundup formulations and the phosphate ester neutralized polyethoxylated tallow amine surfactant constitutes 14.5% of Roundup Pro.

Surfactants are added to glyphosate to allow effective uptake of water-soluble glyphosate across plant cuticles, which are hydrophobic, and reduces the amount of glyphosate washed off plants by rain.

CHARACTERISTICS OF POLYETHOXYLATED TALLOW AMINE:
Polyethoxylated tallow amine is derived from animal fats and consists of a range of non-ionic surfactants.
Its properties can vary depending on the degree of ethoxylation.

Polyethoxylated tallow amine is known for its emulsifying capabilities and is compatible with various chemical formulations.
Polyethoxylated tallow amine is hygroscopic and should be stored under appropriate conditions to maintain its stability.

PROPERTIES AND BENEFITS OF POLYETHOXYLATED TALLOW AMINE:
Properties and Benefits:
Polyethoxylated tallow amine offers excellent emulsifying properties, making it effective in promoting the mixing of immiscible liquids.

Polyethoxylated tallow amine enhances the solubility of herbicides in organic solvents, increasing their penetration through plant surfaces.
In industrial applications, polyethoxylated tallow amine serves as a thickener, improving the consistency and stability of formulations.
Polyethoxylated tallow amine's antistatic and corrosion-inhibiting properties make it valuable in various manufacturing processes.

SYNTHESIS OF POLYETHOXYLATED TALLOW AMINE:
Animal fat is hydrolyzed to give a mixture of free fatty acids, typically oleic (37–43%), palmitic (24–32%), stearic (20–25%), myristic (3–6%), and linoleic (2–3%).
These are then converted to fatty amines via the nitrile process before being ethoxylated with ethylene oxide; this makes them water-soluble and amphiphilic.
The length of the fatty tail and degree of ethoxylation will determine the overall properties of the surfactant.
Due to it being synthesized from an impure material, polyethoxylated tallow amine is itself a mixture of compounds.

CHEMICAL REACTIONS OF POLYETHOXYLATED TALLOW AMINE:
*Hydrolysis of Tallow:
Animal fat (tallow) undergoes hydrolysis to yield free fatty acids, including oleic, palmitic, stearic, and others.

*Formation of Fatty Amines:
The free fatty acids are then converted into fatty amines through a nitrile process.

*Ethoxylation:
The fatty amines are ethoxylated using ethylene oxide, which introduces hydrophilic properties to the molecule, making it amphiphilic and enhancing its surfactant capabilities.
These reactions highlight how the structural characteristics of Polyethoxylated tallow amine are influenced by the types and proportions of fatty acids present in the initial tallow.

METHODS OF APPLICATION OR EXPERIMENTAL PROCEDURES OF POLYETHOXYLATED TALLOW AMINE:
The method described for comprehensive quantitative analysis of 66 polyethoxylated tallow amine (POE-tallowamine) homologs in citrus involves ultrahigh-performance liquid chromatography-mass spectrometry (UHPLC) with electrospray mass spectrometry detection.

Efficient separation, reduced band broadening, and high sensitivity were achieved by employing an acetonitrile-aqueous solution containing a 10 mM ammonium formate gradient on a hydrophilic interaction chromatography (HILIC) column with a modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) method.

Results or Outcomes:
The method was successfully applied to determine polyethoxylated tallow amine in citrus samples from typical Chinese regions in 2021.
Polyethoxylated tallow amine was detected in all 54 samples, and the highest concentration (143 μg/kg) of polyethoxylated tallow amine was found in Jelly orange from Zhejiang Province.

PHYSICAL and CHEMICAL PROPERTIES of POLYETHOXYLATED TALLOW AMINE:
Appearance: White to off-white waxy solid
Odor: Characteristic
Solubility: Slightly soluble in chloroform and methanol
Storage Conditions: Store at room temperature under inert atmosphere
Form: Solid
Color: White to off-white
CAS Number: 61791-26-2
EC Number: 500-153-8
Molecular Formula: Variable (dependent on ethoxylation degree)
Molecular Weight: Not specified

FIRST AID MEASURES of POLYETHOXYLATED TALLOW AMINE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of POLYETHOXYLATED TALLOW AMINE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of POLYETHOXYLATED TALLOW AMINE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of POLYETHOXYLATED TALLOW AMINE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of POLYETHOXYLATED TALLOW AMINE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.

STABILITY and REACTIVITY of POLYETHOXYLATED TALLOW AMINE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available