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CAS Number : 9016-87-9
EC Number : 618-498-9
Molecular Formula : C15H10N2O2
Molecular Weight : 222.07
Polymeric diphenylmethane diisocyanate is an aromatic diisocyanate. ,
Three isomers are common, varying by the positions of the isocyanate groups around the rings.
The 4,4′ isomer is most widely used, and is also known as 4,4′-diphenylmethane diisocyanate.
This isomer is also known as Pure MDI.
Polymeric diphenylmethane diisocyanate is the generic name of a product used in industrial settings.
Polymeric diphenylmethane diisocyanate, is actually a mixture that contains 25-80% monomeric 4,4'-MDI as well as oligomers containing 3-6 rings and other minor isomers, such as the 2,2'-isomer.
The exact composition of Polymeric diphenylmethane diisocyanate varies with the manufacturer.
Polymeric diphenylmethane diisocyanate is used to make rigid and flexible foam, foundry resin sand binders, and heat insulating material.
Polymeric diphenylmethane diisocyanate are essential building blocks in the production of polyurethanes, urethane-prepolymers, and polyisocyanurate polymers in many industries.
Because of their reactivity and versatility of combining with an wide array of curatives and chain extenders, Polymeric diphenylmethane diisocyanates are used in countless diverse applications.
End-uses for these quite versatile diisocyanates include foam products, cast elastomers, thermoplastic polyurethanes (TPUs), fibers, and CASE (coatings, adhesives, sealants & elastomers) products.
Polymeric diphenylmethane diisocyanates are the most-produced diisocyanate on a global basis.
Applications of Polymeric diphenylmethane diisocyanate
Polymeric diphenylmethane diisocyanates are available in multiple structural variants, from pure monomeric MDIs (MMDI) to multifunctional polymeric MDIs (PMDI).
The performance delivered by the variety of Polymeric diphenylmethane diisocyanates differs significantly across the spectrum of MDI grades.
Formulators mainly use monomeric MMDIs in the production of prepolymers for cast polyurethane applications such as wheels & rollers and mechanical goods; TPU elastomers; and spandex fibers. The core markets for Polymeric diphenylmethane diisocyanate manufacturers are rigid foams for appliance insulation, packaging and construction applications; as well as semi-rigid and flexible foams used in furniture, cushioning, transportation, vibration insulation, shoe soles and synthetic leather; and polyisocyanurate and thermoset foams.
Industry Uses of Polymeric diphenylmethane diisocyanate
-Adhesives and sealant chemicals
-spray foam insulation
Consumer Uses of Polymeric diphenylmethane diisocyanate
-Adhesives and sealants
-Building/construction materials not covered elsewhere
Household & Commercial/Institutional Products of Polymeric diphenylmethane diisocyanate
-Home Maintenance
-Inside the Home
-Landscaping/Yard
General Manufacturing Information
Industry Processing Sectors
-All other chemical product and preparation manufacturing
-Construction
-Electrical equipment, appliance, and component manufacturing
-Furniture and related product manufacturing
-Miscellaneous manufacturing
-Transportation equipment manufacturing
Polymeric diphenylmethane diisocyanate is used to manufacture polyurethane adhesives, and can also be directly added to rubber adhesives to improve the adhesion between rubber and nylon or polyester threads.
Usage Areas of Polymeric diphenylmethane diisocyanate
-Rigid polyurethane foam systems,
-Polyurethane adhesives,
-CASE applications,
-Floor coatings,
-Aerosol polyurethane foams
APPLICATIONS of Polymeric diphenylmethane diisocyanate
Insulations for refrigerators and container transport, Insulation panels for construction, LNG carriers, Pre-insulated pipes, Board foam, Wood imitation, Spray insulations, Auto Instrumental Panel, Auto headliner and adhesives
Polymeric diphenylmethane diisocyanates are generally used in manufacturing rigid and semi-rigid polyurethane foam for construction panels, spray-on insulation, refrigeration insulation, and automotive interior panels.
Polymeric diphenylmethane diisocyanate is the generic name of a product used in industrial settings.
Polymeric diphenylmethane diisocyanate, the primary technical/commercial form of MDI, is actually a mixture that contains 25-80% monomeric 4,4′-MDI as well as oligomers containing 3-6 rings and other minor isomers, such as the 2,2′-isomer.
First Aid Measures of Polymeric diphenylmethane diisocyanate
Eye Contact :
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Use lukewarm water if possible.
Use fingers to ensure that eyelids are separated and that the eye is being irrigated.
Get medical attention.
Skin Contact :
If direct skin contact with isocyanates occurs, immediately remove contaminated clothing and shoes.
Wipe off the isocyanate product from the skin using dry towels or other similar absorbent fabric.
If readily available, apply a polyglycol-based cleanser (e.g. SKC, Inc. (SKC) D-TAM™ Skin Cleanser) or corn oil.
Wash with soap and warm water and pat dry.
If a polyglycol-based cleanser is not available, wash with soap and warm water for 15 minutes.
If available, use a wipe test pad to verify decontamination is complete (e.g. SKC SWYPE™).
Get medical attention if irritation develops.
Discard or wash contaminated clothing before reuse.
Inhalation :
Move to an area free from further exposure.
Extreme asthmatic reactions that may occur in sensitized persons can be life threatening.
Get medical attention immediately.
Administer oxygen or artificial respiration as needed.
Asthmatic symptoms may develop and may be immediate or delayed up to several hours.
Ingestion :
Do NOT induce vomiting.
Wash mouth out with water.
Do not give anything by mouth to an unconscious person.
Get medical attention.
Substance identity
EC / List no.: 618-498-9
CAS no.: 9016-87-9
Mol. formula: C15H10N2O2
Hazard classification & labelling of Polymeric diphenylmethane diisocyanate
Danger! According to the classification provided by companies to ECHA in REACH registrations this substance causes serious eye irritation, is harmful if inhaled, is suspected of causing cancer, may cause damage to organs through prolonged or repeated exposure, causes skin irritation, may cause an allergic skin reaction, may cause allergy or asthma symptoms or breathing difficulties if inhaled and may cause respiratory irritation.
About Polymeric diphenylmethane diisocyanate
Polymeric diphenylmethane diisocyanate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 000 to < 10 000 000 tonnes per annum.
Polymeric diphenylmethane diisocyanate is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.
Consumer Uses of Polymeric diphenylmethane diisocyanate
Polymeric diphenylmethane diisocyanate is used in the following products: adhesives and sealants and coating products.
Other release to the environment of Polymeric diphenylmethane diisocyanate is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. binding agent in paints and coatings or adhesives).
Article service life of Polymeric diphenylmethane diisocyanate
Other release to the environment of Polymeric diphenylmethane diisocyanate is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
Polymeric diphenylmethane diisocyanate can be found in products with material based on: plastic (e.g. food packaging and storage, toys, mobile phones).
Widespread uses by professional workers of Polymeric diphenylmethane diisocyanate
ECHA has no public registered data indicating whether or in which chemical products the substance might be used.
ECHA has no public registered data on the types of manufacture using Polymeric diphenylmethane diisocyanate.
Other release to the environment of Polymeric diphenylmethane diisocyanate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.
Formulation or re-packing of Polymeric diphenylmethane diisocyanate
ECHA has no public registered data indicating whether or in which chemical products the substance might be used.
Release to the environment of this substance can occur from industrial use: formulation of mixtures, formulation in materials, for thermoplastic manufacture and in the production of articles.
Uses at industrial sites of Polymeric diphenylmethane diisocyanate
Polymeric diphenylmethane diisocyanate is used in the following products: adhesives and sealants and coating products.
Polymeric diphenylmethane diisocyanate is used in the following areas: formulation of mixtures and/or re-packaging.
Polymeric diphenylmethane diisocyanate is used for the manufacture of: chemicals.
Release to the environment of Polymeric diphenylmethane diisocyanate can occur from industrial use: for thermoplastic manufacture, in the production of articles, in processing aids at industrial sites, formulation of mixtures, formulation in materials and as an intermediate step in further manufacturing of another substance (use of intermediates).
Manufacture of Polymeric diphenylmethane diisocyanate
Release to the environment of Polymeric diphenylmethane diisocyanate can occur from industrial use: manufacturing of the substance, formulation of mixtures and for thermoplastic manufacture.
Synonyms:
Isocyanic acid, polymethylenepolyphenylene ester
Isocyanic acid, polymethylenepolyphenylene ester
4,4’ diphenylmethanediisocyanate, isomere, homologe and mixtures
Difenilmetano diisocianato polimerico
Difenilmetanodiisocianato, isomeri e omologhi
difenylmethandiisokyanát (isomery a homology)
diisocyanate de diphénylméthane, isomères et homologues
Diphenylmethan-4,4'-diisocyanat
diphenylmethandiisocyanate
DIPHENYLMETHANDIISOCYANATE, ISOMERS AND HOMOLOGUES
Diphenylmethandiisocyanate, Isomers And Homologues
Diphenylmethane diisocyanate
Diphenylmethane Diisocyanate, isomers and homologues
Diphenylmethane-4,4-diisocyanate, isomers
Diphenylmethane-diisocyanate, isomers an homologues
Diphenylmethanediisocyanat,
Diphenylmethanediisocyanate
DIPHENYLMETHANEDIISOCYANATE -Isomers & homologues
DIPHENYLMETHANEDIISOCYANATE ISOMERES HOMOLOGUES
diphenylmethanediisocyanate, isomeres and homolgues
diphenylmethanediisocyanate, isomeres and homologues
formaldehyde;isocyanatobenzene
Isocyanate
Isocyanic acid polymethylenenpolyphenylenen ester
isocyanic acid, polymethylenepolyphenylene
Isocyanic acid, Polymethylenepolyphenylene ester
Isocyanic acid, polymethylenepolyphenylene ester
Isocyanic acid,polymethylene polyphenylene ester.
Methylendiphenylisocyanate
no name (mixture)
Not applicable
Not known
Poly(methylene phenylene isocyanate)
Polyethylene polyphenylisocyanate
POLYMER
Polymeric diphenylmethane diisocyanate
Polymeric Diphenylmethane Diisocyanate (pMDI)
Polymeric diphenylmethane diisocynate
Polymeric MDI
Polymethylene polyphenyl isocyanate
Polymethylene polyphenyl isocyante
POLYMETHYLENE POLYPHENYLENE ISOCYANATE
Polymethylene Polyphenylene Isocyanate
Polymethylene polyphenylene isocyanate
Polymethylenepolyphenyl isocyanate
Polymethylenepolyphenyl polyisocyanate
polymethylenepolyphenyl polyisocyanate
Reaction product of formaldehyde, polymer with aniline and phosgene
Isocyanic acid, polymethylenepolyphenylene ester
Difenilmetandiizociianate, isomer and homologous
diphenylmethane diisocyanate
DIPHENYLMETHANE-4,4- DIISOCYANATE (MDI), ISOMERS(1) AND HOMOLOGUES(2)
diphenylmethanediisocyanate, isomeres and homologues
Isocyanic acid polymethylenepolyphenylene ester
Methylenediphenyl-diisocyanate, isomers and homologues mixture (Polymeric MDI)
Polymeric MDI
9016-87-9
Phosgene aniline formaldehyde polymer
32055-14-4
4,4'-Methylenediphenylene diisocyanate
1,1'-methanediylbis(4-isocyanatobenzene)
1,1'-Methylenbis(4-isocyanatobenzol) [German] [ACD/IUPAC Name]
1,1'-Methylenebis(4-isocyanatobenzene) [ACD/IUPAC Name]
1,1'-Méthylènebis(4-isocyanatobenzène) [French] [ACD/IUPAC Name]
101-68-8 [RN]
1-isocyanato-4-[(4-isocyanatophenyl)methyl]benzene
202-966-0 [EINECS]
26447-40-5 [RN]
4,4′-Methylenebis(phenyl isocyanate)
4,4'-Diisocyanatodiphenylmethane
4,4'-Diphenylmethane diisocyanate
4,4'-MDI
4,4'-methylene bisphenyl diisocyanate
4,4'-Methylenebis(phenyl isocyanate)
4,4'-Methylenediphenyl diisocyanate
4,4'-Methylenediphenyl isocyanate
4,4'-METHYLENEDIPHENYLDIISOCYANATE
65916-89-4 [RN]
B0LO6BBS8C
Benzene, 1,1'-methylenebis[4-isocyanato- [ACD/Index Name]
bis(4-isocyanatophenyl)methane
Diphenylmethane diisocyanate
diphenylmethane-4,4'-diisocyanate
Methylene diphenyl diisocyanate [Wiki]
NQ9350000
[101-68-8] [RN]
1,1?methylenebis(4-isocyanato)-benzene
1,1-methylenebis(phenyl)diisocyanate
1,1-Methylenebis4-isocyanatobenzene
12125-47-2 [RN]
142690-07-1 [RN]
153986-89-1 [RN]
156580-59-5 [RN]
1-isocyanato-4-(phenylmethyl)benzene
201528-77-0 [RN]
28515-38-0 [RN]
4, 4'-Diisocyanatodiphenylmethane
4, 4'-Methylenedi-p-phenylene diisocyanate
4,4'-,2,4'-,2,2'-Diisocyanatodiphenylmethane
4,4/'-Diphenylmethane diisocyanate
4,4?-Methylenebis(phenylisocyanate)
4,4′-MDI
4,4′-methylenediphenyl diisocyanate
4,4'-Diisocyanate de diphenylmethane
4,4'-Diisocyanatodiphenylmethane; MDI
4,4-Diphenylmethane Diisocyanate
4,4-Diphenylmethane disocyanate
4,4'-Diphenylmethanediisocyanate
4,4'-Diphenylmethanediisocyante
4,4'-methylene diphenyl diisocyanate
4,4'-methylenebis(phenylisocyanate)
4,4'-Methylenebis[phenyl isocyanate]
4,4'-Methylenedi(phenyl diisocyanate)
4,4'-Methylenedi(phenyl isocyanate)
4,4'-Methylenedi(phenylene isocyanate)
4,4'-Methylenediphenylene isocyanate
4,4'-Methylenediphenylene isocyanateThiulin
4,4'-Methylenedi-p-phenylene diisocyanate
4-[(4-isocyanatophenyl)methyl]benzenisocyanate
4-13-00-00396 (Beilstein Handbook Reference) [Beilstein]
4-4'-Diisocyanate de diphenylmethane [French]
4-4'-Diisocyanate de diphenylmethane
4-4'-Diisocyanate de diphenylmethane [French]
53633-14-0 [RN]
55157-41-0 [RN]
57460-66-9 [RN]
77090-48-3 [RN]
88001-94-9 [RN]
9016-87-9 [RN]
97568-33-7 [RN]
Benzene, {1,1'-methylenebis[4-isocyanato-}
Benzene, 1,1'-methylenebis[isocyanato-
Bis(1,4-isocyanatophenyl)methane
Bis(para-isocyanatophenyl)methane
Bis(p-isocyanatophenyl)methane
C005969
Caradate 30
Crude MDI
Desmodur 44
Desmodur VKS-2, VKS-4, VKS-18
Di-(4-isocyanatophenyl)methane
DI(4-ISOCYANATOPHENYL)METHANE
Difenil-metan-diisocianato
Difenil-metan-diisocianato [Italian]
Difenylmethaan-diisocyanaat
Difenylmethaan-dissocyanaat [Dutch]
Difenylmethaan-dissocyanaat [Dutch]
DIPHENYL METHANE DIISOCYANATE
Diphenylmethan-4,4'-diisocyanat [German]
Diphenylmethan-4,4'-diisocyanat [German]
Diphenylmethan-4,4'-diisocyanate
Diphenylmethane 4,4'-diisocyanate
Diphenylmethane 4,4-diisocyanate
Diphenylmethane 4,4'-diisocyanate (mixture of di-and triisocyanates)
Diphenylmethane p,p'-diisocyanate
Diphenylmethane-4', 4-diisocyanate
diphenyl-methane-diisocyanate
Diphenylmethyl diisocyanate
Diphenylmethyl dIIsocyanate methylene bisphenyl isocyanate
Diphenylmethylene diisocyanate
EINECS 202-966-0
EINECS 247-714-0
Hylene M 50
Hylene M50
Hylene M-50
iphenylmethane-4,4'-diisocyanate
Isocyanic acid, diphenylmethylene ester
Isocyanic acid, ester with diphenylmethane
Isocyanic acid, methylenediphenylene ester
Isocyanic acid, methylenedi-p-phenylene ester
Isonaphthol
Isonate
Isonate 125 MF
Isonate 125M
Isonate 2125M
MBI
MDI
-MDI
MDR
Methylbisphenyl isocyanate
Methylene bisphenyl isocyanate
Methylene di(phenylene isocyanate)
Methylene Diphenyl Diisocyanate and polymeric Methylene Diphenyl Diisocyanate
Methylene diphenyl dIIsocyanate and polymeric methylene diphenyl dIIsocyanate
Methylene diphenyl diisocyanic acid
Methylene di-p-phenylene isocyanate
Methylenebis(4,4'-phenyl isocyanate)
Methylenebis(4-isocyanatobenzene)
Methylenebis(4-phenyl isocyanate)
Methylenebis(4-phenylene isocyanate)
Methylenebis(4-phenylisocyanate)
Methylenebis(para-phenyl isocyanate)
Methylenebis(para-phenylene isocyanate)
-Methylenebis(phenyl isocyanate)
Methylenebis(phenylisocyanate)
Methylenebis(p-phenyl isocyanate)
Methylenebis(p-phenylene isocyanate)
Methylenebis(p-phenylisocyanate)
Methylenebis[4-isocyanatobenzene]
Methylenebis[4-phenyl isocyanate]
Methylenebis[4-phenylene isocyanate]
Methylenebis[p-phenyl isocyanate]
Methylenebis[p-phenylene isocyanate]
methylenebisphenyl diisocyanate
Methylenebisphenylene diisocyanate
Methylenedi(p-phenyl isocyanate)
Methylenedi(p-phenylene diisocyanate)
Methylenedi(p-phenylene isocyanate)
Methylenedi-para-phenylene diisocyanate
Methylenediphenyl 4,4'-Diisocyanate
METHYLENEDIPHENYL DIISOCYANATE
Methylenediphenyl diisocyanate, 4,4'-
Methylenediphenylene diisocyanate
Methylenedi-p-phenyl diisocyanate
Methylenedi-p-phenylene diisocyanate
Nacconate 300
NCGC00091061-02
Nocconate 300
Non-isomeric-specific MDI
p,p'-Diphenylmethane diisocyanate
p,p'-Methylenebis(phenyl isocyanate)
p,p'-Methylenebis[phenyl isocyanate]
para,para'-Diphenylmethane diisocyanate
para,para'-Methylenebis(phenyl isocyanate)
PMDI
Polymeric 4,4-methylenediphenyl diisocyanate
Polymeric MDI
Rubinate 44
Rubinate LF-168
UN 2489
UNII:B0LO6BBS8C
UNII-B0LO6BBS8C
WLN: OCNR D1R DNCO
ジフェニルメタンジイソシアネート [Japanese]
CHEBI:53218 [DBID]
MFCD00036131 [DBID]
256439_ALDRICH [DBID]
33428_RIEDEL [DBID]
AI3-15256 [DBID]
BRN 0797662 [DBID]
CCRIS 2303 [DBID]
CCRIS 5836 [DBID]
HSDB 2630 [DBID]
NCGC00091061-01 [DBID]
NCI-C50668 [DBID]
NSC 9596 [DBID]
NSC9596 [DBID]
UN2489 [DBID]
