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SODIUM BISULFITE

EC / List no.: 231-548-0
CAS no.: 7631-90-5
Mol. formula: H2O3S.Na

Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO3. 
Sodium bisulfite in fact is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. 
Sodium bisulfite is a white solid with an odour of sulfur dioxide. Regardless of its ill-defined nature, "sodium bisulfite" is a food additive with E number E222.


Synthesis
Sodium bisulfite solutions can be prepared by treating a solution of suitable base, such as sodium hydroxide or sodium bicarbonate with sulfur dioxide.

SO2 + NaOH → NaHSO3
SO2 + NaHCO3 → NaHSO3 + CO2
Attempts to crystallise the product yield sodium disulfite, Na2S2O5.[3]

Reactivity and uses
Further information: bisulfite

A tank containing 25% sodium bisulfite at a water treatment plant in Sunnyvale, California.
Sodium bisulfite is a common industrial reducing agent, as it readily reacts with dissolved oxygen:

2 NaHSO3 + O2 → 2 NaHSO4
Sodium bisulfite is usually added to large piping systems to prevent oxidative corrosion. 
In biochemical engineering applications, it is helpful to maintain anaerobic conditions within a reactor.

Sodium bisulfite is used for preserving food and beverages.


Chemical properties    
white monoclinic crystal; sulfur dioxide odor; soluble in water, slightly soluble in alcohol.

Uses:
1. Used as reducing agent, food preservatives and bleach.
2. Used for the bleaching of cotton fabric and organic substance. 
Used as reducing agents in dyes, paper, leather, chemical synthesis and other industries. 
Used for the production of analgin and aminopyrine intermediates in pharmaceutical industry. 
Used as bleach, preservatives, and antioxidants of food grade products.
3. Sodium bisulfite is reduction bleach allowed to use in China. 
Sodium bisulfite has bleaching effect on food and has a strong inhibitory effect on the oxidase within plant foods. 
Sodium bisulfite can be used for candied fruit, glucose, sugar, rock candy, caramel, candy, liquid glucose, dried fruit, dried vegetables, vermicelli, bamboo shoots, mushrooms and mushroom cans in provisions of our country, with a maximum use of 0.45g/kg; it can also be used for potato starch with a maximum use amount of 0.2g/kg and a maximume residual amount (in terms of SO2) of less than 0.03 g/kg.
4. Used as reductants in analysis and also as bleach and bacterial inhibitors
5. Used as reducing agent, antiseptic, disinfectant and bleach.

Identification test    
Both sodium salt test (IT-28) and sulfite test (IT-30) are positive.

Content Analysis    
Transfer 50ml of 0.1mol/L iodine solution into a flask with a stopper, and then add 200mg of accurately weighed sample and plug. 
After placed 5min, add 1ml of hydrochloric acid, and plus starch test solution (TS-235) as an indicator. 
Titrate the excess iodine with 0.1 mol/L sodium thiosulfate. Each mI of 0.1mol/L iodine solution is equivalent to 3.203mg of sulfur dioxide (SO2).

Production method    
Add sodium sulphite mother liquor (containing NaHSO3 40%, Ph value of 3 to 4) slowly into soda ash to generate sodium sulfite solution (to the slurry Ph value of 7~8 for the end); transfer the above sodium sulfite solution into series reactors (2 to 3) to absorb the SO2 gas (10% to 13%) from the combustion of sulfur, forming sodium bisulfite (to the reaction temperature no longer rising for the end). In the reaction process, a large number of crystals precipitate out, which is centrifuged to obtain the wet goods with moisture content of 6% to 10%, and then dehydrated by air drying at 250 to 300 ° C to make the final products.
2NaHSO3 + Na2CO3 → 2Na2SO3 + H2O + CO2↑
NaSO3+H2O→2NaHSO3
Absorb sulfur dioxide from the gas of sulfuric acid production with soda ash solution to generate sodium bisulfite. After further centrifugal separation and air drying at 250~300 ° C, the final sodium bisulfite is obtained.
Na2CO3 + 2SO2 + H2O → 2NaHSO3 + CO2↑


Chemical Properties
Sodium bisulfite is a white crystalline solid. Slight odor of sulfur dioxide and a disagreeable taste. Slowly oxidized to the sulfate on exposure to air

white powder


Uses:    
Reducing agent; convenient source of sulfur dioxide.
As disinfectant and bleach, particularly for wool; 
in dyeing for preparing hot and cold indigo vats; 
in paper-making in place of sodium hyposulfite to remove Cl from bleached fibers; 
as stripper (reducer) in laundering; to remove permanganate stains from skin and clothing; 
to render certain dyes sol; manufacture of sodium hydrosulfite; coagulating rubber latex; 
as preservative for deteriorative liqs or solutions used for technical purposes; 
as antiseptic in fermentation industries. 
As preservative and bleach in food. Pharmaceutic aid (antioxidant).
sodium bisulfite is a preservative and anti-oxidant, it is most frequently used as a pH adjuster.
Sodium Bisulfite is a preservative that exists as a powder, with a solubility of 1 g in 4 ml of water. it prevents discoloration and inhib- its bacterial growth. 
Sodium bisulfite is used in dried fruit to inhibit browning and maintain the bright color. 
Sodium bisulfite is found in reconstituted lemon juice. see sulfur dioxide.

General Description    
Also known as sodium acid sulfite or sodium hydrogen sulfite, NaHS03 is white crystals or crystalline powder that has a slight sulfurous odor and taste.
Specific gravity 1.48. 
Strong irritant to skin and tissue. 
Sodium bisulfite is soluble in water,insoluble in alcohol,unstable in air,and non-combustible. 
Derived by saturating sodium carbonate solution with sulfur dioxide and the solution crystallized. 
Used as a chemical(sodium salts, cream of tartar), in vat dye preparation, textiles (antichlor, mordant, discharge), food preservative, bleaching groundwood, wool,etc., reducing agent, fermentation, antiseptic, cask sterilization (brewing), copper and brass plating,color preservative for pale crepe rubber, wood pulp digestion, analytical reagent,and as a dietary supplement.

Sodium bisulfite appears as white crystals or crystalline powder. 
Slight sulfurous odor. 
Specific gravity 1.48. 
Strong irritant to skin and tissue.

Sodium bisulfite has been used externally for parasitic skin diseases and as gastrointestinal antiseptic.

Sodium hydrogensulfite is an inorganic sodium salt having hydrogensulfite as the counterion. 
Sodium bisulfite has a role as a mutagen and an allergen. 
Sodium bisulfite is an inorganic sodium salt and a sulfite salt. 
Sodium bisulfite contains a hydrogensulfite.

Use and Manufacturing

For Sodium bisulfite (USEPA/OPP Pesticide Code: 078201) ACTIVE products with label matches. /SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./
Mfr chemicals (sodium salts, cream of tartar); vat dye preparation; textiles (antichlor, mordant, discharge); bleaching groundwood, wool, etc; reducing agent; cask sterilization (brewing); copper and brass plating; color preservative for pale crepe rubber; wood pulp digestion; analytical reagent; dietary supplement.
As disinfectant & bleach, particularly for wool; in dyeing for preparing hot & cold indigo vats; in paper making in place of sodium hyposulfite to remove chloride from bleached fibers; as stripper (reducer) in laundering; to remove permanganate stains from skin & clothing; to render certain dyes sol; ... coagulating rubber latex; as preservative for deteriorative liquids or solns used for technical purposes; as antiseptic in fermentation industries. As preservative & bleach in food.
For more Uses (Complete) data for SODIUM BISULFITE (6 total), please visit the HSDB record page.

Industry Uses    
 Bleaching agents
 Corrosion inhibitors and anti-scaling agents
 Food processing
 Intermediates
 Lubricants and lubricant additives
 Oxidizing/reducing agents
 Oxygen scavenger
 Paper mill
 Photosensitive chemicals
 Plating agents and surface treating agents
 Processing aids, not otherwise listed
 Product is typically used as a free chlorine scavenger in wastewater treatment or as a bleach in the pulp and paper industry.
 Product is used as a free chlorine scavenger and as a bleach.
 Product is used as a free chlorine scavenger in wastewater treatment.
 Pulp Manufacturing
 Solids separation agents
 Surface active agents
 This product is typically used as a free chlorine scavenger in wastewater treatment or as a bleach in pulp and paper.
 This product is typically ued as a free chlorine scavenger in wastewater treatment or as a bleach in the pulp and paper industry.
 Used as an oxygen scavenger or chlorine scavenger.
 Wastewater treatment (dechlorination)
 photochemicals


Consumer Uses
 Cleaning and furnishing care products
 Fuels and related products
 Metal products not covered elsewhere
 Non-TSCA use
 Paper products
 Photographic supplies, film, and photo chemicals
 Treatment of swine guts in preparation to extract heprin
 Water treatment products

General Manufacturing Information
Industry Processing Sectors
 All other basic inorganic chemical manufacturing
 All other basic organic chemical manufacturing
 All other chemical product and preparation manufacturing
 Fabricated metal product manufacturing
 Food, beverage, and tobacco product manufacturing
 Industrial gas manufacturing
 Mining (except oil and gas) and support activities
 Miscellaneous manufacturing
 Oil and gas drilling, extraction, and support activities
 Paper De-inking
 Paper manufacturing
 Petroleum lubricating oil and grease manufacturing
 Petroleum refineries
 Pharmaceutical and medicine manufacturing
 Photographic film paper, plate, and chemical manufacturing
 Plastic material and resin manufacturing
 Primary metal manufacturing
 Printing and related support activities
 Prison and military complexes.
 Services
 Soap, cleaning compound, and toilet preparation manufacturing
 Textiles, apparel, and leather manufacturing
 Transportation equipment manufacturing
 Utilities
 Wholesale and retail trade
 Wood product manufacturing


General description
The aqueous solutions of sodium bisulfite are acidic in nature. Degradation of sodium bisulfite with acid forms sulfur dioxide gas.
Application:
Sodium bisulfite (NaHSO3) has been used as a reagent to compose the immunoprecipitation (IP) buffer to chemically modify DNA and to synthesize arsenolipids (AsL).
Sodium bisulfite can also be used as a reagent during the synthesis of 5,6-dihydrouracil-6-sulfonate.

What is Sodium Bisulfite?
Sodium bisulfite is a food additive, antioxidant, antibrowning and preservant. 
Upon heating in aqueous acidic media, it releases SO2.

In dried fruits and jams, it acts as anti-browning agent by preventing enzymatic browning caused by polyphenol oxidase.
In baking, sodium bisulfite is used as an economical alternative to common reducing agents, mainly in cookies and crackers formulations.


Origin
Sodium bisulfite is commonly obtained by treating an alkali such as sodium carbonate or sodium hydroxide with sulfur dioxide.3

Function
Sodium bisulfite has several functions in bakery systems:

Antibacterial: inhibits the growth of bacteria in high pH and high water activity conditions.
Antioxidant: reatards oxidation and rancidity, due to its oxygen scavenging properties.
Retards enzymatic browning reactions: especially in fruit products.
Reducing agent: improves flour properties by inhibiting the restoration of disulfide bonds, providing a pliable dough.
Improves dough machinability: by reducing the amount of shrinkage or set back, thus producing uniform crackers.
Nutrition and Health
In sensitive individuals, sulfites may pose potential respiratory risk. Acceptable daily intake of sulfites should not exceed 0.7 mg/Kg body weight..3

Sodium bisulfite can reduce vitamin B1 (thiamine) content in meat and fruits.

Commercial production
Sodium bisulfite can be commercially produced through the following process:4

First reaction: sodium hydroxide and sulfur dioxide are mixed in an aqueous stream to produce sodium sulfite.
Crystallization: sodium sulfite liquor is introduced into a crystallizer and a purge stream is redirected to be used in the second reaction.

Second reaction: sulfur dioxide is added to the purge stream to produce sodium bisulfite.
Second crystallization: sodium bisulfite is crystallized to obtain the solid product.
Particle reduction and packaging.

Application:
Sodium bisulfite can be used in making cookies and biscuits due to its dough conditioning and antibrowning properties. 
In jams and jellies, it can be used as an antioxidant to prevent color deterioration and as an antimicrobial agent.1,2

When used in baked goods, sodium bisulfite produces the following effects:1,2

Improves sheeting by reducing shrinkage.
Improves uniformity of crackers and cookies by reducing set back and inhibiting excessive browning.
Improves dough texture by inhibiting the restoration of disulfide bonds.

Dechlorination in municipal wastewater, pulp & paper, power, and industrial water treatment plants
Oxygen scavenger
Boiler water treatment
Preservative in photo developer process
Food additive
Flue gas desulfurization
Mild reducing agent in organic synthesis
 Cyanide destruction and leaching in the mining industry (Manganese, Gold, Cobalt, Iodine, Nickel and Silver)
Efficiently remove traces or excess amounts of bromine, iodine, osmate esters, chromium trioxide, and potassium permanganate
Surfactant production

Benefits of Sodium Bisulfite
As a cleaner, sodium bisulfite can help purify toxic wastewater. 
For example, the authors of a paper in the February 2017 issue of Estuarine, Coastal and Shelf Science used chlorine to kill harmful bacteria in wastewater. 
They then neutralized this addition with sodium bisulfite to prevent the chlorine from contaminating the water supply.

As a preservative, manufacturers add sulfites like sodium bisulfite to decrease the growth of bacteria and fungi. 
This addition prevents browning and limits spoilage, according to an article featured in the October 2017 issue of PLOS One.

Aquaculture workers also use sodium bisulfite. 
For example, the authors of a review published in the Journal of Food Science in October 2013 showed how sodium bisulfite greatly improved seafood's appearance. 
The chemical made catfish fillets less yellow and more bright.

Manufacturers often process shrimp in a similar way, according to a paper in the January 2018 issue of the Annual Research and Review in Biology. 
First, workers catch and kill the shrimp. 
They then coat the them with sodium bisulfite as a bleaching agent. 
Finally, they freeze the shrimp to prevent blackening.

Sodium bisulfite has been used externally for parasitic skin diseases and as a gastrointestinal antiseptic.


Sodium bisulfite is an ingredient in parenteral nutrition products for patients with severe liver disorders

Sodium bisulfite (SBS), also known as sodium bisulphite or sodium hydrogen sulfite, one of the sulfites that can be used as a preservative, antioxidant and anti-browning agent in food with the European food additive number E222. 

How is Sodium Bisulfite made?
Sodium bisulfite can be commercially produced from the chemical reaction between sulfur dioxide gas with aqueous sodium hydroxide.

The following is the reaction equation:

SO2 + Na2CO3 (aqueous) –> 2 NaHSO3 + 2 CO2 (in water)

NaHSO3 is not a pure ingredient, and in fact a mixture of NaHSO3 and Na2S2O5 (sodium metabisulfite). Na2S2O5 is produced during the crystallization process of NaHSO3.

The main impurity in the product is SO42 -, as the bisulfite ion is unstable and easily oxidized to sulfate ion, so its solution cannot be stored for a long time. 

Properties 
Other names: Sodium bisulphite, Sodium hydrogen sulphite, Sodium acid bisulfite
CAS number: 7631-90-5
Chemical formula: NaHSO3
Molecular weight: 104.06
Boiling point: 315°C
Melting point: 150°C

Appearance
Solid: white granular or powder with an odour of sulfur dioxide. 
Liquid: A clear, colourless to yellow solution. 

Solubility
Freely soluble in water, slightly soluble in ethanol. 
NaHSO3 is the main form of SO2 that dissolves in water. 
The equilibrium of its different inorganic forms (sulfur dioxide, bisulfite and sulfite ions) forms should be considered.

Sodium bisulfite is a weak acid that releases sulfur dioxide gas on heating or in the presence of acids.

Sodium bisulfite dissociates bisulfite (HSO3−) when dissolved in water and the aqueous solution is acidic with the PH 2.5-5.5 (10 % aqueous solution). 

The following equilibriums exists after NaHSO3 dissolved in water:

HSO3- <===> H+ + SO32-

HSO3- + H2O <===> H2SO3 + OH 

H2SO3 <===> SO2 + H2O


What’re the Uses of Sodium Bisulfite?
Food
Generally, food grade sodium bisulfite can be used as an antimicrobial agent and antioxidant in food. 
Sodium bisulfite releases sulfur dioxide gas when added to water in acidic conditions, which functions as a preservative to kill microorganisms.

Sodium bisulfite can also be used as an oxygen scavenger which reacts with oxygen first and then prevents food spoilage from oxidation. 
And thus protects the color (anti-browning), freshness and flavor of food. 

Fruits and vegetables
NaHSO3 is commonly used in the preservation of fruits and vegetables by preventing the enzymatic browning effect caused by polyphenol oxidase. 
Commonly used in fruit canning and leafy green vegetables.

Shrimp
The shrimp are often treated with sodium bisulfite to prevent or slow down the black spot formation (melanosis) in the head and shell of shrimp after being exposed to oxygen. 
Therefore, sodium bisulfite helps keep a good appearance for shrimp.

Cheese
Its function is to prevent the browning caused by Maillard reaction in the manufacturing of processed cheese at high temperatures.

Corn starch
Sodium bisulfite can be used to soften corn kernels, reduce the mechanical strength of corn kernels, and thus enable fiber and protein easily separated from starch. 

Sodium bisulfite is an acidic salt, which is more stable than sulfurous acid in an aqueous solution. 

Pharmaceuticals
Certain ingredients in some drugs are easily oxidized, and its purpose is used as an antioxidant to improve their stability.

Agriculture
In agriculture, it can be used to increase the photosynthesis rate and therefore increase fruit output. 

Spraying sodium bisulfite during the period of fruit growth can increase the chlorophyll content by reducing sulfur to sulfhydryl (-SH), accelerate the photosynthetic rate by inhibiting the activity of glycolate oxidase and reducing the release of carbon dioxide, promote the accumulation of photosynthetic products in the fruit, and thereby increase the fruit weight gain rate. 

Industrial 
Industrial grade sodium bisulfite is widely used in the bleaching of cotton fabrics, and is also used as a reducing agent in the dye, paper, leather, and some other chemical synthesis.

Water treatment
NaHSO3 can be used as a mild reducing agent for wastewater chlorination. 
Sodium bisulfite is used to remove the residual chlorine in wastewater after chlorine has been used for adequate contact time for disinfection. 

The following is the reaction mechanism with hypochlorous acid:

2NaHSO3 + 2HOCl –> H2SO4 + 2HCl + Na2SO4

Sodium bisulfite can also be used to remove bromine and iodine.

About Sodium bisulfite
Helpful information
Sodium bisulfite is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 100 000 to < 1 000 000 tonnes per annum.

Sodium bisulfite is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Consumer Uses
Sodium bisulfite is used in the following products: fertilisers, photo-chemicals, washing & cleaning products, fillers, putties, plasters, modelling clay and textile treatment products and dyes. Other release to the environment of Sodium bisulfite is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.

Article service life
Release to the environment of Sodium bisulfite can occur from industrial use: industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal), manufacturing of the substance and in processing aids at industrial sites.
Other release to the environment of Sodium bisulfite is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
Sodium bisulfite can be found in products with material based on: stone, plaster, cement, glass or ceramic (e.g. dishes, pots/pans, food storage containers, construction and isolation material), wood (e.g. floors, furniture, toys), leather (e.g. gloves, shoes, purses, furniture), fabrics, textiles and apparel (e.g. clothing, mattress, curtains or carpets, textile toys), paper (e.g. tissues, feminine hygiene products, nappies, books, magazines, wallpaper), fabrics, textiles and apparel used for articles with intense direct dermal (skin) contact during normal use (e.g. clothing, shirts, pants, shorts) and leather used for articles with intense direct dermal (skin) contact during normal use (e.g. clothing such as jackets, shoes, or gloves).
Widespread uses by professional workers
Sodium bisulfite is used in the following products: polishes and waxes, coating products and pH regulators and water treatment products.
Sodium bisulfite is used for the manufacture of: wood and wood products and furniture.
Release to the environment of Sodium bisulfite can occur from industrial use: in processing aids at industrial sites, as processing aid, formulation of mixtures, as an intermediate step in further manufacturing of another substance (use of intermediates), manufacturing of the substance and in the production of articles.
Other release to the environment of Sodium bisulfite is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.
Formulation or re-packing
Sodium bisulfite has an industrial use resulting in manufacture of another substance (use of intermediates).
Release to the environment of Sodium bisulfite can occur from industrial use: formulation of mixtures, as processing aid, in processing aids at industrial sites, manufacturing of the substance, as an intermediate step in further manufacturing of another substance (use of intermediates), in the production of articles and of substances in closed systems with minimal release.
Other release to the environment of Sodium bisulfite is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use as reactive substance.
Uses at industrial sites
Sodium bisulfite has an industrial use resulting in manufacture of another substance (use of intermediates).
Sodium bisulfite is used in the following areas: formulation of mixtures and/or re-packaging, mining and printing and recorded media reproduction.
Sodium bisulfite is used for the manufacture of: chemicals, pulp, paper and paper products, textile, leather or fur, rubber products and plastic products.
Release to the environment of Sodium bisulfite can occur from industrial use: as processing aid, in processing aids at industrial sites, formulation of mixtures, manufacturing of the substance, as an intermediate step in further manufacturing of another substance (use of intermediates) and in the production of articles.
Other release to the environment of Sodium bisulfite is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use as reactive substance.
Manufacture
Release to the environment of Sodium bisulfite can occur from industrial use: manufacturing of the substance, as processing aid, in processing aids at industrial sites, as an intermediate step in further manufacturing of another substance (use of intermediates), formulation of mixtures, for thermoplastic manufacture, as processing aid and of substances in closed systems with minimal release.


Sodium bisulfite (sodium hydrogen sulfite, NaHSO3) is a mild reducing agent, that for example can be used for the decomposition of oxidizing agents during work-up, including halogens and highly oxidized transition metals.

General Description
White crystals or crystalline powder. 
Slight sulfurous odor. 
Specific gravity 1.48. 
Strong irritant to skin and tissue

sodium bisulfite either of two salts usually obtained by passing sulfur dioxide through a solution of sodium carbonate

Sodium Bisulfite is generally immediately available in most volumes. 
High purity, submicron and nanopowder forms may be considered.


Sodium Bisulfite is a very valuable and versatile product that plays several key roles throughout the wine making process. 
It is used, almost without exception, in all commercially made wines.

Among its many uses are: purifying fresh juices before the fermentation begins; using it in heavier doses with water for sanitizing bottles and equipment as needed; and, adding it to your wine at bottling time to reduce some of the negative effects of storage such as oxidation and deterioration of flavor.

What Is Sodium Bisulfite?
For the sake of keeping this article in layman terms, Sodium Bisulfite is essentially very fine crystallized sodium granules that release sulfur gas when it is dissolved in a liquid. 
This sulfur gas permeates the liquid it was added to and then eventually dissipates into the air over the coarse of several hours.

The sulfur gases that are released from the Sodium Bisulfite act as a sanitizer, killing wild molds, bacteria, germs and other unwanted little nasties. 
The sulfur gases also help to preserve the wine by displacing any air that may be saturated in the wine.
The sulfur gas is not so strong as to smell up the whole house, but its odor is noticeable when standing next to a liquid that has been treated.

It is important to note here that Sodium Bisulfite is also the active ingredient found in Campden Tablets. 
Each Campden Tablet equals 1/16 of a teaspoon of Sodium Bisulfite, or to put it another way, it takes 16 Campden Tablets to equal one teaspoon of Sodium Bisulfite. 
So, when we talk about Sodium Bisulfite you can think of it as being interchangeable with Campden Tablets. 

Sodium Bisulfite is also interchangeable with Potassium Bisulfite. 
It comes in the same crystallized form as Sodium Bisulfite, and the dosage is measured the same. 
The main difference is the active sulfur is stabilized in potassium instead of sodium. 

Sanitizing Fresh Juices With Sodium Bisulfite
You can add Sodium Bisulfite in lighter doses directly to any fresh wine making juices before fermentation to sanitize them. 
These fresh squeezed juices can contain a whole host of contaminating organisms, along with the natural yeast. 
These micro-organisms, if allowed to grow, pose a threat to your wine by way of spoilage.

Description
Chemical compound with formula NaHSO3. 
Sodium bisulfite releases sulfur dioxide gas when added to water, killing yeast, fungus, and bacteria, roughly 24 hours before fermentation, when added to wines. 
It may also be added after fermentation to prevent vinegar production and protect the color and flavor of wine. 
It kills microbes and in fruit canning, prevents browning. 
The substance is also added to leafy green vegetables to preserve visual freshness of the greens. 
There is some debate as to whether high doses of sodium bisulfite can cause allergic reactions in individuals.

Culinary Uses:
Prevention of oxidation.
Preservation of flavor.
Used in home winemaking to prevent oxidation and preserve flavor.
Used to kill microbes in canning applications.
Added to greens to prevent oxidation.

Substitutions
Sodium metabisulfite (available to commercial manufacturers and wine makers in large quantities)

Storage
Be careful handling the substance, as it is known to cause irritation to the nasal, throat, and respiratory tracts.  Keep in dry, cool, well ventilated area in a corrosive proof area.

Production
Produced by bubbling sulfur dioxide in a solution of sodium carbonate in water.


IUPAC NAMES:
natriumbisulfiet
Natriumhydrogensulfit...%
Sodium
Sodium bisulfite
sodium bisulfite
Sodium Bisulfite
Sodium bisulfite
sodium bisulfite
sodium bisulphate
Sodium Bisulphite
Sodium bisulphite
sodium bisulphite
Sodium bisulphite 38/40 %
sodium bisulphite … %
SODIUM HYDROGEN SULFITE
Sodium hydrogen sulfite
sodium hydrogen sulfite
Sodium hydrogen sulfite
sodium hydrogen sulfite (aqueous solution)
sodium hydrogenesulphite
Sodium hydrogensulfite
sodium hydrogensulfite
Sodium hydrogensulfite
sodium hydrogensulfite
Sodium hydrogensulphite
sodium hydrogensulphite
sodium hydrogensulphite
sodium hydrogensulphite (aqueous solution)
sodium hydrogensulphite ...%
sodium hydrogensulphite … %
Sodium sulfite
sodium sulfite
sodium;hydrogen sulfite
Sulfurous acid, monosodium salt
sulfurous acid, monosodium salt
Sulfurous acid, sodium salt (1:1)
wodorosiarczyn sodu


SYNONYMS:
SULFUROUS ACID MONOSODIUM SALT
SODIUM METABISULPHITE
SODIUM DISULFITE
SODIUM HYDROGEN SULFITE
SODIUM HYDROGEN SULPHITE
SODIUM ACID SULFITE
SODIUM BISULPHITE
SODIUM BISULFITE
SODIUM BISULFITE, META
SODIUM BISULFITE SOLUTION
PYROSULFITE
monosodium sulfite
NATRII METABISULFIS
SODIUM SULFITE ANH
SODIUM HYDROSULPHITE (HYDROUS)
NAHSO3
SODIUM HYDROSULPHITE 88%MIN
SODIUM METABISULPHITE 97-98%)-FOOD
SodiuM bisulfite, Mixture of NaHSO3 and Na2S2O5, powder, for analysis 1KG
Sulfurousacid, sodiuM salt (1:1)
bisulfitedesodium(french)
fr-62
sodiumbisulfite(1:1)
sodiumbisulfite(nahso3)
sodiumbisulfite,[liquid]
uantaxsbs
Hydrogen sulfite sodium
FORMALIN NEUTRALIZER
DISODIUM DISULFITE
DISODIUM PYROSULFITE
DISULFITE
BISULFITE
Sodium bisulfite ACS reagent, mixture of NaHSO3 and Na2S2O5
Sodium bisulfite solution purum, ~40%
ORANGE G SODIUM SALT HIGH PURITY GRADE
Sodium bisulfite, mixture of NaHSO3 and Na2S2O5
Liquid of Sodium bisulfite
Sodium Hydrogensulfite 〔Sodium Bisulfite〕
Sodium bisulfite anhydrous, free-flowing, mixture of NaHSO3 and Na2S2O5, Redi-Dri, ACS reagent
Sodium bisulfiteACS reagent, ≥ 58.5% (Titration)
FREE SAMPLE NCV SODIUM METABISULPHITE
Sodium bisulfite, For ACS analysis
Sodium Bisulfite, Purified
Sodium acid
sodiumbisulfite,solid
sodiumhydrogensulfite,[solid]
sodiumhydrogensulfite,[solution]
bisulfitedesodium
sodiumsulfite(nahso3)
sodiumsulhydrate
Solfurousacid,monosodiumsalt
SODIUM METABISULPHITE 65PCT
SODIUM METABISULPHAT
SODIUM META BISULPHITE FOOD& TECH GRADE
SODIUM METABISULFITE FOODGRADE
SODIUM META BISULPHATE
soldium hydrogen sulfite
SODIUM HYDROGENE SULFITE SOLN. 38-40% IN
SODIUM BISULFITE
7631-90-5
Sodium hydrogen sulfite
sodium hydrogensulfite
Sodium bisulphite
Sodium sulhydrate
Monosodium sulfite
Sulfurous acid, monosodium salt
UNII-TZX5469Z6I
NaHSO3
Liquid of Sodium bisulfite
TZX5469Z6I
CHEMBL1689285
CHEBI:26709
Sulfurous acid, sodium salt (1:1)
Uantax SBS
Caswell No. 750
Hydrogen sodium sulfite
Sodium hydrosulfite(DOT)
Sodium bisulfite, ACS reagent, powder
Bisulfite de sodium [French]
CCRIS 3950
HSDB 724
sodium hydrogensulphite
sodium hydrogen sulphite
EINECS 231-548-0
NSC 60680
EPA Pesticide Chemical Code 078201
Sodium bisulfite [JAN:NF]
sodiumbisulfit
Sodium hydrogensulphite (aqueous solution)
AI3-08582
Sodium hydrogen sulfite, solution
sodium bi-sulphite
sodiumhydrogensulfit
saures Natriumsulfit
Natriumhydrogensulfit
sodiumhydrogensulphite
sodium hydogen sulfite
primaeres Natriumsulfit
sodium hydrogen-sulfite
E222
Sodium bisulfite (TN)
Sodium bisulfite (JP17)
EC 231-548-0
Sodium hydrogen sulfite solution (45% or less)
DSSTox_CID_14902
DSSTox_GSID_47218
Sodium bisulfite, ACS reagent
DTXSID8034902
Tox21_303826
MFCD00003530
AKOS015856800
DB14015
NCGC00357103-01
Sodium bisulfite solution, purum, ~40%
BP-12336
Sodium bisulfite aqueous solution 35-40%
FT-0698943
D02059
Q407891
Sodium bisulfite, mixture of NaHSO3 and Na2S2O5

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