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SODIUM HEXAFLORALUMINATE

CAS Number: 13775-53-6
Molecular Weight: 209.94
EC Number: 237-410-6
MDL number: MFCD00003507
PubChem Substance ID: 24858435
Appearance: Colorless to dark odorless solid. [pesticide] [Note: Loses color on heating.]

APPLICATIONS


The main application of Sodium hexafluoroaluminate is as a solvent (or flux) for electrolysis of aluminium oxides such as bauxite.
The conversion of aluminium oxides into metallic aluminium requires that the metal ions be dissolved so that they can accept the electrons provided in the electrolysis cell.
A mixture of cryolite and some aluminium trifluoride is used as that solvent.

Unlike typical solutions, this one requires temperatures approaching 1000 °C to melt.
Sodium hexafluoroaluminate is also used as a pesticide.

Other uses of Sodium hexafluoroaluminate include a whitener for enamels and an opacifier for glass.
Sodium hexafluoroaluminate is used as an electrolyte in the production of aluminum by electrolytic reduction.
Sodium hexafluoroaluminate is used in aluminum producing.

Principally, Sodium hexafluoroaluminate can be used as an electrolyte in production and refining of aluminum.
Sodium hexafluoroaluminate can be used in the flux in production of various metals and alloys.

Sodium hexafluoroaluminate is used as electrolyte in the reduction of alumina to aluminum; ceramics; insecticide; binder for abrasives; electric insulation; explosives & polishes.

Some uses of Sodium hexafluoroaluminate:

Abrasives
Chemical Property modifier
Processing aids, not otherwise listed
Solvents (which become part of product formulation or mixture)
Used as a flux for aluminum oxide
Used as a flux/solvent for aluminum oxide
fluxing agent
thermal / chemical resistance
Custom Metals and Alloys
Plating agents and surface treating agents
Process regulators
Solvents (which become part of product formulation or mixture)
Automotive care products
Metal products not covered elsewhere
industrial refractory products

The main application of Sodium hexafluoroaluminate is as a solvent (or flux) for electrolysis of aluminium oxides such as bauxite.
The conversion of aluminium oxides into metallic aluminium requires that the metal ions be dissolved so that they can accept the electrons provided in the electrolysis cell.
A mixture of cryolite and some aluminium trifluoride is used as that solvent.
Unlike typical solutions, this one requires temperatures approaching 1000 °C to melt.

Sodium hexafluoroaluminate is also used as a pesticide.
Other uses include a whitener for enamels and an opacifier for glass.

Sodium hexafluoroaluminate is used as a solvent (or flux) for electrolysis aluminum oxides such as bauxite, whitener for enamels and an opacifier for glass and in the industrial production of aluminum.
Further, Sodium hexafluoroaluminate was originally part of the Alfa Aesar product portfolio.

Sodium hexafluoroaluminate is a biochemical for proteomics research.
Moreover, Sodium hexafluoroaluminate is used as a flux agent or bath material by aluminum smelters in the production of aluminum.
Sodium hexafluoroaluminate is also used in the production of synthetic resins for abrasives and in the manufacture of cutting or grinding discs.

Minor uses of Sodium hexafluoroaluminate are as a coloring agent (opacifier) in the glass, ceramic and pyrotechnic industries.
Sodium hexafluoroaluminate occurs naturally as the mineral cryolite, which is used extensively in the industrial production of aluminium.

Sodium hexafluoroaluminate is mainly used as fluxing agent in the production of aluminum electrolysis, also used as additive to the wear-resisting of abrasive products, iron alloy and the flux of rimming steel, non-ferrous metal flux, casting deoxidizer, enamel of emulsifier, glass opal agent, welding flux and ceramics filler.
Sodium hexafluoroaluminate is used as adhesives, cosolvent in enamel industry.

Sodium hexafluoroaluminate is used in the production of insecticides, in the glass and enamel industries, as well as being a solvent for bauxite in the electrolytic manufacture of aluminium.
Aluminum is the most abundant metal in the earth's crust and is always found combined with other elements such as oxygen, silicon, and fluorine.

DESCRIPTION


Sodium hexafluoroaluminate is an inorganic compound with formula Na3AlF6.
Sodium hexafluoroaluminate, which is discovered in 1799 by Peder Christian Abildgaard (1740–1801),occurs naturally as the mineral cryolite and is used extensively in the industrial production of aluminium metal. The compound is the sodium (Na+) salt of the hexafluoroaluminate (AlF63−) ion.

Sodium hexafluoroaluminate is used as a solvent (or flux) for electrolysis aluminum oxides such as bauxite, whitener for enamels and an opacifier for glass and in the industrial production of aluminum.
Furhter, Sodium hexafluoroaluminate is white and solid. 
Sodium hexafluoroaluminate or sodium aluminium hexafluoride is the inorganic compound with the formula Na3AlF6.

Sodium hexafluoroaluminate occurs naturally as the mineral cryolite, which is also the more common name for this compound.
Most Sodium hexafluoroaluminate is manufactured by a variety of related pathways.
One route entails combining sodium aluminate and hydrofluoric acid:
Na3Al(OH)6 + 6 HF → Na3AlF6 + 6 H2O

Often the hexafluorosilicic acid, which is recovered from phosphate mining, is the precursor in a two-step process beginning with neutralization with ammonia to give ammonium hexafluorosilicate:
H3AlF6 + 3 NH3 → (NH4)3AlF6
(NH4)3AlF6 + 3 NaOH → Na3AlF6 + 3 NH3 + 3 H2O

The mineral form of Sodium hexafluoroaluminate, which is called cryolite, was mined at Ivigtût on the west coast of Greenland until the deposit was depleted in 1987.
Cryolite is poorly soluble in water.

Sodium hexafluoroaluminate is generally immediately available in most volumes.
High purity, submicron and nanopowder forms of Sodium hexafluoroaluminate may be considered.
Sodium hexafluoroaluminate is a chemical compound of sodium, fluorine, and aluminum that occurs naturally as the mineral cryolite.

PROPERTIES

Purity: 99.9%
CAS No.: 13775-53-6
Molecular Formula: Na3AlF6
Formula Weight: 209.95
Physical Form: Powder
Density: 2.90
Appearance: White
Odour: Odourless
Melting Point: 1000°
UN No.: 3260
MDL No.: MFCD00003507
Formula: AlF₆Na₃
MW: 209,94 g/mol
Melting Pt: 1000 °C
Density: 2,90
Storage Temperature: Ambient

HANDLING


Safety:
Sodium hexafluoroaluminate has relative low toxicity.

Storage:
Sodium hexafluoroaluminate doesn't require special storage conditions.
Any clean plastic bottle can be used as a storage container for Sodium hexafluoroaluminate.

Disposal:
Sodium hexafluoroaluminate doesn't require special disposal.
Further, Sodium hexafluoroaluminate can be dumped in the trash.

SYNONYMS

Trisodium hexafluoroaluminate
aluminum;trisodium;hexafluoride
Sodium Cryolite
Trisodium hexafluoroaluminate(3)
Sodium fluoroaluminate (Na3AlF6)
Aluminum sodium fluoride (Na3AlF6)
EINECS 237-410-6
Sodium hexafluoroaluminate (Na3AlF6)
Aluminate(3-), hexafluoro-, trisodium
Aluminum sodium hexafluoride (AlNa3F6)
FT-0688793
EC 237-410-6
Cover bath
Cryolite as single subtance or within the preparation Bath or "Hall Cell Bath"
Cryolite bath
EINECS 237-410-6
Sodium hexafluoroaluminate (Na3AlF6)
Cryolite synth.
Cryolite synthetic
electrolyte
Na3AlF6
Aluminate(3-), hexafluoro-, trisodium
Aluminum sodium hexafluoride (AlNa3F6)
FT-0688793
EC 237-410-6
aluminum trisodium hexafluoride
AlF6.3Na
1S/Al.6FH.3Na/h;6*1H;;;/q+3;;;;;;;3*+1/p-6
16693908
CRYOLITE
trisodium hexafluoroaluminate
trisodium hexafluoroalumanetriuide
Trisodium hexafluoro aluminate
trisodium hexafluoroalumanetriuide
11431435
Trisodium hexafluoroaluminate
aluminum;trisodium;hexafluoride
Sodium Cryolite
Trisodium hexafluoroaluminate(3)
Sodium fluoroaluminate (Na3AlF6)
Aluminum sodium fluoride (Na3AlF6)

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