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SODIUM PEROXODISULFATE

DESCRIPTION:

Sodium peroxodisulfate is the inorganic compound with the formula Na2S2O8. 
Sodium peroxodisulfate is the sodium salt of peroxydisulfuric acid, H2S2O8, an oxidizing agent. 
Sodium peroxodisulfate is a white solid that dissolves in water. 

 

CAS NUMBER: 7775-27-1

MOLECULAR FORMULA: Na2S2O8

MOLECULAR WEIGHT: 238.13

 

DESCRIPTION:

Sodium peroxodisulfate is mainly used as a radical initiator for emulsion polymerization reactions for styrene based polymers such as Acrylonitrile butadiene styrene.
Sodium peroxodisulfate is also applicable for accelerated curing of low formaldehyde adhesives.
Sodium peroxodisulfate is a bleach, both standalone (particularly in hair cosmetics) and as a detergent component. 
Sodium peroxodisulfate is a replacement for ammonium persulfate in etching mixtures for zinc and printed circuit boards, and is used for pickling of copper and some other metals.
Sodium peroxodisulfate is also used as a soil conditioner and for soil and groundwater remediation and in manufacture of dyestuffs, modification of starch, bleach activator, desizing agent for oxidative desizing, etc.
Sodium peroxodisulfate is a specialized oxidizing agent in chemistry, classically in the Elbs persulfate oxidation and the Boyland–Sims oxidation reactions. 

Sodium peroxodisulfate is also used in radical reactions; for example in a synthesis of diapocynin from apocynin where iron(II) sulfate is the radical initiator.
Sodium peroxodisulfate appears as a white crystalline solid. 
Sodium peroxodisulfate is very irritating to skin and eyes. 
Sodium peroxodisulfate may be toxic by skin absorption. 
Sodium peroxodisulfate is used as a bleaching agent.
Sodium peroxodisulfate is used as a radical initiator for emulsion polymerization reactions like acrylonitrile butadiene styrene, detergent component, soil conditioner and soil remediation. 

Sodium peroxodisulfate is also used for curing of formaldehyde adhesives. 
Sodium peroxodisulfate acts as a bleaching agent and in the production of dyestuffs. 
Sodium peroxodisulfate finds application in zinc and printed circuit boards and considered to be a replacement for ammonium persulfate in etching mixtures. 
Sodium peroxodisulfate is used in the preparation of diapocynin from apocynin. 
Sodium peroxodisulfate plays a role in the conversion of phenols to para-diphenols in alkaline solution and of arylamines to aminophenols. 
Sodium peroxodisulfate is actively involved in the Elbs persulfate oxidation and the Boyland-Sims oxidation reactions as an oxidizing agent.

Sodium peroxodisulfate is a strongly oxidizing chemical used as a bleaching and oxidizing agent. 
Sodium peroxodisulfate is used as a promoter for polymerization reactions. 
Sodium peroxodisulfate has also been used as a chemical oxidant to treat laboratory slurry reactors for the accumulation of surfactants.
Sodium peroxodisulfate is used in surface treatment (pickling of copper and metals), for etching, as a bleach and in detergents.
Sodium peroxodisulfate is a chemical compound. 
Sodium peroxodisulfate is a strong oxidizer. 

Sodium peroxodisulfate's risk and safety phrases.
Sodium peroxodisulfate is a severe irritant of skin, eyes, and respiratory system. 
Sodium peroxodisulfate is almost non-hygroscopic and has particularly good ability to be stored for long time. 
Sodium peroxodisulfate is easy and safe to handle. 
Sodium peroxodisulfate is not combustible, but releases oxygen easily and assists combustion of other materials.

Sodium peroxodisulfate is used as a bleach, both standalone (particularly in hair cosmetics) and as a detergent component. 
Sodium peroxodisulfate is a replacement for ammonium persulfate in etching mixtures for zinc and printed circuit boards, and is used for pickling of copper and some other metals. 
Sodium peroxodisulfate is a source of free radicals, making it useful as an initiator for eg. emulsion polymerization reactions and for accelerated curing of low formaldehyde adhesives. 
Sodium peroxodisulfate is also used as a soil conditioner and in manufacture of dyestuffs, modification of starch, bleach activator, desizing agent for oxidative desizing, etc.
Sodium peroxodisulfate is an inorganic sodium salt. 

Sodium peroxodisulfate is a cheap, eco-friendly oxidizing reagent. 
Sodium peroxodisulfate is widely employed in bleaches and hair-coloring formulations.
Sodium peroxodisulfate appears as a white crystalline solid. 
Sodium peroxodisulfate is used as a bleaching agent.
Sodium peroxodisulfate is preferred by many chemists over other persulfate salts, as it has good solubility in water and long shelf-life, while also having better performance than other persulfate salts.
Sodium peroxodisulfate is an oxidizer. 

Sodium peroxodisulfate is a common oxidizing agent.
Sodium peroxodisulfate is a proven oxidant for in-situ chemical oxidation (ISCO) that can treat a wide range of contaminants including chlorinated solvents, petroleum-based chemicals and PAHs.  
Sodium peroxodisulfate is ideal for quick, source zone and hot spot treatment.
Sodium peroxodisulfate can be injected by direct push (DPT), into fixed, injection wells and soil blending.  
Because one of the end products of this chemistry is sulfuric acid (H2SO4), Sodium peroxodisulfate is important that all equipment that is in contact with the solution is compatible with strong acid.

Sodium peroxodisulfate is a strong oxidizing chemical compound. 
Sodium peroxodisulfate is a white crystalline powder that is soluble in water, decomposed by alcohol and in moist air.
Sodium peroxodisulfate is mostly used as a bleaching agent and detergent component. 
Sodium peroxodisulfate is also used to destroy a broad range of soil and groundwater contaminants. 
Sodium peroxodisulfate is often used for environmental applications like as a soil conditioner and for groundwater and soil remediation. 

Sodium peroxodisulfate is a bleaching agent used in hair cosmetics and as a detergent. 
Sodium peroxodisulfate is an oxidizer and may intensify fire.
Sodium peroxodisulfate is an irritant, causing damage and irritation to eyes and skin. 
Sodium peroxodisulfate may cause an allergic skin reaction. 
Sodium peroxodisulfate can also irritate the respiratory tract, causing inflammation and allergy or asthma-like symptoms. 
Sodium peroxodisulfate is harmful if swallowed at high concentrations.

Sodium peroxodisulfate is a white crystal or crystalline powder, odorless, tasteless. 
Sodium peroxodisulfate is soluble in water (70.4 when 20 ℃).
Sodium peroxodisulfate is used as a bleach, both standalone (particularly in hair cosmetics) and as a detergent component. 
Sodium peroxodisulfate is a replacement for ammonium persulfate in etching mixtures for zinc and printed circuit boards, and is used for pickling of copper and some other metals. 
Sodium peroxodisulfate is a source of free radicals, making it useful as an initiator for e.g. emulsion polymerization reactions and for accelerated curing of low formaldehyde adhesives. 
Sodium peroxodisulfate is also used as a soil conditioner and in manufacture of dyestuffs, modification of starch, bleach activator, desizing agent for oxidative desizing, etc.
For waste processing in the photographic industry, used as a soft metal surface corrosion agents of the printed circuit board and textile desizing agents, sulfur dyes colorformer.

Sodium peroxodisulfate is used as a radical initiator for emulsion polymerization reactions like acrylonitrile butadiene styrene, detergent component, soil conditioner and soil remediation. 
Sodium peroxodisulfate is also used for curing of formaldehyde adhesives. 
Sodium peroxodisulfate acts as a bleaching agent and in the production of dyestuffs. 
Sodium peroxodisulfate finds application in zinc and printed circuit boards and considered to be a replacement for ammonium persulfate in etching mixtures. 
Sodium peroxodisulfate is used in the preparation of diapocynin from apocynin. 
Sodium peroxodisulfate plays a role in the conversion of phenols to para-diphenols in alkaline solution and of arylamines to aminophenols. 
Sodium peroxodisulfate is actively involved in the Elbs persulfate oxidation and the Boyland-Sims oxidation reactions as an oxidizing agent.

 

USES:

-Polymerization: 

Sodium peroxodisulfate is used as initiator for the polymerization of monomers and as a strong oxidizing agent in many application. 
Sodium peroxodisulfate has the particular advantage of being almost non-hygroscopic, of having a particularly good storage stability and of being easy and safe to handle.


-PCB Etching/Surface preparation:

The oxidation power of Sodium peroxodisulfate is used to clean and microetch a variety of printed circuit board substrates. 
Persulfates are important oxidants in plating and coating processes. 
They are also etchants for nickel, titanium, and zink alloys. 


-Radical Initiator: 

Sodium peroxodisulfate is used as a radical initiator for emulsion polymerization reactions and for accelerated curing of low formaldehyde adhesives.


-Soil stabilization: 

Sodium peroxodisulfate is used as a curing agent in chemical grout systems used to stabilize soil near dams, tunnels, and buildings.


-Hair Cosmetics: 

Sodium peroxodisulfate is used as a bleach, both standalone (particularly in hair cosmetics) and as a detergent component.
Sodium peroxodisulfate is safe as used as oxidizing agents in hair colorants and lighteners designed for brief discontinuous use followed by thorough rinsing from the hair and skin.


-Oil and Gas Production:

Breaker; Allows a delayed breakdown of the gel in Drilling Muds.Oil fracturing additives, Drilling Fluid Additives. 
In enhanced oil recovery, persulfates are used "down hole" for gel forming and breaking.


-Textiles: 

De-slurry and bleach - especially for low-temperature bleaching.


-Others: 

Sodium peroxodisulfate is also used as a soil conditioner and in manufacture of dyestuffs, modification of starch, bleach activator, desizing agent for oxidative desizing, etc.

 

PROPERTIES:

Sodium peroxodisulfate is a white, crystalline, odorless salt. 
Sodium peroxodisulfate is used as initiator for the polymerisation of monomers and as a strong oxidizing agent in many application. 
Sodium peroxodisulfate has the particular advantage of being almost non-hygroscopic, of having a particularly good storage stability as a result of its extremely high purity and of being easy and safe to handle.

 

PHYSICAL PROPERTIES:

Sodium peroxodisulfate is a white colorless, odorless crystal, or powder with a density of 2.4g/cm 3 , which is decomposed by ethanol and has good stability at room temperature. 
Sodium peroxodisulfate is often used as a strong oxidant, 
Sodium peroxodisulfate can also act as a monomer polymerization initiator. 
Sodium peroxodisulfate absorbs little moisture, is easy to store, and is easy to use and safe.

 

PRODUCTION:

The salt is prepared by the electrolytic oxidation of sodium bisulfate:

2 NaHSO4 -> Na2S2O8 + H2

Oxidation is conducted at a platinum anode.
The standard redox potential of sodium persulfate into hydrogen sulfate is 2.1 V, which is higher than that of hydrogen peroxide (1.8 V) but lower than ozone (2.2 V).
The sulfate radical formed in situ has a standard electrode potential of 2.7 V.
However, there are a few drawbacks in utilizing platinum anodes to produce the salts; the manufacturing process is inefficient due to oxygen evolution and the product could contain contaminants coming from platinum corrosion (mainly due to extremely oxidizing nature of the sulfate radical). 
Thus, boron-doped diamond electrodes have been proposed as alternatives to the conventional platinum electrodes.

 

STRUCTURE:

The sodium and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. 
In the sodium salt, the O-O distance is 1.476 Å. 
The sulfate groups are tetrahedral, with three short S-O distances near 1.44 and one long S-O bond at 1.64 Å.

 

PROPERTIES:

-Molecular Weight: 238.11     
-Hydrogen Bond Donor Count: 0     
-Hydrogen Bond Acceptor Count: 8     
-Rotatable Bond Count: 1     
-Exact Mass: 237.88299787     
-Monoisotopic Mass: 237.88299787     
-Topological Polar Surface Area: 150 Ų     
-Heavy Atom Count: 12     
-Complexity: 206     
-Isotope Atom Count: 0     
-Defined Atom Stereocenter Count: 0     
-Undefined Atom Stereocenter Count: 0     
-Defined Bond Stereocenter Count: 0     
-Undefined Bond Stereocenter Count: 0     
-Covalently-Bonded Unit Count: 3     
-Compound Is Canonicalized: Yes

 

TECHNICAL INFORMARTION:

-Appearance: Crystalline powder
-Physical State: Solid
-Solubility: Soluble in water (549 mg/ml at 20° C), and alcohol (decomposes).
-pH: 2.5 - 4.0
-Melting Point: 100° C
-Density: 1.68 g/cm3

 

APPLICATION:

-Initiator for the emulsion or solution Polymerization of acrylic monomers, vinyl acetate, vinyl chloride etc. and for the
-emulsion co-polymerization of styrene, acrylonitrile, butadiene etc.
-Oxidizing agent, used in cleaning and pickling of metal surface, accelerated curing of low formaldehyde adhesives and modification of starch, production of binders and coating materials,
-Desizing agent and bleach activator,
-Sodium peroxodisulfate is an essential component of bleaching formulations for hair cosmetics.

 

PHYSICAL AND CHEMICAL PROPERTIES:

-Density: 1.2 g/cm3 (20 °C)
-pH value: 3.5 - 3.8 (100 g/l, H₂O, 20 °C)
-Vapor pressure: <0.0001 hPa
-Bulk density: 1150 kg/m3
-Solubility: 545 g/l

 

STORAGE:

Well closed. 
Separated from combustible substances, reducing agents, strong bases and powdered metals. 
Sodium peroxodisulfate is not flammable, but Sodium peroxodisulfate can help to release odor due to the release of oxygen. 
When stored, Sodium peroxodisulfate must be stored in a dry, airtight container, away from direct sunlight and near heat sources. 
Do not come in contact with reducing substances such as organic matter, iron rust, and trace metals to prevent decomposition and explosion of sodium persulfate. 
Due to the bleaching and slight corrosive effects of wet sSodium peroxodisulfate powders and their aqueous solutions, eye, skin and clothing are avoided from direct contact during use.

 

SYNONYM:
Sodium persulfate
7775-27-1
Sodium peroxydisulfate
Sodium peroxodisulfate
Peroxydisulfuric acid, disodium salt
disodium;sulfonatooxy sulfate
J49FYF16JE
DSSTox_CID_9698
Disodium peroxodisulphate
DSSTox_RID_78813
DSSTox_GSID_29698
Peroxydisulfuric acid (((HO)S(O)2)2O2), sodium salt (1:2)
sodium persulphate
CAS-7775-27-1
Persulfate de sodium
Persulfate de sodium  
Sodium peroxydisulphate
Disodium peroxydisulfate
EINECS 231-892-1
MFCD00003501
UN1505
UNII-J49FYF16JE
Peroxydisulfuric acid (((HO)S(O)2)2O2), disodium salt
sodium peroxidisulfate
ORISTAR SP
Sodium peroxy disulfate
Na2S2O8
EC 231-892-1
SODIUM PERSULFATE  
DTXSID4029698
SODIUM PERSULFATE 
SODIUM PERSULFATE 
Tox21_201326
Tox21_303592
SODIUM PERSULFATE 
AKOS025244086
NCGC00257410-01
NCGC00258878-01
Sodium persulfate  
disodium [(sulfonatoperoxy)sulfonyl]oxidanide
FT-0698963
Q419438

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