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Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is clear colorless viscous liquid. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate Generally a super-cooled liquid at room temperature but may occasionally solidify when held at low temperatures for prolonged periods. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is a flame retardant present in polyurethane foams.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is a chlorinated organophosphate. Organophosphate chemicals have a wide variety of applications and are used as flame retardants, pesticides, plasticizers, and nerve gases. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is structurally similar to several other organophosphate flame retardants, such as tris(2-chloroethyl) phosphate (TCEP) and tris(chloropropyl)phosphate (TCPP). Tris[2-chloro-1-(chloromethyl)ethyl] phosphate and these other chlorinated organophosphate flame retardants are all sometimes referred to as "chlorinated tris".
CAS NO: 13674-87-8
EC NUMBER: 237-159-2
IUPAC NAMES:
TDCP
Tris(1,3-dichloro-2-propyl) Phosphate
tris(1,3-dichloropropan-2-yl) phosphate
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate
tris[2-chloro-1-(chloromethyl)ethyl] phosphate
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate (TDCP)
tris[2-chloro-1-chloromethyl)ethyl] phosphate
SYNONYMS:
13674-87-8;TDCPP;Tris(1,3-dichloro-2-propyl)phosphate;Fyrol FR 2;TRIS(1,3-DICHLORO-2-PROPYL) PHOSPHATE;tris(1,3-dichloropropan-2-yl) phosphate;Tris(1,3-dichloroisopropyl)phosphate;Emulsion 212;Phosphoric Acid Tris(1,3-dichloro-2-propyl) Ester;2-Propanol, 1,3-dichloro-, phosphate (3:1);CRP (fireproofing agent);PF 38;TDCIPP;1,3-Dichloro-2-propanol phosphate (3:1);UNII-B1PRV4G0T0;Tris(1-chloromethyl-2-chloroethyl)phosphate;Tris(2-chloro-1-(chloromethyl)ethyl) phosphate;PF 38/3;B1PRV4G0T0;Fosforan troj-(1,3-dwuchloroizopropylowy);DTXSID9026261;Tris[2-chloro-1-(chloromethyl)ethyl] phosphate;2-Propanol, 1,3-dichloro-, 2,2',2''-phosphate;DSSTox_CID_6261;DSSTox_RID_78078;DSSTox_GSID_26261;Fyrol FR-2;CAS-13674-87-8;CCRIS 6284;HSDB 4364;Tri(beta,beta'-dichloroisopropyl)phosphate;Tris(1,3-dichloro-2-propyl) phosphate, 95%;Tris(2-chloro-1-(chloromethyl)ethyl)phosphate;EINECS 237-159-2;BRN 1715458;C9H15Cl6O4P;1,3-Dichloro-2-propanol phosphate;Phosphoric acid tris(1,3-dichloro-2-propyl)ester;Fosforan troj-(1,3-dwuchloroizopropylowy) [Polish];Fyrol FR2;EC 237-159-2;TDCPP, analytical standard;3-01-00-01473 (Beilstein Handbook Reference);SCHEMBL333198;CHEMBL3182032;CHEBI:143729;tri(2,3-dichloropropyl) phosphate;ZINC2019519;Tox21_202166;Tox21_300194;ANW-20172;MFCD00083121;AKOS015856734;CS-8011;Tris(1.3-dichloro-2-propyl) phosphate;Tris-(1,3-dichloro-2-propyl)phosphate;NCGC00247923-01;NCGC00247923-02;NCGC00254047-01;NCGC00259715-01;I991;HY-108712;FT-0654115;P0269;Tris(1,3-dichlorisopropyl)phosphate (TDCPP);Tri(.beta.,.beta.'-dichloroisopropyl)phosphate;tris[1,3-bis(chloranyl)propan-2-yl] phosphate;A807122;Tris[2-chloro-1-(chloromethyl)ethyl] phosphate #;J-006902;Q2454085;phosphoric acid tris(1,3-dichloropropan-2-yl) ester;phosphoric acid tris-(2-chloro-1-chloromethyl-ethyl) ester;Tris-(1,3-dichloroisopropyl) phosphate Standard 50 microg/mL in Acetonitrile;2-Propanol, 1,3-dichloro-, phosphate (3:1); Tris(1,3-dichloro-2-propyl) phosphate; Tris(1-chloromethyl-2-chloroethyl) phosphate; Tris[2-chloro-1- (chloromethyl)ethyl] phosphate; tris (1,3-dichloroisopropyl) phosphate; 1,3-Dichloro-2-propanol phosphate (3:1); Phosphoric acid, tris(1,3-dichloro-2-propyl)ester; TDCP; TDCPP; Antiblaze 195; Antiblaze TDCP; Amgard TDCP; CRP; Fyrol FR-2; Tolgard TDCP; Tris
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used in articles, in formulation or re-packing, at industrial sites and in manufacturing.
Release to the environment of Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can occur from industrial use: industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal) and formulation in materials. Another release to the environment of this substance is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment). Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can be found in complex articles, with no release intended: vehicles. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can be found in products with material based on: fabrics, textiles and apparel (e.g. clothing, mattress, curtains or carpets, textile toys) and plastic (e.g. food packaging and storage, toys, mobile phones).
Formulation or re-packing
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used in the following products: polymers and semiconductors.
Release to the environment of this substance can occur from industrial use: formulation in materials and industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal).
Uses at industrial sites
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used in the following products: polymers.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used for the manufacture of machinery and vehicles and furniture.
Release to the environment of Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can occur from industrial use: formulation in materials and industrial abrasion processing with low release rate (e.g. cutting of textile, cutting, machining or grinding of metal).
Manufacture
Release to the environment of Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can occur from industrial use manufacturing of the substance.
Uses
Flame retardant
Until the late 1970s, Tris[2-chloro-1-(chloromethyl)ethyl] phosphate was used as a flame retardant in children’s pajamas in compliance with the U.S. Flammable Fabrics Act of 1953. This use was discontinued after children wearing fabrics treated with a very similar compound, tris(2,3-dibromopropyl) phosphate, were found to have mutagenic byproducts in their urine.
Following the 2005 phase-out of PentaBDE in the United States, Tris[2-chloro-1-(chloromethyl)ethyl] phosphate became one of the primary flame retardants used in flexible polyurethane foam used in a wide variety of consumer products, including automobiles, upholstered furniture, and some baby products. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can also be used in rigid polyurethane foam boards used for building insulation.[6] In 2011 it was reported that Tris[2-chloro-1-(chloromethyl)ethyl] phosphate was found in about a third of tested baby products.
Presence in the environment
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is an additive flame retardant, meaning that it is not chemically bonded to treated materials. Additive flame retardants are thought to be more likely to be released into the surrounding environment during the lifetime of the product than chemically bonded, or reactive, flame retardants.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate degrades slowly in the environment and is not readily removed by wastewater treatment processes.
Indoor Uses
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate has been detected in indoor dust, although concentrations vary widely. The second study found an average concentration similar to that of the previous study but a greater range of concentrations: one sample collected from a vehicle contained over 300 ppm Tris[2-chloro-1-(chloromethyl)ethyl] phosphate in the dust. Similar concentrations have been reported for dust samples collected in Europe and Japan.
Outdoors Uses
Although Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is generally found at the highest concentrations in enclosed environments, such as homes and vehicles, it is widespread in the environment. Diverse environmental samples, ranging from surface water to wildlife tissues, have been found to contain Tris[2-chloro-1-(chloromethyl)ethyl] phosphate. The highest levels of contamination are generally near urban impacted areas; however, samples from even relatively remote reference sites have contained Tris[2-chloro-1-(chloromethyl)ethyl] phosphate.
Tris(1,3-dichloro-2-propyl)phosphate(TDCPP) can be used in mining conveyor belts, cables, electrical appliances, wallpaper, leather and other industries
USE AREAS
Materials used in the building process, such as flooring, insulation, caulk, tile, wood, glass, etc.
Fire prevention materials, or additives/coatings to prevent flammability in paints, textiles, plastics, etc
Related to bedding used in the home (e.g. mattresses, bed pillows)
Furniture, or the manufacturing of furniture (can include chairs and tables, and more general furniture such as mattresses, patio furniture, etc.)
Plastic products, industry for plastics, manufacturing of plastics, plastic additives.
Rubber products (e.g. tires) and their manufacture
Flame-retardant in plastics and as a secondary plasticizer
Leading additive for flexible urethane foams and can be added to the isocyanate or the polyol/catalyst mixture. ... Useful as a flame retardant in styrene-butadiene and acrylic latices for textile back coating and binding of non-wovens.
Flexible foam formulations containing tris(1,3-dichloro-2-propyl)phosphate and other haloalkyl phosphates can be further stabilized against scorch by appropriate antioxidants (q.v.) and acid acceptors.
Combinations with melamine are used in cushioning formulations.
Flame retardants
Foam seating and bedding products
Industry Processing Sectors
All other chemical product and preparation manufacturing
Furniture and related product manufacturing
What is Tris[2-chloro-1-(chloromethyl)ethyl] phosphate?
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is soluble in organic solvents such as alcohol, benzene, ester, carbon tetrachloride and insoluble in water and aliphatic hydrocarbons. Because the molecule contains both phosphorus and chlorine at the same time, it has a significant flame retardant effect and is plasticizing, moisture-proof, Antistatic and other effects, it is an additive flame retardant. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used as a flame retardant in the production of strip and fast foam. It is a low-cost flame retardant and has good stability.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate Usage
1. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is mainly used for soft (hard) polyurethane foam, epoxy resin, polystyrene, acrylic acid, cellulose acetate, ethylcellulose resin and phenolic plastic, polyvinyl acetate, and gun foam caulking agent produce.
2. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is especially recommended for rigid polyurethane foam with excellent thermal conductivity and hydrolytic stability, especially suitable for ASTME84 (Class II), used to compound polyurethane foam and unsaturated resin and phenolic plastics with low viscosity at low temperatures. Usually also used in conjunction with antimony trioxide to improve flame retardant efficiency.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is a flame retardant with low cost and good stability. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is used as a flame retardant in strip and block foam production. It is also used in polyurethane foams, adhesives and other resins.
Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is an alkyl phosphate flame retardant, specifically Tris(1,3-dichloro-2-propyl) phosphate. is an alkyl phosphate flame retardant and plasticizer. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is also suitable for use in flexible polyurethane foam and is known for its low fogging performance. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate is also used in PVC, epoxy resins, unsaturated resins, etc. Tris[2-chloro-1-(chloromethyl)ethyl] phosphate can also be used as extreme pressure and antiwear additive in lubricants.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints coatings, furniture and related products, building/construction materials, fabrics textiles leather products, and foam seating and bedding products.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a generally purpose chlorinated phosphate ester flame retardant, with high heat stability, excellent hydrolysis stability, low viscosity, remarkable compatibility with resin.
Tris(1,3-dichloro-2-propyl) phosphate (TDCPP) mass spectral data can be found in a separate interface.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a clear - yellowish liquid that has a chlorine content of 47%. It is primarily used as a general purpose chlorinated phosphate flame retardant. Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is recommended for use in multiple resin types including, plyurethane, epoxy and phenolic.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a flame retardant currently used in many applications including polyurethane foam found in upholstered furniture. Although banned from use in children’s pyjamas in the 1970s due to its mutagenic properties, Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP remains in household furniture and baby products. It can escape from foam and attach to house dust or remain in the air.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a chlorinated phosphate ester. It is a colourless, viscous liquid at temperatures greater than 27 degrees C.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is an additive flame retardant, meaning that is not chemically bound to products and can escape over time. Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is used in both soft and rigid polyurethane foam, as well as in plastics, resins, and some fabric backings. In a study conducted in 2011, chlorinated Tris was the most common flame retardant found in baby products with foam. Products intended for children with chlorinated Tris included car seats, baby changing pads, and baby carriers.
Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a flame retardant used on plastics, flexible urethane foams, and textile back coatings. Synonyms for it include TDCPP and Fyrol FR 2. It is an organophosphate, a class of chemicals often used as flame retardants and pesticides. "Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) is a viscous, colourless liquid; is not volatile, and is soluble in water and most organic solvents."
The Tris [2‐chloro‐1‐(chloromethyl) ethyl] phosphate (TDCP) has a high-efficiency flame retardant, low volatility, high thermal stability, water resistance, alkali resistance, stable solubility in most organic substances, good processability, plastic, moisture-proof, antistatic, tensile and compressive properties. Widely used in unsaturated polyester, polyurethane foam, epoxy resin, phenolic resin, rubber, soft polyvinyl chloride, synthetic fibre and other plastics and coatings at high temperature.
