PRODUCTS

TETRA ISOPROPYL TITANATE

Tetra isopropyl titanate, a highly reactive organic titanate, finds extensive use as a catalyst in various chemical processes, such as esterification reactions, transesterification, and as a crosslinking agent, particularly in industries like plastics, coatings, and polymer production.
Tetra isopropyl titanate is a diamagnetic tetrahedral molecule and a key component in the Sharpless epoxidation method for synthesizing chiral epoxides, showcasing its significance in organic synthesis and materials science applications.
Tetra isopropyl titanate's reactivity with hydroxyl-containing compounds makes valuable in bonding processes and surface modification applications, although precautions must be taken due to its sensitivity to moisture.

CAS Number: 546-68-9
EC Number: 208-909-6
Molecular Formula: C12H28O4Ti
Molecular Weight: 284.22

Synonyms: Titanium tetraisopropanolate, 546-68-9, Titanium(IV) isopropoxide, Titanium isopropoxide, Tetraisopropyl orthotitanate, Tetra isopropyl titanate, Titanium isopropylate, Titanium tetraisopropylate, Tilcom TIPT, Ti Isopropylate, Tetraisopropoxytitanium(IV), Isopropyl orthotitanate, Tetraisopropoxytitanium, Tetraisopropanolatotitanium, TETRAISOPROPYL TITANATE, A 1 (titanate), Orgatix TA 10, Tetrakis(isopropoxy)titanium, Isopropyl titanate(IV), Tyzor TPT, Isopropyl Titanate, Propan-2-olate;titanium(4+), TTIP, Tetraisopropoxide titanium, Titanium tetra-n-propoxide, Titanium(4+) isopropoxide, Titanic acid isopropyl ester, Titanium, tetrakis(1-methylethoxy)-, Titanium(IV) i-propoxide, Isopropyl alcohol, titanium(4+) salt, Titanium tetrakis(isopropoxide), Isopropyl titanate(IV) ((C3H7O)4Ti), Titanium(IV)tetraisopropoxide, 2-Propanol, titanium(4+) salt, Titanium(IV) propan-2-olate, 2-Propanol, titanium(4+) salt (4:1), Titanium(IV) Tetraisopoxide, Isopropyl alcohol titanium(4+) salt, 76NX7K235Y, Titanium tetra(isopropoxide), MFCD00008871, Tetrakis(propan-2-yloxy)titanium, Titanium isopropylate (VAN), TITANIUM (IV) ISOPROPOXIDE, HSDB 848, Tetraksi(isopropanolato)titanium, NSC-60576, Isopropyl alcohol, titanium salt, Titanic acid tetraisopropyl ester, Titanium isopropoxide (Ti(OC3H7)4), EINECS 208-909-6, Titanium isopropoxide (Ti(OCH7)4), NSC 60576, Titanic(IV) acid, tetraisopropyl ester, C12H28O4Ti, UNII-76NX7K235Y, TIPT, Ti(OiPr)4, Tetraisopropoxy titanium, Tetraisopropoxy-titanium, Titaniumtetraisopropoxide, Titaniumtetraisopropylate, Titanium(IV)isopropoxide, Tetra-isopropoxy titanium, Titanium (IV)isopropoxide, Tetra-iso-propoxy titanium, Titanium tetra-isopropoxide, Titanium-tetra-isopropoxide, EC 208-909-6, Titanium (4+) isopropoxide, VERTEC XL 110, Tetraisopropoxytitanium (IV), Titanium tetra (isopropoxide), Titanium (IV)tetraisopropoxide, Titanium (IV) tetraisopropoxide, TITANUM-(IV)-ISOPROPOXIDE, CHEBI:139496, AKOS015892702, Tetra isopropyl titanate [MI], Titanium(4+) tetrakis(propan-2-olate), TITANIUM TETRAISOPROPANOLATE [HSDB], T0133, Q2031021.

Tetra isopropyl titanate belongs to the product group of organic titanates, which are known to be highly reactive organics that can be used in a broad range of processes and applications.
Tetra isopropyl titanate is a colorless, slighty yellowish liquid that is very sensitive to moisture.

Tetra isopropyl titanate is an organic titanate that has a wide range of applications across several industries.
Tetra isopropyl titanate can be used as an esterification catalyst for plasticizers, polyesters, methacrylic esters, resins, polycarbonates, polyolefins and RTV silicone sealants.

Tetra isopropyl titanate can also be used for coating chemicals as a cross linker for wire enamel varnish, glass and zinc flake coatings.
Tetra isopropyl titanate is most suitable for use in the glass and glass fiber manufacturing. TIPA may be used as an adhesion promoter for packaging ink such as flexo and gravure.

Tetra isopropyl titanate, is a chemical compound with the formula Ti{OCH(CH3)2}4.
This alkoxide of titanium(IV) is used in organic synthesis and materials science.

Tetra isopropyl titanate is a diamagnetic tetrahedral molecule.
Tetra isopropyl titanate is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.

The structures of the Tetra isopropyl titanates are often complex.
Crystalline titanium methoxide is tetrameric with the molecular formula Ti4(OCH3)16.

Alkoxides derived from bulkier alcohols such as isopropyl alcohol aggregate less.
Tetra isopropyl titanate is mainly a monomer in nonpolar solvents.

Tetra isopropyl titanate is a titanium alkoxide, specifically a tetraalkoxy derivative of titanium.
Tetra isopropyl titanate is commonly used as a precursor or catalyst in various chemical processes, including the synthesis of organic and inorganic materials.

The "tetraisopropyl" part of the name indicates that there are four isopropyl (C3H7) groups bonded to the titanium atom.
Tetra isopropyl titanate is often employed in the preparation of sol-gel derived materials, coatings, and as a crosslinking agent in the production of polymers.

Tetra isopropyl titanate is reactivity with hydroxyl-containing compounds makes it useful in bonding processes and surface modification applications.
As with many titanium alkoxides, Tetra isopropyl titanate is sensitive to moisture, and precautions are often taken to handle it under dry conditions.

Tetra isopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol.
Tetra isopropyl titanate, vapors heavier than air.

Tetra isopropyl titanate is used in organic synthesis and materials science.
Tetra isopropyl titanate is a diamagnetic tetrahedral molecule.

Tetra isopropyl titanate, about the same density as water.
The structures of the Tetra isopropyl titanate are often complex.

Crystalline Tetra isopropyl titanate is tetrameric with the molecular formula Ti4(OCH3)16.
Alkoxides derived from bulkier alcohols such as Tetra isopropyl titanate aggregate less.

Tetra isopropyl titanate is mainly a monomer in nonpolar solvents.
Tetra isopropyl titanate is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.

Tetra isopropyl titanate is a widely used item of commerce and has acquired many names in addition to those listed in the table.
Tetra isopropyl titanate belongs to the product group of organic titanates, which are known to be highly reactive organics that can be used in a broad range of processes and applications.

Tetra isopropyl titanate a colorless, slighty yellowish liquid that is very sensitive to moisture.
Tetra isopropyl titanate has a complex structure.

Tetra isopropyl titanate, also commonly referred to as Titanium tetraisopropoxide or is a chemical compound with the formula Ti{OCH(CH3)2}4.
Tetra isopropyl titanate is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.

In crystalline state, Tetra isopropyl titanate is a tetramer.
Non-polymerized in non-polar solvents,Tetra isopropyl titanate is a tetrahedral diamagnetic molecule.

Tetra isopropyl titanate, also known as titanium isopropoxide, Titanium tetraisopropoxide is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Tetra isopropyl titanate has a complex structure.

In crystalline state, Tetra isopropyl titanate is a tetramer.
Non-polymerized in non-polar solvents, Tetra isopropyl titanate is a tetrahedral diamagnetic molecule.

Tetra isopropyl titanate is an intermediate derived from titanium.
Tetra isopropyl titanate appears as a light yellow, transparent liquid.

Tetra isopropyl titanate can be used as a catalyst additive in coating primers or added to that formulation as an adhesion promoter.
Tetra isopropyl titanate is a type of very lively primary alcohol titanium oxide; it hydrolyzes when contacted with moisture in air.

Tetra isopropyl titanate is mainly used as catalyst in esterification reaction or transesterification,also being used as catalyst of polyolefin.
Tetra isopropyl titanate can be used to improve the adherence and crosslinking of resin having alcohol group or carboxyl group, used in heat resistant and corrosion resistant coating.

Tetra isopropyl titanate also can be used in the manufacture of glass and glass fiber.
Tetra isopropyl titanate can only be used in oil system.

Tetra isopropyl titanate is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Tetra isopropyl titanate is a 100% active tetra-isopropyl titanate in liquid form.

Tetra isopropyl titanate is typically used as a metal catalyst in producing polyolefins and polycarbonate.
Tetra isopropyl titanate improves the yield of olefin polymerization, esterification, condensation, and addition reactions while eliminating unwanted byproducts.

Compared to other Tetra isopropyl titanate, Tetraisopropyl titanate is highly moisture sensitive and will decompose when exposed to water.
Tetra isopropyl titanate is useful as a replacement for tin, organostannanes, and sulfuric acid in esterification reactions when toxicity reduction is desired.

Tetra isopropyl titanate is even more efficient than sulfuric acid in esterification reactions.
When added to solvent-based paints, Tetra isopropyl titanate will cross-link hydroxyl and carboxyl functional polymers to increase chemical and heat resistance.

Tetra isopropyl titanate is also used as a catalyst in the preparation of certain cyclopropanes in the Kulinkovich reaction.
Prochiral thioethers are oxidized enantioselectively using a catalyst derived from Ti(O-i-Pr)4.

Tetra isopropyl titanate reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH

This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
Tetra isopropyl titanate, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.

Tetra isopropyl titanate, isopropyl alcohol and liquid ammonia are esterified in toluene, absorbed and filtered to remove by-product ammonium chloride, and then distilled to obtain the finished product.
Raw material consumption (kg/t) toluene (98%) 1000 titanium tetrachloride (99%) 1500 isopropanol (98%) 1600 liquid ammonia 1400

Tetra isopropyl titanate will be easily ignited by heat, sparks or flames.
Tetra isopropyl titanate vapors may form explosive mixtures with air.

Tetra isopropyl titanate vapors may travel to source of ignition and flash back.
Tetra isopropyl titanate vapors are heavier than air.

Tetra isopropyl titanate will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
Tetra isopropyl titanate vapor explosion hazard indoors, outdoors or in sewers.

Tetra isopropyl titanate designated with a may polymerize explosively when heated or involved in a fire.
Tetra isopropyl titanate runoff to sewer may create fire or explosion hazard.

Tetra isopropyl titanate containers may explode when heated.
Tetra isopropyl titanate many liquids will float on water.

Metal alkyls, such as Tetra isopropyl titanate, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones.
Tetra isopropyl titanate, they are likely to ignite on contact with alcohols.
Tetra isopropyl titanate is highly flammable.

Tetra isopropyl titanate fumes in air. Soluble in water.
Tetra isopropyl titanate decomposes rapidly in water to form flammable isopropyl alcohol.

Uses of Tetra isopropyl titanate:
Tetra isopropyl titanate is widely used in sol-gel processing, a method for producing ceramics and thin films.
Tetra isopropyl titanate is a precursor in the formation of titanium dioxide (TiO2) thin films, which find applications in optical coatings, sensors, and photovoltaic devices.

Tetra isopropyl titanate can be used as a crosslinking agent in the production of polymers.
Tetra isopropyl titanate reacts with polymers containing hydroxyl groups, contributing to the crosslinking of the polymer chains.

This enhances the mechanical and thermal properties of the polymers.
Tetra isopropyl titanate is employed as an adhesion promoter in coatings and adhesives.

Tetra isopropyl titanate helps improve the adhesion of coatings to various substrates, such as metals, glass, and ceramics.
Tetra isopropyl titanate is used for surface modification of materials, particularly in the development of functionalized surfaces with improved properties.

This can be relevant in areas like biomaterials and catalysis.
Tetra isopropyl titanate is sometimes used as a catalyst or a component in catalyst formulations, especially in reactions involving transesterification or esterification processes.

Tetra isopropyl titanate serves as a reagent in various chemical synthesis processes, contributing to the formation of new compounds.
In the rubber industry, Tetra isopropyl titanate can be used as a crosslinking agent for elastomers, contributing to improved mechanical properties and stability.

Tetra isopropyl titanate can be used as a photocatalyst in environmental applications, such as air and water purification.
Tetra isopropyl titanate can also be used as surface modifier, adhesion promoter and paraffin and oil additives.

Tetra isopropyl titanate for ester exchange reaction.
Tetra isopropyl titanate used as an auxiliary agent and chemical product intermediate.

Tetra isopropyl titanate used to make adhesives, used as a catalyst for transesterification and polymerization reactions.
Binders for preparing metals and rubber, metals and plastics, also used as catalysts for transesterification and polymerization reactions and raw materials for the pharmaceutical industry.

Tetra isopropyl titanate for esterification reaction, transesterification reaction of acrylic acid and other esters.
Tetra isopropyl titanate in polymerization reactions such as epoxy resin, phenolic plastic, silicone resin, polybutadiene, etc., it has high stereoselectivity.

Tetra isopropyl titanate, a variety of polymers or resins play a cross-linking role, improve the anti-corrosion ability of the coating, etc., and also promote the adhesion of the coating to the surface.
Tetra isopropyl titanate can be directly used as material surface modifier, adhesive promoter.

Tetra isopropyl titanate especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2.
Tetra isopropyl titanate complexing agent in sol-gel process.

Tetra isopropyl titanate is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films.
Tetra isopropyl titanate is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes.

Tetra isopropyl titanate is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides.
Tetra isopropyl titanate is involved as a catalyst in the preparation of cyclopropanes.

Tetra isopropyl titanate can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Tetra isopropyl titanate is used in the following products: pH regulators and water treatment products, laboratory chemicals and water treatment chemicals.

Tetra isopropyl titanate is used in the following areas: health services and scientific research and development.
Tetra isopropyl titanate is used for the manufacture of: Chemicals.

Release to the environment of Tetra isopropyl titanate can occur from industrial use: manufacturing of the substance.
Other release to the environment of Tetra isopropyl titanate is likely to occur from : İndoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).

Tetra isopropyl titanate is used in the following products: polymers, fuels, coating products, lubricants and greases, pH regulators and water treatment products and laboratory chemicals.
Tetra isopropyl titanate has an industrial use resulting in manufacture of another substance.

Tetra isopropyl titanate is used in the following areas: health services and scientific research and development.
Tetra isopropyl titanate is used for the manufacture of: chemicals and plastic products.

Release to the environment of Tetra isopropyl titanate can occur from industrial use: as processing aid, as an intermediate step in further manufacturing of another substance (use of intermediates), of substances in closed systems with minimal release and in processing aids at industrial sites.
Tetra isopropyl titanate for the esterification reaction is used for the transesterification reaction of esters such as acrylic acid and the polymerization of epoxy resin, phenolic plastic, silicone resin, polybutadiene, PP and PE.

Tetra isopropyl titanate can also be used as raw materials for the pharmaceutical industry and the preparation of metal and rubber, metal and plastic adhesives.
Tetra isopropyl titanate for the Sharpless asymmetric epoxidation reaction of allyl alcohol; as a Tetra isopropyl titanate for transesterification reaction with various alcohols under neutral conditions; Tetra isopropyl titanate can be formed by a sol-gel two-step method New metal oxide/phosphonate hybrid; used as a raw material for barium strontium titanate film; used to prepare porous titanosilicate, which is a potential ion exchange material for removing radioactive waste; Tetraisopropyl titanateis used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes.

Tetra isopropyl titanate has been proved that it can undergo light-induced electron transfer
Tetra isopropyl titanate is mainly used for transesterification and condensation reactions in organic synthesis Catalyst.

Tetra isopropyl titanate is often used as a precursor to prepare titanium dioxide (TiO2).
A new metal oxide/phosphonate hybrid can be formed from Tetra isopropyl titanate by sol-gel two-step method.

The raw material of barium strontium Tetra isopropyl titanate film.
Tetra isopropyl titanate is used to prepare porous titanosilicates, which are potential ion exchange materials for the removal of radioactive wastes.

Tetra isopropyl titanate is used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes, which have been shown to be capable of light-induced electron transfer.
Tetra isopropyl titanate can be used directly or in directly as a catalyst or catlyst additive,as a coating primer or added to formulation as a adhesion promoter and as the base material in the formation fo sol-get systems or nanoparticle systems or products.

Tetra isopropyl titanate can be used as sharpless oxidation catalyst.
Tetra isopropyl titanate can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.

Tetra isopropyl titanate is used in the formulation of coatings and paints.
Tetra isopropyl titanate can contribute to improved adhesion, durability, and weather resistance of the coatings.

In the ceramics industry, Tetra isopropyl titanate is utilized as a precursor for the synthesis of ceramic materials, including ceramics used in electronic components.
Tetra isopropyl titanate can be employed in glass manufacturing processes, contributing to the improvement of certain properties of glass, such as hardness and scratch resistance.

Tetra isopropyl titanate has been investigated for its potential use in fuel cell applications.
Tetra isopropyl titanate can be part of the fabrication process for materials used in fuel cell technologies.

The hydrophobic nature of Tetra isopropyl titanate-derived coatings makes them suitable for applications where water repellency is desired, such as in self-cleaning surfaces or anti-fog coatings.
Tetra isopropyl titanate is sometimes used in the formulation of coatings designed to provide corrosion resistance to metal surfaces.

Tetra isopropyl titanate can be used as a modifier to impart certain properties to fabrics, such as water repellency or flame retardancy.
Tetra isopropyl titanate has been explored for use in antimicrobial coatings, which can find applications in healthcare settings and other areas where bacterial resistance is a concern.

Tetra isopropyl titanate is employed in the production of thin films for electronic devices, such as semiconductors and sensors.
Tetra isopropyl titanate-derived materials are used in the production of thin films for photovoltaic devices, contributing to the development of solar cells.

Tetra isopropyl titanate can be used as a bonding agent, improving the performance and durability of adhesives.
Tetra isopropyl titanate is a valuable tool in research and development for exploring new materials and synthesizing compounds with specific properties.

Applications of Tetra isopropyl titanate:
Tetra isopropyl titanate can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.

Tetra isopropyl titanate is commonly used as a precursor for the preparation of Titania (TiO2).
Novel metal oxide/phosphonate hybrids were formed from Tetra isopropyl titanate in a two-step sol-gel process.
Starting material for barium-strontium-titanate thin films.

Tetra isopropyl titanate is used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes.
Tetra isopropyl titanate is applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

Preparation of Tetra isopropyl titanate:
Tetra isopropyl titanate is prepared by treating titanium tetrachloride with isopropanol in presence of ammonia.

Hydrogen chloride is formed as a coproduct:
TiCl4 + 4 (CH3)2CHOH → Ti{OCH(CH3)2}4 + 4 HCl
Properties

Tetra isopropyl titanate reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH

This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
The composition, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.

Naming of Tetra isopropyl titanate:
Tetra isopropyl titanate is a widely used item of commerce and has acquired many names in addition to those listed in the table.
A sampling of the names include: titanium(IV) i-propoxide, isopropyl titanate, tetraisopropyl titanate, tetraisopropyl orthotitanate, titanium tetraisopropylate, orthotitanic acid tetraisopropyl ester, Isopropyl titanate(IV), titanic acid tetraisopropyl ester, isopropyltitanate, titanium(IV) isopropoxide, Tetra isopropyl titanate, iso-propyl titanate, titanium tetraisopropanolate, tetraisopropoxytitanium(IV), tetraisopropanolatotitanium, tetrakis(isopropoxy) titanium, tetrakis(isopropanolato) titanium, titanic acid isopropyl ester, titanic acid tetraisopropyl ester, titanium isopropoxide, titanium isopropylate, tetrakis(1-methylethoxy)titanium.

Handling and Storage of Tetra isopropyl titanate:

Precautions for safe handling:

Advice on safe handling:
Work under hood.
Do not inhale substance/mixture.
Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion:
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures:
Change contaminated clothing. Wash hands after working with substance.

Conditions for safe storage, including any incompatibilities

Storage conditions:
Handle under nitrogen, protect from moisture.
Store under nitrogen.

Keep container tightly closed in a dry and well-ventilated place.
Keep away from heat and sources of ignition.
Hydrolyzes readily.

Storage class:
Storage class (TRGS 510): 3: Flammable liquids

Stability and Reactivity of Tetra isopropyl titanate:

Reactivity:
Vapor/air-mixtures are explosive at intense warming.

Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
May decompose on exposure to moist air or water.

Possibility of hazardous reactions:
No data available

Conditions to avoid:
Heating.

Incompatible materials:
Strong oxidizing agents, Strong acids

Safety Profile of Tetra isopropyl titanate:
Tetra isopropyl titanate is flammable.
Tetra isopropyl titanate should be stored away from open flames, sparks, and heat sources.
Adequate ventilation is essential to prevent the accumulation of flammable vapors.

Tetra isopropyl titanate reacts violently with water, releasing flammable gases.
Tetra isopropyl titanate should be kept away from moisture, and contact with water or humid conditions should be avoided.
Tetra isopropyl titanate is corrosive to metals.

Tetra isopropyl titanate can cause corrosion and damage to certain materials.
Tetra isopropyl titanatecan cause irritation to the skin and eyes.
Protective equipment, such as gloves and safety goggles, should be worn when handling the compound.

First aid measures of Tetra isopropyl titanate:

General advice:
Show this material safety data sheet to the doctor in attendance.

If inhaled:

After inhalation:
Fresh air.
Call in physician.

In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.

In case of eye contact:

After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.

If swallowed:

After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.

Indication of any immediate medical attention and special treatment needed:
No data available

Firefighting Measures of Tetra isopropyl titanate:

Suitable extinguishing media:
Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture:
Carbon oxides
Titanium/titanium oxides

Flash back possible over considerable distance.
Container explosion may occur under fire conditions.
Combustible.

Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.

Advice for firefighters:
In the event of fire, wear self-contained breathing apparatus.

Further information:
Remove container from danger zone and cool with water.
Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental Release Measures of Tetra isopropyl titanate:

Personal precautions, protective equipment and emergency procedures:

Advice for non-emergency personnel:
Do not breathe vapors, aerosols.
Avoid substance contact.

Ensure adequate ventilation.
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions:
Do not let product enter drains.
Risk of explosion.

Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills. Observe possible material restrictions.

Take up with liquid-absorbent material (e.g. Chemizorb).
Dispose of properly.
Clean up affected area.

Identifiers of Tetra isopropyl titanate:
CAS Number: 546-68-9
ChEBI: CHEBI:139496
ChemSpider: 21106214
ECHA InfoCard: 100.008.100
EC Number: 208-909-6
PubChem CID: 11026
UNII: 76NX7K235Y
UN number: 1993
CompTox Dashboard (EPA): DTXSID5027196
InChIKey: VXUYXOFXAQZZMF-UHFFFAOYSA-N
InChI=1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
SMILES: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

Synonym(s): TTIP, Tetraisopropyl orthotitanate
Linear Formula: Ti[OCH(CH3)2]4
CAS Number: 546-68-9
Molecular Weight: 284.22
Beilstein: 3679474
EC Number: 208-909-6
MDL number: MFCD00008871
PubChem Substance ID: 24852318
NACRES: NA.22

Properties of Tetra isopropyl titanate:
Chemical formula: C12H28O4Ti
Molar mass: 284.219 g·mol−1
Appearance: colorless to light-yellow liquid
Density: 0.96 g/cm3
Melting point: 17 °C (63 °F; 290 K) approximation
Boiling point: 232 °C (450 °F; 505 K)
Solubility in water: Reacts to form TiO2
Solubility: soluble in ethanol, ether, benzene, chloroform
Refractive index (nD): 1.46

Quality Level: 200
Assay: 97%
form: liquid

reaction suitability:
core: titanium
reagent type: catalyst

refractive index: n20/D 1.464 (lit.)
bp: 232 °C (lit.)
mp: 14-17 °C (lit.)
density: 0.96 g/mL at 20 °C (lit.)
SMILES string: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
InChI: 1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChI key: VXUYXOFXAQZZMF-UHFFFAOYSA-N

Related compounds of Tetra isopropyl titanate:

Other anions:
Titanium methoxide
Titanium ethoxide
Titanium butoxide

Other cations:
Aluminium isopropoxide

Names of Tetra isopropyl titanate:

IUPAC name:
Titanium isopropoxide

Other names:
Tetraisopropyl titanate
Titanium(IV) i-propoxide
Tetra isopropyl titanate
Tetraisopropyl orthotitanate