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THIOCARBAMYL SULFENAMIDE

Acceleratorotos is an accelerator; used in preparation of a Rubber anti-fatigue agent.
Gray-white crytal powder with taste bitter. 
The density is 1.35, partly soluble in water.

CAS:    13752-51-7
MF:    C9H16N2O2S2
MW:    248.37
EINECS:    237-335-9

Synonyms: 4-[(4-Morpholinylthio)thioxomethyl]-morpholine;ACCELERATOR OTOS;CURE-RITE 18;N-OXYDIETHYLENE THIOCARBAMYL-N-OXYDIETHYLENE SULFENAMIDE;morpholin-4-yl morpholine-4-carbodithioate;4-((4-morpholinylthio)thioxomethyl)-morpholin;4-((morpholinothiocarbonyl)thio)-morpholin;4-((morpholinothiocarbonyl)thio)morpholine

Thiocarbamyl Sulfenamide is a morpholin-4-yl morpholine-4-carbodithioate.
Acts as a vulcanization accelerator. 
Thiocarbamyl Sulfenamide contains 20 wt% polymer binder and dispersing agent. 
Thiocarbamyl Sulfenamide is an activator which has great activity above 149°C for high temperature vulcanization. 
Thiocarbamyl Sulfenamide is a fast vulcanization rate and long scorching time accelerator for NR, BR, SBR, NBR, etc and its vulcanizate has excellent properties such as high tensile strength, small permanent deformation, low compression heat, good elasticity. 
Thiocarbamyl Sulfenamide has excellent vulcanization reversion resistance for high temperature vulcanization of NR. 
Combination with benzothiazoles or sulfonamides accelerators can lead to a remarkable synergistic effect and reduce total dosage of accelerators significantly to reduce the cost of rubber mixing. 
Thiocarbamyl Sulfenamide is a sulfur donor in effective or ineffective vulcanization system. Used in rubber products.

Thiocarbamyl Sulfenamide Chemical Properties
Melting point: 139 °C
Boiling point: 378.1±52.0 °C(Predicted)
density: 1.2971 (rough estimate)
vapor pressure: 0.001Pa at 25℃
refractive index: 1.6800 (estimate)
pka: 1.08±0.20(Predicted)
Water Solubility: 127mg/L at 20℃
LogP: 1.65
EPA Substance Registry System: Thiocarbamyl Sulfenamide (13752-51-7)

Uses
Thiocarbamyl Sulfenamide is a primary accelerator for NR,SBR,EPDM etc. 
Thiocarbamyl Sulfenamide is a vulcanizing agent and delayed accelerator, and has better scorch safety than MBD. 
Thiocarbamyl Sulfenamide's critical temperature is 149οC.

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