Titanium tetraisopropoxide, a highly reactive organic titanate, finds extensive use as a catalyst in various chemical processes, such as esterification reactions, transesterification, and as a crosslinking agent, particularly in industries like plastics, coatings, and polymer production.
Titanium tetraisopropoxide is a diamagnetic tetrahedral molecule and a key component in the Sharpless epoxidation method for synthesizing chiral epoxides, showcasing its significance in organic synthesis and materials science applications.
Titanium tetraisopropoxide's reactivity with hydroxyl-containing compounds makes valuable in bonding processes and surface modification applications, although precautions must be taken due to its sensitivity to moisture.
CAS Number: 546-68-9
EC Number: 208-909-6
Molecular Formula: C12H28O4Ti
Molecular Weight: 284.22
Synonyms: Titanium tetraisopropanolate, 546-68-9, Titanium(IV) isopropoxide, Titanium isopropoxide, Tetraisopropyl orthotitanate, Titanium tetraisopropoxide, Titanium isopropylate, Titanium tetraisopropylate, Tilcom TIPT, Ti Isopropylate, Tetraisopropoxytitanium(IV), Isopropyl orthotitanate, Tetraisopropoxytitanium, Tetraisopropanolatotitanium, TETRAISOPROPYL TITANATE, A 1 (titanate), Orgatix TA 10, Tetrakis(isopropoxy)titanium, Isopropyl titanate(IV), Tyzor TPT, Isopropyl Titanate, Propan-2-olate;titanium(4+), TTIP, Tetraisopropoxide titanium, Titanium tetra-n-propoxide, Titanium(4+) isopropoxide, Titanic acid isopropyl ester, Titanium, tetrakis(1-methylethoxy)-, Titanium(IV) i-propoxide, Isopropyl alcohol, titanium(4+) salt, Titanium tetrakis(isopropoxide), Isopropyl titanate(IV) ((C3H7O)4Ti), Titanium(IV)tetraisopropoxide, 2-Propanol, titanium(4+) salt, Titanium(IV) propan-2-olate, 2-Propanol, titanium(4+) salt (4:1), Titanium(IV) Tetraisopoxide, Isopropyl alcohol titanium(4+) salt, 76NX7K235Y, Titanium tetra(isopropoxide), MFCD00008871, Tetrakis(propan-2-yloxy)titanium, Titanium isopropylate (VAN), TITANIUM (IV) ISOPROPOXIDE, HSDB 848, Tetraksi(isopropanolato)titanium, NSC-60576, Isopropyl alcohol, titanium salt, Titanic acid tetraisopropyl ester, Titanium isopropoxide (Ti(OC3H7)4), EINECS 208-909-6, Titanium isopropoxide (Ti(OCH7)4), NSC 60576, Titanic(IV) acid, tetraisopropyl ester, C12H28O4Ti, UNII-76NX7K235Y, TIPT, Ti(OiPr)4, Tetraisopropoxy titanium, Tetraisopropoxy-titanium, Titaniumtetraisopropoxide, Titaniumtetraisopropylate, Titanium(IV)isopropoxide, Tetra-isopropoxy titanium, Titanium (IV)isopropoxide, Tetra-iso-propoxy titanium, Titanium tetra-isopropoxide, Titanium-tetra-isopropoxide, EC 208-909-6, Titanium (4+) isopropoxide, VERTEC XL 110, Tetraisopropoxytitanium (IV), Titanium tetra (isopropoxide), Titanium (IV)tetraisopropoxide, Titanium (IV) tetraisopropoxide, TITANUM-(IV)-ISOPROPOXIDE, CHEBI:139496, AKOS015892702, TITANIUM TETRAISOPROPOXIDE [MI], Titanium(4+) tetrakis(propan-2-olate), TITANIUM TETRAISOPROPANOLATE [HSDB], T0133, Q2031021.
Titanium tetraisopropoxide belongs to the product group of organic titanates, which are known to be highly reactive organics that can be used in a broad range of processes and applications.
Titanium tetraisopropoxide is a colorless, slighty yellowish liquid that is very sensitive to moisture.
Titanium tetraisopropoxide is an organic titanate that has a wide range of applications across several industries.
Titanium tetraisopropoxide can be used as an esterification catalyst for plasticizers, polyesters, methacrylic esters, resins, polycarbonates, polyolefins and RTV silicone sealants.
Titanium tetraisopropoxide can also be used for coating chemicals as a cross linker for wire enamel varnish, glass and zinc flake coatings.
Titanium tetraisopropoxide is most suitable for use in the glass and glass fiber manufacturing. TIPA may be used as an adhesion promoter for packaging ink such as flexo and gravure.
Titanium tetraisopropoxide, is a chemical compound with the formula Ti{OCH(CH3)2}4.
This alkoxide of titanium(IV) is used in organic synthesis and materials science.
Titanium tetraisopropoxide is a diamagnetic tetrahedral molecule.
Titanium tetraisopropoxide is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.
The structures of the Titanium tetraisopropoxides are often complex.
Crystalline titanium methoxide is tetrameric with the molecular formula Ti4(OCH3)16.
Alkoxides derived from bulkier alcohols such as isopropyl alcohol aggregate less.
Titanium tetraisopropoxide is mainly a monomer in nonpolar solvents.
Titanium tetraisopropoxide is a titanium alkoxide, specifically a tetraalkoxy derivative of titanium.
Titanium tetraisopropoxide is commonly used as a precursor or catalyst in various chemical processes, including the synthesis of organic and inorganic materials.
The "tetraisopropyl" part of the name indicates that there are four isopropyl (C3H7) groups bonded to the titanium atom.
Titanium tetraisopropoxide is often employed in the preparation of sol-gel derived materials, coatings, and as a crosslinking agent in the production of polymers.
Titanium tetraisopropoxide is reactivity with hydroxyl-containing compounds makes it useful in bonding processes and surface modification applications.
As with many titanium alkoxides, Titanium tetraisopropoxide is sensitive to moisture, and precautions are often taken to handle it under dry conditions.
Titanium tetraisopropoxide appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol.
Titanium tetraisopropoxide, vapors heavier than air.
Titanium tetraisopropoxide is used in organic synthesis and materials science.
Titanium tetraisopropoxide is a diamagnetic tetrahedral molecule.
Titanium tetraisopropoxide, about the same density as water.
The structures of the Titanium tetraisopropoxide are often complex.
Crystalline Titanium tetraisopropoxide is tetrameric with the molecular formula Ti4(OCH3)16.
Alkoxides derived from bulkier alcohols such as Titanium tetraisopropoxide aggregate less.
Titanium tetraisopropoxide is mainly a monomer in nonpolar solvents.
Titanium tetraisopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.
Titanium tetraisopropoxide is a widely used item of commerce and has acquired many names in addition to those listed in the table.
Titanium tetraisopropoxide belongs to the product group of organic titanates, which are known to be highly reactive organics that can be used in a broad range of processes and applications.
Titanium tetraisopropoxide a colorless, slighty yellowish liquid that is very sensitive to moisture.
Titanium tetraisopropoxide has a complex structure.
Titanium tetraisopropoxide, also commonly referred to as Tetra isopropyl titanate or is a chemical compound with the formula Ti{OCH(CH3)2}4.
Titanium tetraisopropoxide is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.
In crystalline state, Titanium tetraisopropoxide is a tetramer.
Non-polymerized in non-polar solvents,Titanium tetraisopropoxide is a tetrahedral diamagnetic molecule.
Titanium tetraisopropoxide, also known as titanium isopropoxide, Tetra isopropyl titanate is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Titanium tetraisopropoxide has a complex structure.
In crystalline state, Titanium tetraisopropoxide is a tetramer.
Non-polymerized in non-polar solvents, Titanium tetraisopropoxide is a tetrahedral diamagnetic molecule.
Titanium tetraisopropoxide is an intermediate derived from titanium.
Titanium tetraisopropoxide appears as a light yellow, transparent liquid.
Titanium tetraisopropoxide can be used as a catalyst additive in coating primers or added to that formulation as an adhesion promoter.
Titanium tetraisopropoxide is a type of very lively primary alcohol titanium oxide; it hydrolyzes when contacted with moisture in air.
Titanium tetraisopropoxide is mainly used as catalyst in esterification reaction or transesterification,also being used as catalyst of polyolefin.
Titanium tetraisopropoxide can be used to improve the adherence and crosslinking of resin having alcohol group or carboxyl group, used in heat resistant and corrosion resistant coating.
Titanium tetraisopropoxide also can be used in the manufacture of glass and glass fiber.
Titanium tetraisopropoxide can only be used in oil system.
Titanium tetraisopropoxide is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Titanium tetraisopropoxide is a 100% active tetra-isopropyl titanate in liquid form.
Titanium tetraisopropoxide is typically used as a metal catalyst in producing polyolefins and polycarbonate.
Titanium tetraisopropoxide improves the yield of olefin polymerization, esterification, condensation, and addition reactions while eliminating unwanted byproducts.
Compared to other Titanium tetraisopropoxide, Tetraisopropyl titanate is highly moisture sensitive and will decompose when exposed to water.
Titanium tetraisopropoxide is useful as a replacement for tin, organostannanes, and sulfuric acid in esterification reactions when toxicity reduction is desired.
Titanium tetraisopropoxide is even more efficient than sulfuric acid in esterification reactions.
When added to solvent-based paints, Titanium tetraisopropoxide will cross-link hydroxyl and carboxyl functional polymers to increase chemical and heat resistance.
Titanium tetraisopropoxide is also used as a catalyst in the preparation of certain cyclopropanes in the Kulinkovich reaction.
Prochiral thioethers are oxidized enantioselectively using a catalyst derived from Ti(O-i-Pr)4.
Titanium tetraisopropoxide reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH
This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
Titanium tetraisopropoxide, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.
Titanium tetraisopropoxide, isopropyl alcohol and liquid ammonia are esterified in toluene, absorbed and filtered to remove by-product ammonium chloride, and then distilled to obtain the finished product.
Raw material consumption (kg/t) toluene (98%) 1000 titanium tetrachloride (99%) 1500 isopropanol (98%) 1600 liquid ammonia 1400
Titanium tetraisopropoxide will be easily ignited by heat, sparks or flames.
Titanium tetraisopropoxide vapors may form explosive mixtures with air.
Titanium tetraisopropoxide vapors may travel to source of ignition and flash back.
Titanium tetraisopropoxide vapors are heavier than air.
Titanium tetraisopropoxide will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
Titanium tetraisopropoxide vapor explosion hazard indoors, outdoors or in sewers.
Titanium tetraisopropoxide designated with a may polymerize explosively when heated or involved in a fire.
Titanium tetraisopropoxide runoff to sewer may create fire or explosion hazard.
Titanium tetraisopropoxide containers may explode when heated.
Titanium tetraisopropoxide many liquids will float on water.
Metal alkyls, such as Titanium tetraisopropoxide, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones.
Titanium tetraisopropoxide, they are likely to ignite on contact with alcohols.
Titanium tetraisopropoxide is highly flammable.
Titanium tetraisopropoxide fumes in air. Soluble in water.
Titanium tetraisopropoxide decomposes rapidly in water to form flammable isopropyl alcohol.
Uses of Titanium Tetraisopropoxide:
Titanium tetraisopropoxide is widely used in sol-gel processing, a method for producing ceramics and thin films.
Titanium tetraisopropoxide is a precursor in the formation of titanium dioxide (TiO2) thin films, which find applications in optical coatings, sensors, and photovoltaic devices.
Titanium tetraisopropoxide can be used as a crosslinking agent in the production of polymers.
Titanium tetraisopropoxide reacts with polymers containing hydroxyl groups, contributing to the crosslinking of the polymer chains.
This enhances the mechanical and thermal properties of the polymers.
Titanium tetraisopropoxide is employed as an adhesion promoter in coatings and adhesives.
Titanium tetraisopropoxide helps improve the adhesion of coatings to various substrates, such as metals, glass, and ceramics.
Titanium tetraisopropoxide is used for surface modification of materials, particularly in the development of functionalized surfaces with improved properties.
This can be relevant in areas like biomaterials and catalysis.
Titanium tetraisopropoxide is sometimes used as a catalyst or a component in catalyst formulations, especially in reactions involving transesterification or esterification processes.
Titanium tetraisopropoxide serves as a reagent in various chemical synthesis processes, contributing to the formation of new compounds.
In the rubber industry, Titanium tetraisopropoxide can be used as a crosslinking agent for elastomers, contributing to improved mechanical properties and stability.
Titanium tetraisopropoxide can be used as a photocatalyst in environmental applications, such as air and water purification.
Titanium tetraisopropoxide can also be used as surface modifier, adhesion promoter and paraffin and oil additives.
Titanium tetraisopropoxide for ester exchange reaction.
Titanium tetraisopropoxide used as an auxiliary agent and chemical product intermediate.
Titanium tetraisopropoxide used to make adhesives, used as a catalyst for transesterification and polymerization reactions.
Binders for preparing metals and rubber, metals and plastics, also used as catalysts for transesterification and polymerization reactions and raw materials for the pharmaceutical industry.
Titanium tetraisopropoxide for esterification reaction, transesterification reaction of acrylic acid and other esters.
Titanium tetraisopropoxide in polymerization reactions such as epoxy resin, phenolic plastic, silicone resin, polybutadiene, etc., it has high stereoselectivity.
Titanium tetraisopropoxide, a variety of polymers or resins play a cross-linking role, improve the anti-corrosion ability of the coating, etc., and also promote the adhesion of the coating to the surface.
Titanium tetraisopropoxide can be directly used as material surface modifier, adhesive promoter.
Titanium tetraisopropoxide especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2.
Titanium tetraisopropoxide complexing agent in sol-gel process.
Titanium tetraisopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films.
Titanium tetraisopropoxide is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes.
Titanium tetraisopropoxide is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides.
Titanium tetraisopropoxide is involved as a catalyst in the preparation of cyclopropanes.
Titanium tetraisopropoxide can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Titanium tetraisopropoxide is used in the following products: pH regulators and water treatment products, laboratory chemicals and water treatment chemicals.
Titanium tetraisopropoxide is used in the following areas: health services and scientific research and development.
Titanium tetraisopropoxide is used for the manufacture of: Chemicals.
Release to the environment of Titanium tetraisopropoxide can occur from industrial use: manufacturing of the substance.
Other release to the environment of Titanium tetraisopropoxide is likely to occur from : İndoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).
Titanium tetraisopropoxide is used in the following products: polymers, fuels, coating products, lubricants and greases, pH regulators and water treatment products and laboratory chemicals.
Titanium tetraisopropoxide has an industrial use resulting in manufacture of another substance.
Titanium tetraisopropoxide is used in the following areas: health services and scientific research and development.
Titanium tetraisopropoxide is used for the manufacture of: chemicals and plastic products.
Release to the environment of Titanium tetraisopropoxide can occur from industrial use: as processing aid, as an intermediate step in further manufacturing of another substance (use of intermediates), of substances in closed systems with minimal release and in processing aids at industrial sites.
Titanium tetraisopropoxide for the esterification reaction is used for the transesterification reaction of esters such as acrylic acid and the polymerization of epoxy resin, phenolic plastic, silicone resin, polybutadiene, PP and PE.
Titanium tetraisopropoxide can also be used as raw materials for the pharmaceutical industry and the preparation of metal and rubber, metal and plastic adhesives.
Titanium tetraisopropoxide for the Sharpless asymmetric epoxidation reaction of allyl alcohol; as a Titanium tetraisopropoxide for transesterification reaction with various alcohols under neutral conditions; titanium tetraisopropoxide can be formed by a sol-gel two-step method New metal oxide/phosphonate hybrid; used as a raw material for barium strontium titanate film; used to prepare porous titanosilicate, which is a potential ion exchange material for removing radioactive waste; Tetraisopropyl titanateis used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes.
Titanium tetraisopropoxide has been proved that it can undergo light-induced electron transfer
Titanium tetraisopropoxide is mainly used for transesterification and condensation reactions in organic synthesis Catalyst.
Titanium tetraisopropoxide is often used as a precursor to prepare titanium dioxide (TiO2).
A new metal oxide/phosphonate hybrid can be formed from Titanium tetraisopropoxide by sol-gel two-step method.
The raw material of barium strontium Titanium tetraisopropoxide film.
Titanium tetraisopropoxide is used to prepare porous titanosilicates, which are potential ion exchange materials for the removal of radioactive wastes.
Titanium tetraisopropoxide is used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes, which have been shown to be capable of light-induced electron transfer.
Titanium tetraisopropoxide can be used directly or in directly as a catalyst or catlyst additive,as a coating primer or added to formulation as a adhesion promoter and as the base material in the formation fo sol-get systems or nanoparticle systems or products.
Titanium tetraisopropoxide can be used as sharpless oxidation catalyst.
Titanium tetraisopropoxide can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Titanium tetraisopropoxide is used in the formulation of coatings and paints.
Titanium tetraisopropoxide can contribute to improved adhesion, durability, and weather resistance of the coatings.
In the ceramics industry, Titanium tetraisopropoxide is utilized as a precursor for the synthesis of ceramic materials, including ceramics used in electronic components.
Titanium tetraisopropoxide can be employed in glass manufacturing processes, contributing to the improvement of certain properties of glass, such as hardness and scratch resistance.
Titanium tetraisopropoxide has been investigated for its potential use in fuel cell applications.
Titanium tetraisopropoxide can be part of the fabrication process for materials used in fuel cell technologies.
The hydrophobic nature of Titanium tetraisopropoxide-derived coatings makes them suitable for applications where water repellency is desired, such as in self-cleaning surfaces or anti-fog coatings.
Titanium tetraisopropoxide is sometimes used in the formulation of coatings designed to provide corrosion resistance to metal surfaces.
Titanium tetraisopropoxide can be used as a modifier to impart certain properties to fabrics, such as water repellency or flame retardancy.
Titanium tetraisopropoxide has been explored for use in antimicrobial coatings, which can find applications in healthcare settings and other areas where bacterial resistance is a concern.
Titanium tetraisopropoxide is employed in the production of thin films for electronic devices, such as semiconductors and sensors.
Titanium tetraisopropoxide-derived materials are used in the production of thin films for photovoltaic devices, contributing to the development of solar cells.
Titanium tetraisopropoxide can be used as a bonding agent, improving the performance and durability of adhesives.
Titanium tetraisopropoxide is a valuable tool in research and development for exploring new materials and synthesizing compounds with specific properties.
Applications of Titanium Tetraisopropoxide:
Titanium tetraisopropoxide can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Titanium tetraisopropoxide is commonly used as a precursor for the preparation of Titania (TiO2).
Novel metal oxide/phosphonate hybrids were formed from Titanium tetraisopropoxide in a two-step sol-gel process.
Starting material for barium-strontium-titanate thin films.
Titanium tetraisopropoxide is used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes.
Titanium tetraisopropoxide is applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.
Preparation of Titanium Tetraisopropoxide:
Titanium tetraisopropoxide is prepared by treating titanium tetrachloride with isopropanol in presence of ammonia.
Hydrogen chloride is formed as a coproduct:
TiCl4 + 4 (CH3)2CHOH → Ti{OCH(CH3)2}4 + 4 HCl
Properties
Titanium tetraisopropoxide reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH
This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
The composition, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.
Titanium tetraisopropoxide is also used as a catalyst in the preparation of certain cyclopropanes in the Kulinkovich reaction.
Prochiral thioethers are oxidized enantioselectively using a catalyst derived from Ti(O-i-Pr)4.
Naming of Titanium Tetraisopropoxide:
Titanium tetraisopropoxide is a widely used item of commerce and has acquired many names in addition to those listed in the table.
A sampling of the names include: titanium(IV) i-propoxide, isopropyl titanate, tetraisopropyl titanate, tetraisopropyl orthotitanate, titanium tetraisopropylate, orthotitanic acid tetraisopropyl ester, Isopropyl titanate(IV), titanic acid tetraisopropyl ester, isopropyltitanate, titanium(IV) isopropoxide, titanium tetraisopropoxide, iso-propyl titanate, titanium tetraisopropanolate, tetraisopropoxytitanium(IV), tetraisopropanolatotitanium, tetrakis(isopropoxy) titanium, tetrakis(isopropanolato) titanium, titanic acid isopropyl ester, titanic acid tetraisopropyl ester, titanium isopropoxide, titanium isopropylate, tetrakis(1-methylethoxy)titanium.
Handling and Storage of Titanium Tetraisopropoxide:
Precautions for safe handling:
Advice on safe handling:
Work under hood.
Do not inhale substance/mixture.
Avoid generation of vapours/aerosols.
Advice on protection against fire and explosion:
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Hygiene measures:
Change contaminated clothing. Wash hands after working with substance.
Conditions for safe storage, including any incompatibilities
Storage conditions:
Handle under nitrogen, protect from moisture.
Store under nitrogen.
Keep container tightly closed in a dry and well-ventilated place.
Keep away from heat and sources of ignition.
Hydrolyzes readily.
Storage class:
Storage class (TRGS 510): 3: Flammable liquids
Stability and Reactivity of Titanium Tetraisopropoxide:
Reactivity:
Vapor/air-mixtures are explosive at intense warming.
Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
May decompose on exposure to moist air or water.
Possibility of hazardous reactions:
No data available
Conditions to avoid:
Heating.
Incompatible materials:
Strong oxidizing agents, Strong acids
Safety Profile of Titanium Tetraisopropoxide:
Titanium tetraisopropoxide is flammable.
Titanium tetraisopropoxide should be stored away from open flames, sparks, and heat sources.
Adequate ventilation is essential to prevent the accumulation of flammable vapors.
Titanium tetraisopropoxide reacts violently with water, releasing flammable gases.
Titanium tetraisopropoxide should be kept away from moisture, and contact with water or humid conditions should be avoided.
Titanium tetraisopropoxide is corrosive to metals.
Titanium tetraisopropoxide can cause corrosion and damage to certain materials.
Titanium tetraisopropoxidecan cause irritation to the skin and eyes.
Protective equipment, such as gloves and safety goggles, should be worn when handling the compound.
First aid measures of Titanium Tetraisopropoxide:
General advice:
Show this material safety data sheet to the doctor in attendance.
If inhaled:
After inhalation:
Fresh air.
Call in physician.
In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
Indication of any immediate medical attention and special treatment needed:
No data available
Firefighting Measures of Titanium Tetraisopropoxide:
Suitable extinguishing media:
Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture:
Carbon oxides
Titanium/titanium oxides
Flash back possible over considerable distance.
Container explosion may occur under fire conditions.
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
Advice for firefighters:
In the event of fire, wear self-contained breathing apparatus.
Further information:
Remove container from danger zone and cool with water.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Accidental Release Measures of Titanium Tetraisopropoxide:
Personal precautions, protective equipment and emergency procedures:
Advice for non-emergency personnel:
Do not breathe vapors, aerosols.
Avoid substance contact.
Ensure adequate ventilation.
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
Environmental precautions:
Do not let product enter drains.
Risk of explosion.
Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills. Observe possible material restrictions.
Take up with liquid-absorbent material (e.g. Chemizorb).
Dispose of properly.
Clean up affected area.
Identifiers of Titanium Tetraisopropoxide:
CAS Number: 546-68-9
ChEBI: CHEBI:139496
ChemSpider: 21106214
ECHA InfoCard: 100.008.100
EC Number: 208-909-6
PubChem CID: 11026
UNII: 76NX7K235Y
UN number: 1993
CompTox Dashboard (EPA): DTXSID5027196
InChIKey: VXUYXOFXAQZZMF-UHFFFAOYSA-N
InChI=1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
SMILES: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
Synonym(s): TTIP, Tetraisopropyl orthotitanate
Linear Formula: Ti[OCH(CH3)2]4
CAS Number: 546-68-9
Molecular Weight: 284.22
Beilstein: 3679474
EC Number: 208-909-6
MDL number: MFCD00008871
PubChem Substance ID: 24852318
NACRES: NA.22
Properties of Titanium Tetraisopropoxide:
Chemical formula: C12H28O4Ti
Molar mass: 284.219 g·mol−1
Appearance: colorless to light-yellow liquid
Density: 0.96 g/cm3
Melting point: 17 °C (63 °F; 290 K) approximation
Boiling point: 232 °C (450 °F; 505 K)
Solubility in water: Reacts to form TiO2
Solubility: soluble in ethanol, ether, benzene, chloroform
Refractive index (nD): 1.46
Quality Level: 200
Assay: 97%
form: liquid
reaction suitability:
core: titanium
reagent type: catalyst
refractive index: n20/D 1.464 (lit.)
bp: 232 °C (lit.)
mp: 14-17 °C (lit.)
density: 0.96 g/mL at 20 °C (lit.)
SMILES string: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
InChI: 1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChI key: VXUYXOFXAQZZMF-UHFFFAOYSA-N
Related compounds of Titanium Tetraisopropoxide:
Other anions:
Titanium methoxide
Titanium ethoxide
Titanium butoxide
Other cations:
Aluminium isopropoxide
Names of Titanium Tetraisopropoxide:
IUPAC name:
Titanium isopropoxide
Other names:
Tetraisopropyl titanate
Titanium(IV) i-propoxide
Titanium tetraisopropoxide
Tetraisopropyl orthotitanate