PRODUCTS

TREGDMA (TRIETHYLENE GLYCOL DIMETHACRYLATE)

CAS Number: 109-16-0
EC Number: 203-652-6
MDL number: MFCD00008591
Molecular Formula: CH2=C(CH3)COO(CH2CH2O)3COC(CH3)=CH2 / C14H22O6

TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a hydrophilic difunctional methacrylic monomer.
TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a monomer that belongs to the group of triethylene glycols.

TREGDMA (Tri Ethylene Glycol Di Methacrylate) forms homopolymers and copolymers which can be prepared with acrylic acid and its salts, amides and esters, and with methacrylates, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, unsaturated polyesters and drying oils, etc.

TREGDMA (Tri Ethylene Glycol Di Methacrylate) is also a very useful feedstock for chemical syntheses, because TREGDMA (Tri Ethylene Glycol Di Methacrylate) readily undergoes addition reactions with a wide variety of organic and inorganic compounds.

Imparts adhesion, weather resistance, high crosslink density, flexibility, improved impact resistance, hydrophilicity, heat resistance and abrasion resistance properties to polymer.
TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a hydrophilic, low viscosity, difunctional methacrylic monomer employed as a crosslinking agent.

TREGDMA (Tri Ethylene Glycol Di Methacrylate), also known as triethylene glycoldimethacrylate or TEGDMA, belongs to the class of organic compounds known as dicarboxylic acids and derivatives.

These are organic compounds containing exactly two carboxylic acid groups.
Based on a literature review very few articles have been published on TREGDMA (Tri Ethylene Glycol Di Methacrylate).

TREGDMA (Tri Ethylene Glycol Di Methacrylate) can be analyzed by this reverse phase (RP) HPLC method with simple conditions.
The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid.
For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid.

Smaller 3 µm particles columns available for fast UPLC applications.
This liquid chromatography method is scalable and can be used for isolation impurities in preparative separation.

TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a difunctional monomer that has been the foundation of many long-standing dental formulations.
TREGDMA (Tri Ethylene Glycol Di Methacrylate) has ideal water absorptivity and stability properties.

USES and APPLICATIONS of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Cosmetic Uses: nail conditioning
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is used as a cross-linking agent in the synthesis of poly (methacrylic acid-g-ethylene glycol) hydrogels which shows large changes in swelling due to changes in pH, temperature and solvent composition.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is also used as divinylic methacrylic monomers which are widely used to form copolymers with divinylbenzene (DVB) and glycidyl methacrylate (GMA) or hydroxyethyl methacrylate (HEMA) comonomers.

-As a monomer, TREGDMA (Tri Ethylene Glycol Di Methacrylate) is typically used in dental resin materials that can cause specific stress responses in eukaryotic cells.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) commonly used to aesthetically restore the structure and function of teeth impaired by caries, erosion, or fracture.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is also used as a diluent co-monomer in dimethacrylate based dental composites as well as being used as a branching agent in the atom transfer radical polymerization (ATRP) of styrene.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a resin monomer widely used in the composition of dentin bonding agents and composite resins to restore teeth structures impaired by caries and/or fractures.

-Esters of acrylic acid and methacrylic acid, more commonly known as acrylates and methacrylates are key raw materials in the coatings and printing industry, and in food packaging.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a methacrylic monomer for use as cross-linking agent for adhesives and dental restorative materials.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a monomer typically used in dental resin materials that can cause specific stress responses in eukaryotic cells.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) also suitable for pharmacokinetics.
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a hydrophilic, low viscosity, difunctional methacrylic monomer employed as a crosslinking agent.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) was employed to optimize the dilution of high-viscosity monomers and to link together the macromolecules constituting the polymer, to make their three-dimentional structure more rigid.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is also a crosslinking agent of acrylic resins, used in sealents or in dental bonding resins.
These are mainly used in dentistry, by dental technicians and dentists.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a monomer typically used in dental resin materials that can cause specific stress responses in eukaryotic cells.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a hydrophilic, low viscosity, difunctional methacrylic monomer employed as a crosslinking agent.

-Crosslinking agent for hard contact lenses, dental materials, thermoset and UV curable acrylics and vinyls.
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is used in dentistry as an agent that inhibits water vapor, and TREGDMA (Tri Ethylene Glycol Di Methacrylate) is also found in some metal chelates.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate), also known as Triglycol or TEG, is used as a plasticizer for vinyl, as a liquid desiccant for natural gas, and in air conditioning systems; TREGDMA (Tri Ethylene Glycol Di Methacrylate) belongs to a homologous series of dihydroxy alcohols.

-Ungraded products supplied by Spectrum are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for human consumption or therapeutic use.
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is ideal colorant for dyeing polyester filament and staple fiber before spinning.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a co-monomer used to regulate the viscosity of resin-based dental materials.
Resin-based dental materials; TREGDMA (Tri Ethylene Glycol Di Methacrylate) can release their parts into the biological environment as a result of dissolution, erosion or destruction.
Significant amounts of TEGDMA can be released from polymerized dental materials.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a co-monomer that has been generally used to dilute viscous polymers (like Bis-GMA) to obtain suitable viscosities for dental applications.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is a common component of the bonding agents and resin composites used in dentistry for restorative dentistry.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is mainly used as the crosslinking agent, dental materials, optical materials, rubber, adhesives modified, leather processing, paper processing AIDS, etc.
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is often found in dental composite materials such as sealants and fillings.

-TREGDMA (Tri Ethylene Glycol Di Methacrylate) is an important multifunctional monomer,mainly used in the fields of acrylic resin,printing ink,anaerobic adhesives,elastomer,sealant,photosensitive macromolecule,plastic and paper coating.
-TREGDMA (Tri Ethylene Glycol Di Methacrylate) can also increase the rigidity of PVC.

ALTERNATIVE PARENTS of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
*Enoate esters
*Dialkyl ethers
*Organic oxides
*Hydrocarbon derivatives
*Carbonyl compounds

SUBSTITUENTS of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
*Dicarboxylic acid or derivatives
*Alpha,beta-unsaturated carboxylic ester
*Enoate ester
*Carboxylic acid ester
*Ether
*Dialkyl ether

*Organic oxygen compound
*Organic oxide
*Hydrocarbon derivative
*Organooxygen compound
*Carbonyl group
*Aliphatic acyclic compound

PHYSICAL and CHEMICAL PROPERTIES of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
Molecular Weight: 286.32
Appearance Form: liquid
Color: light yellow
Odor: ester-like
Odor Threshold: No data available
pH: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: 170 - 172 °C at 7 hPa - lit.
Flash point: 167 °C - closed cup
Evaporation rate: No data available

Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Vapor pressure: No data available
Vapor density: No data available
Relative density: No data available
Water solubility: 3,6 g/l at 20 °C - OECD Test Guideline 105- soluble
Partition coefficient: n-octanol/water: log Pow: 2,3
Autoignition temperature: 255 °C at 1.025 hPa

Decomposition temperature: No data available
Viscosity
Viscosity, kinematic: 9,15 mm2/s at 20 °C
Viscosity, dynamic: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information: No data available

Molecular Weight: 286.32
XLogP3-AA: 1.6
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 13
Exact Mass: 286.14163842
Monoisotopic Mass: 286.14163842
Topological Polar Surface Area: 71.1 Å²
Heavy Atom Count: 20

Formal Charge: 0
Complexity: 314
Melting point: -52°C
Boiling point: 170-172 °C5 mm Hg(lit.)
Density: 1.092 g/mL at 25 °C(lit.)
refractive index: n20/D 1.461(lit.)
Flash point: >230 °F
Storage temp.: 2-8°C
Solubility: Chloroform, Methanol

Form: Oil
Color: Colourless to Pale Yellow
Specific Gravity: 1.092
BRN: 1797351
Stability: Light Sensitive
Physical State :Liquid
Storage :Store at 4° C
Boiling Point :170-172° C (lit.) at 5 mmHg
Density :1.09 g/mL at 25° C
Refractive Index :n20/D 1.461(lit.)

Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 1.09200 @ 25.00 °C.
Boiling Point: 335.52 °C. @ 760.00 mm Hg (est)
Flash Point: > 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 1.880
Soluble in:
water, 3600 mg/L @ 37 °C (exp)
water, 365.5 mg/L @ 25 °C (est)

FIRST AID MEASURES of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.

*If inhaled:
After inhalation:
Fresh air.

*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.

*In case of eye contact
After eye contact:
Rinse out with plenty of water.
Remove contact lenses.

*If swallowed
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.

-Indication of any immediate medical attention and special treatment needed:
No data available

ACCIDENTAL RELEASE MEASURES of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Environmental precautions:
Do not let product enter drains.

-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Extinguishing media:
--Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
--Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.

-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:

*Eye/face protection:
Use Safety glasses.

*Skin protection:
Handle with gloves.
Wash and dry hands.

Full contact:
Material: butyl-rubber
Minimum layer thickness: 0,3 mm
Break through time: 480 min

Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 30 min

*Body Protection:
protective clothing.

-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Storage stability
Recommended storage temperature: 2 - 8 °C

STABILITY and REACTIVITY of TREGDMA (TRI ETHYLENE GLYCOL DI METHACRYLATE):
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).

-Possibility of hazardous reactions:
No data available

SYNONYMS:
2-propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
TRIETHYLENE GLYCOL DIMETHACRYLATE
Tedma
NK ester 3G
Triethylene dimethacrylate
(Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
TGM 3PC
TGM 3S
TGM 3
TGM 35
Ethylenebis(oxyethylene) methacrylate
2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
Methacrylic acid, diester with triethylene glycol
UNII-14I47YJ5EY
NSC 84260
Polyester TGM-3
2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate
Triethylene glycol dimethylacrylate
1,2-Bis(2-(methacryloyloxy)ethoxy)ethane
14I47YJ5EY
1,2-Bis[2-(Methacryloyloxy)ethoxy]ethane
DSSTox_CID_9607
DSSTox_RID_78784
DSSTox_GSID_29607
Polyester TGM 3
Triethylene Glycol Dimethacrylate (stabilized with MEHQ)
2-Propenoic acid, 2-methyl-, 1,1'-[1,2-ethanediylbis(oxy-2,1-ethanediyl)] ester, homopolymer
Triethylene glycol dimethacrylate,min 95%
triethylene glycoldimethacrylate
triethyleneglycol dimethacrylate
TEGDMA
TEGMA
2,2'-Ethylenedioxydiethyl dimethacrylate
HSDB 5388
BRN 1797351
CCRIS 8224
2-Propenoic acid, 2-methyl-, 1,1'-(1,2-ethanediylbis(oxy-2,1-ethanediyl)) ester
2-Propenoic acid, 2-methyl-, 1,1'-[1,2-ethanediylbis(oxy-2,1-ethanediyl)] ester
Bisomer TEGDMA
POLYESTER RESIN
3EDMA
EC 203-652-6
SCHEMBL15258
CHEMBL3187544
DTXSID3029607
NSC84260
Tri Ethylene Glycol Di Methacrylate
ZINC3875759
Tox21_202238
Tox21_303364
MFCD00008591
NSC-84260
AKOS015913975
CS-W012220
MCULE-3222202803
s12331
NCGC00164116-01
NCGC00164116-02
NCGC00257499-01
NCGC00259787-01
LS-14338
FT-0675469
T0948
A801973
Q-201874
Q27251632
Triethylene glycol dimethacrylate(11 cp(20 degrees c))
Triethylene Glycol Dimethacrylate, (stabilized with MEHQ)
ethane-1,2-diylbis(oxyethane-2,1-diyl) bis(2-methylacrylate)
2-(2-[2-(Methacryloyloxy)ethoxy]ethoxy)ethyl 2-methylacrylate #
(Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl)bis(2-methylacrylate)
2,2'-(ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
2-methyl-2-propenoic acid 2-[2-[2-(2-methyl-1-oxoprop-2-enoxy)ethoxy]ethoxy]ethyl ester
Triethylene glycol dimethacrylate, contains 80-120 ppm MEHQ as inhibitor, 95%
Triethylene glycol dimethacrylate, contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99%
TEGDMA
TEDMA
Ethy
TRGDMA
tgm3
tgm35
tgm3s
TGM 3
TGM 35
tgm3pc
1,2-Bis[2-(methacryloyloxy)ethoxy]ethane
2,2'-Ethylendioxydiethyldimethacrylat
2,2'-Ethylenedioxydiethyl Dimethacrylate
2-Propenoic acid 2-methyl-, 1,1'-[1,2-ethanediylbis(oxy-2,1-ethanediyl)] ester
2-Propenoic acid 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
2-[2-[2-(2-Methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate
2-methyl-2-Propenoic acid 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
3,6-Dioxaoctane-1,8-diyl dimethacrylate
ATM 2 (methacrylate)
Acryester 3ED
Atm 2
Bisomer Tegdma
Blemmer PDE 150
Dimetacrilato De 2,2'-Etilendioxidietilo
Dimethacrylate De 2,2'-Ethylenedioxydiethyle
Em 328
Esschem 943X7469
Ethane-1,2-Diylbis(Oxyethane-2,1-Diyl) Bis(2-Methylprop-2-Enoate)
Ethylenebis(oxyethylene) methacrylate
Light Ester 3EG
Luvomaxx TEDMA
M 233
Methacrylic acid, diester with triethylene glycol
Methacrylic acid, ethylenebis(oxyethylene) ester
Miramer M 233
NK Ester 3G
Neomer PM 20
Neomer PM 201
New Frontier NF Bisomer TEGDMA
Newfrontier NF Bisomer TEGDMA
Nk 3G
Nsc 84260
Polyester resin
Polyglycol Dimethacrylate
Prop-2-Enoate, 2-Methyl-, 1,2-Ethanediylbis (Oxy-2,1-Ethanediyl)
Regdma
Sartomer SR 205
Sr 205
Sr 205Ns
T 0498
Tedma
Tegdma
Tgm 3
Tgm 3Pc
Tgm 3S
V 389
1,2-Bis[2-(Methacryloyloxy)ethoxy]ethane
2,2'-Ethylenedioxydiethyl dimethacrylate
2-Methyl-2-propenoic acid 2-[2-[2-(2-methyl-1-oxoprop-2-enoxy)ethoxy]ethoxy]ethyl ester
2-Methylacrylic acid 2-[2-(2-methacryloyloxyethoxy)ethoxy]ethyl ester
2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate
Ethylenebis(oxyethylene) methacrylate
Methacrylic acid, diester with triethylene glycol
NK Ester 3G
Polyester TGM-3
TEDMA
TGM 3
TGM 35
TGM 3PC
TGM 3S
Triethylene dimethacrylate
Triethylene glycol dimethacrylate
BRN 1797351
EINECS 203-652-6
HSDB 5388
NSC 84260