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Triallylamine appears as a colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.
CAS NO: 102-70-5
SYNONYM :
102-70-5; 2-Propen-1-amine, N,N-di-2-propenyl-; Tris(2-propenyl)amine; N,N-bis(prop-2-enyl)prop-2-en-1-amine; UNII-B6N19XC04R; CCRIS 4876; HSDB 2904; EINECS 203-048-2; NSC 32635; UN2610; N,N-Di-2-propenyl-2-propen-1-amine; BRN 1740881; tris (prop-2-en-1-yl) amine; AI3-52705; B6N19XC04R; 4-04-00-01061 (Beilstein Handbook Reference); MFCD00026093; 2-Propen-1-amine, N,N-di-2-propen-1-yl-; Triallyl Amine; N,N-diallylprop-2-en-1-amine; triallyl-amine; (CH2=CHCH2)3N; Triallylamine, 99%; ACMC-1BZCI; DSSTox_CID_6174; DSSTox_RID_78046; DSSTox_GSID_26174; SCHEMBL20656; KSC490G8R; CHEMBL3188834; DTXSID5026174; CTK3J0388; LS-83; KS-00000X4Y; NSC32635; ZINC1665016; Tox21_300670; ANW-14735; NSC-32635; 2-Propen-1-amine,N-di-2-propenyl; WLN: 1U2N2U1 & 2U1; AKOS015840489; UN 2610; NCGC00248135-01; NCGC0025457801; CAS-102-70-5; I780; N,N-bis(prop-2-enyl)-2-propen-1-amine; FT-0653420; Triallylamine [UN2610] [Flammable liquid]; Triallylamine [UN2610] [Flammable liquid]; A800604; J-000772; Q23779745
Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely irritating at 75 ppm. Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. It is used as a solvent and in organic syntheses. A colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals. Triallylamine is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. May cause toxic effects if inhaled or ingested/swallowed.
Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion and inhalation. An eye and severe skin irritant. Human systemic effects by inhalation: structural or functional changes in trachea or bronchi. Flammable liquid when exposed to heat, flame or oxidlzers. To fight fire, use foam, alcohol foam, fog. When heated to decomposition it emits toxic fumes of NOx. Trillyamine is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn. Neutralizes acids in exothermic reactions to form salts plus water.
May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Triallylamine is used as an intermediate for the manufacture of rubber chemicals, ion exchange resins, polymerization initiators, quaternary ammonium salts, cross-linking agents
Triallylamine is mainly applied in organic synthesis and resin modifier, also can be used in the crosslinking of high absorbent and the intermediates of ion exchange resin. Triallylamine can be used in producing polyester activator and the evocating agent of butadiene polymerization. Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. Triallylamine is used as a solvent and in organic syntheses. Triallylamine is an intermediate to produce quaternary ammonium compounds. Triallylamine is an organic material, the monomer of polymers, pharmaceutical intermediate and modified agent for resin Triallylamine appears as a colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.
Triallylamine is a strong reducing agent that reacts violently with oxidizing agents. Triallylamine is corrosive towards Al and Zn. Triallylamine neutralizes acids in exothermic reactions to form salts plus water. Triallylamine may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Triallylamine can be analyzed by this reverse phase (RP) HPLC method with simple conditions. The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid. For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid. Smaller 3 µm particles columns available for fast UPLC applications. This liquid chromatography method is scalable and can be used for isolation impurities in preparative separation. It also suitable for pharmacokinetics. Triallylamine is used as an intermediate for the manufacture of rubber chemicals, ion exchange resins, polymerization initiators, quaternary ammonium salts, cross-linking agents. Triallylamine is a chemical compound from the aliphatic amines group.
Triallylamine is a flammable, colorless liquid with an amine-like odor, slightly soluble in water. This aqueous solution has an alkaline reaction. Triallylamine is used in the production of other chemicals. For example, it can be used in the crosslinking of highly absorbent materials and in the production of intermediates for the production of ion exchange resins. It can also be used in the production of polyester activators and stimulant agents for the polymerization of butadiene. Triallylamine vapors can form an explosive mixture with air. Triallylamine is mainly applied in organic synthesis and resin modifier, also can be used in the crosslinking of high absorbent and the intermediates of ion exchange resin. According to some reports, it can be used in producing polyester activator and the evocating agent of butadiene polymerization. There is no fixed pattern for application technology, therefore, the customer should base on your own technology and the equipment conditions to execute the program and utilize the product. Pack and preserve the product in a sealed, cool and dry condition, avoid contacting strong oxidants, keep away from open fire. It is transparent and colorless to yellowish liquid, has ammoniacal odor.
A chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together. The Triallysmine molecule contains a total of 24 bond(s) There are 9 non-H bond(s), 3 multiple bond(s), 6 rotatable bond(s), 3 double bond(s) and 1 tertiary amine(s) (aliphatic). The 2D chemical structure image of Triallylamine is also called skeletal formula, which is the standard notation for organic molecules. The carbon atoms in the chemical structure of Triallylamine are implied to be located at the corner(s) and hydrogen atoms attached to carbon atoms are not indicated – each carbon atom is considered to be associated with enough hydrogen atoms to provide the carbon atom with four bonds. The 3D chemical structure image of Triallylamine is based on the ball-and-stick model which displays both the three-dimensional position of the atoms and the bonds between them. The radius of the spheres is therefore smaller than the rod lengths in order to provide a clearer view of the atoms and bonds throughout the chemical structure model of Triallylamine .
Use of a poly quaternary ammonium polymer derived from a cationic monomer and a crosslinking monomer to control the anionic deposition of detritus and pitch and to treat coated manufacturing breaks in a pulp and paper making system; wherein said cationic monomer is diallyldimethylammonium chloride and said crosslinking monomer is selected from the group consisting of N, N-diallylamine, N-diallylamine hydrochloride, N-triallylamine, N hydrochloride, N-triallylamine, methylene bisacrylamide, N'-tetraallylpiperazinium dichloride and mixtures thereof; wherein the molar ratio of said cationic monomer to said crosslinking monomer is between 95/5 and 99.9999 / 0.0001 and wherein said polyquaternary ammonium polymer is added to the paste in said system in an amount of 0.05 to 2.72 kg (0.1 to 6 pounds) of polyquaternary ammonium polymer per 907 kg (tonnes) of dry pulp. Triallylamine appears as a colorless liquid. The density is 0.800 g / cm3 and it is insoluble in water. So it floats on water. Flash point 103 ° F. Vapors heavier than air. May irritate the skin and eyes. It is used to make other chemicals. Trialliamin (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines. It is a colorless liquid with a fishy odor. The density is 0.800 g / cm3 and it is insoluble in water.
So it floats on water. Flash point 103 ° F. Vapors heavier than air. May irritate the skin and eyes. It is used to make other chemicals. Triallylamine is a colorless or yellowish volatile liquid that is highly flammable and moderately reactive with oxidizing materials. Fully soluble in water with 9.7 pKa and has a very sharp ammonia-like odor that irritates mucous membranes. In addition to being a severe respiratory, eye, and skin irritant, allylamine is cardiotoxic when administered orally, by inhalation or by injection in high doses. It has been used to stimulate heart and vascular lesions in laboratory animals to model human cardiovascular disease. The trial is used as an intermediate of rubber chemicals, ion exchange resins, polymerization initiators, quaternary ammonium salts, crosslinking agents.
Trialylamine can mainly be used in organic synthesis and modifier, as well as highly absorbent and exchange exchange resin. Trialylamine, polyester activator and butadiene polymerization inducing agent can be used. Trialylamine is a powerful reducing agent that reacts with oxidizing agents. Trialylamine is corrosive to Al and Zn. Trialylamine neutralizes acids in exothermic reactions, forming salts and water. Physical properties of this chemical: (1) ACD / LogP: 3.32; (2) ACD / LogD (pH 5.5): 1.69; (3) ACD / LogD (pH 7.4): 3.13; (4) ACD / BCF (pH 5.5): 4.61; (5) ACD / BCF (pH 7.4): 127.74; (6) ACD / KOC (pH 5.5): 35.71; (7) ACD / KOC (pH 7.4): 990.08; (8) #H bond acceptors: 1; (9) # Free Spin Bonds: 6; (10) Polar Surface Area: 3.24 Å2; (11) Refractive Index: 1.462; (12) Molar Break: 46.64 cm3; (13) Molar Volume: 169.6 cm3; (14) Polarizability: 18.49 × 10-24cm3; (15) Surface Tension: 25.9 dynes / cm; (16) Density: 0.808 g / cm3; (17) Flash Point: 30.6 ° C; (18) Enthalpy of Evaporation: 39.43 kJ / mol; (19) Boiling Point: 157.6 ° C at 760mmHg; (20) Vapor Pressure: 2.74 mmHg at 25 ° C. Preparation of Triallylamine: It can be prepared with dialylamine and 3-acetoxy-propene. This reaction will require reactive cis, cis, cis-1,2,3,4-tetrakis (Ph2PCH2) cyclopentane, catalyst [PdCl (C3H5)] 2, and solvent tetrahydrofuran. The reaction time is 130 hours at the reaction temperature of 25 ° C. The yield is about 95%.
Trialylamine may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides and acid halides. Combustible gaseous hydrogen can be produced in combination with strong reducing agents such as hydrides. Trialylamine is produced using allyl chloride and ammonia under heat and pressure. Triallylamine is used as a solvent and in organic synthesis. Trialilamine appears as a colorless liquid with a fishy odor. The density is 0.800 g / cm3 and it is insoluble in water. Hence it floats on water. Flash point 103 ° F. Vapors heavier than air. May irritate the skin and eyes. It is used to make other chemicals. Triallylamine is a flammable, colorless liquid with an amine-like odor, slightly soluble in water. Its aqueous solution has an alkaline reaction.
Triallylamine is used in the production of other chemicals. For example, it can be used in the crosslinking of highly absorbent materials and in the production of intermediates for the production of ion exchange resins. It can also be used in the production of polyester activators and stimulant for butadiene polymerization.
This chemical is used as extractant of uranium and rare metals and can be used for organic synthesis and modified resin. It can also be used as an intermediate of ion exchange resins, highly absorbent and metal resistant crosslinker. Moreover, it can react with 4-ethyl-aniline to obtain 2,6-diethyl-3-methyl-quinoline. This reaction will require the reagents ruthenium (III) chloride hydrate, bis (diphenylphosphino) methane and tin (II) chloride dihydrate, and the solvent dioxane. The reaction time at the reaction temperature of 180 ° C is 20 hours. The yield is about 65%. Triallylamine with CAS registration number 102-70-5 is also called 2-Propene-1-amine, N, N-di-2-propen-1-yl-. The IUPAC name is N, N-bis (prop-2-enyl) prop-2-en-1-amine. The EINECS registration number is 203-048-2. In addition, the molecular formula is C9H15N and the molecular weight is 137.22.
It is a kind of dark brown liquid and belongs to Acyclic classes; Alkenes; Organic Building Blocks. And it should be stored in a cool and ventilated place. Triallylamine is used in the production of other chemicals. Triallylamine is also mainly applied in organic synthesis and resin modifiers. Triallylamine is used in high absorbency crosslinking and intermediates of ion exchange resin. Triallylamine can also be used in the production of polyester activator and butadiene polymerization inducing agent.
