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TRIETHYLENE GLYCOL


CAS NO:112-27-6
EC NO:203-953-2

Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH2CH2OCH2CH2OCH2CH2OH. 
Triethylene glycol is used as a plasticizer for vinyl polymers. 
Triethylene glycol is also used in air sanitizer products, such as "Oust" or "Clean and Pure". When aerosolized it acts as a disinfectant. Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. 
Triethylene glycol is an additive for hydraulic fluids and brake fluids and is used as a base for "smoke machine" fluid in the entertainment industry.

Properties
Triethylene glycol is a member of a homologous series of dihydroxy alcohols. 
Triethylene glycol is a colorless, odorless and stable liquid with high viscosity and a high boiling point. Apart from its use as a raw material in the manufacture and synthesis of other products, TEG is known for its hygroscopic quality and its ability to dehumidify fluids. This liquid is miscible with water, and at standard atmospheric pressure (101.325 kPa) has a boiling point of 286.5 °C and a freezing point of -7 °C. 
Triethylene glycol is also soluble in ethanol, acetone, acetic acid, glycerine, pyridine, aldehydes; slightly soluble in diethyl ether; and insoluble in oil, fat and most hydrocarbons.

Properties:
Chemical formula:    C6H14O4
Molar mass:    150.174 g·mol−1
Appearance:    Colorless liquid
Density:    1.1255 g/mL
Melting point:    −7 °C (19 °F; 266 K)
Boiling point:    285 °C (545 °F; 558 K)

Preparation
Triethylene glycol is prepared commercially as a co-product of the oxidation of ethylene at high temperature in the presence of silver oxide catalyst, followed by hydration of ethylene oxide to yield mono(one)-, di(two)-, tri(three)- and tetraethylene glycols.

Applications
Triethylene glycol is used by the oil and gas industry to "dehydrate" natural gas. 
Triethylene glycol may also be used to dehydrate other gases, including CO2, H2S, and other oxygenated gases.
Triethylene glycol is necessary to dry natural gas to a certain point, as humidity in natural gas can cause pipelines to freeze, and create other problems for end users of the natural gas. 
Triethylene glycol is placed into contact with natural gas, and strips the water out of the gas. 
Triethylene glycol is heated to a high temperature and put through a condensing system, which removes the water as waste and reclaims the TEG for continuous reuse within the system. The waste TEG produced by this process has been found to contain enough benzene to be classified as hazardous waste(benzene concentration greater than 0.5 mg/L).

Triethylene glycol is well established as a relatively mild disinfectant toward a variety of bacteria, influenza A viruses and spores of Penicillium notatum fungi.

Triethylene glycol is a colorless liquid with a mild odor. Dense than water.
Triethylene glycol is a poly(ethylene glycol) that is octane-1,8-diol in which the carbon atoms at positions 3 and 6 have been replaced by oxygen atoms.
Triethylene glycol has a role as a plasticiser.
Triethylene glycol is a poly(ethylene glycol), a diol and a primary alcohol.

Uses
Used as a fragrance (cosmetics), solvent (resins, pesticides, textile dyeing), humectant (printing inks and tobacco), plasticizer, and disinfectant.

Industry Uses:
-Adhesives and sealant chemicals
-Adsorbents and absorbents
-Fuels and fuel additives
-Functional fluids (closed systems)
-Intermediates
-Lubricants and lubricant additives
-Plasticizers
-Processing aids, not otherwise listed
-Processing aids, specific to petroleum production
-Solvents (for cleaning and degreasing)
-Solvents (which become part of product formulation or mixture)
-Wholesales

Consumer Uses:
-Adhesives and sealants
-Anti-freeze and de-icing products
-Automotive care products
-Building/construction materials not covered elsewhere
-Chemical intermediate
-Cleaning and furnishing care products
-Electrical and electronic products
-Fabric, textile, and leather products not covered elsewhere
-Floor coverings
-Fuels and related products
-Ink, toner, and colorant products
-Laundry and dishwashing products
-Lubricants and greases
-Paints and coating
-Plastic and rubber products not covered elsewhere

Industry Processing Sectors:
-Adhesive manufacturing
-All other basic inorganic chemical manufacturing
-All other basic organic chemical manufacturing
-All other chemical product and preparation manufacturing
-All other petroleum and coal products manufacturing
-Asphalt paving, roofing, and coating materials manufacturing
-Construction
-Industrial gas manufacturing
-Miscellaneous manufacturing
-Oil and gas drilling, extraction, and support activities
-Paint and coating manufacturing
-Petrochemical manufacturing
-Petroleum lubricating oil and grease manufacturing
-Petroleum refineries
-Plastic material and resin manufacturing
-Plastics product manufacturing
-Printing ink manufacturing
-Rubber product manufacturing
-Soap, cleaning compound, and toilet preparation manufacturing
-Synthetic rubber manufacturing
-Utilities
-Wholesale and retail trade

Triethylene glycol (TEG) is a liquid higher glycol of very low vapor pressure with uses that are primarily industrial. 
Triethylene glycol has a very low order of acute toxicity by iv, ip, peroral, percutaneous and inhalation (vapor and aerosol) routes of exposure.

Triethylene glycol (also known as TEG, triglycol and trigen) is a colourless, viscous, non-volatile liquid with the formula C6H14O4.  
Triethylene glycol is well known for its hygroscopic quality and its ability to dehumidify fluids.

Triethylene glycol is prepared commercially as a co-product of the oxidation of ethylene at high temperature, in the presence of a silver oxide catalyst.  The ethylene oxide is then hydrated to yield mono, di, tri, and tetra ethylene glycols.

Triethylene glycol is estimated that the total world consumption of TEG is in excess of 175 metric tonnes annually.

Oil & Gas Industry:
The main uses for tri ethylene glycol are based upon its hygroscopic quality. This means that it can absorb moisture from the air through absorption or adsorption. Triethylene glycol is used as a dehydrating agent for natural gas pipelines where it removes the water from the gas before being condensed. 
The triethylene glycol can then be continually reused, although the by-product of benzene needs to be disposed of carefully. 
Triethylene glycol is useful as it prevents the gas from freezing making the gas easier to transport and manage for end consumers.

Mild Disinfectant:
Triethylene glycol can also be used as a mild disinfectant. Due to its low toxicity, antimicrobial properties, and low odour, it is commonly used for air disinfection in occupied areas where more aggressive disinfectants cannot be used. Due to these disinfectant properties and the dehydrating properties, it is an ideal dehumidifying agent in air-conditioning units.

Uses:
-Antifreeze
-Coolants
-Chemical intermediates
-Gas dehydration and treating
-Heat transfer fluids
-Polyester resins
-Solvents

Benefits:
-Versatile intermediates
-Low volatility
-Low boiling point
-TETRA EG is completely miscible with water and a wide range of organic solvents.

Triethylene glycol (TEG) is a colorless, viscous liquid with a slight odor. 
Triethylene glycol is non-flammable, mildly toxic, and considered non-hazardous. Triethylene glycol is a member of a homologous series of dihydroxy alcohols. 
Triethylene glycol is used as a plasticizer for vinyl polymers as well as in the manufacture of air sanitizer and other consumer products.

Triethylene Glycol (TEG) is a liquid chemical compound with the molecular formula C6H14O4 or HOCH2CH2CH2O2CH2OH. 
Triethylene Glycols CAS is 112-27-6. 
Triethylene Glycol is recognized for its hygroscopic quality and ability to dehumidify fluids. 
Triethylene Glycol is miscible with water and soluble in ethanol, acetone, acetic acid, glycerine, pyridine, and aldehydes. 
Triethylene Glycol is slightly soluble in diethyl ether, and insoluble in oil, fat, and most hydrocarbons.

Triethylene Glycol is commercially produced as a co-product of the oxidation of ethylene at a high temperature in the presence of silver oxide catalyst, followed by hydration of ethylene oxide to yield mono, di, tri, and tetraethylene glycols.

The oil and gas industries use TEG to dehydrate natural gas as well as other gases including CO2, H2S, and other oxygenated gases. Industrial uses include adsorbents and absorbents, functional fluids in both closed and open systems, Intermediates, petroleum production processing aids, and solvents. 
Triethylene Glycol is used in the manufacture of a host of consumer products that include anti-freeze, automotive care products, building and construction materials, cleaning and furnishing care products, fabric, textile, and leather products, fuels and related products, lubricants and greases, paints and coatings, personal care products, and plastic and rubber products.

Formula: C6H14O4 / HOCH2(CH2CH2O)2CH2OH
Molecular mass: 150.2
Boiling point: 285°C
Melting point: -5 - -7°C
Relative density (water = 1): 1.1
Solubility in water: very good
Vapour pressure, Pa at 20°C: 0.02
Relative vapour density (air = 1): 5.2
Flash point: 165°C
Auto-ignition temperature: 371°C
Explosive limits, vol% in air: 0.9-9.2
Octanol/water partition coefficient as log Pow: -1.24/-1.9 (calculated) 

Triethylene glycol is viscous at room temperature. 
Triethylene glycol is colorless, odorless, and sweet-tasting. 
Triethylene glycol is miscible in water in all ratios.

Applications:
Polyol, a cellophane plasticizer, synthetic resin raw materials.

Triethylene glycol results from the reaction of water with ethylene oxide. By adding a third mole of ethylene oxide, Triethylene glycol is obtained. Applications for this product include synthesis agents, coolant additives, cement additives, wetting and plasticizing agents, agrochemical, polyester, and resin.

Triethylene glycol is used as a plasticizer, as an additive for hydraulic fluids and brake fluids, and as a disinfectant. 
Triethylene glycol is an active component of certain pigments, printing dyes, inks and paste. 
Triethylene glycol finds application as a liquid desiccant and used in the dehydration of natural gas, carbon dioxide, hydrogen sulfide and air conditioning systems. 
Triethylene glycol plays as an important role in anti-freeze and de-icing products, cleaning and furnishing care products, lubricant and greases.

Technical Information
Physical State :Liquid
Storage :Store at room temperature
Melting Point :-7° C (lit.)
Boiling Point :125-127° C (lit.) at 0.1 mmHg
Density :1.12 g/mL at 20° C

Triethylene Glycol (TEG) is a colorless, liquefied by-product from Diethylene Glycol and Ethylene Oxide production. 
Triethylene Glycol (TEG) is used as a plasticizer for the production of PBT films and for water soluble lubricants for pumps. Additionally, TEG is used in gas purification and gas drying processes.

Triethylene glycol, commonly referred to as TEG, is similar in properties to diethylene glycol (DEG), but with a higher boiling point, viscosity and specific gravity. 
Triethylene Glycol is used where a high boiling point and low volatility are important.

The major use of TEG is in the drying of natural gas due to its strong hygroscopic properties. 
Triethylene glycol is also used as a chemical intermediate in the production of vinyl plasticizers, polyester resins, adhesives, and a variety of solvents and cleaners.

Triethylene glycol is a hydrophilic difunctional methacrylic monomer. 
Triethylene glycol forms homopolymers and copolymers which can be prepared with acrylic acid and its salts, amides and esters, and with methacrylates, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, unsaturated polyesters and drying oils, etc. 
Triethylene glycol is also a very useful feedstock for chemical syntheses, because it readily undergoes addition reactions with a wide variety of organic and inorganic compounds.

Triethylene glycol is a colorless, odorless and stable liquid with a high viscosity and high boiling point. Also referred to as TEG or Triglycol, it used in natural gas dehydration systems.
Triethylene glycols natural affinity to water vapor makes it an ideal liquid desiccant for this process. The goal is to remove water from natural gas and prevent pipeline freezing and hydrate blockages, scale and corrosion.

Triethylene Glycol (TEG) is the third members of a homologous series of dihydroxyalcohols. 
Triethylene glycol is produced in the Master Process by the direct hydration of ethylene oxide. TEG is co-produced with MEG and DEG. 
Triethylene glycol is a colourless liquid.
The main uses for triethylene glycol are based upon its hygroscopic quality. 
Triethylene glycol is used as a dehydrating agent for natural gas pipelines where it removes the water from the gas before being condensed and reused in the system. 
Triethylene glycol is also a dehumidifying agent in air-conditioning units.
Triethylene glycol is also used to make chemical intermediates such as plasticisers and polyester resins. 
Triethylene glycol is an additive in hydraulic fluids and brake fluids, and TEG is also used as a solvent in many applications, including as a selective solvent for aromatics, and a solvent in textile dyeing.
Triethylene glycol also has mild disinfectant qualities and, when volatised, is used as an air disinfectant for virus and bacteria control.

Chemical Properties
Triethylene glycol is a clear, colorless, viscous, stable liquid with a slightly sweetish odor. Soluble in water; immiscible with benzene, toluene, and gasoline. Combustible. Because it has two ether and two hydroxyl groups its chemical properties are closety related to ethers and primary alcohols. 
Triethylene glycol is a good solvent for gums, resins, nitrocellulose, steam-set printing inks and wood stains. With a low vapor pressure and a high boiling point, its uses and properties are similar to those of ethylene glycol and diethylene glycol. Because it is an efficient hygroscopic agent it serves as a liquid desiccant for removing water from natural gas. 
Triethylene glycol is also used in air conditioning systems designed to dehumidify air.

Production Methods
Triethylene glycol, like diethylene glycol, is produced commercially as a by-product of ethylene glycol production. 
Triethylene glycols formation is favored by a high ethylene oxide to water ratio.

Definition
ChEBI: A poly(ethylene glycol) that is octane-1,8-diol in which the carbon atoms at positions 3 and 6 have been replaced by oxygen atoms.

About Triethylene glycol
Helpful information
Triethylene glycol is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 10 000 to < 100 000 tonnes per annum.

Triethylene glycol is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Consumer Uses
Triethylene glycol is used in the following products: inks and toners, coating products, heat transfer fluids, lubricants and greases and hydraulic fluids.
Other release to the environment of Triethylene glycol is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids).

Article service life
Other release to the environment of Triethylene glycol is likely to occur from: indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment) and outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials). Triethylene glycol can be found in complex articles, with no release intended: vehicles, machinery, mechanical appliances and electrical/electronic products (e.g. computers, cameras, lamps, refrigerators, washing machines) and electrical batteries and accumulators. Triethylene glycol can be found in products with material based on: paper (e.g. tissues, feminine hygiene products, nappies, books, magazines, wallpaper), plastic (e.g. food packaging and storage, toys, mobile phones), fabrics, textiles and apparel (e.g. clothing, mattress, curtains or carpets, textile toys), metal (e.g. cutlery, pots, toys, jewellery), stone, plaster, cement, glass or ceramic (e.g. dishes, pots/pans, food storage containers, construction and isolation material), leather (e.g. gloves, shoes, purses, furniture), rubber (e.g. tyres, shoes, toys) and wood (e.g. floors, furniture, toys).

Widespread uses by professional workers
Triethylene glycol is used in the following products: inks and toners, paper chemicals and dyes, hydraulic fluids, washing & cleaning products, coating products, non-metal-surface treatment products and polymers.
Triethylene glycol is used in the following areas: printing and recorded media reproduction.
Triethylene glycol is used for the manufacture of: plastic products, chemicals, machinery and vehicles, food products, textile, leather or fur, wood and wood products and rubber products.
Other release to the environment of Triethylene glycol is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids).

Formulation or re-packing
Triethylene glycol is used in the following products: inks and toners, washing & cleaning products, non-metal-surface treatment products, paper chemicals and dyes and polymers.
Release to the environment of Triethylene glycol can occur from industrial use: formulation of mixtures and formulation in materials.

Uses at industrial sites
Triethylene glycol is used in the following products: inks and toners, coating products, polymers, washing & cleaning products, heat transfer fluids, fuels and extraction agents.
Triethylene glycol has an industrial use resulting in manufacture of another substance (use of intermediates).
Triethylene glycol is used in the following areas: mining, formulation of mixtures and/or re-packaging and printing and recorded media reproduction.
Triethylene glycol is used for the manufacture of: chemicals and plastic products.
Release to the environment of Triethylene glycol can occur from industrial use: in processing aids at industrial sites, as an intermediate step in further manufacturing of another substance (use of intermediates), of substances in closed systems with minimal release, for thermoplastic manufacture and in the production of articles.

Manufacture
Release to the environment of Triethylene glycol can occur from industrial use: manufacturing of the substance, formulation of mixtures, formulation in materials, in processing aids at industrial sites, in the production of articles, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, for thermoplastic manufacture, as processing aid and of substances in closed systems with minimal release.


IUPAC names
1,2-bis(2-hydroxyethoxy)ethane
2,2'-(ethylenedioxy) diethanol
2,2'-(Ethylenedioxy)diethanol
2,2'-(ethylenedioxy)diethanol
2,2'-(ethylenedioxy)diethanol
2,2'-(etilendioxi)dietanol
2,2'-[ethane-1,2-diylbis(oxy)]diethanol
2,2-(ethylenedioxy)diethanol
2,2’- {ethane-1,2-diylbis(oxy)}diethanol
2,2’-[1,2-Ethanediylbis(oxy)]bisethanol
2-[2-(2-hydroxyethoxy)ethoxy]ethan-1-ol
2-[2-(2-Hydroxyethoxy)ethoxy]ethanol
2-[2-(2-hydroxyethoxy)ethoxy]ethanol
Ethanol, 2,2'-(1,2-ethanediylbis(oxy))bis-
Ethanol, 2,2'-[1,2-ethanediylbis(oxy)]bis-
not applicable
TEG
TRIETHYLENE GLYCOL
Triethylene Glycol
Triethylene glycol
Triethylene Glycol
Triethylene glycol
Triethylene Glycol (TEG)
Triethylene glycol, also known as TEG.
TRIETHYLENEGLYCOL
triethyleneglycol
Triethyleneglycol
Triethylenglykol

SYNONYMS:
1,2-bis(2-hydroxyethoxy)ethane
112-27-6 [RN]
2,2'-(Ethane-1,2-diylbis(oxy))diethanol
2,2'-(Ethylenedioxy)diethanol
2,2'-[1,2-Ethandiylbis(oxy)]diethanol [German] [ACD/IUPAC Name]
2,2'-[1,2-Ethanediylbis(oxy)]diethanol [ACD/IUPAC Name]
2,2'-[1,2-Éthanediylbis(oxy)]diéthanol [French] [ACD/IUPAC Name]
2,2'-[Ethane-1,2-diylbis(oxy)]diethanol
203-953-2 [EINECS]
3P5SU53360
928-40-5 [RN]
969357 [Beilstein]
Ethanol, 2,2'-[1,2-ethanediylbis(oxy)]bis- [ACD/Index Name]
MFCD00002880 [MDL number]
TEG
Triethylene glycol [Wiki]
triethyleneglycol
Triglycol
YE4550000
1-(2-METHOXY-ETHOXY)-2-{2-[2-(2-METHOXY-ETHOXY]-ETHOXY}-ETHANE
1,2-bis-(2-hydroxyethoxy)-ethane
1,2-BIS(2-HYDROXYETHOXY)ETHANE
2,2-ETHYLENEDIOXYDIETHANOL
2,2'-ETHYLENEDIOXYETHANOL
3,6-DIOXA-1,8-OCTANEDIOL
DI-B-HYDROXYETHOXYETHANE
ETHYLENE GLYCOL DIHYDROXYDIETHYL ETHER
GLYCOL BIS(HYDROXYETHYL)ETHER
TEG
TRIETHYLENE GLYCOL
TRIGLYCOL
TRIGOL
2,2'-(1,2-Ethanediylbis(oxy))bisethanol
2,2’-(1,2-ethanediylbis(oxy))bis-ethano
2,2’-(1,2-ethanediylbis(oxy))bisethanol
2,2’-(ethylenedioxy)di-ethano
2,2’-[1,2-ethanediylbis(oxy)]bis-ethano
2,2’-[1,2-Ethanediylbis(oxy)]bisethanol
2,2’-[1,2-ethanediylbis(oxy)]bis-Ethanol
2,2’-ethylenedioxybis(ethanol)
2,2'-Ethylenedioxybis(ethanol)


 

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