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TRIMETHYL BORATE

Trimethyl borate is the organoboron compound with the formula B(OCH3)3. 
Trimethyl borate is a colourless liquid that burns with a green flame.
Trimethyl borate power to aid the preparation of sodium borohydride and act as a weak Lewis acid (AN = 23) is well respected among chemists worldwide. 

CAS Number: 121-43-7
EC Number: 204-468-9
Molecular Formula: C3H9BO3
Molecular Weight: 103.91

Trimethyl borate is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. 
Trimethyl borate is a weak Lewis acid (AN = 23, Gutmann-Beckett method).

Borate esters are prepared by heating boric acid or related boron oxides with alcohols under conditions where water is removed.

Trimethyl borate is the main precursor to sodium borohydride. 
Trimethyl borate is often used as a reagent in organic synthesis reactions, such as Suzuki couplings and Grignard reactions.

Trimethyl borate is the organoboron compound with the formula B(OCH3)3. 
Trimethyl borate is a colourless liquid that burns with a green flame.
Trimethyl borate power to aid the preparation of sodium borohydride and act as a weak Lewis acid (AN = 23) is well respected among chemists worldwide. 

Trimethyl borate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 100 to < 1 000 tonnes per annum.
Trimethyl borate is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Trimethyl Borate is generally immediately available in most volumes. 
Broad range of products for hydrogen storage research, advanced fuel cells and battery applications. 

Hydrogen can easily be generated from renewable energy sources and is the most abundant element in the universe. 
Hydrogen is produced from various sources such as fossil fuels, water and renewables. 

Hydrogen is nonpolluting and forms water as a harmless byproduct during use. 
The challenges associated with the use of hydrogen as a form of energy include developing safe, compact, reliable, and cost-effective hydrogen storage and delivery technologies. 

Currently, hydrogen can be stored in these three forms: Compressed Hydrogen, Liquid Hydrogen and Chemical Storage. 
High purity, submicron and nanopowder forms may be considered. 

A member of the class of Borate Ester, Trimethyl borate is a colorless liquid that ignites with an impressive green flame. 
Trimethyl borate power to aid the preparation of sodium borohydride and act as a weak Lewis acid (AN = 23) is well respected among chemists worldwide. 
Borate ester, prepared by heating boron oxides and alcohols under dehydrating conditions, is a popular reagent in organic chemistry.

Trimethyl borate reacts with a Grignard reagent or organolithium compounds to yield dimethyl boronates, which upon subsequent aqueous acid treatment afford corresponding boronic acids.
The resultant boronic acids or esters are useful intermediates in various cross-coupling reactions such as Suzuki coupling and Chan-Lam coupling.
Trimethyl borate is also used in the preparation of sodium borohydride.

Trimethyl borate is a useful reagent in organic synthesis. 
Trimethyl borate is involved in the production of resins, waxes and paints and acts as a methylation agent. 

As a boron source, Trimethyl borate is used to prepare flame retardants, anti-oxidants and corrosion inhibitors. 
Trimethyl borate reacts with Grignard reagents followed by hydrolysis to prepare boronic acid. 

Trimethyl borate is also used as a precursor of borate esters, which finds application in the Suzuki coupling reaction. 
Trimethyl borate is an intermediate in the preparation of sodium borohydride.

Applications of Trimethyl borate:
Trimethyl borate reacts with a Grignard reagent or organolithium compounds to yield dimethyl boronates, which upon subsequent aqueous acid treatment afford corresponding boronic acids.
The resultant boronic acids or esters are useful intermediates in various cross-coupling reactions such as Suzuki coupling and Chan-Lam coupling.
Trimethyl borate is also used in the preparation of sodium borohydride.

Trimethyl borate is the main precursor to sodium borohydride by Trimethyl borate reaction with sodium hydride:
4 NaH + B(OCH3)3 → NaBH4 + 3 NaOCH3

Trimethyl borate is a gaseous anti-oxidant in brazing and solder flux. 
Otherwise, trimethyl borate has no announced commercial applications. 
Trimethyl borate has been explored as a fire retardant, as well as being examined as an additive to some polymers.

Organic synthesis:
Trimethyl borate is a useful reagent in organic synthesis, as a precursor to boronic acids, which are used in Suzuki couplings. 

These boronic acids are prepared via reaction of the trimethyl borate with Grignard reagents followed by hydrolysis:
ArMgBr + B(OCH3)3 → MgBrOCH3 + ArB(OCH3)2
ArB(OCH3)2 + 2 H2O → ArB(OH)2 + 2 HOCH3

Uses of Trimethyl borate:
Trimethyl borate is also an anti-oxidant in the brazing and solder flux and has been explored as a fire retardant. 
Additionally, Trimethyl borate has been examined as an additive to some polymers. 

Trimethyl borate is the main reactant in the Brown-Schlesinger method of producing sodium borohydride, and Trimethyl borate is successfully recreated from sodium metaborate (NaBO2) via a sequential process that includes reacting with sulfuric acid, cooling crystallization, and reactive esterification distillation.

The metaborate is first transformed to boric acid (H3BO3) by treating Trimethyl borate with sulfuric acid, obviating the need to synthesize borax (Na2B4O710H2O) in traditional techniques. 
Boric acid is separated and purified from coexisting sodium sulphate by cooling crystallization (Na2SO4). 

Following that, Trimethyl borate is made by esterifying boric acid with methanol, with reactive esterification distillation used to speed up the process and purify Trimethyl borate . 
X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and gas chromatography are used to demonstrate the formation of boric acid and trimethyl borate (GC). 
Sodium metaborate could be converted to boric acid at a rate of about 55%, with a manufacturing yield of 74.1 to 96.5% for trimethyl borate esterified from boric acid as-produced.

Trimethyl borateis potassium (sodium) boron hydrogen intermediate. 
Vulcanizing agent, wood preservative, catalyst, gelling agent, heat stabilizer, hydrogen flame extinguishing agent, also used for flame retardant treatment of cotton and preparation of active silica, and as a gas chromatographic analysis reagent for carbohydrate derivatives.

Trimethyl borate is used as a flame retardant, welding and brazing flux, chemical intermediate, fungicide, and a solvent for waxes, resins, and oils.
Trimethyl borate is used as solvent for waxes, resins, oils; catalyst in manufacture of ketones; analysis of paint and varnish ingredients; as neutron detector gas in presence of a scintillation counter; as promoter of diborane reactions
Trimethyl borate is intermediate in preparation of metal borohydrides.

Protection of Wood-based Materials:
Trimethyl borate has a high vapour pressure injected into a container containing the wood beneath a vacuum during vapour phase treatments. 
Trimethyl borate then volatilizes and diffuses into the wood by combining with any moisture to form methanol and boric acid. 

The borate is released during the reaction and is deposited in the wood. 
Some methanol and borate remain in the wood when the vacuum is released. 
This method has been used to cure a variety of composites, but Trimethyl borate utility is limited because the wood being processed cannot be too wet (moisture content less than 6–8%).

Widespread uses by professional workers:
Trimethyl borate is used in the following products: welding & soldering products and laboratory chemicals. 
Trimethyl borate is used in the following areas: building & construction work and scientific research and development. 

Trimethyl borate is used for the manufacture of: fabricated metal products. 
Other release to the environment of Trimethyl borate is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use as reactive substance.

Uses at industrial sites:
Trimethyl borate is used in the following products: welding & soldering products, biocides (e.g. disinfectants, pest control products) and plant protection products.
Trimethyl borate has an industrial use resulting in manufacture of another substance (use of intermediates).

Trimethyl borate is used for the manufacture of: chemicals.
Release to the environment of Trimethyl borate can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates) and as processing aid.

Industry Uses:
Intermediates

Industrial Processes with risk of exposure:
Welding
Brazing
Farming (Pesticides)

Properties of Trimethyl borate:

Chemical Properties:
Dehydration produces trimethyl borate, which decomposes to methanol and boric acid when coming in contact with water. 
In the presence of oxygen, Trimethyl borate burns to generate boron trioxide. 
Trimethyl borate emits a vivid green hue in flames, which overpowers other flame colours.

Synthesis of Trimethyl borate:
Trimethyl borate is a boron triester with a single boron atom and three methoxide groups. 
Trimethyl borate can be made by mixing a large amount of dry methanol with boric acid, boron oxide, and a tiny amount of sulfuric acid, and heating the mixture to dehydrate Trimethyl borate if necessary. 

Due to the extra methanol used, the finished product would be an azeotropic mixture of methanol (25%) and trimethyl borate (75%). 
Pure trimethyl borate can be obtained by converting methanol to trimethyl borate with a boron trihalide, such as boron tribromide. 
However, the trihalide should be added gradually to avoid hydrolysis of the previously present boron tribromide.

Trimethyl borate is an essential reagent in organic synthesis because Trimethyl borate acts as a precursor to boronic acids. 
These boronic acids, used in Suzuki couplings, are made by reacting trimethyl borate with Grignard reagents.

B(OCH3)3 + ArMgBr → MgBrOCH3 + ArB(OCH3)2

ArB(OCH3)2 + 2 H2O → ArB(OH)2 + 2 HOCH3

Methods of Manufacturing of Trimethyl borate:
Trimethyl borate is manufacture from pyridine-boron trichloride complex; from methanol and boric oxide, borax or boric acid; from methyl orthosilicates and boron halide; from boric acid and methanol.

Handling and Storage of Trimethyl borate:

Advice on safe handling:
Work under hood. 
Do not inhale substance/mixture. 
Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion:
Keep away from open flames, hot surfaces and sources of ignition.
Take precautionary measures against static discharge.

Hygiene measures of Trimethyl borate:
Immediately change contaminated clothing. 
Apply preventive skin protection. 
Wash hands and face after working with substance.

Conditions for safe storage, including any incompatibilities:

Storage conditions:
Keep container tightly closed in a dry and well-ventilated place. 
Keep away from heat and sources of ignition. 
Keep locked up or in an area accessible only to qualified or authorized persons.

Storage class:
Storage class (TRGS 510): 3: Flammable liquids

Stability and Reactivity of Trimethyl borate:

Reactivity:
Vapors may form explosive mixture with air.

Chemical stability:
Trimethyl borate is chemically stable under standard ambient conditions (room temperature).

Possibility of hazardous reactions:

Exothermic reaction with:
Oxidizing agents
Acids
Fluorine
Water
Violent reactions possible with:
Alkali metals

Conditions to avoid:
Methanol is given off during processing and by reaction with water. 
Avoid moisture.
Warming.

Incompatible materials:
Strong oxidizing agents

First Aid Measures of Trimethyl borate:
Call 911 or emergency medical service. 
Ensure that medical personnel are aware of Trimethyl borate (s) involved and take precautions to protect themselves. 

Move victim to fresh air if Trimethyl borate can be done safely. 
Give artificial respiration if victim is not breathing. 

Administer oxygen if breathing is difficult. 
Remove and isolate contaminated clothing and shoes. 

In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. 
Wash skin with soap and water. 

In case of burns, immediately cool affected skin for as long as possible with cold water. 
Do not remove clothing if adhering to skin. 

Keep victim calm and warm. 
Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

General advice:
First aiders need to protect themselves. 
Show Trimethyl borate safety data sheet to the doctor in attendance.

After inhalation:
Fresh air. 
Immediately call in physician. 

If breathing stops:
Immediately apply artificial respiration, if necessary also oxygen.

In case of skin contact: 
Take off immediately all contaminated clothing. 
Rinse skin with water/ shower. 
Call a physician immediately.

After eye contact:
Rinse out with plenty of water. 
Call in ophthalmologist. 
Remove contact lenses.

If swallowed:
Give water to drink (two glasses at most). 
Seek medical advice immediately.
In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

Fire Fighting Measures:
The majority of these products have a very low flash point. 
Use of water spray when fighting fire may be inefficient.

SMALL FIRE: 
Dry chemical, CO2, water spray or alcohol-resistant foam. 
Do not use dry chemical extinguishers to control fires involving nitromethane (UN1261) or nitroethane (UN2842).

LARGE FIRE: 
Water spray, fog or alcohol-resistant foam. 
Avoid aiming straight or solid streams directly onto Trimethyl borate . 
If Trimethyl borate can be done safely, move undamaged containers away from the area around the fire.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: 
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. 
Cool containers with flooding quantities of water until well after fire is out. 

Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. 
ALWAYS stay away from tanks engulfed in fire. 
For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Suitable extinguishing media:
Carbon dioxide (CO2) Foam Dry powder

Unsuitable extinguishing media:
For Trimethyl borate no limitations of extinguishing agents are given.

Special hazards arising from Trimethyl borate or mixture:
Carbon oxides
Borane/boron oxides

Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.

Advice for firefighters:
Stay in danger area only with self-contained breathing apparatus. 
Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information:
Remove container from danger zone and cool with water. 
Prevent fire extinguishing water from contaminating surface water or the ground water system.

Fire Fighting Procedures:
To fight fire use dry chemical, CO2, spray, foam.

If material on fire or involved in fire: 
Do not extinguish fire unless flow can be stopped. 
Use water in flooding quantities as fog. 

Solid stream of water may be ineffective. 
Cool all affected containers with flooding quantities of water. 

Use "alcohol" foam, dry chemical or carbon dioxide. 
Keep run-off water out of sewers and water sources.

Accidental Release Measures of Trimethyl borate:

Personal precautions, protective equipment and emergency procedures:

Advice for non-emergency personnel: 
Do not breathe vapors, aerosols. 
Avoid substance contact. 

Ensure adequate ventilation. 
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions of Trimethyl borate:
Do not let product enter drains. 
Risk of explosion.

Methods and materials for containment and cleaning up:
Cover drains. 
Collect, bind, and pump off spills. 

Observe possible material restrictions.
Take up carefully with liquid-absorbent material. 

Dispose of properly. 
Clean up affected area.

Identifiers of Trimethyl borate:
CAS Number: 121-43-7
ChEBI: CHEBI:38913
ChemSpider: 8157
ECHA InfoCard: 100.004.063
EC Number: 204-468-9
PubChem CID: 8470
UNII: 82U64J6F5N
CompTox Dashboard (EPA): DTXSID0037738
InChI: InChI=1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
Key: WRECIMRULFAWHA-UHFFFAOYSA-N
InChI=1/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
Key: WRECIMRULFAWHA-UHFFFAOYAY
SMILES: O(B(OC)OC)C

Synonym(s): Boric acid trimethyl ester, Methyl borate
Linear Formula: B(OCH3)3
CAS Number: 121-43-7
Molecular Weight: 103.91
Beilstein: 1697939
EC Number: 204-468-9
MDL number: MFCD00008346
PubChem Substance ID: 24868738

CAS number: 121-43-7
EC index number: 005-005-00-1
EC number: 204-468-9
Hill Formula: C₃H₉BO₃
Chemical formula: (CH₃O)₃B
Molar Mass: 103.91 g/mol
HS Code: 2920 90 70

Linear Formula: B(OCH3)3
MDL Number: MFCD00008346
EC No.: 204-468-9
Beilstein/Reaxys No.: 1697939
Pubchem CID: 8470
IUPAC Name: trimethyl borate
SMILES: O(B(OC)OC)C
InchI Identifier: InChI=1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
InchI Key: WRECIMRULFAWHA-UHFFFAOYSA-N

Typical Properties of Trimethyl borate:
Chemical formula: C3H9BO3
Molar mass: 103.91 g·mol−1
Appearance: colourless liquid
Density: 0.932 g/ml
Melting point: −34 °C (−29 °F; 239 K)
Boiling point: 68 to 69 °C (154 to 156 °F; 341 to 342 K)
Solubility in water: decomposition

Compound Formula: C3H9BO3
Molecular Weight: 103.91
Appearance: Colorless Liquid
Melting Point: −34 °C
Boiling Point: 68-69 °C
Density: 0.932 g/mL at 20 °C
Solubility in H2O: N/A
Exact Mass: 104.064475 g/mol
Monoisotopic Mass: 104.064475 g/mol

Vapor density: 3.59 (vs air)
Quality Level: 200
Assay: ≥98%
Refractive index: n20/D 1.346 (lit.)
bp: 68-69 °C (lit.)
mp: −34 °C (lit.)
Density: 0.932 g/mL at 20 °C (lit.)
SMILES string: COB(OC)OC
InChI: 1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
InChI key: WRECIMRULFAWHA-UHFFFAOYSA-N

Boiling point: 67 - 69 °C (1013 hPa)
Density: 0.915 g/cm3 (20 °C)
Flash point: -11 °C
Ignition temperature: 305 °C
Melting Point: -31 °C
Vapor pressure: 147.9 - 148 hPa (20 °C)
Refractive Index: 1.3568 (20 °C)

Molecular Weight: 103.92 g/mol
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 3
Rotatable Bond Count: 3
Exact Mass: 104.0644743 g/mol
Monoisotopic Mass: 104.0644743 g/mol
Topological Polar Surface Area: 27.7Ų
Heavy Atom Count: 7
Complexity: 31.7
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Specifications of Trimethyl borate:
Assay (acidimetric): ≥ 99.0 %
Density (d 20 °C/ 4 °C): 0.931 - 0.933
Identity (IR): passes test

Density: 0.915g/mL
Assay Percent Range: >99.9995% (metals basis)
Linear Formula: (CH3O)3B
Quantity: 10 g
UN Number: UN2416
Beilstein: 1697939
Merck Index: 14,9712
Formula Weight: 103.92
Percent Purity: ≥99.9995%
Physical Form: Liquid
Assay: (metals basis)
Chemical Name or Material: Trimethyl borate

Related compounds of Trimethyl borate:

Other cations:
Trimethyl phosphite
Tetramethyl orthosilicate

Names of Trimethyl borate:

Regulatory process names:
Borester O
Boric acid (H3BO3), trimethyl ester
Boric acid, trimethyl ester
Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-
Ethene, trifluoro(trifluoromethoxy)-
Ether, trifluoromethyl trifluorovinyl
Methyl borate
Perfluoro(methyl vinyl ether)
Trifluoro(trifluoromethoxy)ethylene
Trifluoromethyl trifluorovinyl ether
Trimethoxyborane
Trimethoxyborine
Trimethoxyboron
Trimethyl borate
TRIMETHYL BORATE
Trimethyl borate
trimethyl borate
Trimethylester kyseliny borite

Translated names:
borate de triméthyle (fr)
borato de trimetilo (es)
borato de trimetilo (pt)
ortoboran trimetylu (pl)
trimethyl-borát (cs)
trimethylboraat (nl)
trimethylborat (da)
Trimethylborat (de)
trimetil borat (ro)
trimetil borat (sl)
trimetil borato (it)
trimetil-borat (hr)
trimetil-borát (hu)
trimetilboratas (lt)
trimetilborāts (lv)
trimetoksyboran (pl)
trimetoksyboran ortoboran trimetylu (pl)
trimetyl-borát (sk)
trimetylborat (no)
trimetylborat (sv)
Trimetyyliboraatti (fi)
Trimetüülboraat (et)
βορικός τριμεθυλεστέρας (el)
триметил борат (bg)

IUPAC names:
1,1,2-trifluoro-2-(trifluoromethoxy)ethene
Boric acid (h3bo3), trimethyl ester
Methyl borate
trimethoxyborane
Trimethyl Borate
Trimethyl borate
trimethyl borate
trimethyl borate
Trimethylborate
Tromentyl borate

Preferred IUPAC name:
Trimethyl borate

Trade names:
Trimethyl borate Azeotrope
Trimethyl Borate Pure

Other names:
trimethoxyborane, boron trimethoxide

Other identifiers:
005-005-00-1
1187-93-5
121-43-7
31649-91-9
63156-11-6

Synonyms of Trimethyl borate:
(MeO)3B
121-43-7
1212-43-7
197926-EP2269975A2
197926-EP2269997A2
197926-EP2275415A2
27060-EP2281822A1
27060-EP2292589A1
27060-EP2308866A1
27060-EP2314583A1
32599-EP2270006A1
32599-EP2272817A1
32599-EP2284148A1
32599-EP2295421A1
32599-EP2298770A1
32599-EP2298774A1
32599-EP2301926A1
32599-EP2301933A1
32599-EP2305627A1
32599-EP2311826A2
32599-EP2311827A1
3349-42-6
4-01-00-01269 (Beilstein Handbook Reference)
46674-EP2292604A2
46674-EP2308873A1
46674-EP2311826A2
63156-11-6
82U64J6F5N
95696-EP2371831A1
A804732
AI3-60245
AKOS000121036
AMY11113
AT28213
B(OCH3)3
B(OMe)3
B0226
B0522
Borate de trimthyle
Borester O
boric acid (H_3_BO_3_), trimethyl ester
Boric acid (H3BO3), trimethyl ester
Boric acid trimethyl
Boric acid trimethyl ester
Boric acid, trimethyl ester
BORON METHOXIDE
Borsaeuretrimethylester
BRN 1697939
C3-H9-B-O3
C3H9BO3
CHEBI:38913
DTXSID0037738
EC 204-468-9
EINECS 204-468-9
F0001-0343
FT-0600432
HSDB 5589
J-004497
LS-45040
Methyl borate
Methyl borate, ((MeO)3B)
Methyl borate, (MeO)3 B
MFCD00008346
NA2416
NSC 777
NSC-777
NSC777
Q423710
SCHEMBL15840
STL264209
trimethoxy borane
trimethoxy boron
trimethoxyboran
Trimethoxyborane
Trimethoxyborine
Trimethoxyboron
trimethy borate
trimethyborate
TRIMETHYL BORATE
TRIMETHYL BORATE [HSDB]
TRIMETHYL BORATE [MI]
Trimethyl borate [UN2416] [Flammable liquid]
Trimethyl borate [UN2416] [Flammable liquid]
Trimethyl borate, >=98%
Trimethyl borate, 99.999% (trace metal basis)
Trimethyl borate, azeotrope, 70%, in methanol
Trimethyl borate, purified by redistillation, >=99.5%
Trimethyl borate, purum, >=99.0% (GC)
Trimethyl borate-11B
Trimethyl borate-11B, 99 atom % 11B, 98% (CP)
trimethyl boric acid
trimethyl orthoborate
trimethyl-borate
Trimethylborat
trimethylborate
trimethylboric acid
Trimethylester kyseliny borite
Trimethylester kyseliny borite [Czech]
UN 2416
UN2416
UNII-82U64J6F5N
Urea,N-(cyclohexylmethyl)-N'-cyclopentyl-
WLN: 1OBO1 & O1
1212-43-7 [RN]
121-43-7 [RN]
1697939 [Beilstein]
204-468-9 [EINECS]
3349-42-6 [RN]
82U64J6F5N
Borate de triméthyle [French] [ACD/IUPAC Name]
Boric acid (H3BO3), trimethyl ester [ACD/Index Name]
BORIC ACID TRIMETHYL ESTER
ED5600000
METHYL BORATE
MFCD00008346 [MDL number]
Trimethyl borate [ACD/IUPAC Name] [Wiki]
TRIMETHYL BORATE-11B, 97 ATOM
Trimethylborat [German] [ACD/IUPAC Name]
(MeO)3B
31649-91-9 [RN]
4-01-00-01269 [Beilstein]
4-01-00-01269 (Beilstein Handbook Reference) [Beilstein]
486-73-7 [RN]
63156-11-6 [RN]
B(OCH3)3
B(OMe)3
borato de trimetila [Portuguese]
Borester O
boric acid, trimethyl ester
BORON METHOXIDE
Borsaeuretrimethylester
CHEBI:38913
EINECS 204-468-9
ST5409749
TL8000570
trimethoxyboramethane
trimethoxyborane
TRIMETHOXYBORINE
TRIMETHOXYBORON
Trimethyl borate [UN2416] [Flammable liquid]
Trimethylborate
Trimethylester kyseliny borite [Czech]
Trimethylester kyseliny borite [Czech]
UN 2416
UNII:82U64J6F5N
UNII-82U64J6F5N
Urea,N-(cyclohexylmethyl)-N'-cyclopentyl-
WLN: 1OBO1 & O1
 

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