TRIS(1-CHLORO-2-PROPYL) PHOSPHATE

TRIS(1-CHLORO-2-PROPYL) PHOSPHATE = TCPP = TRIS MONOCHLORO ISOPROPYL PHOSPHATE

CAS Number: 13674-84-5
EC Number: 237-158-7
MDL Number: MFCD00040408
Molecular Fomula: C9H18Cl3PO4

Tris(1-chloro-2-propyl) phosphate is an additive type low molecular weight halogen phosphorus flame retardant with good flame retardant effect. 
Tris(1-chloro-2-propyl) phosphate is recommended as flame retardant for PU foams, PVC and adhesives.
Tris(1-chloro-2-propyl) phosphate (TCPP) is a colorless or light yellow transparent liquid. 

Tris(1-chloro-2-propyl) phosphate's molecular formula is C9H18Cl3O4P. 
Tris(1-chloro-2-propyl) phosphate is a clear colorless viscous liquid.
Tris(1-chloropropan-2-yl) phosphate is a trialkyl phosphate.
Tris(1-chloro-2-propyl) phosphate is a clear colorless viscous liquid.

Tris (1-chloro-2-propyl) phosphate (TCPP) is a clear colorless liquid which is stable at ambient temperature and is not volatile.
Tris(1-chloro-2-propyl) phosphate chemical does not dissolve in water, but Tris(1-chloro-2-propyl) phosphat can dissolve in organic solvents such as ethyl alcohol, acetone and others.

Tris(1-chloro-2-propyl) phosphate has good heat conductivity and is a hydrolysis stabilizer with good retarding ability for containing phosphor and chlorine. 
Tris(1-chloro-2-propyl) phosphate is a low-cost flammable inhibitor and a good stabilizer. 
TCC’s Tris(1-chloro-2-propyl) phosphate (TCPP) is a clear colorless liquid that is stable at ambient temperature and is not volatile. 
Tris(1-chloro-2-propyl) phosphate's molecular formula is C9H18Cl3O4P. 

Tris(1-chloro-2-propyl) phosphate is manufactured to a purity of 75 ± 10%. Major impurities are bis(1-chloro-2-propyl)-2-chloropropyl phosphate (20-30%) and bis(2-chloropropyl)-1-chloro-2-propyl phosphate (3-5%).
Tris(1-chloro-2-propyl) phosphate is the reaction of phosphorous oxytrichloride with propylene oxide in the presence of a catalyst. 
The reaction is carried out in a closed reactor. 

Tris(1-chloro-2-propyl) phosphate product is washed and dehydrated in a closed vessel to remove acidic impurities and residual catalyst. 
All transfers are done using closed lines. 
Tris(1-chloro-2-propyl) phosphate is then filtered, transferred, and packaged using sealed pumps through closed lines. 
Storage is in closed vessels under nitrogen to exclude moisture and oxygen. 

Tris(1,3-dichloro-2-propyl) phosphate (TDCPP) and tris(1-chloropropyl) phosphate (TCPP) belong to a group of chemicals collectively known as triester organophosphate flame retardants (OPFRs).
Tris(1-chloro-2-propyl) phosphate is added at various points in the polyurethane supply chain:to final foam producers; to “system houses” who pre-blend and formulate ready-made systems; and to base polyol producers who may use Tris(1-chloro-2-propyl) phosphate to reduce polyol viscosity/mobility. 

Colorless or slightly yellow liquid, immiscible with water. 
TCPP, Tris(1-chloro-2-propyl)phosphate, CAS 13674-84-5, is a clear colorless liquid, stable and not volatile at ambient temperature. 
Tris(1-chloro-2-propyl) phosphate is produced starting from phosphorous oxytrichloride and propylene oxide in the presence of a catalyst agent.

Tris(1-chloro-2-propyl) phosphate escapes over time from the foam Tris(1-chloro-2-propyl) phosphate’s used in.
Tris(1-chloro-2-propyl) phosphate is not volatile. 
Tris(1-chloro-2-propyl) phosphate's solubility in water is 1.6 g/litre, Tris(1-chloro-2-propyl) phosphate is soluble in most organic solvents, and Tris(1-chloro-2-propyl) phosphate has a log octanol/water partition coefficient of 2.59.
Tris(1-chloro-2-propyl) phosphate is manufactured from propylene oxide and phosphorus oxychloride.

Tris (chloroisopropyl) phosphate is a colorless or light-yellow transparent liquid. 
Tris(1-chloro-2-propyl) phosphate's molecular formula is C9H18Cl3O4P. 
Manufacturers reported to U.S. Environmental Protection Agency (EPA) in 2016, that foam insulation for commercial and consumer uses has a maximum concentration of TCPP of 1- 30% by weight. 
Wood and engineered wood products used as building materials have less than 1% by weight Tris(1-chloro-2-propyl) phosphate. 

Another commercial use in an unspecified building construction material contains at least 90% by weight.
Commercial use in fabrics, textile, and leather products results in maximum concentrations of Tris(1-chloro-2-propyl) phosphate of 30 - 60% by weight.
Tris(1-chloro-2-propyl) phosphate is clear colorless viscous liquid. 
Tris(2-chloroisopropyl) Phosphate(TCPP), mixture of isomers is suitable for use in environmental and food residue analysis. 

Tris(1-chloro-2-propyl) phosphate is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.
Tris(1-chloro-2-propyl) phosphate, TCPP, is a general purpose chlorinated phosphate ester flame retardant used in rigid and flexible polyurethane foams, whose superiority is demonstrated in low odor, high heat stability, excellent hydrolysis stable.

Tris(1-chloro-2-propyl) phosphate is transparent and colorless oil liquid, can be dissolved in organic solvent such as alcohol, benzene, carbon tetrachloride, not in water.
Another feature of Tris(1-chloro-2-propyl) phosphate is its ability to promote moisture resistance. 
Tris(1-chloro-2-propyl) phosphate is not water soluble but will dissolve in most organic solvents. 
This makes Tris(1-chloro-2-propyl) phosphate a great additive for resins.

USES and APPLICATIONS of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
-Tris(1-chloro-2-propyl) phosphate is widely used for flexible and rigid polyurethane,polyvinyl chloride,polyvinyl acetate, phenolic resins and epoxy, as flame retardant. 
-Tris(1-chloro-2-propyl) phosphate is a general purpose chlorinated phosphate ester flame retardant used in rigid and flexible polyurethane foams, whose superiority is demonstrated in low odor, high heat stability, excellent hydrolysis stability, low viscosity, superior compatibility with resin. 

-Tris(1-chloro-2-propyl) phosphate is recommended as flame retardant for PU foams, PVC and adhesives.
-Tris(1-chloro-2-propyl) phosphate is mainly used for the manufacture of PU foams, epoxy resins,polystyrene, acrylic acid, cellulose acetate, ethyl cellulose resin etc.
-Tris(1-chloro-2-propyl) phosphate is mainly used in the flame retardant of polyvinyl chloride, polystyrene, phenolic resin, acrylic resin, rubber and paint, and is also widely used In soft polyurethane foam, hard foam and plastic products. 

-Tris(1-chloro-2-propyl) phosphate is also a good plasticizer.
-Tris(1-chloro-2-propyl) phosphate is used as a flame retardant primarily for polyurethane foams; Minor uses include textile back-coating formulations and special coatings.
-Tris(1-chloro-2-propyl) phosphate is also used in adhesives and binding agents, insulating materials, extinguishing agents, fillers, construction materials, intermediates, and paints, lacquers, and varnishes.

-Tris(2-chloroisopropyl)phosphate (TCPP) is a general purpose chlorinated phosphate ester flame retardant used in rigid and flexible polyurethane foams, whose superiority is demonstrated in low odor, high heat stability, excellent hydrolysis stability, low viscosity, superior compatibility with resin . 
-Tris(1-chloro-2-propyl) phosphate is used as a low-cost flame inhibitor in the production of bar-shaped and lump-shaped foam. 

-Other applications include use as raw material for the manufacture of polyester foam plastic, binder and other resins.
-Tris(1-chloro-2-propyl)phosphate is normally used at 10~15 phr depending on applications.
-TCC’s Tris(1-chloro-2-propyl) phosphate (TCPP) is primarily used as a flame retardant in rigid and flexible polyurethane foam. 

-Specifically, Tris(1-chloro-2-propyl) phosphate is used as a flame inhibitor in the production of bar-shaped or lump-shaped foam. 
-Other applications include use as raw material for the manufacture of polyester foam plastic, binders and other resins.
-Tris(1-chloro-2-propyl) phosphate can be manufactured by either a batch or continuous process. 
-Tris(1-chloro-2-propyl)phosphate is used as a flame retardant in rigid and flexible polyurethane foam. 

-Tris(1-chloro-2-propyl)phosphate's known use is industrial.
-Tris(1-chloro-2-propyl)phosphate (TCPP) is part of the group of Brominated and Chlorinated Flame Retardants.
-Tris(1-chloro-2-propyl) phosphate (TCIPP) is frequently applied to consumer products as a flame retardant and is commonly detected in indoor environments.

-Tris(1-chloro-2-propyl) phosphate (TCPP) and tris(1,3-dichloro-2-propyl) phosphate (TDCPP) are added to polyurethane foams in a variety of industrial and consumer products to prevent flame ignition. 
-Tris(1-chloro-2-propyl) phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA and phenolics and epoxy resin.
-The vast majority of Tris(1-chloro-2-propyl) phosphate is used in rigid polyurethane foams. 

-Tris(1-chloro-2-propyl) phosphate is also used in flexible polyurethane foams for furniture and Tris(1-chloro-2-propyl) phosphate's upholstery, principally in the United Kingdom and Ireland .
-The use in rigid polyurethane foams may be further sub-divided into blocks and spray systems for building insulation and for refrigerator casings. 
-Very small use of Tris(1-chloro-2-propyl)phosphate also exists in textile back-coating formulations and in certain coatings.

-Flame redartant is used in polyurethanes, PVC, EVA and phenol/epoxide resins.
-Tris(1-chloro-2-propyl) phosphate is used in rigid polyurethane foam and furniture foam, textiles, leather, electronics and building construction laminates as an additive flame retardant.
-Tris(1-chloro-2-propyl) phosphate has been found in furniture and baby products such as nursing pillows, portable mattresses, car seats, seat positioners and changing table pads.

-Tris(1-chloro-2-propyl) phosphate main application is flame retardant in rigid and flexible polyurethane foam PVC, EVA, phenolic and epoxy resins.
-Tris(chloropropyl) phosphate (TCPP) is an organophosphorus flame retardant and plasticizer used in manufacturing and multiple consumer products. 
-Tris (1-chloro-2-propyl) phosphate is a flame retardant commonly used in polyurethane foam in consumer products and in home insulation, and in electronics. 

-Tris(1-chloro-2-propyl) phosphate is used as an additive to polyurethane foam and is not chemically bound, and Tris(1-chloro-2-propyl) phosphate escapes from products into the indoor environment.
-Tris(1-chloro-2-propyl) phosphate (TCPP) is a colourless liquid used as a flame retardant, mainly in polyurethane foams. 
-Tris(1-chloro-2-propyl) phosphate is used as a low-cost flame inhibitor in the production of foam. 

-Tris(1-chloro-2-propyl) phosphate is also used as an additive to other products like polyester foam plastic, binder, resins, home furnishings, phenolic materials, acetate fibers, and textile waterproofing. 
-Tris(1-chloro-2-propyl) phosphate is an additive flame retardant used in flexible polyurethane foam, textiles, apparel, leather, and electronics. 

-Tris(1-chloro-2-propyl) phosphate uses in building construction materials include rigid polyisocyanurate foam insulation, adhesives and sealants, and roofing laminates. 
-Tris(1-chloro-2-propyl) phosphate has been detected in U.S. household furniture and in baby products that contain flexible polyurethane foam including: car seats, changing table pads, sleep positioners, portable mattresses, nursing pillows and children’s furniture. 

-Tris(1-chloro-2-propyl) phosphate is used for industrial manufacturing of plastic materia and resins.
-Detection rates in foam are reported to be 0.5-22% by weight in furniture foam and 1-14% in baby product foam.
-Tris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA and phenolics and epoxy resin.

CHEMICAL PROPERTIES of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
Tris(1-chloro-2-propyl) phosphate is clear colorless oily liquid with high water solubility and low lipophilicity (as indicated by logKOW). 
Tris(1-chloro-2-propyl) phosphate is manufactured as a reactionmixture, which contains four isomers. 
Tris(1-chloro-2-propyl) phosphate is the primary isomer in the mixture at 50–85% weight/weight (w/w), followed by bis(1- chloro-2-propyl)-2-chloropropyl phosphate [15–40% (w/w); CASRN: 76025-08-6], bis(2-chloropropyl)-1-chloro-2-propyl phosphate [<15% (w/w); CASRN: 76649-15-5], and tris(2- chloropropyl) phosphate [<1% (w/w); CASRN: 6145-73-9]

Tris(1-chloro-2-propyl) phosphate is colorless transparent oily liquid, specific wt.: (25°C/25°C)1.29, refractive index: nD20 1.46, flash point (open cup)180°C, phosphorus content: 9.5%, viscosity: :65mps 25°C, soluble in ethanol and chloroform, insoluble in aliphatic hydrocarbon.

PHYSICAL and CHEMICAL PROPERTIES of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
Molecular Weight: 327.57
Appearance: Liquefied
Color/Colour: colorless/colourless
Odor/Odour: Not available
Viscosity (25℃): 65.0-70.0
Density: 1.2900+-0.02
Acid value: ≤0.1%
Moisture: ≤0.1%

Flash point: ≥210
Color: ≤50
Refractive index: 1.4600-1.4690
P: 9.3-9.45
Cl: 32.1-32.5
Melting Point: -42 °C
Boiling Point: 220 °C at 760 mmHg
Vapor Pressure: 2 mmHg @ 25 °C
Molecular Weight: 327.6    
XLogP3-AA: 2.6    

Hydrogen Bond Donor Count: 0    
Hydrogen Bond Acceptor Count: 4    
Rotatable Bond Count: 9    
Exact Mass: 326.000829    
Monoisotopic Mass: 326.000829    
Topological Polar Surface Area: 44.8 Ų    

Heavy Atom Count: 17    
Formal Charge: 0    
Complexity: 216
PSA: 54.57000
LogP: 1.53
Index of Refraction: 1.462
Water Solubility: <0.1 g/100 mL at 19.5 ºC

FIRST AID MEASURES of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
-General Advice:
Consult a physician.
-If Inhaled:
If inhaled, move person to fresh air. 
Consult a physician.

-In Case of Skin Contact:
Wash affected area with soap and water. 

-In Case of Eye Contact:
Immediately rinse eyes with plenty of water for at least 15 minutes. 
Consult a physician.
-If Swallowed:
Rinse mouth with water. 
Seek medical attention.

ACCIDENTAL RELEASE MEASURES of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
-Personal precautions: 
Ensure adequate ventilation. 

-Environmental precautions:
Do not let product enter drains.
-Method and materials for containment and cleaning up:
Sweep up and shovel. 
Keep in suitable, closed containers for disposal.

FIRE FIGHTING MEASURES of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
-Extinguishing Media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
-Advice for Firefighters:
Use personal protection equipment.
-Further Information:
No data available.

EXPOSURE CONTROLS/PERSONAL PROTECTION of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
-Control Parameters:
Contains no components with established occupational exposure limits.
-Exposure Controls:
*Eye/Face Protection:
Safety goggles or face shield. 
*Skin Protection:
Gloves should be used when handling this material. 

HANDLING and STORAGE of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE
-Conditions for safe storage:
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
-Storage conditions: 
Refrigerator, Under Inert Atmosphere

STABILITY and REACTIVITY of TRIS(1-CHLORO-2-PROPYL) PHOSPHATE
-Reactivity:
No data available.
-Chemical Stability:
Stable under recommended storage conditions.

SYNONYMS
Amgard TMCP
Hostaflam OP 820
Tri-(2-chloroisopropyl)phosphate
Tris(1-chloro-2-propyl) phosphate
Tris(2-chloroisopropyl)phosphate
2-Propanol, 1-chloro-, 2,2',2''-phosphate
2-Propanol, 1-chloro-, phosphate (3:1)
Phosphoric acid, tris(2-chloro-1-methylethyl) ester
Tris(2-chloro-1-methylethyl) phosphate
2-Propanol, 1-chlorophosphate (3:1)
Tris(1-chloromethylethyl) phosphate
Antiblaze 80; Levagard PP
Tolgard TMCP
TCPP
TMCP
TCIP
Fyrol PCF
Tris(1-methyl-2-chloroethyl) phosphate
Tris(beta-chloroisopropyl) phosphate
Tris(chloroisopropyl) phosphate
Tris monochloro isopropyl phosphate
Tris (1-methyl-2-chloroethyl) phosphate
TMCPP
ANTIBLAZE TMCP
Tris(2-chloroisopropyl) Phosphate
Antiblaze 80
Antiblaze TMCP
Daltoguard F
Fyrol PCF
Hostaflam OP 820
Levagard PP
Levagard PP-Z
PUMA 4010
Tolgard TMCP
Tris(1-methyl-2-chloroethyl) Phosphate
Tris(2-chloro-1-methylethyl) Phosphate
Tris(chloroisopropyl) Phosphate
Tris(β-chloroisopropyl) Phosphate
Antiblaze TMCP
Daltoguard F
Fyrol PCF
Hostaflam OP 820
Levagard PP
Levagard PP-Z
PUMA 4010
Tolgard TMCP
Tris(2-chloroisopropyl) phosphate
Phosphoric acid tris(2-chloro-1-methylethyl) ester
Tris(1-chloropropyl)phosphate
Tris(2-chloro-1-methylethyl) phosphate
Tris(chloroISOPROPYL)phosphate
Tris(monochloropropyl) phosphate
1-Chloro-2-propanolphosphate(3:1)
1-chloro-2-propanophosphate(3:1)
Tris(2-chloro-1-methyl-ethyl) phosphate
Tris(2-chloropropyl) phosphate
Tris(1-chloropropan-2-yl) phosphate
Tris(clorisopropyl)phosphate
Tri(chloropropyl) phosphate
Tris(1-chloro-2-propyl)phosphate
Tris(chloropropyl)phosphate
Tris(monochloropropyl) phosphate
tris(1-chloropropyl) phosphate
2-Propanol, 1-chloro-, phosphate (3:1)
tris ( 2-chloro-1-methylethyl ) phosphate
tri- ( 2-chloroisopropyl ) phosphate
tris(2-chloro-1-methylethyl) phosphate
Tris(1-Chloro-2-Propyl)Phosphate (Tcpp, Tmcp)
Tris(1-chloro-2-propyl) phosphate
Tris(1-chloro-2-propyl)phosphate (TCPP)
2-Propanol, 1-chloro-, phosphate
tris(2-chloro-1-methylethyl)phosphate
Tris(2-chlor-1-methylethyl)phosphat
Tris(2-chloro-1-methylethyl) phosphate (TCPP)
2-Propanol, 1-chloro-, 2,2',2''-phosphate
Tris (1-chloro-2-propyl) phosphate (TCPP)
Tris(1-chloro-2-propyl) phosphate (TCPP)
Tris(1-chloro-2-propyl)phosphate
Phosphoric acid tris(2-chloro-1-methylethyl) ester